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Elemental Analysis by Neutron Induced Nuclear Reaction - Prompt Gamma Neutron Activation Analysis for Chemical Measurement - (중성자 핵반응을 이용한 원소 검출기술 - 즉발감마선 중성자 방사화분석법을 이용한 검출기술 -)

  • Song, Byung Chul;Park, Yong Joon;Jee, Kwang Yong
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.1041-1051
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    • 2003
  • Neutron induced prompt gamma activation analysis (PGAA) offers a nondestructive, sensitive and relatively rapid method for the determination of trace and major elements and is proven to be convenient for online analysis of minerals, metals, coal, cement, petrochemical, coating, paper as well as many other materials and products. The technique has found many uses in medicine, industry, research, security and the detection of contraband items. This report reviews the present status and future trends of the PGAA techniques. Requirements for the system are neutron source, high resolution HPGe detectors with a high-voltage power supply, an amplifier, analog-to-digital converter, and a multichannel analyzer for the detection and measurement of prompt ${\gamma}$-ray emit form the neutron capture elements. Introducing a ${\gamma}$-${\gamma}$ coincidence system also improves the quality of the ${\gamma}$-ray spectrum by suppressing the background created from the Compton scattering of high energy prompt ${\gamma}$-rays. A PGAA system using a $^{252}Cf$ neutron source is currently under construction for the on-line measurement of several elements in aqueous samples at KAERI. The system can be applied for the detection of chemical weapons and explosives as well as various narcotics.

Preliminary Study on Applicability of Accumulate Personal Neutron Dosimeter for Cosmic-ray Exposure of Aviators (운항승무원의 우주방사선 피폭 평가에 있어 누적형 개인 중성자 선량계의 적용가능성 예비 연구)

  • Kim, Hyeong-Jin;Chang, Byung-Uck;Byun, Jong-In;Song, Myeong Han;Kim, Jung-Ho
    • Journal of Radiation Protection and Research
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    • v.38 no.1
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    • pp.44-51
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    • 2013
  • ICRP recommended that cosmic ray exposure to the pilot and cabin crew would be considered as an occupational exposure due to their relatively high exposure. Since 2012 with the Act No. 10908 (Natural radiation management), the guideline of cosmic ray exposure to the pilot was established in Korea. The applicability of the solid-state nuclear track detector for personal dose assessment of pilot and cabin crew was evaluated. Dose linearity and angle dependence of dosimeters to the neutron were evaluated by $^{252}Cf$ neutron emitting source. The track density has a good agreement with the dose ($r^2$=0.99) and highly dependent on the degree of an angular of the dosimeter to the neutron source. In addition, the dosimeters (SSNTD) were exposed to cosmic ray in an aircraft during its cruising for more than two months in collaboration with Airline Pilots Association of Korea. Although the correlation between the track density from aircraft cruising altitude and expected neutron dose is low, however RSNS dosimeter could be used for personal neutron dosimeter. For application of RSNS as a personal dosimeter for pilot and cabin crew, additional studies are required.

Development of a TL pellet based on $CaSO_4:Dy$ for Neutron Measurement ($CaSO_4:Dy$ 물질 기반 중성자 측정용 TL소자 개발)

  • Yang, Jeong-Seon;Lee, Jeong-Il;Kim, Jang-Lyul;Kim, Bong-Hwan;Sou, Dong-Sup
    • Journal of Radiation Protection and Research
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    • v.31 no.3
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    • pp.129-134
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    • 2006
  • A TL pellet for a neutron dose measurement (KCT-306) by embedding a $^6Li$-compound into a $CaSO_4:Dy$ phohphor was developed based upon the technical information of KCT-300. The KCT-300 is an another kind of $CaSO_4:Dy$ TL detector shich was developed at KAERI, in which small amounts of $NH_4H_2PO_4$ have been emvedded as a binding material. This paper presented the optimized manufacturing condition of KCT-306 and compared its sensitivity with that of the commercialized neutron TL pellets. $CaSO_4:Dy$ Phosphor with grain size ranging less than $45{\mu}m$ are used for the KCT-306. The optimum $CaSO_4:Dy$ TL phosphor, $^6Li$-compounds and P-compound as the binding material are determined as 20-40wt%, 50-70wt% and 20wt%. The TL pellet combination of our KCT-306/KCT-300, TLD-600/TLD-700 and TLD-600H/TLD-700H(Harshaw) have been irradiated in the neutron/gamma mixed fields from a $D_2O$ moderated $^{252}Cf$ neutron source. The KCT-300, TLD-700 and TLD-700H were used at the same time as gamma ray discriminators in the neutron/gamma mixed fields. It was found that the neutron/gamma response ratios of KCT-306/KCT-300, which were developed in this study, were approximately 4 times higher than those of the commercial TLD-600H/TLD-700H.

