• Polymer(Korea)
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• v.29 no.6
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• pp.588-592
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• 2005

For the purpose of obtaining polycarbonate film which blocks ultra-violet ion beam was irradiated onto the surface of PC film. This method has gotten several advantages compared with the techniques, such as the protection of changes in film thickness and UV blocking material deposited onto a base film. In order to investigate UV blocking PC film, the optical and chemical characteristics, surface morphology and lightfastness were confirmed by UV/Vis, FTIR(ATR) spectroscopy, AFM, and Q-UV fasoess analyses. As a result, it was shown that the modified PC film was able to block almost all of UV region and easily control the degree of UV block. The optical changes in the film were attributed to chemical changes in PC surface by ion beam irradiation. Moreover, we expect that the modified PC film can durably block UV due to no changes in colour and UV transmittance after UV fastness test.

• Journal of the Korean GEO-environmental Society
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• v.21 no.11
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• pp.11-20
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• 2020

For water barrier and reinforcing grout in soft ground, the verification of durability was conducted over the initial and long-term ages under various curing conditions. The grout was made of water glass system, fast-hardening mineral (FHM) system, and acrylic polymer system. There were three types of curing conditions that were tab water curing, artificial seawater curing, and atmospheric curing. And the various tests were performed for each sample by age, uniaxial compressive strength, length change, and weight change. As artificial seawater, MgCl₂ and MgSO₄ aqueous solutions were prepared and used, respectively. As the test results, the fast-hardening mineral system and acrylic polymer system were cured stably without significant change in durability in tap water and artificial sea water, whereas water glass system showed a very rapid drop in durability under artificial sea water conditions compared to tap water. In atmospheric curing conditions, durability is lowered compared to water curing in all cases, and in particular, the weight loss in the FHM system and water glass system is about 62% and 60%, respectively, resulting in a significant decrease in durability.

• Journal of the Korean Geosynthetics Society
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• v.15 no.4
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• pp.53-62
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• 2016

This paper presents the results of a reduced-scale physical model investigation into the effect of drilling fluid with different mix designs for use in offshore bore hole collapse prevention. Compare the bentonite and Attapulgite use. Reduced-scale model tests were then carried out considering field procedures for cases with decomposed granitic soil with fines and a sand with various drilling fluids with different mix designs. The results were indicated that the addition of polymer to the bentonite based drilling fluid decreases the amount of injected drilling fluid and increases the final depth of excavation. Also revealed that the effect of polymer on the performance of drilling fluid is more pronounced in the decomposed granite soil with fines than sand. Practical implications of the findings from this study are discussed in detail.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.216-222
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• 2002

With deterioration of the nation's infrastructure comes the growing, need for effective means of rehabilitating structures. Possibly one for the most challenging tasks is to upgrade the overall capacity of concrete structure. Therefore, considerable efforts are still being made to develop new construction materials. Rehabilitation of damaged RC structures occasionally requires the removal and replacement of concrete in the tension zone of the structural members. Typical situation where the tension zone repair is necessary is when the concrete in the tension zone in beams or slabs has spalled off as a result of corrosion in the bottom reinforcing bars or due to extensive fire. The rehabilitation of such conditions normally involves the removal of the concrete beyond the reinforcement bars, cleaning or replacing the tensile bars and reinstatement of concrete to cover the steel bars the original shape and size. This study focused on the flexural behavior of reinforced concrete beams strengthened by steel strand and carbon fiber sheet in the tension zone. The properties of beams are 15$\times$25 cm rectangular and over a 200cm span. Test parameters in this experimental study were strengthening methods, jacking volume, the number of sheet. We investigated the flexural behavior of simply supported RC beams which are strengthened with the carbon fiber sheet, monotonic loads. Attention is concentrated upon overall bending capacity, deflection, ductility index, failure mode and crack development of repaired and rehabilitated beams.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.6
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• pp.623-634
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• 2014

This study examined a feasibility of coagulation as post-treatment to remove sulfide and phosphorus for the effluent of anaerobic fluidized bed reactor (AFBR) treating domestic wastewater. Removal efficiencies of sulfide, phosphorus and COD by coagulation were not affected by pH in the range of 5.9 to 7.2. Alkalinity requirement could be estimated by the amount of $Fe^{3+}$ to form $Fe(OH)_{3(S)}$ and to remove sulfide and phosphorus. At coagulant aid dosage of 2 mg/L, anionic polymer showed best results regarding size and settleability of flocs. Sulfide removal for the AFBR effluent at the $Fe^{3+}/S^{2-}$ ratio of 0.64, close to the theoretical value of 0.67 found with a synthetic wastewater, was only 75.2%. One of the reasons for this high $Fe^{3+}/S^{2-}$ ratio requirement is that the AFBR effluent contains sulfide, phosphorus, hydroxide and bicarbonate which can react with $Fe^{3+}$ competitively. Concentrations of sulfide and phosphorous reduced to below 0.1 and 0.5 mg/L, respectively, at the $Fe^{3+}/S^{2-}$ ratio of 2.0. Average effluent COD of 80 mg/L, mostly soluble COD, was obtained at the dosage 50 mg $Fe^{3+}/L$ ($Fe^{3+}/S^{2-}$ ratio of 2.0) with corresponding COD removal of 55%. For better removal of COD, soluble COD removal at the AFBR should be enhanced. Coagulation with $Fe^{3+}$ removed sulfide, phosphorus and COD simultaneously in the AFBR effluent, and thus could be an alternative process for the conventional wastewater treatment processes where relatively high quality effluent is not required.

