• Title/Summary/Keyword: 환원작용

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Analysis by reduction in the development of algebra (분석의 환원적 기능이 대수 발달에 미친 영향)

  • Kim, Jae-Hong;Kwon, Seok-Il;Hong, Jin-Kon
    • Journal for History of Mathematics
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    • v.20 no.3
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    • pp.167-180
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    • 2007
  • In this study, we explored the role of analysis in the algebra development. For this, we classified ancient geometric analysis into an analysis by reduction and a Pappusian problematic analysis. this shows that both analyses have the function of reduction. Pappus' analysis consists of four steps; transformation, resolution, construction, demonstration. The transformation, by which conditions of given problem is transformed into other conditions which suggest a problem-solving, seems to be a kind of reduction. Mathematicians created new problems as a result of the reductional function of analysis, and became to see mathematics in the different view. An analytical thinking was a background at the birth of symbolic algebra, the reductional function of analysis played an important role in the development of symbolic algebra.

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Inhibition of Biological Perchlorate Reduction by Nitrate and Oxygen (질산염과 산소에 의한 생물학적 퍼클로레이트 환원의 저해)

  • Choi, Hyeok-Sun
    • Journal of Soil and Groundwater Environment
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    • v.14 no.6
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    • pp.29-34
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    • 2009
  • In this study, a chloride ion probe as a direct measurement for perchlorate reduction was used to determine whether biological perchlorate reduction was inhibited by other electron acceptors ($O_2$ and ${NO_3}^-$) and to investigate competition of electron acceptors for using electron donors. Profiles of chloride production (= perchlorate reduction) in flasks containing perchlorate reducing populations were monitored by a chloride ion probe. Biological reduction of 2 mM perchlorate was inhibited by 2 mM nitrate that chloride production rate was decreased by 30% compared to perchlorate used as the only electron acceptor and chloride production rate was decreased by 70% when acetate was limited. Reduction of 2mM perchlorate was completely inhibited by oxygen at 7~8 mg/L, regardless of acetate excess / limitation.

Electrochemical Reduction of Thionyl Chloride by Tetradentate Schiff Base Transition Metal(II) Complexes : Catalytic Effects (네자리 Schiff Base 전이금속(II) 착물들에 의한 SOCl$_2$의 전기화학적 환원 : 촉매 효과)

  • Woo-Seong Kim;Yong-Kook Choi;Chan-Young Kim;Ki-Hyung Chjo;Jong-Soon Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.702-710
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    • 1993
  • Electrochemical reduction of thionyl chloride has been carried out at glassy carbon and molybdenum electrodes, the surface of which is modified by binuclear tetradentate schiff base Co(II), Ni(II),Cu(II) and Fe(II) complexes. The catalyst molecules of transition metal(II) complexes were adsorbed on the electrode surface and reduced thionyl chloride resulting in a generation of oxidized catalyst molecules. There was an optimum concentration for each catalyst compound. The catalytic effects of SOCl$_2$ reduction were larger on glassy carbon electrodes compared to molybdenum electrodes and enhancements in reduction current of up to 120${\%}$ at the glassy carbon electrodes. The reduction currents of thionyl chloride were increased and the reduction potentials were shifted to the negative potential when scan rates became faster. The reduction of thionyl chloride was proceed to diffusion controlled reaction.

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The Effects of Acebutolol and Carbamazepine on the Ouabain-Induced Arrhythmias in Rabbits (가토의 ouabain 유발 부정맥에 미치는 acebuolol 및 carbamazepine의 영향)

  • Kim, Won-Joon;Ha, Jeoung-Hee
    • The Korean Journal of Pharmacology
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    • v.23 no.1
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    • pp.9-14
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    • 1987
  • The effects of acebutolol and carbamazepine on ouabain-induced arrhythmias were investigated in rabbits. Ouabain produced ventricular arrhythmias which persisted for 7-8 min at the mean dose of $69{\pm}1.3\;{\mu}g/kg$. Ouabain arrhythmias were converted to normal sinus rhythm by administration of acebutolol or carbamazepine singly but lower dosages increased the recovery time. And then, ouabain arrhythmias were effectively converted to normal sinus rhythm and prevented by combined administration of carbamazepine and acebutolol. Each of the combined doses was ineffective when given singly. From the above results, it may be concluded that carbamazepine and acebutolol inhibited the ouabain-induced arrhythmias depending on the level of dosage and showed synergistic interaction.

