• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.3
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• pp.15-20
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• 2013

The graphites as airtight structure seals prevent high-pressure and high-temperature gas from flowing into actuator of propulsion system and generate lubricant film during wear procedure to assist lubricant and sealing. In this study, the tribological characteristics of the graphite in high-temperature are evaluated. In order to evaluate the tribological characteristics of high density graphite(HK-6), variables which are temperature, sliding speed and contact load are set. this study suggest optimized environment conditions through the wear properties of graphite. Consequeantly, high temperature is better than at room temperature to generate lubricant film, so that friction coefficient of graphite is lower at high temperature than at room temperature.

• Journal of the Korean Electrochemical Society
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• v.13 no.2
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• pp.81-88
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• 2010

Small size polymer electrolyte membrane fuel cell (PEMFC) stacks were prepared using carbon composite and graphite bipolar plates and their performances were evaluated on reactant gas and operating time. In comparison to single cell and stack, it was identified that home-made bipolar plate was well-designed to maximize stack performance as high as that of single cell. During long-term operation, the performances of stacks using two different kinds of bipolar plates were compared. The decrease of performance in both stacks was accelerated with increasing load current. It was observed from stack test that the stack performance using carbon composite bipolar plate was very similar to that using graphite bipolar plate.

• Journal of Convergence for Information Technology
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• v.8 no.5
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• pp.95-100
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• 2018

The metal oxide/graphene nanocomposites are promising functional materials for high capacitive electrode material of secondary batteries, and high sensitive material of high performance gas sensors. In this study, vanadium dioxide($VO_2$) nanostructrures were grown on CVD graphene which was synthesized on Cu foil by thermal CVD, and exfoliated graphene which was exfoliated from highly oriented pyrolytic graphite(HOPG) using a vapor transport method. As results, $VO_2$ nanostructures on CVD graphene were grown preferential growth on abundant functional groups of graphene grain boundaries. The functional groups are served to nucleation site of $VO_2$ nanostructures. On the other hand, 2D & 3D $VO_2$ nanostructures were grown on exfoliated graphene due to uniformly distributed functional groups on exfoliated graphene surface. The characteristics of morphology controlled growth of $VO_2$/graphene nanocomposites would be applied to fabrication process for high capacitive electrode materials of secondary batteries, and high sensitive materials of gas sensors.

• Clean Technology
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• v.27 no.3
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• pp.223-231
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• 2021

In order to address many issues associated with large volume changes of silicon, which has very low electrical conductivity but offers about 10 times higher theoretical capacity than graphite (Gr), a silicon nanoparticles/hollow carbon (SiNP/HC) composite having bimodal-mesopores was prepared using silica nanoparticles as a template. A control SiNP/C composite without a hollow structure was also prepared for comparison. The physico-chemical and electrochemical properties of SiNP/HC were analyzed by X-ray diffractometry, X-ray photoelectron spectroscopy, nitrogen adsorption/desorption measurements for surface area and pore size distribution, scanning electron microscopy, transmission electron microscopy, galvanostatic cycling, and cyclic voltammetry tests to compare them with those of the SiNP/C composite. The SiNP/HC composite showed significantly better cycle life and efficiency than the SiNP/C, with minimal increase in electrode thickness after long cycles. A hybrid composite, SiNP/HC@Gr, prepared by physical mixing of the SiNP/HC and Gr at a 50:50 weight ratio, exhibited even better cycle life and efficiency than the SiNP/HC at low capacity. Thus, silicon/carbon composites designed to have hollow spaces capable of accommodating volume expansion were found to be highly effective for long cycle life of silicon-based composites. However, further study is required to improve the low initial coulombic efficiency of SiNP/HC and SiNP/HC@Gr, which is possibly because of their high surface area causing excessive electrolyte decomposition for the formation of solid-electrolyte-interface layers.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.901-908
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• 2018

Graphite is used as a sample anode active material. However, since the maximum theoretical capacity is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of a high capacity lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is higher than that of graphite. However, it is not suitable for direct application to the anode active material because it has a volume expansion of 400%. In order to minimize the decrease of the discharge capacity due to the volume expansion, the Si was pulverized by the dry method to reduce the mechanical stress and the volume change of the reaction phase, and the change of the volume was suppressed by coating the carbon layers to the particle size controlled Si particles. And carbon fiber is grown like a thread on the particle surface to control secondary volume expansion and improve electrical conductivity. The physical and chemical properties of the materials were measured by XRD, SEM and TEM, and their electrochemical properties were evaluated. In this study, we have investigated the synthesis method that can be used as anode active material by improving cycle characteristics of Si.

