• Journal of the Korean Vacuum Society
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• v.13 no.2
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• pp.59-64
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• 2004

A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

• Proceedings of the Optical Society of Korea Conference
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• 2002.07a
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• pp.2-2
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• 2002

검은공진현상은 양자광학현상으로 비흡수 공진으로 간단히 표현할 수 있다. 즉, 공진전이에서 광흡수가 일어나지 않는 현상인데 이는 1976년 Pisa대학에서 분광학 실험으로 우연히 관측된 이래 90년대 이후 수많은 응용분야가 제시되면서 검은공진 연구에 있어 비약적인 발전을 가져오게 된다. 그 중 비선형광학, 밀도전이 없는 레이저, 양자메모리, 고해상 분광학, 광스위치, 빛속도조절 등은 그 좋은 예이다. (중략)

• Proceedings of the Optical Society of Korea Conference
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• 2000.08a
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• pp.218-219
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• 2000

공동광자감쇠 분광학(Cavity Ringdown Spectroscopy, CRDS)은 고감도의 흡수분광법으로 미량기체의 농도나 흡수분광선의 연구에 사용되어 왔으며 화염이나 플라스마에도 응용되고 있다. 이 분광법은 시간에 따라 지수함수로 감쇠하는 공동광자감쇠신호의 감쇠상수를 측정하는 기술인데, 레이저의 밴드폭이 흡수선폭보다 넓으면 감쇠신호가 지수함수에서 벗어나 오차를 발생하게 된다. 그러므로 오차를 줄이려면 좁은선폭의 레이저를 사용하거나 공동광자감쇠신호의 주파수를 분리하여야 한다. 분광선폭보다 매우 넓은 선폭의 레이저를 사용하고 분광기를 이용하여 공동광자감쇠신호를 분리하는 방법들이 제안되었다. (중략)

• Korean Journal of Crystallography
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• v.10 no.2
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• pp.110-113
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• 1999

x의 범위가 0.5

• Proceedings of the Optical Society of Korea Conference
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• 2000.08a
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• pp.216-217
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• 2000

상자성을 갖는 분자에 대한 분광학 연구에서는 제만(Zeeman) 효과로 생기는 이색성을 이용한 magnetic rotation spectroscopy (MRS)가 널리 사용되고 있다.$^{(1)}$ MRS가 일반적인 흡수 분광법에 비해 더 민감한 측정을 할 수 있기는 하지만 사용하는 편광기의 extinction ratio에 의해 감도가 한정된다. MRS의 감도를 높이는 방법으로는 광경로를 길게 만드는 것을 고려할 수 있다. 일반적으로 공진기 광자감쇠 분광학(Cavity Ring-Down Spectroscopy, CRDS)은$^{(2)}$ 높은 반사율을 갖는 거울을 사용해서 수 km 이상의 광 경로를 만들기 때문에 감도가 높다. (중략)

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.4
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• pp.397-410
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• 2018

When considering the long-term safety assessment of spent-nuclear fuel management, americium is one of the most radio-toxic actinides. Although spectroscopic methods are widely used for the study of actinide chemistry, application of those methods to americium chemistry has been limited. Herein, we purified $^{241}Am$ to obtain a highly pure stock solution required for spectroscopic studies. Quantitative and qualitative analyses of purified $^{241}Am$ were carried out using liquid scintillation counting, and gamma and alpha radiation spectrometry. Highly sensitive absorption spectrometry coupled with a liquid waveguide capillary cell and time-resolved laser fluorescence spectroscopy were employed for the study of Am(III) hydrolysis and oxalate (Ox) complexation. $Am^{3+}$ ions under acidic conditions exhibit maximum absorbance at 503 nm, with a molar absorption coefficient of $424{\pm}8cm^{-1}{\cdot}M^{-1}$. $Am(OH)_3(s)$ colloidal particles formed under near neutral pH conditions were identified by monitoring the absorbance at around 506-507 nm. The formation of ${Am(Ox)_3}^{3-}$ was detected by red-shifts of the absorption and luminescence spectra of 4 and 5 nm, respectively. In addition, considerable enhancements of the luminescence intensities were observed. The luminescence lifetime of ${Am(Ox)_3}^{3-}$ increased from 23 to 56 ns, which indicates that approximately six water molecules are replaced by carboxylate ligands in the inner-sphere of the Am(III). These results suggest that ${Am(Ox)_3}^{3-}$ is formed through the bidentate coordination of the oxalate ligands.

