• Korean Journal of Crystallography
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• v.7 no.2
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• pp.113-119
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• 1996

Reaction of Re(O)(PPh3)2Cl3,I, with 2,3,4,5,6-pentafluoroaniline (C6F5NH2), produced Re(NC6F5)(PPh3)2Cl3, II. The product has been characterized by 1H-NMR, elemental analysis, and X-ray diffraction. II crystallizes in the orthorhombic system, space group Pna21 with cell parameters a=18.763Å, b=14.737(2)Å, c=16.707(3)Å, Z=4. Least-square refinement of the structure led to an R(wR2)factor of 0.0455(0.1148) for 3319 unique reflections of I > 2σ(I) and for 174 variables.

• Journal of the Korean Mathematical Society
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• v.56 no.5
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• pp.1403-1418
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• 2019

Let R be a commutative ring with unity. If f(x) is a zero-divisor polynomial such that $f(x)=c_f f_1(x)$ with $c_f{\in}R$ and $f_1(x)$ is not zero-divisor, then $c_f$ is called an annihilating content for f(x). In this case $Ann(f)=Ann(c_f )$. We defined EM-rings to be rings with every zero-divisor polynomial having annihilating content. We showed that the class of EM-rings includes integral domains, principal ideal rings, and PP-rings, while it is included in Armendariz rings, and rings having a.c. condition. Some properties of EM-rings are studied and the zero-divisor graphs ${\Gamma}(R)$ and ${\Gamma}(R[x])$ are related if R was an EM-ring. Some properties of annihilating contents for polynomials are extended to formal power series rings.

• Applied Biological Chemistry
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• v.49 no.1
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• pp.25-29
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• 2006

This study was carried out to isolate the possible anti-tumor promoters from the citrus peel (Citrus natsudaidai Hayata). We fractionated the cold-pressed oil of citrus peel by column chromatography, HPLC and TLC. The analysis on column chromate-graphy yielded seven peaks $(F-I{\sim}F-VII)$, all of which showed single spot on TLC analysis ($R_f$ for $F-I{\sim}VIII$; 0.31, 0.13, 0.13, 0.78, 0.79, 0.69 and 0.84). Among the seven fractions, three fractions (F-I, -II and F-IV) were re-analyzed on HPLC, also showing single peak except for one fraction (F-IV) which was divided two peaks. The retention times $(R_f)$ of F-I and F-II was 3 min. and 2.5 min., respectively, but these of two peaks from F-IV were 2 min. and 4.5 min., respectively. Since the area of the latter peak (4.5 min.) was very smaller than that of the former one (2 min.), it is considered that the latter one did not appear on TLC analysis. The inhibitory effect on tumor promoter 12-O-tetradecanoylphorbol-13-acetate(TPA)-induced Epstein-Barr virus activation in Raji cells was tested for the seven fraction obtained. It decreased in order of F-VI (82.3+1.3%) > F-I (80.4+1.6%) > F-II (77.2+0.9%) > F-III (75.0+1.2%) > F-IV (74.1=1.0%) > F-V (71.0+1.1%) > F-VII (70.2+1.2%). These results imply that some constiuents contained in citrus peels have the inhibitory activity of TPA-induced tumor promotion.

• Korean journal of applied entomology
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• v.43 no.1
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• pp.43-48
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• 2004

Development of 3,700 folds resistance to etoxazole was found in the population of twospotted spider mite, Tetranychus urticae, collected from rose greenhouses in Buyo, Chungnam Provience in August 2000. This population was selected for 3yr with etoxazole to get 5,000,000 folds increase in resistance as compared to susceptible (S) strain. The etoxazole resistance was stablized for 16 months under the condition of no acaricide application. Inheritance and cross resistance in etoxazole to some acaricides of the etoxazole resistance strain (R) were investigated. There were differences of susceptibility in the etoxazole concentration-mortality relationships between $F_1$, $F_2$ progenies obtained from reciprocal cross with the S and R strains (R$_{♂}$${\times}$S$_{♂}$${\times}$R$_{♂}$). Degrees of dominance were 0.98 and 0.98 in $F_1$ and $F_2$ progenies of R$_{♂}$${\times}$S$_{♂}$, and -0.97 and -0.68 in $F_1$ and $F_2$ progenies of S$_{♀}$${\times}$R$_{♂}$ respectively. Inheritance in $F_1$ and $F_2$ progenies of R$_{♀}$${\times}$S$_{♂}$ were complete dominant. However $F_1$ and $F_2$ progenies of S$_{♀}$${\times}$R$_{♂}$ were incomplete recessive. These results suggest that inheritance of etoxazole resistance is controlled by a complete dominance. The R strain exhibited cross resistance to acequinocyl and emamectin benzoates in adult females, and milbemectin, amitraz and pyridaben in eggs. However they showed negatively correlated cross-resistance to bifenazate, a carbazate acaricide. These results may indicate bifenazate could be useful for the control of etoxazole resistant T. urticae population.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.1
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• pp.1-5
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• 1999

