• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2175-2179
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• 2010

Quantum mechanical properties of unsymmetrical and unfunctionalized trans-stilbene derivatives 1-3, which had been prepared by solid-phase parallel syntheses, were characterized using mPW1PW91/6-311G(d,p) (hybrid HF-DF) calculations. The total electronic energies, normal vibrational modes, Gibbs free energies, and HOMOs and LUMOs of sixteen different structures from three different groups were analyzed. The energy differences between the HOMOs and LUMOs of the various unsymmetrical trans-stilbenes are in accord with the maximum absorption peaks of the experimental UV spectra of 1-3. The calculated normal vibrational modes of 21 were comparable with its experimental IR spectrum. The $\pi$-conjugation in the para-connected biphenyl group of 2 is better than the one in the metaconnected biphenyl group on the shorter side of 3.

• Journal of Environmental Science International
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• v.13 no.9
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• pp.799-806
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• 2004

The filtration tests were made in cell with a low concentrated suspension. The suspension with a concentration of $C_{M}$=1.14～2.67$\cdot$$10^{-3}$ g/g consists of paper paint and water. The particles in the suspension have a particle size x<1${\mu}m$. The used depth filters consists of glass fibres, which are coated by polymer. The filtration in depth filters accorded in different mechanism, which were explained by physical models. The model which would be allows to make a promise of the filtration reaction. This filter media allows to get a high filtration time and a good separation rate. The Particle distribution is measured by a photon correlation spectroscopy(PCS). PCS measures particle sizes 0.03 ${\mu}m$${\mu}m$ in the suspension. The filtered suspension has a very low concentration Co{\le}5{\times}10_{-4}$ g/g of solid in sample. The PCS also informs us about the number of the particles in the suspension. The makes it possible to calculate the concentration of the in sample.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2003.04a
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• pp.288-295
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• 2003

An adaptive procedure in finite element analysis is presented by p-refinement of meshes in conjunction with a posteriori error estimator that is based on the recovery technique. In case of the recovery technique, the SPR(superconvergent patch recovery) approach has been modified for p-adaptive mesh refinement. The strategy of finding a nearly optimal distribution of polynomial degrees on a fixed finite element mesh is discussed such that a particular element has to be refined automatically to obtain an acceptable level of accuracy by increasing p-levels non-uniformly. To verify the proposed algorithm, the limit value approach is proposed which utilizes the exact strain energy computed from the extrapolation equation. A new pre-processor is developed for the p-version finite element program in which the vector graphic editor is used for the automatic generation of node connection and coordinate by halfedge solid data structure according to uniform or nonuniform p-distribution. The general 2-D algorithm is also developed to generate face modes and internal modes in accordance with different mesh types. The quality of the error estimator is investigated with the help of two mumerical examples. The results show that the sequences of p-distributions obtained by the proposed error indicator closely follow the optimal trajectory.

• Solar Energy
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• v.17 no.3
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• pp.59-66
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• 1997

The present study adopted the PTV method for the velocity acquisition. The system consists of an image grabber built-in a personal computer and a laser-based sheet light projector and particle identification softwares. Velocity vectors are obtained, by PTV and they are used as velocity components for Poisson equation for pressure. Related boundary conditions and no-slip condition at solid wall and the linear velocity extrapolation on the upper side of cavity are well examined for the present study. For calculation of pressure, resolution of grid is basically $40{\times}40$ and 2-dimensional uniform mesh using MAC staggered grid is adopted. The result of experiment reveal that, newly suggested measuring method is capable of estimating pressure and velocity distribution of flow field reasonably.

• Journal of the Korean Society of Industry Convergence
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• v.19 no.3
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• pp.133-143
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• 2016

The objective in here is to find the density, stiffness, and strength of truss-wall rectangular (TWR) model which is combined with lattice truss (MLT) inside space. The TWR unit-cell model is defined as a unit cell originated from a solid-wall rectangular (SWR) model and it has an empty space inside. Thus, the empty space inside of the TWR is filled with lattice truss model defined as TWR-MLT. The ideal solutions derived of TWR-MLT are based on TWR with MLT model and it has developed by Gibson-Ashby's theory. To validate the ideal solutions of the TWR-MLT, ABAQUS software is applied to predict the density, strength, and stiffness, and then each of them are compared with the Gibson-Ashby's ideal solution as a log-log scale. Applied material property is stainless steel 304 because of cost effectiveness and easy to get around. For the analysis, SWR and TWR-MLT models are 1mm, 2mm, and 3mm truss diameter separately within a fixed 20mm opening width. In conclusion, the relative Young's modulus and relative yield strength of the TWR-MLT unit model is reasonably matched to the ideal expectations of the Gibson-Ashby's theory. In nearby future, TWR-MLT model can be verified by advanced technologies such as 3D printing skills.t.

