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Development of prediction models of chlorine bulk decay coefficient by rechlorination in water distribution network (상수도 공급과정 중 재염소 투입에 따른 잔류염소농도 수체감소계수 예측모델 개발)

  • Jeong, Bobae;Kim, Kibum;Seo, Jeewon;Koo, Jayong
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.1
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    • pp.17-29
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    • 2019
  • This study developed prediction models of chlorine bulk decay coefficient by each condition of water quality, measuring chlorine bulk decay coefficients of the water and water quality by water purification processes. The second-reaction order of chlorine were selected as the optimal reaction order of research area because the decay of chlorine was best represented. Chlorine bulk decay coefficients of the water in conventional processes, advanced processes before rechlorination was respectively $5.9072(mg/L)^{-1}d^{-1}$ and $3.3974(mg/L)^{-1}d^{-1}$, and $1.2522(mg/L)^{-1}d^{-1}$ and $1.1998(mg/L)^{-1}d^{-1}$ after rechlorination. As a result, the reduction of organic material concentration during the retention time has greatly changed the chlorine bulk decay coefficient. All the coefficients of determination were higher than 0.8 in the developed models of the chlorine bulk decay coefficient, considering the drawn chlorine bulk decay coefficient and several parameters of water quality and statistically significant. Thus, it was judged that models that could express the actual values, properly were developed. In the meantime, the chlorine bulk decay coefficient was in proportion to the initial residual chlorine concentration and the concentration of rechlorination; however, it may greatly vary depending on rechlorination. Thus, it is judged that it is necessary to set a plan for the management of residual chlorine concentration after experimentally assessing this change, utilizing the methodology proposed in this study in the actual fields. The prediction models in this study would simulate the reduction of residual chlorine concentration according to the conditions of the operation of water purification plants and the introduction of rechlorination facilities, more reasonably considering water purification process and the time of chlorination. In addition, utilizing the prediction models, the reduction of residual chlorine concentration in the supply areas can be predicted, and it is judged that this can be utilized in setting plans for the management of residual chlorine concentration.

Influence of Charging Condition of Al-dross on Maximum Concentration of Al in Molten Steel : Fundamental study for improvement of chemical energy in EAF process (용강 중 Al 최대 농도에 대한 Al 드로스 장입 조건의 영향: 전기로 공정 내 화학 에너지 향상을 위한 기반 연구)

  • Kim, Gyu-Wan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.4
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    • pp.44-50
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    • 2019
  • In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.

The Effects of Project Learning of Pre-service Teachers on Self Directed Learning Ability and Creative Personality (초등예비교사의 프로젝트 학습이 자기주도적 학습능력 및 창의적 인성에 미치는 효과)

  • Lee, Yong-seob
    • Journal of the Korean Society of Earth Science Education
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    • v.12 no.2
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    • pp.141-150
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    • 2019
  • The purpose of this study is to investigate the effect of the pre-service teacher's maker project learning on self -directed learning ability and creative personality. This study established an eight-week period of experimental treatment from March to April 2019, and the students who participated in the study formed a research group of 75 students in three of their advanced classes who are attending the second semester of B University of Education and taking courses in 'Teaching Research 1'. The experimental treatment of research groups was conducted by the process of producing creative outputs through training of manufacturers. The experimental group of the study group was a process of producing creative output through maker education. The theme was set up to create creative output by group, worked with the main tool, 3D pen, and utilized the recycling material. When the creative output is completed, it is announced by presenting the actual product in each group. The results of the study are as follows. First, project learning by pre-service teachers had an effect on self-directed learning ability. Second, project learning by pre-service teachers had an effect on creative personality. Third, pre-service teachers was interested in learning about the project and responded positively to the students' perception.

Effect of Temperature on Growth of Tin Oxide Nanostructures (산화주석 나노구조물의 성장에서 기판 온도의 효과)

  • Kim, Mee-Ree;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.497-502
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    • 2019
  • Metal oxide nanostructures are promising materials for advanced applications, such as high sensitive gas sensors, and high capacitance lithium-ion batteries. In this study, tin oxide (SnO) nanostructures were grown on a Si wafer substrate using a two-zone horizontal furnace system for a various substrate temperatures. The raw material of tin dioxide ($SnO_2$) powder was vaporized at $1070^{\circ}C$ in an alumina crucible. High purity Ar gas, as a carrier gas, was flown with a flow rate of 1000 standard cubic centimeters per minute. The SnO nanostructures were grown on a Si substrate at $350{\sim}450^{\circ}C$ under 545 Pa for 30 minutes. The surface morphology of the as-grown SnO nanostructures on Si substrate was characterized by field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Raman spectroscopy was used to confirm the phase of the as-grown SnO nanostructures. As the results, the as-grown tin oxide nanostructures exhibited a pure tin monoxide phase. As the substrate temperature was increased from $350^{\circ}C$ to $424^{\circ}C$, the thickness and grain size of the SnO nanostructures were increased. The SnO nanostructures grown at $450^{\circ}C$ exhibited complex polycrystalline structures, whereas the SnO nanostructures grown at $350^{\circ}C$ to $424^{\circ}C$ exhibited simple grain structures parallel to the substrate.