The rare-earth ions ($R^{3+}$, R=Nd, Er) doped $CaF_{2}$ layers have been grown on $CaF_{2}$ (111) substrate by molecular beam epitaxy. The surface structure and the crystallinity of $CaF_{2}:R^{3+}$ layers depending on the doping concentration of $R^{3+}$ and layer thickness were studied by reflection high-energy electron diffraction (RHEED). In aspect of application as buffer layer in semiconductor-related hybrid structure, the lattice displacement between $CaF_{2}:R^{3+}$ layers and $CaF_{2}$ (111) substrate was investigated by X-ray rocking curve analysis.

• Journal of Korean Physical Therapy Science
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• v.8 no.2
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• pp.997-1003
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• 2001

The purpose of this study is to know the average of pint range of motion and difference according to the aging for the elderly, This study consisted of elder male(n=75) and elder female(n=l09), The result of assessment and analysis in shoulder pint range of motion are as follows: 1) The average shoulder flexion pint range of motion in 60-69(from sixty to sixty-nine)years old are 163.04(Left-Male), 162.91(Right-Male), 158.74 (Left-Female), 158.74 (Right-Female). 70-79years old are 149.40(L-M), 152.38(R-M), 153,37(L-F), 153.37(R-F). 80-89 years old are 149.57(L-M), 147.93(R-M), 151.17(L-F), 150.33(R-F). There was no significant difference among group, 2) The average shoulder extension pint range of motion in 60-69years old are 48.15(L-M), 47.20(R-M), 45.16(L-F), 44.23(R-F), 70-79years old are 37.l1(L-M), 38.70(R-M), 35.17(L-F), 36.71(R-F), 80-89 years old are 34.46(L-M). 36.71(R-M), 33.90(L-F), 33.09(R-F). There was significant difference among group(p<.05). 3) The average shoulder abduction pint range of motion in 60-69years old are 164.22(L-M), 165.96(R-M), 159.34(L-F), 159.97(R-F), 70-79years old are 152.27(L-M), 155.05(R-M), 152.32(L-F), 53.66(R-F), 80-89 years old are 152.17(L-M), 153.76(R-M), 147.53(L-F), 147.37(R-F). There was significant difference in right shoulder abduction among group(p<05). 4) The average shoulder internal rotation pint range of motion in 60-69years old are 63.52(L-M), 65.70(R-M), 64.16(L-F), 64.61(R-F), 70-79years old are 64.50(L-M), 65.81(R-M) 61.10(L-F), 61.83(R-F). 80-89 years old are 61.60(L-M), 61.66(R-M), 57.53(L-F), 57.53(R-F). There was no significant difference among group. 5) The average shoulder external rotation pint range of motion in 60-69years old are 50.87(L-M), 50.22(R-M), 51.03(L-F), 50.42(R-F), 70-79years old are 50.91(L-M), 50.20(R-M) 48.37(L-F), 50.20(R-F). 80-89 years old are 46.83(L-M), 47.93(R-M), 43.43(L-F), 43.72(R-F).There was significant difference in left shoulder external rotation among group(p<.05).