• 전기의세계
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• v.26 no.6
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• pp.78-85
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• 1977

This paper studies flashover voltage and surface corona loss of A.C and D.C in the mixed gas of air and SF$_{6}$ for solid insulators P.V.C, arcylic, glass and bakelite in two cases. In one case, those solids are covered with transformer oil and the other case, those solids are not covered with it. 1) The flashover voltage for each solids in SF$_{6}$ is more than three times compared with that in the air. The flashover voltage for P.V.C is the highest and then arcylic, glass, bakelite in a decreasing order. 2) The more the amount of SF$_{6}$ in the mixing ratio, the less corona loss. The P.V.C shows the least amount of corona loss and the bakelite the largest. 3) Compared with the corona loss of positive polarity and the negative polarity, the former has less corona loss than the latter. 4) The more the number of flashover discharge, the less insulation of each solids, but in case of bakelite, insulation almost vanishes after a couple of discharge. 5) When each insulator is covered with transformer oil, the flashover voltage generally increases and the corona loss decreases.eases.

• Korea-Australia Rheology Journal
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• v.18 no.4
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• pp.171-181
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• 2006

We present a short review for authors' previous work on direct numerical simulations for inertialess hard particle suspensions formulated either with a Newtonian fluid or with viscoelastic polymeric fluids to understand the microstructural evolution and the bulk material behavior. We employ two well-defined bi-periodic domain concepts such that a single cell problem with a small number of particles may represent a large number of repeated structures: one is the sliding bi-periodic frame for simple shear flow and the other is the extensional bi-periodic frame for planar elongational flow. For implicit treatment of hydrodynamic interaction between particle and fluid, we use the finite-element/fictitious-domain method similar to the distributed Lagrangian multiplier (DLM) method together with the rigid ring description. The bi-periodic boundary conditions can be effectively incorportated as constraint equations and implemented by Lagrangian multipliers. The bulk stress can be evaluated by simple boundary integrals of stresslets on the particle boundary in such formulations. Some 2-D example results are presented to show effects of the solid fraction and the particle configuration on the shear and elongational viscosity along with the micro-structural evolution for both particles and fluid. Effects of the fluid elasticity has been also presented.

• Transactions of Materials Processing
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• v.16 no.4 s.94
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• pp.266-270
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• 2007

Inertia welding is a solid-state welding process in which butt welds in materials are made in bar and in ring form at the joint face, and energy required for welding is obtained from a rotating flywheel. The stored energy is converted to frictional heat at the interface under axial load. The quality of the welded joint depends on many parameters, including axial force, initial revolution speed and energy, amount of upset, working time, and residual stresses in the joint. Inertia welding was conducted to make the large rotor shaft for low speed marine diesel engine, alloy steel for shaft of 140mm. Due to material characteristics, such as, thermal conductivity and high temperature flow stress, on the two sides of the weld interface, modeling is crucial in determining the optimal weld parameters. FE simulation is performed by the commercial code DEFORM-2D. A good agreement between the predicted and actual welded shape is observed. It is expected that modeling will significantly reduce the number of experimental trials needed to determine the weld parameters.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.2
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• pp.128-136
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• 2004

The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by different Al(III) coagulants. When an Al(III) salt is added to water, monomers, polymers, or solid precipitates may form. Different Al(III) coagulants (alum and PACl) show to have different Al species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved Al(III) (monomer and polymer) increases, but for PACl, precipitates of $Al(OH)_{3(s)}$. increases rapidly. Also, for alum, higher mixing speed favoured Al(III) polymers formation over precipitates of $Al(OH)_{3(s)}$ but for PACl, higher mixing speed formed more precipitates of $Al(OH)_{3(s)}$. At A/D and sweep condition, both $Al(OH)_{3(s)}$ and dissolved Al(III) (monomer and polymer) exist, concurrent reactions by both mechanism appear to cause simultaneous precipitation.

• Journal of Surface Science and Engineering
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• v.49 no.6
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• pp.498-506
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• 2016

Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).