Influence of Reduction Atmosphere and Temperature on the Separability and Distribution Behavior of Fe from FeTiO3 via Sulfurization (고온 황화반응에 의한 FeTiO3로부터 Fe의 분리성과 분배거동에 미치는 환원/황화 분위기 및 온도의 영향)

  • Shin, Seung-Hwan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.3
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    • pp.45-52
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    • 2019
  • $TiO_2$ as a raw material for producing titanium can be produced by carbon reduction of natural ilmenite ores over 1823 K and acid leaching of the obtained titanium-rich slag. However, the conventional process can cause very high energy consumption and a large amount of leaching residues. In the present study, we proposed the sulfurization of $FeTiO_3$ with $Na_2SO_4$ at temperatures below 1573 K, which can separate Fe in $FeTiO_3$ as the FeS based sulfide phase and Ti as the $TiO_2-Na_2O$ based oxide phase. This study is a fundamental study for sulfurization of $FeTiO_3$ to investigate the influence of reducing atmosphere, reaction temperature and the sulfur/Fe ratio on the separability and distribution behaviors of of Fe, Ti, and Na between the oxide phase and the sulfurized phase. At 1573 K and carbon saturation condition, the Fe can be separated from $FeTiO_3$ as Fe-C-S metal and a part of FeS, and the concentration of Fe in oxide decreased to 4 mass% after sulfurization.

Evaluation of Compression Molding Simulation with Compression Properties of Carbon Fiber Prepreg (탄소 섬유 프리프레그의 압축 물성을 고려한 복합재 고온 압축 성형 해석 평가)

  • Bae, Daeryeong;Lee, Jung Wan;Yi, Jin-Woo;Um, Moon-Kwang
    • Composites Research
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    • v.31 no.6
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    • pp.421-428
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    • 2018
  • In order to optimize the prepreg compression molding (PCM) process, the forming simulation is required to cope with any problems that may be raised during the process. For the improvement of simulation accuracy, the input data of material property should be measured accurately. However, most studies assume that the compressive properties of the prepreg are identical to the tensile properties without quantifying them separately. Therefore, in this study, the in - plane compressive properties of the prepreg are presented to improve the accuracy of the forming simulation. As a result, the compressive modulus of the fibers was measured to be about $10^{-2}$ times lower than the tensile modulus. Also we designed a square-cup mold with a tilting angle of $110^{\circ}$ to simulate the prepreg formability during the high temperature compression mold process. Shear angles were measured at each corner, which were compared with the simulation results. It was observed that the simulation results using the accurate compressive properties of the prepreg showed a similar trend with the experimental results. It was confirmed that the measured data of the in-plane compression property improved the accuracy of the forming simulation results.

Effects of Flux Activator on Wettability and Slump of Sn-Ag-Cu Solder Paste (플럭스 활성제 종류에 따른 Sn-Ag-Cu 솔더 페이스트의 젖음성 및 슬럼프 특성 평가)

  • Kwon, Soonyong;Seo, Wonil;Ko, Yong-Ho;Lee, Hoo-Jeong;Yoo, Sehoon
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.123-128
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    • 2018
  • Effect of activators in flux on the printability and wettability of a solder paste was evaluated in this study. The activators in this study were dicarboxylic acids, which were oxalic acid (n = 0), malonic acid (n = 1), succinic acid (n = 2), glutaric acid (n = 3), adipic acid (n = 4), and pimelic acid (n = 5). When the solder pastes were observed with a SMT scope, solder with glutaric acid showed clean and shiny surface when it was melted. Slump ratio of the solder pastes was low when the carbon numbers of the dicarboxylic acid were 1-3. Spreadability was high when the carbon number was over 2. Zero cross time of wetting balance test was under 1 sec when the carbon number was over 3. When activator was oxalic acid or malonic acid, zero cross time was over 1 sec and maximum wetting force was low. Fluxes with the oxalic acid and malonic acid showed decomposition at the temperature close to melting point. Among the dicarboxylic acids, glutaric acid provided excellent slump, spreadability, and wettability.

