• Title/Summary/Keyword: Age hardening

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Microstructural Feature and Aging Characteristics of Spray-Formed Cu-5Ni-10Sn Alloy (가스분무성형 Cu-5Ni-10Sn 합금의 미세조직 및 시효강화)

  • Roh, Dae-Gyun;Kang, Hee-Soo;Baik, Kyeong-Ho
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.317-321
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    • 2012
  • In this study, Cu-5Ni-10Sn(wt%) spinodal alloy was manufactured by gas atomization spray forming, and the microstructural features and mechanical properties of Cu-5Ni-10Sn alloy have been investigated during homogenization, cold working and age-hardening. The spray formed Cu-5Ni-10Sn alloy consisted of an equiaxed microstructure with a mixture of solid solution ${\alpha}$-(CuNiSn) grains and lamellar-structure grains. Homogenization at $800^{\circ}C$ and subsequent rapid quenching formed a uniform solid solution ${\alpha}$-(CuNiSn) phase. Direct aging at $350^{\circ}C$ from the homogenized Cu-5Ni-10Sn alloy promoted the precipitation of finely distributed ${\gamma}$' or ${\gamma}-(Cu,Ni)_3Sn$ phase throughout the matrix, resulting in a significant increase in microhardness and tensile strength. Cold working prior to aging was effective in strengthening Cu-5Ni-10Sn alloy, which gave rise to a maximum tensile strength of 1165 MPa. Subsequent aging treatment slightly reduced the tensile strength to 1000-1100 MPa due to annealing effects.

Precipitation of L21-type Ni2AlTi Phase in B2-type Intermetallic Compounds NiTi (B2형 금속간화합물 NiTi 중에 L21형 Ni2AlTi상의 석출)

  • Han, Chang-Suk
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.420-424
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    • 2007
  • Precipitation behavior has been studied in NiTi-based ordered alloy using transmission electron microscopy. The hardness after solution treatment is high in NiTi alloy suggesting the large contribution of solid solution strengthening in this alloy system. However, the amount of age hardening is not large as compared to the large microstructural variations during aging. At the beginning of aging, the $L2_1-type$ $Ni_2AlTi$ precipitates keep a lattice coherency with the NiTi matrix. By longer periods of aging $Ni_2AlTi$ precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. Misfit dislocations, which are observed on {100} planes of H-precipitates have the Burgers vector of a <100> with a pure edge type. The lattice misfits of $NiTi-Ni_2AlTi$ system is estimated from the spacings of misfit dislocations to be 1.3% at 1273 K. The lattice misfits decrease with increasing aging temperature in this system.

Track-Structure Interaction Analysis of Fast Hardening Track on Railway Bridge Considering Effect of Anchor and Friction (앵커와 마찰의 영향을 고려한 교량상 급속경화궤도의 궤도-교량 상호작용해석)

  • Cho, Sang-Hyeon;Lee, Il-Wha;Chung, Won-Seok;Lee, Hee-Young;Lee, Kyoung-Chan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.1
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    • pp.53-61
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    • 2018
  • Ballast track requires constant maintenance work due to progress of track irregularity. Fast Hardening Track(FHT) has been developed to reduce the maintenance effort done by injecting fast hardening mortar in aged ballast to convert slab track. For the application of FHT to a railway bridge, post-installed anchors should be placed at center of the track segment to fix it on bridge. This paper presents track-bridge interaction analysis results with FHT considering stiffness and strength of post-installed anchor, age of FHT concrete and friction between FHT and bridge deck surface. Based on the analysis results, this study suggests when is good to install the anchors and allow normal operation of passing train.

A Study on the Hardening Characteristics of Ground Injection Grout under Various Curing Conditions (다양한 양생조건에서 지반주입 그라우트의 경화특성에 대한 연구)

  • Heo, Hyungseok;Park, Innjoon
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.11
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    • pp.11-20
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    • 2020
  • For water barrier and reinforcing grout in soft ground, the verification of durability was conducted over the initial and long-term ages under various curing conditions. The grout was made of water glass system, fast-hardening mineral (FHM) system, and acrylic polymer system. There were three types of curing conditions that were tab water curing, artificial seawater curing, and atmospheric curing. And the various tests were performed for each sample by age, uniaxial compressive strength, length change, and weight change. As artificial seawater, MgCl2 and MgSO4 aqueous solutions were prepared and used, respectively. As the test results, the fast-hardening mineral system and acrylic polymer system were cured stably without significant change in durability in tap water and artificial sea water, whereas water glass system showed a very rapid drop in durability under artificial sea water conditions compared to tap water. In atmospheric curing conditions, durability is lowered compared to water curing in all cases, and in particular, the weight loss in the FHM system and water glass system is about 62% and 60%, respectively, resulting in a significant decrease in durability.