• Journal of The Korean Society of Grassland and Forage Science
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• v.34 no.1
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• pp.60-67
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• 2014

The comparisons between cellulolytic bacteria adhesion on rice straw and fiber digestion in time course during rumen fermentation were studied in situ. The adhesions of cellulolytic bacteria, F. succinogenes. R. albus and R. flavefaciens, were measured by RT-PCR. When the rice straws were incubated at 0. 2, 4, 8, 12 and 24 hours of the in situ rumen, straw was degraded with increasing speed during the incubation and showed the highest disappearance increasing rate (DM g/h) from 8 to 12 hour. The adhesions of F. succinogenes, R. flavefaciens and R. albus were achieved above 80% in 1 hour of in situ rumen fermentation and then keep adhesive population up after the time of fermentation. When the in situ samples were collected at 0, 5, 10, 30 and 60 min to detect the early stages of adhesion on the rice straws ingested into rumen, the numberous adhesive colony of F. succinogenes, R. flavefaciens and R. albus were detected in 5 min. In case of rice straw treated with 0, 2, 4 and 8% NaOH, all of three cellulolytic bacteria showed the increasing trends of adhesion with increasing DM disappearance of rice straw by higher concentration of NaOH at 12 hour of in situ. However, there were showed respectively difference at 24 hour. The present results gave certain evidence that adhesion of cellulolytic bacteria is definitely achieved in early stage of roughage ingestion into rumen, their colony develop the stable communities on roughage in process of rumen fermentation and then fiber degradation is accelerated.

• Journal of the Korean Wood Science and Technology
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• v.8 no.1
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• pp.22-27
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• 1980

Quantitative assessment of edge blunting of saw-teeth was carried out by TALYSURF. 1. Using the following equation, the real shape of a saw-tooth can be traced on the graph of TALYSURF. ${\frac{{\Delta}h}{h}}={\frac{V{\Delta}_x}{V_x}}$ {${\Delta}h$: vertical distance of stylus h: vertical distance in chart $V{\Delta}_x$: Velocity of stylus $V_x$: velocity of chart} 2. As shown on Fig 2, the error from stylus itself can be calculated by following equation. i) 13.8${\mu}{\leqq}$x<20.4${\mu}$ y=-0.2246x+4.59${\mu}$ ii) 0${\leqq}$x<13.8${\mu}$ y=${\sqrt{(-18{\mu})^2-x^2}}-1.42x+32.7{\mu}}$ 3. The relationship between profile of saw-tooth and error from stylus itself can be calculated by following equation. $E(%)=\frac{f(r){\times}{\frac{4}{18{\mu}}}}{f(R){\times}{\frac{R}{18.5{\mu}}}-f(r){\times}{\frac{r}{18{\mu}}}}{\times}100$ {E(%)${\frac{error\;of\;stylus}{dullness\;of\;saw\;tooth}}{\times}100$ r: radius of stylus tip R: radius of tip which is drawn in graph of talysurf f(r) : error of stylus f(R) : dullness of tip which is drawn in graph of talysurf} 4. The graph of maximum error and profile of saw-tooth was parabola.

• Bulletin of the Korean Chemical Society
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• v.16 no.7
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• pp.634-641
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• 1995

The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

• Journal of the Korean Applied Science and Technology
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• v.37 no.5
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• pp.1159-1170
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• 2020

In this study, to improve the stability of fermented squalene developed using microorganisms, Microsome-SQ20 was prepared, and its physical behavior, properties, and efficacy were studied. The appearance of Microsome-SQ20 was a transparent liquid, no smell, and had a specific smell. The color was a transparent liquid, and the specific gravity was 0.928 and the pH was 5.82 (20% solution), forming a nano-emulsion suitable for use in cosmetics. It was confirmed that the content of the main component of squalene was 20.05%, which was stably sealed. The particle size measured by 0.1% aqueous solution of Microsome-SQ20 was 134.8 nm to obtain a bluish emulsified phase. The antioxidant effects of F-SQ and MF-SQ by DPPH radicals were 80.72% and 81.5%, respectively, showing superior effects compared to L-ascorbic acid. The cell viability of squalene (SQ), fermented squalene (F-SQ) and microsome squalene (MF-SQ) was at 10 ppm, respectively, showing 121.2%, 150.3%, and 129.9% cell viability. It was found that SQ, F-SQ, and MF-SQ had an elastase inhibitory ability of 8.7%, 10.33% and 8.7% at 10 ppm, respectively. In addition, the inhibitory ability of MMP-1 was 1.55%, 41.44%, 31.79% at 10 ppm for SQ, F-SQ, and MF-SQ, respectively, indicating that F-SQ significantly reduced the MMP-1 expression.