• Title/Summary/Keyword: 2성분계

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Physico-chemical stability of pesticide formulations under different storage conditions (저장조건별 농약제품의 물리.화학적 안정성)

  • Lee, Hee-Dong;Kim, Kwang-Ho;Rhi, Ja-Hyeun;Shin, Wook-Cheol;Park, Hyeon-Ju;Lee, Soo-Hyung;Park, Seung-Soon
    • The Korean Journal of Pesticide Science
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    • v.8 no.2
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    • pp.103-106
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    • 2004
  • To confirm physico-chemical stability of formulated products, this study was conducted under different storage conditions; room temperature and accelerated temperature of $54^{\circ}C$. The tested pesticide formulations were dichlorvos 50% EC, acephate 50% WP, hymexazol 4% DP, thiram 80% WP and isoprothiolane 12% GR. The selected formulations were stored for 10 weeks and 5 years under the given temperature in maximum and contents of active ingredients were also analyzed by GLC or HPLC after each time of storage. The degradation rates of 5 active ingredients under the two conditions showed a similar trend except acephate. Acephate was rapidly decomposed at $54^{\circ}C$ but slowly decomposed at room temperature, and the degradation rate under the accelerated condition was 2.4 to 5-fold higher than that under the room temperature. Consequently, the stability test on active ingredients in pesticide formulations was able to recommend to be carried out under the accelerated condition except acephate. And the physical properties of all formulations tested under two storage conditions were good.

Studies on the Chemical Components and Biological Activities of Edible Plants in Korea (II) - Isolation and Quantitative Analysis of Flavonoids from the Leaves of Cedrela sinensis A. Juss. by HPLC - (한국산 식용식물의 화학성분 및 생리활성에 관한 연구 (II) - HPLC에 의한 참죽나무 잎중 Flavonoid 성분의 확인 및 정량 -)

  • 박종철;전순실;양한석;김성환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.5
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    • pp.581-585
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    • 1993
  • Five flavonoids isolated from the ethyl acetate fraction of Cedrela sinensis A. Juss. were identified by high performance liquid chromatography. Separation was achieved by reversed phase chromatography on ${\mu}-bondapak$ C18 column with isocratic elution method. The content of the major flavonoid, quercitrin was about 9.48%(w/w) and 37.06%(w/w) for the methanol extract and ethyl acetate fraction, respectively.

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Properties of TLCP/PEN/PET ternary blend fibers with annealing condition (열처리 조건에 따른 TLCP/PEN/PET삼성분계 블렌드 섬유의 특성)

  • 서은수;김준영;김성훈
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.227-230
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    • 2003
  • 열방성 액정고분자 (Thermotropic liquid crystal polymer, TLCP)는 초고강도 섬유로의 응용가능성을 갖고 있어 많은 관심이 집중되고 있으며, 액정고분자의 고강도와 고탄성, 우수한 내열성과 내화학성, 가공시 성형수축률 및 선팽창계수가 작기 때문에 고성능 섬유 및 엔지니어링 플라스틱, 그리고 고분자 복합재료 등 다양한 분야에 응용되고 있다 [1]. 또한 범용성 열가소성 수지와 TLCP와의 용융블렌드는 고분자 복합재료의 강도 및 탄성의 향상뿐만 아니라 우수한 가공성 및 고성능 발현이 가능하기 때문에 현재 많은 연구가 진행되고 있다 [2]. (중략)