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Lignocellulose Biodegradation and Interaction between Cellulose and Lignin under Sulfate Reducing Conditions (황산염 환원 조건에서 리그노셀룰로오스의 분해 및 리그닌과 셀룰로오스의 상호작용)

  • Ko, Jae-Jung;Kim, Seog-Ku;Shimizu, Yoshihisa
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.4
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    • pp.131-137
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    • 2007
  • In this study, the biodegradation test on lignocellulose under sulfate reducing conditions was carried out. In particular, the interaction between cellulose and lignin was investigated with various g-cellulose/g-lignin (C/L) ratios: 42.15, 4.59, 2.51, 1.14 and 0.7. It was shown that the rate of cellulose degradation decreased in proportion to the lignin content. Assuming first order degradation kinetics, the consequences of competitive inhibition were graphically shown for different C/L ratios. The relation between cellulose reduction rate and C/L ratio was expressed by logarithm function with a determination coefficient of 0.97. Lignocellulose reduction rate was also described as a logarithm function of C/L ratio showing a inhibition effect by lignin. In the mean time, the rate of lignin decomposition was higher at C/L ratio of 2.51 and 1.14 compared with C/L ratios of 4.59 and 0.7, indicating that excessive extra carbon source is not appropriate for lignin biodegradation.

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NAD(P)H Quinone Oxidoreductase 1 (NQO1) as a Cancer Therapeutic Target (암 치료 표적으로의 NAD(P)H Quinone Oxidoreductase 1 (NQO1))

  • Park, Eun Jung;Kwon, Taeg Kyu
    • Journal of Life Science
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    • v.24 no.1
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    • pp.98-103
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    • 2014
  • NAD(P)H quinone oxidoreductase 1 (NQO1) is a flavoprotein that catalyzes the two electron reduction of diverse substrates, including quinones. It uses NADH or NADPH as a cofactor for enzymatic machinery. In the metabolism of quinones, NQO1 has two conflicting functions because of the different stability of converted hydroquinones. The stable form of hydroquinone is excreted from cells by conjugation with glutathione or glucuronic acid. The unstable form of hydroquinone induces cell death by induction of oxidative stress and DNA damage. Certain quinones known as bio-reductive agents have a cytotoxic function following reduction by NQO1. Bio-reductive agents, such as ${\beta}$-lapachone or mitomycin C, induce the depletion of NAD(P)H and the generation of oxidative stress in an NQO1-dependent manner. NQO1 is highly expressed in several cancer tissues. Therefore, NQO1 is a good therapeutic target for cancer treatment with bio-reductive agents.

Effect of Nitrification Inhibition on Soil Phosphate Release and Nutrient Absorption and Growth of Rice Plant (질산화작용 억제 처리가 논토양의 인산 가용화와 벼의 양분흡수 및 생육에 미치는 영향)

  • Chung, Jong-Bae;Kim, Byoung-Ho
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.336-342
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    • 2010
  • In a pot experiment, we studied the effect of nitrification inhibition on Fe reduction and P release in paddy soil and growth and nutrient uptake of rice plant. Recommended level of fertilizers, 6 kg N, 5 kg $P_2O_5$ and 4 kg $K_2O$ per 10a, were applied, and for N fertilizer urea, urea+N-serve, and $KNO_3$ were included. Four 30-day-old seedlings were transplanted in a waterlogged 9 L pot filled with Yuga series soil, and 3 pots were prepared in each N fertilizer treatment. Changes of soil redox potential and concentration of ${NH_4}^-$, ${NO_3}^-$, $Fe^{2+}$ and ${PO_4}^{3-}$ in soil solution at 10 cm depth were monitored, and also the growth and nutrient uptake of rice plants were measured. Concentration of ${NH_4}^+$ in soil solution was highest in urea+N-serve treatment, and followed by urea and $KNO_3$ treatments. Addition of N-serve could effectively inhibit nitrification in the soil. In the treatment of $KNO_3$, relatively higher ${NO_3}^-$ concentration was found at 10 cm depth soil. In urea+N-serve treatment redox potential was lower than -100 mV during the experiment, but in the treatment of $KNO_3$ the potential was maintained above 0 mV until ${NO_3}^-$ remaining in soil solution. Reduction of Fe(III) and solubilization of P were highly correlated with redox potential changes in the three N fertilizer treatments. Concentrations of Fe(II) and ${PO_4}^{3-}$ in soil solution at 10 cm depth were much higher in the urea+N-serve treatment. The most vigorous rice seedling growth was found in the urea treatment. Although the availability of N and P in soil was enhanced in the urea+N-serve treatment through the suppression of nitrification, excessive solubilization of Fe could limit the growth of rice plants.