The Effect of Au Addition on the Hardening Mechanism in Ag-20wt% Pd-20wt% Cu (Ag-20wt% Pd-20wt% Cu 3원합금(元合金) 및 Au첨가합금(添加合金)의 시효경화특성(時效硬化特性))

  • Park, M.H.;Bae, B.J.;Lee, H.S.;Lee, K.D.
    • Journal of Technologic Dentistry
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    • v.19 no.1
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    • pp.21-35
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    • 1997
  • The Ag-Pd-Cu alloys containing a small amount of Au is commonly used for dental purposes, because this alloy is cheaper than Au-base alloys for clinical use. However, the most important characteristic of this alloy is age-hardenability, which is not exhibited by other Ag-base dental alloys. The specimens used were Ag-20Pd-20Cu ternary alloy and Au addition alloy. These alloys were melted and casted by induction electic furace and centrifugal casting machine in Ar atmoshpere. These specimens were solution treated for 2hr at $800^{\circ}C$ and were then quenched into iced water, and aged at $350{\sim}550^{\circ}C$ Age-hardening characteristics of the small Au-containing Ag-pPd-Cu dental alloys were investigated by means of hardness testing, X-ray diffraction and electron microscope observations, electrical resistance, differential scanning calorimetric, emergy dispersed spectra and electron probe microanalysis. Principal results are as follows : Hardening occured in two stages, I. e., stage I in low temperature and stage II in high temperature regions, during continuous aging. The case of hardening in stage I was due to the formation of the Llo type face centered tetragonal PdCu-ordered phase in the grain interior and hardening in stage I was affedted by the Cu concentration. In stage II, decomposition of the $\alpha$ solid solution to a PdCu ordered phase(L1o type) and an Agrich ${\alpha}2$ phase occurred and a discontiunous precipitation occurred at the grain boundary. Form the electron microscope study, it was concluded that the cause of age-hardening in this alloy is the precipitation of the PdCu ordered phase, which has AuCu I type face-centered tetragonal structure. Precipitation procedure was ${\alpha}\to{\alpha}+{\alpha}2+PdCu\to{\alpha}1+{\alpha}2+PdCu$ at Pd/Cu = 1 Ag-Pd-Cu alloy is more effective dental alloy as ageing treatment and is suitable to isothermal ageing at $450^{\circ}C$.

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The Experimental Study on Early Strength Properties of High Volume Fly-Ash Concrete (플라이애쉬를 다량 치환한 콘크리트의 초기강도성상에 관한 실험적 연구)

  • 이동하;김상미;강태경;백민수;이영도;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.281-286
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    • 2002
  • To study of binder and fine aggregate a lot of replacement fly-ash concrete, initial characteristics, standard environment of curing temperature $20^{\circ}C$, hot-weather environment of curing temperature $35^{\circ}C$, . Flesh concrete tested slump. air contest and Hardening concrete valuated setting period of form, day of age 1, 3, 5. 7, 10, 28 compression strength in sealing curing. Purpose of study is consultation materials in field that variety of fly-ash replacement concrete mix proportion comparison and valuation. (1) Experiment result age 28day compression strength more higher plan concrete then standard environment in curing temperature $20^{\circ}C$, , most strength F43 is hot-weather environment in curing temperature $35^{\circ}C$, replacement binder 25%, fine aggregate 15%. (2) Hot-weather environment replacement a mount of fly-ash is a same of plan concrete setting period of form. Age 28day compression strength replacement a mount of fly-ash more hot-weather concrete then plan concrete.

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A Study on the Early-Age Strength Property of Concrete Using Liquid Admixture (액상형 조강제를 사용한 콘크리트의 초기강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;Ryu, Deug-Hyun;Park, Cho-Bum
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.469-472
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    • 2006
  • Amount used of admixture fare is increasing for concrete economic efficiency and ability security. Security of economic efficiency and ability can expect by use of this admixture fare but is displaying a lot of problems on early age strength hold by hydrate delay relatively. Specially, in the case of construction site, concrete strength can speak that interrelation is high with mold removal of forms time. Therefore, is economical and need examination of plan that can secure robber within 3 days using admixture fare such as fly ash and blast furnace slage differential speech to secure function. In this study, adding liquid admixture within 1% of a binding agent quantity to examine these problem with physical characteristic after hardening ago specially, strength change at standard and air dry curing of observed change in priority. Air dried and water curing total strength enhancement effects appeared by thing which is in case of add test result liquid admixture by below 1% and strength deputy by passage of age could know is not big.

