• Proceedings of the Korea Water Resources Association Conference
• /
• 2023.05a
• /
• pp.401-401
• /
• 2023

터널이나 폐기물저장소와 같은 지하 구조물 또는 지표에서부터 상당한 깊이로 설계되거나 건설되는 구조물을 계획하거나 건축할 때 구조물의 안전성에 영향을 주는 수많은 요인 중에 간과할 수 없는 것이 바로 지하수이다. 뿐만 아니라 지상 혹은 지하에서 오염이 발생하여 오염물질이 지중환경으로 유입되는 경우, 지하수 거동은 오염물의 이송·확산에 지대한 요인으로 작용한다. 최근에는 지구온난화와 같은 유례없는 기후변화를 경험하고 있고, 따라서 수자원으로써 지하수의 역할이 더욱 중요해지고 있다. 지하수의 저류와 거동은 지하매질의 특성에 지배되고 있지만, 지표 아래 자리잡고 있는 매질의 특성을 정확히 파악하기란 매우 힘들고, 따라서 지하수 거동을 해석함에 항상 불확실성이 존재한다. 전통적으로 지하매질의 특성을 이해하기 위해 다양한 지구물리탐사를 수행하여 왔고, 더욱 직접적인 관찰을 위해 시추를 수행하여, 시료를 수집·관찰하고, 시추공에서의 다양한 현장수리실험을 통해 수리특성을 알고자 하였다. 하지만 그동안의 다양한 노력에도 불구하고, 지하매질 및 지하수 거동에 대한 불확실성은 여전히 줄어들지 않고, 오히려 증가하고 있다. 따라서, 본 연구에서는 지하수 거동을 결정짓는 지하매질의 수리특성에 대한 불확실성을 정량화하기 위한 도구로써, 매개변수 보정법의 하나인 Pilot Point Method(PPM)을 소개하고자 한다. 우물 또는 관측정을 통해 관측되는 지하수의 수위는 지하매질의 특성을 반영하고 있으며, 인간이 가장 쉽게 취득할 수 있는 지하 정보에 해당한다. 지하수 수위를 이용하여 수치모형의 매개변수를 보정하게 되며, 이 때 PPM이 적용된다. Pilot points의 공간적인 분포에 따라 다양한 보정 결과가 산출될 수 있으며, 다양한 결과들을 통해 변동계수를 산정한 후 수리특성의 불확실성이 높은 지역을 나타낼 수 있다. 본 연구를 통해 얻은 결과는 물리탐사 또는 시추 작업을 위한 위치 선정의 기초자료로 활용될 수 있다.

• Environmental and Resource Economics Review
• /
• v.31 no.4
• /
• pp.531-559
• /
• 2022

It is necessary to study the need for introduction of nuclear energy tax in Korea to internalize the externality cost of nuclear power and to make more balanced taxation system considering LNG and coal power. This study adopts choice experiment method to estimate the willingness to pay (WTP) for possible new tax on nuclear power. The finding is that the tax on nuclear fuel is more preferable to other tax base with KRW2.19/kWh of WTP, compared to KRW1.46/kWh for nuclear waste. The WTP for using the tax revenue to facilitate economic activity is KRW6.39/kWh compared to KRW6.12/kWh of WTP for funding climate change investment. The finding suggests that the design of nuclear power taxation needs to focus more on the use of tax revenue than on the choice of tax base.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.31 no.2
• /
• pp.53-61
• /
• 2023

Most of the sewage sludge is organic waste containing a large amount of organic substances decomposable by microorganisms by biological treatment. As for existing sewage sludge treatment methods, reduction and fuel conversion are being carried out using technologies such as drying, incineration, torrefaction, carbonization. However, the disadvantage of high energy consumption has been pointed out as latent heat of 539 kcal/kg is consumed based on drying. Therefore, in this study, we intend to produce solid fuel through hydrothermal carbonization(HTC), which is a thermochemical treatment. To evaluate the value of solid fuel, the characteristics of carbonization and fuel ratio were analyzed. As a result, as the hydrothermal carbonization reaction temperature increased, the lower heating value also increased by about 500 kcal/kg due to the increase in the degree of carbonization. H/C, O/C, ratio showed a decreasing trend from 1.78, 0.46 to 1.57, 0.32. When the ratio of ash to combustible content (fixed carbon + volatile) of dry sludge was 0.25 or more, it was derived that the degree of carbonization and calorific value did not increase even when hydrothermal carbonization was performed.

• The Journal of the Korea institute of electronic communication sciences
• /
• v.19 no.3
• /
• pp.507-514
• /
• 2024

In the semiconductor manufacturing line, continuous efforts are being made to reduce the cost of products produced, and the demand for this is accelerating in the chemical mechanical polishing(CMP) process, and a representative example of these cost reduction items is the 5-Zone Ring. After about 150 hours of use in the CMP process, the thickness of the ring decreases to less than 1 mm and must be replaced with a new product. Therefore, in this study, bonding dispensers and press machines with a dispensing amount error of 10g±0.8% or less and a pressure uniformity of ±1.8% or less were developed to reduce semiconductor manufacturing costs by repeatedly regenerating worn parts of the retainer ring, and to minimize environmental pollution caused by industrial waste treatment.