• Korean Journal of Optics and Photonics
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• v.6 no.1
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• pp.76-90
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• 1995

반도체 양자구조에 대한 광특성을 이해하기 위하여 정상상태에서의 흡수 스펙트럼과 광여기 발광측정을 통하여 양자구속효과 등의 선형 광특성에 대해 알아보았다. 또한 반도체 양자 구조를 이용한 광소자 개발에 있어서 매우 중요한 반도체의 비선형 광특성을 이해하기 위하여 비선형성을 일으키는 쿨롱 스크리닝, 띠채움, 밴드갭 재규격화, 그리고 열효과 등에 대해 알아 보았다. 그리고 광여기에 의해 생성되는 운반자들의 동력학에 대해 알아보고 이러한 운반자들의 시간에 따른 움직임을 측정하는 degenerate four-wave mixing과 differential transmission spectroscopy등의 시간 분해 분광학에 대해 소개하였다.

• The Journal of the Petrological Society of Korea
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• v.22 no.1
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• pp.1-8
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• 2013

Physical properties, XRF, UV-Vis, FTIR studies were carried out in order to characterize gemological features of ruby from Tajikistan. Fluorescence reaction of the Tajikistan ruby to short wave ultraviolet was moderate to very strong in red and long wave ultraviolet rays was weakly detected. UV-visible analysis strong absorption bands at 468.5, 475, 476.5 nm and broaden bands at 550 nm were observed for ruby due to $Cr^{3+}$. According to FT-IR analysis, all rubies from Tajikistan showed the similar patterns and kaolinite peaks at 3500, 3617, 3630, $3677cm^{-1}$ and boehmite broaden absorption bands at 3085 and $3320cm^{-1}$. Inclusions in Tajikistan ruby are observed solid inclusions, negative crystals, needle and silk inclusions. These distinctive characteristics mentioned above can be used to identify the locality and source of ruby stones from Tajikistan.

• Journal of the Korean Vacuum Society
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• v.15 no.1
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• pp.24-30
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• 2006

Integrated cavity output spectroscopy(ICOS) is a simple, non-intrusive absorption measurement technique that can detect and quantify trace-level gas species. The spectral absorbance of a gas is quantified from the integrated optical output of the modulated high-finesse cavity containing the sample which is irradiated by a wavelength-swept laser source. We constructed an experimental setup by using a tunable single mode external cavity diode laser operating at the wavelength near 765 nm and a Fabry-Perot cavity with length modulation achieved by a piezoelectric transducer where one of the cavity mirrors sat on. In the experiment performed on minute oxygen gas at the wave-length near 764.5nm, we demonstrated the minimum detectable absorption of $8.45\times10^{-8}cm^{-1}$.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.447-459
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• 2003

Generalized 2D correlation spectroscopy has been applied extensively to the analysis of spectral data sets obtained during the observation of a system under some external perturbation. It is used in various fields of spectroscopy including IR, Raman, UV, fluorescence, X-ray diffraction, and X-ray absorption spectroscopy (XAS) as well as chromatography. 2D hetero-spectral correlation analysis compares two completely different types of spectra obtained for a system under the same perturbation. Because of the wide range of applications of this technique, it has become one of the standard analytical techniques for the analytical chemistry, physical chemistry, biochemistry, and so on, and for studies of polymers, biomolecules, nanomaterials, etc. In this paper, we will introduce the principle of generalized 2D correlation spectroscopy and its applications that we have studied.