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IGRINS를 이용한 태양계 행성 관측

  • Son, Mi-Rim;Kim, Sang-Jun;Seo, Haeng-Ja;Sim, Chae-Gyeong
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.44-44
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    • 2011
  • 상대적으로 온도가 낮은 태양계 천체의 적외선 분광관측 자료는 행성대기의 구성성분, 온도 분포와 haze및 구름을 포함한 대기의 수직구조에 대한 연구를 수행하는 기본이 된다. 외국 망원경의 관측자료에 의존했던 거대 행성 및 타이탄의 적외선 분광자료를 IGRINS를 통해 자체적으로 획득한 자료는 행성대기 연구를 주도적으로 진행할 수 있다는 점에서 큰 의미가 있다. 특히 목성, 토성, 타이탄 대기의K-band(2.0-2.45mm), H-band(1.45-1.80mm) 고분산 분광자료는 기존의 저분산 분광 관측 결과 또는 다른 파장대의 관측 결과와의 비교도 의미가 있을 것으로 기대한다. 그리고 IGRINS의 고 분해능을 이용하면 지구대기에 의해 지상관측이 쉽지 않은 $2.4-2.45{\mu}m$ 파장대에서 지구 흡수선 사이로 도플러 이동되어 들어오는 행성의 분광 자료를 얻을 수 있을 것으로 예상된다. 이에 따라 우리는 IGRINS를 이용한 태양계 행성관측의 시나리오를 마련하고자 한다.

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LLE of Solvent-Water-2-Propanol Ternary Systems (Solvent-water-2-propanol 삼성분계의 액-액평형)

  • Jeong, Sang-Hoon;Lee, Jin-Woo;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.653-659
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    • 1997
  • Due to the rising cost of energy, new separation processes based on extraction are becoming more attractive than before. Thus, the need for calculating and predicting liquid-liquid equilibria(LLE) compositions has very much increased. The purpose of this study is to determine the binodal curves, tie line, plait point, distribution and selectivity for the ternary systems of 2-propanol-water with methyl ethyl ketone, methyl isobutyl ketone, ethylacetate, toluene and o-xylene as solvents at $25^{\circ}C$. And those tie line data were used to examine thermodynamic consistency. The experimental tie line data were correlated with NRTL and UNIQUAC models.

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Isoflavone, Phytic Acid and Oligosaccharide Contents of Domestic and Imported Soybean Cultivars in Korea (국내산 콩과 수입콩의 Isoflavone, Phytic Acid 및 Oligosaccharides 함량)

  • 류승현;김성란;김경탁;김성수
    • The Korean Journal of Food And Nutrition
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    • v.17 no.2
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    • pp.229-235
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    • 2004
  • Chemical composition, total dietary fiber(TDF), oligosaccharide, isoflavone and phytic acid contents of seven domestic and three imported soybean cultivars were determined. TDF contents were ranged from 16.83 to 21.71%(w/w) without remarkable differences among soybean cultivars. Phytic acid contents of domestic cultivars such as Geomjongkong 1 (3.02%) and Dawonkong (2.92%) were higher than imported ones such as Canadian (2.07%) and American (2.22%) soybeans for soybean sprout and US No. 1 (2.16%). The phytic acid contents of cotyledon parts were 1.5 to 2 times higher than those of hypocotyl parts. Isoflavone contents in whole seed were wide ranged from 371 to 2,398 $\mu\textrm{g}$/g among cultivars and it were existed mainly as glucoside isomers. Profiles of isoflavone aglycones were composed of 52% genistein, 36% daidzein and 11% glycitein. Hwanggumkong, Dawonkong, Geomjongkong 1 and American soybean for sprout contained lower isoflavone than others. Hypocotyl parts of soybeans contained from 6120.1 to 16921.1 $\mu\textrm{g}$/g isoflavone with ratio of 48% glycitein, 35% daidzein and 10% genistein. Isoflavone contents of cotyledon parts were ranged 375-2393 $\mu\textrm{g}$/g, composition of which had no glycitein, 55% genistein and 38% daidzein. Oligosaccharide contents were similar among cultivars. Stachyose of 3.0-3.9%, raffinose of 0.8-1.2%, sucrose of 4.5-7.8% and fructose of 0.3-0.8% were determined.