Rheological Properties of Cement Paste Mixed with Aqueously Dispersed Single-Walled Carbon Nanotubes (Single-Walled 탄소나노튜브 수용액 혼입 시멘트 페이스트의 유변학적 특성)

  • Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.2
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    • pp.113-121
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    • 2019
  • Single walled carbon nanotube (SWCNT) has been used as a material for reinforcing various advanced materials because it has superior mechanical properties. However, pure SWCNT that does not have any functional group has a hydrophobic character, and exists as bundles due to the strong Van der Waals attraction between each SWCNT. Due to these reasons, it is very difficult to disperse SWCNTs in the water. In this work, in order to use SWCNT for production of cementitious composites, SWCNT was first dispersed in water to make an aqueous solution. Sodium deoxycholate (DOC) and Sodium dodecyl sulfate (SDS) were chosen as surfactants, and the dosage of DOC and SDS were 2wt% and 1wt%, respectively. Sonication and ultracentrifugation were applied to separate each SWCNT and impurities. Using such processed SWCNT solutions, cement paste was prepared and its shear stress vs. strain rate relationship was studied. The yield stress and plastic viscosity of cement paste were obtained using Bingham model. According to the results in this work, cement pastes made with DOC and SDS showed similar rheological behavior to that of air entrained cement paste. While cement paste made with DOC 2 wt.% SWCNT solution showed similar rheological behavior to that of plain cement paste, cement paste made with SDS 1 wt.% SWCNT solution showed different rheological behavior showing much less yield stress than plain cement paste.

Adjunctive hyperbaric oxygen therapy for irradiated rat calvarial defects

  • An, Heesuk;Lee, Jung-Tae;Oh, Seo-Eun;Park, Kyeong-mee;Hu, Kyung-Seok;Kim, Sungtae;Chung, Moon-Kyu
    • Journal of Periodontal and Implant Science
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    • v.49 no.1
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    • pp.2-13
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    • 2019
  • Purpose: The aim of this study was to conduct a histologic evaluation of irradiated calvarial defects in rats 4 weeks after applying fibroblast growth factor-2 (FGF-2) with hyaluronan or biphasic calcium phosphate (BCP) block in the presence or absence of adjunctive hyperbaric oxygen (HBO) therapy. Methods: Twenty rats were divided into HBO and non-HBO (NHBO) groups, each of which was divided into FGF-2 and BCP-block subgroups according to the grafted material. Localized radiation with a single 12-Gy dose was applied to the calvaria of rats to simulate radiotherapy. Four weeks after applying this radiation, 2 symmetrical circular defects with a diameter of 6 mm were created in the parietal bones of each animal. The right-side defect was filled with the materials mentioned above and the left-side defect was not filled (as a control). All defects were covered with a resorbable barrier membrane. During 4 weeks of healing, 1 hour of HBO therapy was applied to the rats in the HBO groups 5 times a week. The rats were then killed, and the calvarial specimens were harvested for radiographic and histologic analyses. Results: New bone formation was greatest in the FGF-2 subgroup, and improvement was not found in the BCP subgroup. HBO seemed to have a minimal effect on new bone formation. There was tendency for more angiogenesis in the HBO groups than the NHBO groups, but the group with HBO and FGF-2 did not show significantly better outcomes than the HBO-only group or the NHBO group with FGF-2. Conclusions: HBO exerted beneficial effects on angiogenesis in calvarial defects of irradiated rats over a 4-week healing period, but it appeared to have minimal effects on bone regeneration. FGF-2 seemed to enhance new bone formation and angiogenesis, but its efficacy appeared to be reduced when HBO was applied.

Fundamental study on sound absorption of a dental hand piece using micro-porous EPP substrate processed by UV laser (UV 레이저응용 마이크로 다공성 EPP 기판의 치과용 핸드피스 흡음성능에 관한 기초연구)

  • You, Dong-Bin;Shin, Myung-Ho;Byun, Hyo-Jin;Choi, Do-Jung;Sung, Kuo-Won;Ma, Yong-Won;Shin, Bo-Sung
    • Journal of Convergence for Information Technology
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    • v.9 no.5
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    • pp.158-164
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    • 2019
  • Recently many studies to reduce the noise of dental hand piece which generate inevitably mechanical sound to offend to the ear of a patient have been spotlighted. Generally, methods of adding a sound absorbing material inside the exhaust valve, air pump of machine or automobile are widely reported as optimal way to reduce the mechanical noise. In this paper we studied a new UV laser aided manufacturing of micro-porous structure of EPP substrate and applied dental hand piece to improve the efficiency of sound absorption. A lot of micro-sized pores were fabricated with UV laser processing on the surface of sliced EPP substrate. From fundamental experiments, more high-performance of micro-porous EPP substrate has finally demonstrated for sound-absorbing structure of the micro muffler inside dental hand piece, which actually has the excellent potential to apply a lot of potable machine.