A Study on DPPC Lipid Membrane and its Carbohydrate Mixture Membrane for Preparation of a Functional Membrane (기능성 막 제조를 위한 DPPC 지질막과 탄수화물 혼합막에 관한 연구)

  • Jeong, Teak-Suh;Rhee, Jae-Seong;Lee, Ki-Chang;Hong, Jang-Hoo
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.252-260
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    • 1996
  • In this article, we investigate into the structural changes of liposome to design its functional membranes by the synthesis of two types of liposomes, DPPC liposome and DTAB of hydrocarbon substance/DPPC liposome. The changes of membrane structures are evaluated by the CF fluorescent intensity measured above and below the phase transition temperature of the membrane, $t_c=41^{\circ}C$. CF fluorescent intensities are enhanced by the CF leakage from DPPC liposome at $45^{\circ}C$, while no changes are observed at $20^{\circ}C$. Under the same conditions, it is observed that the intensity enhanced by CF leakage from DPPC/DTAB liposome is larger than that of DPPC liposome alone, which suggests that DPPC/DTAB liposome has irregular arrangement. Under the presence of $Ca^{2+}$, Quin 2 fluorescent intensity in either DPPC liposome or DPPC/DTAB liposome is significantly increasing at $45^{\circ}C$, while almost none of the changes are observed at $20^{\circ}C$. The fluorescent intensity of DPPC liposome turns out to be larger than that of DPPC/DTAB liposome, which suggests that the DPPC/DTAB liposome is structurally more stable than the DPPC liposome. Additionally, when the analysis is done to observe changes in the shapes of membrane surfaces with ANS fluorescent, ANS fluorescent under DPPC or DPPC/DTAB liposome shows each of different appearances at $45^{\circ}C$ and $20^{\circ}C$ respectively. This result indicates that its respective membrane fluidity is changing above and below of the designated temperatures in phase transition. As to the magnitude of change of its membrane fluidity, DPPC liposome is much larger than DPPC/DTAB liposome. As far as the temperature in phase transition measured by DSC are concerned, it is $41^{\circ}C$ and $32^{\circ}C$ for DPPC and DPPC/DTAB liposome respectively, which suggests that DPPC/DTAB liposome has an irregular molecular arrangement in its structure. That is, it is summed up that DPPC/DTAB turns out to be structurally stable, even so, its structure is irregularly arranged.

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Fertilizing Effects of Swine Compost Fermented with Sawdust on Mixed Pastures (혼파초지에 대한 톱밥발효돈분의 시용효과)

  • Shin, J. Soon;Cho, Young-Mu;Lee, Hyo-Ho;Yoon, Sea-Hung;Park, Geun-Je;Choi, Ki-Chun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.24 no.3
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    • pp.245-252
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    • 2004
  • Experiment was carried out to find the fertilizing effects of 8 different application rates of swine compost fermented with sawdust(SCS) including Chemical fertilizer(CF) on forage yield and soil chemical characteristics of mixed pastures sown in Sep. 1993 at National Livestock Research Institute, RDA., in Suwon during low years. It was arranged in a randomized complete block design with three replicates. Dry matter yield were shown at similar among treatments except Control and $50\%$ SCS of standard amount plot. In botanical composition, the legume and weeds percentages of each treatment were increased as advancing year. The final year's legume percentage were high in line with SCS fertilizing plots($39\%{\sim}43\%$), SCS + CF plots($30\%{\sim}41\%$) and CF plot($32\%$). In productions of TDN, NE and crude protein yield, SCS or SCS($75\%$) + CF($25\%$) were nearly same comparing those of CF, respectively. Phosphate, potassium, magnesium contents and K/(Ca + Mg) except calcium contents of those SCS fertilizing plots in plant were generally high with comparing CF. Those contents were proportional according to the fertilizing amount These result indicate the possibility to substitute chemical fertilizer for SCS($75\%$, 25ton/ha) + CF, $25\%$) as manure-N 210 kg/ha, but might be considered accumulation phosphate in the soil.

A REVIEW OF NEUTRON SCATTERING CORRECTION FOR THE CALIBRATION OF NEUTRON SURVEY METERS USING THE SHADOW CONE METHOD

  • KIM, SANG IN;KIM, BONG HWAN;KIM, JANG LYUL;LEE, JUNG IL
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.939-944
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    • 2015
  • The calibration methods of neutron-measuring devices such as the neutron survey meter have advantages and disadvantages. To compare the calibration factors obtained by the shadow cone method and semi-empirical method, 10 neutron survey meters of five different types were used in this study. This experiment was performed at the Korea Atomic Energy Research Institute (KAERI; Daejeon, South Korea), and the calibration neutron fields were constructed using a $^{252}Californium$ ($^{252}Cf$) neutron source, which was positioned in the center of the neutron irradiation room. The neutron spectra of the calibration neutron fields were measured by a europium-activated lithium iodide scintillator in combination with KAERI's Bonner sphere system. When the shadow cone method was used, 10 single moderator-based survey meters exhibited a smaller calibration factor by as much as 3.1-9.3% than that of the semi-empirical method. This finding indicates that neutron survey meters underestimated the scattered neutrons and attenuated neutrons (i.e., the total scatter corrections). This underestimation of the calibration factor was attributed to the fact that single moderator-based survey meters have an under-ambient dose equivalent response in the thermal or thermal-dominant neutron field. As a result, when the shadow cone method is used for a single moderator-based survey meter, an additional correction and the International Organization for Standardization standard 8529-2 for room-scattered neutrons should be considered.