• 기계와재료
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• v.22 no.3
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• pp.96-109
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• 2010

자동차는 다양한 형상과 기능을 가진 부품소재의 집합체라 할 수 있다. 자동차의 고출력화에 의한 연비향상과 각국의 환경규제 강화 요건을 충족시키기 위해 자동차 엔진의 작동온도와 이에 따른 배기가스의 온도가 꾸준히 높아지는 추세이다. 따라서 고온재료의 선택과 사용이 보다 중요해 지고 있다. 자동차에 사용되는 고온 부품은 설계사양에 맞추어 그리고 경제적인 측면을 고려하여 내열재료를 사용하는 방법과 표면처리를 하는 두 가지 방법이 주로 채택되고 있다. 내열재료를 사용하는 대표적인 부품은 엔진을 구성하는 부품과 연소실로부터 나오는 고온 고압의 배기가스가 이동하는 배기계 부품이다. 엔진을 구성하는 부품 중에는 냉각수에 의해 온도가 제어되는 부분은 경제적인 소재가 사용되나 밸브와 같은 부품은 고온재료가 채용된다. 가장 높은 온도에서 사용되는 배기계 부품에는 경제성이 감안되면서도 높은 열적, 기계적 안정성이 동시에 요구되고 있다. 전통적으로 배기부품에는 구상흑연주철이 널리 사용되어 왔고 현재에도 원가 측면의 강점을 이용해 대부분의 차량에 적용되고 있으나 일부 고출력, 고배기량 엔진의 경우에는 주철의 한계온도 이상의 배기온도가 요구되어 스테인리스 강을 도입하고 있다. 또한 내열 타이타늄 합금, 금속간화합물과 같은 고온재료가 개발됨에 따라 고가의 차종에는 신재료가 이들 부품으로 채용되고 있다. 이 글에서는 배기계 부품의 설계적인 요소에 의한 열적, 기계적 측면의 내구 특성을 살펴보고, 이들 부품에 보편적으로 적용되는 고온 금속재료의 종류 및 기계적 특성을 소개하였다. 아울러 미래의 환경친화적 자동차용 고온 부품을 개발하기 위하여 연구되고 있는 Super Si+MO, 스테인리스 강, TiAl, 고온 타이타늄 합금 등과 같은 자동차 내열 부품으로 사용되는 신소재의 연구개발 동향에 관하여 기술하였다.

• Journal of Practical Engineering Education
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• v.13 no.2
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• pp.327-332
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• 2021

Materials used for education include SM20C, Al6061, and acrylic. SM20C materials are used a lot in certification tests and functional competitions as carbon steel, but they are also used in industrial sites. Al6061 is said to be a material that produces a lot of tools because it has lower hardness than carbon steel and is highly flexible. When practical guidance is given to students using acrylic materials, it is a material that causes vibration and tool damage due to excessive cutting. In this process, we examine how impact on the 5-axis equipment 2NC head can affect precision control. The weakest part of a five-axis equipment is the head that controls the AC axis. In the event of precision and cumulative tolerances in this area, the precision of all products is reduced. Thus, a key part of the 2NC head, the spindle housing was carried out using Al7075 T6 (U.S. Alcoasa) material and the entire body using FCD450 (spherical graphite cast iron). In the vibration and cutting process acting on these two materials, the analysis was carried out to determine the value of applying the force as a finite element analysis under extreme conditions. We hope that using these analytical data will help students see and understand the structure of 5-axis machining rather than 5-axis cutting.

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.514-519
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• 2020

Graphite materials for lithium ion battery anode materials are the most commercially available due to their structural stability and low price. Recently, research efforts have been conducted on carbon coatings by improving side reactions at the edge site of carbon materials. The carbon coating process has classified into a CVD by chemical reaction, wet coating process with solvent and dry coating by mechanical impact. In this paper, the rapid crush/coating process was used to solve the problem of which only few parts of the carbon precursor (pitch) can be used and also environmental problems caused by solvent removal in the wet coating process. When the ratio of needle coke to pitch was 8 : 2 wt%, and the rapid crush/coating process was carried out, it was confirmed that the fracture surface was coated by pitch. The pitch-coated sample was treated at 2400 ℃ and 41.8% improvement in 10C/0.1C rate characteristic was observed. It is considered that the material simply manufactured through the simple crush/coating process can be used as an anode electrode material for a lithium ion battery.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.248-251
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• 2005

Graphite reinforced conductive polymer composites for PEMFC bipolar plates were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. In this study, conductive polymer composites with high filler $loadings(>60wt.\%)$ were manufactured to accomplish high electrical conductivity above 100S/cm. The level of compaction is important because graphite powder increase electrical conductivity of composites by direct physical contact between particles. The optimum molding pressure according to filler was proposed experimentally. Various tests(electrical conductivity, flexural strength, compressive strength, leach test, etc) were carried out to verify the performance of fabricated composites for PEMFC bipolar plates. Fabricated composites have good electrical conductivity and mechanical strength. The results of leach test and contact angle measurement showed similar characteristics compared with commercial bipolar plates.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.162-166
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• 2005

A thermal resistance estimation of carbon/carbon composites used as the nozzle throat insert of solid rocket motor was performed using TPEM motor. Three types of TPEM motor and two types of propellant were employed. The ablation rate is higher for the higher chamber pressure and also higher for the higher concentration of oxidizing species in combustion gas, but it is lower for the higher material density.