• Tunnel and Underground Space
• /
• v.34 no.1
• /
• pp.71-87
• /
• 2024

In deep geological disposal of high-level radioactive waste, the surrounding rock at the immediate vicinity of the deposition hole may experience localized changes in permeability due to in-situ stress at depth, swelling pressure from resaturated bentonite buffer, and the heat generated from the decay of radioactive isotopes. In this study, experimental data on changes in permeability of granite, a promising candidate rock type in South Korea, were obtained by applying various confining pressures and temperature conditions expected in the actual disposal environment. By conducting the permeability test on KURT granite specimens under three or more hydrostatic pressure conditions, the relation in which the permeability decreases exponentially as the confining pressure increases was derived. The temperature-induced changes in permeability were found to be negligible at temperatures below the expected maximum of 90℃. In addition, by establishing a relation in which the initial permeability is proportional to the power of the initial porosity, it was possible to estimate permeability value for granite with a specific porosity under a certain confining pressure.

• Economic and Environmental Geology
• /
• v.56 no.2
• /
• pp.125-138
• /
• 2023

Most of previous cesium (Cs) sorbents have limitations on the treatment in the large-scale water system having low Cs concentration and high ion strength. In this study, the new Cs sorbent that is eco-friendly and has a high Cs removal efficiency was developed by improving the coal mine drainage treated sludge (hereafter 'CMDS') with the addition of Na and S. The sludge produced through the treatment process for the mine drainage originating from the abandoned coal mine was used as the primary material for developing the new Cs sorbent because of its high Ca and Fe contents. The CMDS was improved by adding Na and S during the heat treatment process (hereafter 'Na-S-CMDS' for the developed sorbent in this study). Laboratory experiments and the sorption model studies were performed to evaluate the Cs sorption capacity and to understand the Cs sorption mechanisms of the Na-S-CMDS. The physicochemical and mineralogical properties of the Na-S-CMDS were also investigated through various analyses, such as XRF, XRD, SEM/EDS, XPS, etc. From results of batch sorption experiments, the Na-S-CMDS showed the fast sorption rate (in equilibrium within few hours) and the very high Cs removal efficiency (> 90.0%) even at the low Cs concentration in solution (< 0.5 mg/L). The experimental results were well fitted to the Langmuir isotherm model, suggesting the mostly monolayer coverage sorption of the Cs on the Na-S-CMDS. The Cs sorption kinetic model studies supported that the Cs sorption tendency of the Na-S-CMDS was similar to the pseudo-second-order model curve and more complicated chemical sorption process could occur rather than the simple physical adsorption. Results of XRF and XRD analyses for the Na-S-CMDS after the Cs sorption showed that the Na content clearly decreased in the Na-S-CMDS and the erdite (NaFeS₂·2(H₂O)) was disappeared, suggesting that the active ion exchange between Na⁺ and Cs⁺ occurred on the Na-S-CMDS during the Cs sorption process. From results of the XPS analysis, the strong interaction between Cs and S in Na-S-CMDS was investigated and the high Cs sorption capacity was resulted from the binding between Cs and S (or S-complex). Results from this study supported that the Na-S-CMDS has an outstanding potential to remove the Cs from radioactive contaminated water systems such as seawater and groundwater, which have high ion strength but low Cs concentration.

• Korean Journal of Environmental Agriculture
• /
• v.23 no.2
• /
• pp.92-98
• /
• 2004

The adsorption and desorption of Pb, Cd, Co, Zn, Cr, Co, Ni, and Mo on the waste Undaria sp. were studied. Except for Pb. the mono adsorption rate for all heavy metals were lower than that of the heavy metals mixed. However, the adsorption capacity of the heavy metals by 1g of biosorption, in mixed heavy metals increased According to FT-IR analysis of the biosorbent after heavy metal biosorption, the replacement of the functional group by the heavy metals ions could be confirmed and the inverted peaks became larger after heavy metals adsorption. The adsorption equilibrium of heavy metals was reached in about 1 hour. The equilibrium parameters were determined based on Langmuir and Freundlich isotherms. The affinity of metals on the biosorbent decreased in the following order: Pb>Cu>Cr>Cd>Co. The desorption rate decreased in the following sequence: NTA>$H_2SO_4$>HCl>EDTA. The desorption rate of heavy metals by NTA increased with increase in the concentration from 0.1 to 0.3% but the desorption rate became constant beyond 0.3%. Therefore, it represented that desorption rate of heavy metals was suitable under optimized condition ($30^{\circ}C$, pH 2 and 0.3% NTA solution) and was fast with 80% or more the uptake occurring within 10 min of contact time.