The Effect of Organic Acids in Decontamination Solution on Ion Exchange of Metal Ions (제염용액내 유기산이 금속이온 이온교환에 미치는 영향)

  • Yang, Yeong-Seok;Kang, Young-Ho;Jheong, Gyeong-Rak
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.171-177
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    • 1993
  • In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

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Geochemistry and Origin of $CO_2$-rich Groundwater from Sedimentary Rocks of Kyungsang System (경상계 퇴적암에서 산출되는 탄산지하수의 지화학적 특성과 생성기원)

  • 정찬호;이진국
    • The Journal of Engineering Geology
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    • v.10 no.1
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    • pp.51-62
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    • 2000
  • The $CO_2$-richrich water pumps or springs out at two sites (Sinchon and Kohran) consisting of Cretaceous sedimentary rocks in Kyungpook area. The water has been long known as its soda pop-liketaste and therapeutic effect against calcium deficit, stomach and skin troubles, etc. The water arecharacterized by a high $CO_2$ concentration $(P_{CO2}=0.29~l.01 atm)$ and electrical conductance (1,093~2,810$\mu$S/cm). The $CO_2$-rich water belongs to Ca(Na)-$HCO_3$ type in chemical classification. The contents of Ca, Mg, Na, HCO$_3$ and Fe of $CO_2$-rich water show much higher values than those of general groundwater Environmental isotopic data $(^2H/^1H, ^{18}O/^{16}O and ^3H/^1H)$ indicate that the water is ofmeteoric origin recharged after 1950s. The $CO_2$ in the springs seems to be originated from deep-seatedsource related to acidic porphyry and granite nearby sedimentary rocks. Carbonate minerals and albiteare likely to be the major source minerals of the dissoved inorganic constituents in the $CO_2$-rich water.The equilibrium state between major minerals and $CO_2$-rich water was calculated by a thermodynamicprogram.

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칼만필터를 이용한 Baro-Inertial 고도루프의 설계 및 성능분석

  • Kim, Hyeon-Seok;Lee, Yun-Seon;Je, Chang-Hae
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.2
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    • pp.455-458
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    • 2006
  • 관성항법장치는 관성항법장치를 구성하는 관성센서인 가속도계 및 자이로의 오차요소에 의해 수평축 항법오차는 슐러주기를 가지고 서서히 증가하는 반면에 수직축 오차는 기하급수적으로 증가하는 특성을 가지고 있다. 그러므로 관성항법장치를 장시간 운용하는 경우에는 비관성 보조센서를 이용하여 관성항법장치의 수직축 항법오차에 대한 보정을 반드시 수행하여야 한다. 관성항법장치의 수직축 항법오차를 보정하기 위한 비관성 보조센서의 일종인 기압고도계는 계측된 대기압과 모델링 된 대기압을 비교하여 항체의 고도를 측정하는 방법을 이용하기 때문에 항체의 자세변화 등에 매우 민감하고 대기압 측정오차에 의해 매우 큰 진폭의 잡음 및 바이어스가 존재한다. 본 논문에서는 시뮬레이션 및 시험을 통하여 기압 고도계의 잡음 및 바이어스 오차 성분에 의한 baro-inertial 고도루프의 성능분석 결과를 제시하고 기압고도계 잡음에 둔감한 INS/기압고도계 칼만필터의 설계 결과를 제시한다.

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A Study of Minimum Autoignition Temperature Behavior (MAITB) of Benzene and n-Hexane Mixture (벤젠과 노말헥산 혼합물의 최소자연발화온도 거동에 관한 연구)

  • Ha, Dong-Myeong;Kim, Kyu-Hyun
    • Fire Science and Engineering
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    • v.27 no.1
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    • pp.8-13
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    • 2013
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for Benzene and n-Hexane system by using ASTM E659 apparatus. The AITs of Benzene and n-Hexane which constituted binary system were $583^{\circ}C$ and $240^{\circ}C$, respectively. The experimental AITs of Benzene and n-Hexane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).