Development and Characterization of Tissue Equivalent Proportional Counter for Radiation Monitoring in International Space Station

  • Nam, Uk-Won;Lim, Chang Hwy;Lee, Jae Jin;Pyo, Jeonghyun;Moon, Bong-Kon;Lee, Dae-Hee;Park, Youngsik;Kim, Hyun Ok;Moon, Myungkook;Kim, Sunghwan
    • Journal of Astronomy and Space Sciences
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    • v.30 no.2
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    • pp.107-112
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    • 2013
  • Tissue equivalent proportional counter (TEPC) can measure the Linear Energy Transfer (LET) spectrum and calculate the equivalent dose for the complicated radiation field in space. In this paper, we developed and characterized a TEPC for radiation monitoring in International Space Station (ISS). The prototype TEPC which can simulate a 2 ${\mu}m$ of the site diameter for micro-dosimetry has been tested with a standard alpha source ($^{241}Am$, 5.5 MeV). Also, the calibration of the TEPC was performed by the $^{252}Cf$ neutron standard source in Korea Research Institute of Standards and Science (KRISS). The determined calibration factor was $k_f=3.59{\times}10^{-7}$ mSv/R.

The Effect of Mustard Meal in Laying Hen Diets

  • Cheva-Isarakul, B.;Tangtaweewipat, S.;Sangsrijun, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.11
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    • pp.1605-1609
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    • 2001
  • A total of 252, 50 week-old Isa-brown laying hens were randomly allotted to 7 groups of 3 replicates. Mustard meal (MM) which is a by-product from mustard processing plant, was dried under the sun or in a gas heated pan. It contained on DM basis 30-32% CP, 19-22% EE and 12-13% CF. The meal from either drying method was incorporated into the diets at 0, 10, 20 and 30% which was equivalent to the substitution levels for soybean meal at 0, 31, 63 and 94%, respectively. All birds were individually kept in battery cages where feed and water were freely accessed throughout 84 days experimental period. It was found that egg production, feed intake, body weight gain and egg weight significantly decreased with the increased MM level. The inclusion of 20% MM did not show a significant difference in egg production and quality from the control, but produced 6-8% lower egg production. Feed intake was linearly decreased with the MM levels, except the 10% sun dried MM group. Fat deposition of the birds fed MM diets significantly decreased, while kidney weight increased when compared with the control group. However, the weight of thyroid glands and spleen trended to be heavier in the MM groups, but this was not significantly different among dietary treatments. It was concluded, MM from both drying methods could be incorporated in laying hen diets at the level of 10% without any adverse effect.

CHARACTERISTICS OF FABRICATED SiC RADIATION DETECTORS FOR FAST NEUTRON DETECTION

  • Lee, Cheol-Ho;Kim, Han-Soo;Ha, Jang-Ho;Park, Se-Hwan;Park, Hyeon-Seo;Kim, Gi-Dong;Park, June-Sic;Kim, Yong-Kyun
    • Journal of Radiation Protection and Research
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    • v.37 no.2
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    • pp.70-74
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    • 2012
  • Silicon carbide (SiC) is a promising material for neutron detection at harsh environments because of its capability to withstand strong radiation fields and high temperatures. Two PIN-type SiC semiconductor neutron detectors, which can be used for nuclear power plant (NPP) applications, such as in-core reactor neutron flux monitoring and measurement, were designed and fabricated. As a preliminary test, MCNPX simulations were performed to estimate reaction probabilities with respect to neutron energies. In the experiment, I-V curves were measured to confirm the diode characteristic of the detectors, and pulse height spectra were measured for neutron responses by using a $^{252}Cf$ neutron source at KRISS (Korea Research Institute of Standards and Science), and a Tandem accelerator at KIGAM (Korea Institute of Geoscience and Mineral Resources). The neutron counts of the detector were linearly increased as the incident neutron flux got larger.

Development and Characterization of Multi-Segmented Tissue Equivalent Proportional Counter for Microdosimetry (마이크로 도시메트리용 다분할 조직등가비례계수기의 개발과 특성 평가)

  • Nam, Uk-Won;Park, Won-Kee;Lee, Jaejin;Pyo, Jeonghyun;Moon, Bong-Kon;Moon, Myung Kook;Lim, Chang Hwy;Lee, Suhyun;Kim, Sunghwan
    • Journal of Sensor Science and Technology
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    • v.24 no.2
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    • pp.101-106
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    • 2015
  • We designed, developed and characterized a multi-segmented tissue equivalent proportional (TEPC) counter for microdosimetry. The energy resolution of the multi-segmented TEPC was about 12% for $^{241}Am$ 5.45 MeV alpha particles. The resolution was better than 33% for a single un-segmented TEPC. A compact and low power consumption TEPC could be made by using digital pulse processor (DPP). We also successfully calibrated the TEPC by using $^{252}Cf$ standard neutron source in Korea Research Institute of Standards and Science (KRISS). According to the results, the TEPC is useful for several application of radiation monitoring such as a neutron monitor, air crew monitor and space dosimeter.