• Economic and Environmental Geology
• /
• v.28 no.3
• /
• pp.259-269
• /
• 1995

Column leaching tests were conducted using fresh and weathered pulverised fuel ash of some 17 and 40 years old from two major British power plants, with deionised water and simulated synthetic industrial leachate. The former was to see the leaching behaviour of weathered ash and the latter was to see if the formation of secondary products from water and PFA interaction and ameliorating effect in removing metals from industrial leachates. Fresh PFA liberates elevated concentrations of surface-enriched inorganics, including Ca, Na, K, B, $Cr_{total}$, Li Mo, Se and $SO^{2-}_4$. This might indicate their association with the surface of PFA particles. In the column leaching tests using weathered ash and deionised water, elements are not readily leached but are released more slowly, showing relatively constant concentrations. For the case of weathered ash, some readily soluble surface-enriched elements appears to have been liberated in their early stage of leaching and the liberation of glass associated elements are thought to be more important function in controlling the element concentration. The result from column leaching tests exceed for a number of elements when compared with various Water Standards and suggests the leachate from PFA disposal mound needs dilution to achieve target concentrations. PF A shows element retention effect for many elements, including B, Fe, Zn, Hg, Ni, Li and Mo, in the order of fresh Drax ash > weathered Drax ash > Weathered Meaford ash in retaining capacity. Geochemical modelling using a computer program WATEQ4F reveals some solubility controlling secondary solid products. These include $CaSO_4{\cdot}2H_2O$ for Ca, $Al(OH)_3$ for Al and $Fe(OH)_3$ for Fe.

• Economic and Environmental Geology
• /
• v.50 no.2
• /
• pp.117-128
• /
• 2017

Occurrence characteristics and existing forms of U-Th containing minerals in KURT (KAERI Underground Research Tunnel) granite are investigated to understand long-term behavior of radionuclides in granite considered as a candidate rock for the geological disposal of high-level radioactive waste. KURT granite primarily consists of quartz, feldspar and mica. zircon, REE(Rare Earth Element)-containing monazite and bastnaesite are also identified. Besides, secondary minerals such as sericite, microcline and chlorite including quartz vein and calcite vein are observed. These minerals are presumed to be accompanied by a post-hydrothermal process. U-Th containing minerals are mainly observed at the boundaries of quartz, feldspar and mica, mostly less than $30{\mu}m$ in size. Quantitative analysis results using EPMA (Electron Probe Micro-Analyzer) show that 74.2 ~ 96.5% of the U-Th containing minerals consist of $UO_2$ (3.39 ~ 33.19 wt.%), $ThO_2$ (41.61 ~ 50.24 wt.%) and $SiO_2$ (15.43 ~ 18.60 wt.%). Chemical structure of the minerals calculated using EPMA quantitative analysis shows that the U-Th minerals are silicate minerals determined as thorite and uranothorite. The U-Th containing silicate minerals are formed by a magmatic and hydrothermal process. Therefore, KURT granite formed by a magmatic differentiation is accompanied by an alteration and replacement owing to a hydrothermal process. U-Th containing silicate minerals in KURT granite are estimated to be recrystallized by geochemical factors and parameters such as temperature, pressure and pH owing to the hydrothermal process. By repeated dissolution/precipitation during the recrystallization process, U-Th containing silicate minerals such as thorite and uranothorite are formed according to the variation in the concentrated amount of U and Th.

• Korean Journal of Environmental Agriculture
• /
• v.12 no.1
• /
• pp.41-49
• /
• 1993

The Study was conducted to develope the low temperature tolerant methane-producing bacteria(LTTB) and to increase the efficiency of anaerobic fermentation for the treatment of agricultural and livestock wastes at low temperature. The samples were collected from muddy soil, water logged sediment, organic layer and anaerobic sludge at three latitudes, $34.8{\sim}37.4\;^{\circ}N(Korea)$, $41.4\;^{\circ}N(USA)$ and $54.5{\sim}56.9\;^{\circ}N(Canada)$. They were used for determination of the methanogenesis rates for isolation and identification of the LTTB. The methanogenesis rate of smaples at low temperature were higher in the cellulose medium than methanol medium. The methanogenesis rate in the samples of subarctic region were $15{\sim}19$ moles/ml during 30 days at low temperature($8\;^{\circ}C$), whereas not detected in the samples of temperate region. The methanogenesis rate in the enrichment culture of subarctic samples were inhibited by the $40\;{\mu}g/ml$ of streptomycin + vancomycin or ampicillin + oleandomycin which were not effect to the methanogens. An inhabitation of high temperature tolerant methane producing bacteria was identified in the samples of temperate region, whereas that of the LTTB growing at $8{\sim}13^{\circ}C$ was identified in the subarctic region.