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Bond Characteristics of Reinforced Concrete Beams According to Material Age (콘크리트 재령에 따른 철근콘크리트 보의 부착응력에 관한 실험적 연구)

  • Ryu, Soo-Hyun;Choi, Hyo-Seok;Lee, Joo-Il;Yu, Ho-Hyun;Jeong, Jae-Hun;Kim, Jin-Mu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.1
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    • pp.103-109
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    • 2002
  • Reinforced concrete structure resist to external load caused by integration of steel bar and concrete and this integration is obtained from bond stress between steel bar and concrete. Researches of bond stress between steel bar and concrete have been performed by many researcher, but existent researches of bond stress are concerned with compression strength of well cured concrete and insufficient study of bond stress according to early material. The secure regular strength of concrete in early age is caused by rapid velocity of early hardening process, but questionable bond stress in early age is proportion to strength of that. So this study performed experiments to compare bond stress according to material age and compression strength. The result is showed that bonding strength in early material age compare the ratio of concrete compression strength with the ratio of maximum bond stress the later inferior on the former.

Age-Hardening Behavior of SiCp Reinforced 6061 Aluminum Alloy Composites (SiCp/6061Al합금복합재료의 시효거동)

  • An, Haeng-Geun;Yu, Jeong-Hui;Kim, Seok-Won;U, Gi-Do
    • Korean Journal of Materials Research
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    • v.10 no.12
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    • pp.793-798
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    • 2000
  • The age-hardening behavior of unreinforced 6061 Al alloy and SiCp/6061 Al alloy composites reinforced with different size of SiC particle (average diameter ; 0.7$\mu\textrm{m}$ and 7.0$\mu\textrm{m}$) was investigated by hardness measurement, calorimetric technique and transmission electron microscopy. At 17$0^{\circ}C$ isothermal aging treatment, the peak aging time of 0.7$\mu\textrm{m}$SiCp/6061Al alloy composite and 7.0$\mu\textrm{m}$SiCp/6061Al alloy composite is shorter than that of unreinforced 6061Al alloy, and the aging of 7.0$\mu\textrm{m}$SiCp/6061Al alloy composite is accelerated more than that of 0.7$\mu\textrm{m}$SiCp/6061Al alloy composite. This acceleration is due to the increase of dislocation density by the compositeness with SiCp and the SiC particle size. In the peak aged condition, the major strengthening phase of these materials is intermediate $\beta$ phase(Mg$_2$Si), and the activation energy for the formation of $\beta$ phase is considerably decreased by the compositeness with SiCp and the increasing of SiC Particle site.

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Evaluation of Thermal and Shrinkage Stresses in Hardening Concrete Considering Early-Age Creep Effect (초기재령 콘크리트의 크리프를 고려한 온도 및 수축응력 해석)

  • 차수원;오병환;이형준
    • Journal of the Korea Concrete Institute
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    • v.14 no.3
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    • pp.382-391
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    • 2002
  • This study is devoted to the problems of thermal and shrinkage stresses in order to avoid cracking at early ages. The early-age damage induced by volume change has great influence on the long-term structural performance of the concrete structures such as its durability and serviceability To solve this complex problem, the computer programs for analysis of thermal and shrinkage stresses were developed. In these procedures, numerous material models are needed and the realistic numerical models have been developed and validated by comparison with relevant experimental results in order to solve practical problems. A framework has been established for formulation of material models and analysis with 3-D finite element method. After the analysis of the temperature, moisture and degree of hydration field in hardening concrete structure, the stress development is determined by incremental structural formulation derived from the principle of virtual work. In this study, the stress development is related to thermal and shrinkage deformation, and resulting stress relaxation due to the effect of early-age creep. From the experimental and numerical results it is found that the early-age creep p)ays important role in evaluating the accurate stress state. The developed analysis program can be efficiently utilized as a useful tool to evaluate the thermal and shrinkage stresses and to find measures for avoiding detrimental cracking of concrete structures at early ages.