Effect of Solvents on the Yield, Brown Color Intensity, UV Absorbance, Reducing and Antioxidant Activities of Extracts from White and Red Ginseng (홍삼(紅蔘) 및 백삼(白蔘)의 용매별(溶媒別) 추출물(抽出物)의 수율(收率), 갈색도(褐色度), 자외선흡수특성(紫外線吸收特性), 환원성(還元性) 및 항산화(抗酸化) 작용(作用))

  • Choi, Kang-Ju;Kim, Man-Wook;Hong, Soon-Keun;Kim, Dong-Hoon
    • Applied Biological Chemistry
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    • v.26 no.1
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    • pp.8-18
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    • 1983
  • The effects of fat-solvents was investigated on the yield. brown color intensity, UV absorbance patterns, reducing and antioxidant activities, and variation of fatty acid composition of the extracts from white and red ginseng. The yield and intensity of brown color of extracts were generally greater as the polarity of the solvent used became stronger. The intensity of the brown color of extract of red ginseng was greater than that of white ginseng. The orders of reducing and antioxidant activities of extracts of red ginseng was similar that of white ginseng, resulting in decreasing order of: ethanol>methanol>ethyl acetate, acetone>ether>chloroform>benzene, hexane. The ethanol, methanol, and ethyl acetate extracts of red ginseng showed stronger UV absorption than the corresponding extracts of white ginseng. The former also possessed stronger reducing and antioxidant activities than the latter. The composition of the major unsaturated fatty acids (linoleic, linolenic, and nervonic acid) in the ethanol and ethyl acetate extracts from both white and red ginseng did not change appreciably for 60 days at $45^{\circ}C$. In case of the hexane extracts which had shown the weakest reducing and antioxidant activities among the extracts, linolenic acid disappeared almost under the same condition.

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Metal Reduction and Mineral formation by fe(III)-Reducing Bacteria Isolated from Extreme Environments (철환원 박테리아에 의한 금속 환원 및 광물형성)

  • Yul Roh;Hi-Soo Moon;Yungoo Song
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.231-240
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    • 2002
  • Microbial metal reduction influences the biogeochemical cycles of carbon and metals as well as plays an important role in the bioremediation of metals, radionuclides, and organic contaminants. The use of bacteria to facilitate the production of magnetite nanoparticles and the formation of carbonate minerals may provide new biotechnological processes for material synthesis and carbon sequestration. Metal-reducing bacteria were isolated from a variety of extreme environments, such as deep terrestrial subsurface, deep marine sediments, water near Hydrothemal vents, and alkaline ponds. Metal-reducing bacteria isolated from diverse extreme environments were able to reduce Fe(III), Mn(IV), Cr(VI), Co(III), and U(VI) using short chain fatty acids and/or hydrogen as the electron donors. These bacteria exhibited diverse mineral precipitation capabilities including the formation of magnetite ($Fe_3$$O_4$), siderite ($FeCO_3$), calcite ($CaCO_3$), rhodochrosite ($MnCO_3$), vivianite [$Fe_3$($PO_4$)$_2$ .$8H_2$O], and uraninite ($UO_2$). Geochemical and environmental factors such as atmospheres, chemical milieu, and species of bacteria affected the extent of Fe(III)-reduction as well as the mineralogy and morphology of the crystalline iron mineral phases. Thermophilic bacteria use amorphous Fe(III)-oxyhydroxide plus metals (Co, Cr, Ni) as an electron acceptor and organic carbon as an electron donor to synthesize metal-substituted magnetite. Metal reducing bacteria were capable of $CO_2$conversion Into sparingly soluble carbonate minerals, such as siderite and calcite using amorphous Fe(III)-oxyhydroxide or metal-rich fly ash. These results indicate that microbial Fe(III)-reduction may not only play important roles in iron and carbon biogeochemistry in natural environments, but also be potentially useful f3r the synthesis of submicron-sized ferromagnetic materials.

Selective Reduction of Nitro Compounds Using CeY Zeolite Under Microwaves (마이크로웨이브와 CeY Zeolite를 이용한 니트로화합물의 선택적인 환원반응)

  • Arya, Kapil;Dandia, Anshu
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.55-58
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    • 2010
  • Aliphatic and aromatic nitro compounds were selectively reduced to their corresponding amino derivatives in good yields using formic acid and CeY zeolite under monomode reactor. This system is found to be compatible with several sensitive functionalities. Beside the recycling result showed it had a long catalyst lifetime and could maintain activity even after being used for 20 cycles.