• Journal of the Korean Electrochemical Society
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• v.8 no.3
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• pp.139-145
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• 2005

[ $SnO_x$ ] films on the flexible substrate of PET film were prepared at ambient temperature under a $(CH_3)_4Sn(TMT: tetra-methyl tin)-H_2-O_2$ atmosphere in order to obtain transparent conductive polymer by using ECR-MOCVD(Electro Cyclotron Resonance Metal Organic Chemical Yfpor Deposition) system. The prepared $SnO_x$ thin films show generally over $90\%$ of optical transmittance at wavelength range of 380-780nm and about $1\times10^{-2\~3}ohm{\cdot}cm$ of electrical resistivity. In the present study, effects of $O_2/TMT\;and\;H_2/TMT$ mole ratio on the properties of $SnO_x$ films are investigated and the other process parameters such as microwave power, magnetic current power, substrate distance and working pressure are fixed. Based on our experimental results, the $SnO_x$ film composition ratio of Sn and O directly influences on the electrical and optical properties of the films prepared. The $SnO_x$ film with low electric resistivity and high transmittance could be obtained by controlling the process parameters such as $O_2/TMT\;and\;H_2/TMT$ mole ratio, which play an important role to change the composition ratio between Sn and O. An increase of $O_2/TMT$ mole ratio brought on the increases 0 content in the $SnO_x$ film. On the other hand, an increase of $H_2/TMT$ mole ratio lead to decreases the oxygen content in the film. The optimized composition ratio of oxygen : tin Is determined as 2.4: 1 at $O_2/TMT$ of 80 and $H_2/TMT$ of 40 mole ratio, respectively.

• Polymer(Korea)
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• v.34 no.1
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• pp.38-44
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• 2010

Core-shell particles of inorganic/organic pair were synthesized from $CaCO_3$ absorbed sodium dodecyl benzene sulfonate(SDBS) surfactant. Shell components were synthesized by sequential emulsion polymerization. Various monomers were used as shell components such as methyl methacrylate(MMA), ethyl acrylate(EA), butyl acrylate(BA), and styrene(St). Ammonium persulfate(APS) was used as an initiator and 2-ethylhexyl acylate(2-EHA) was used as a functional monomer, In the $CaCO_3$/organic core-shell particle polymerization, $CaCO_3$ absorbed surfactant SDBS of 0.5 wt% was prepared first and then core $CaCO_3$ was encapsulated by emulsion polymerization. 0.1 wt% of APS was added sequentially to minimize the formation of new monomer particle during shell polymerization. The structure of inorganic/organic core-shell particles were characterized by measuring the decomposition degree of $CaCO_3$ using HCl solution, thermogravimetric analyzer, scanning electron microscope, and transmission electron microscope.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.10
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• pp.865-871
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• 2016

In recent years, traditional scaffold fabrication techniques such as gas foaming, salt leaching, sponge replica, and freeze casting in tissue engineering have significantly limited sufficient mechanical property and cell interaction effect due to only random pores. Fused deposition modeling is the most apposite technology for fabricating the 3D scaffolds using the polymeric materials in tissue engineering application. In this study, 3D slurry mould was fabricated with a blended biphasic calcium phosphate (BCP)/Silica/Alginic acid sodium salt slurry in PCL mould and heated for two hours at $100^{\circ}C$ to harden the blended slurry. 3D dual-pore BCP/Silica scaffold, composed of macro pores interconnected with micro pores, was successfully fabricated by sintering at furnace of $1100^{\circ}C$. Surface morphology and 3D shape of dual-pore BCP/Silica scaffold from scanning electron microscopy were observed. Also, the mechanical properties of 3D BCP/Silica scaffold, according to blending ratio of alginic acid sodium salt, were evaluated through compression test.

• Polymer(Korea)
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• v.28 no.4
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• pp.344-351
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• 2004

Poly(ethylene glycol)-based diblock and triblock polyester copolymers stimulating to temperature were studied as injectable biomaterials in drug delivery system because of their nontoxicity, biocompatibility and biodegradability. We synthesized the diblock copolymers consisting of methoxy poly(ethylene glycol) (MPEG) (M$_{n}$=750 g/mole) and poly($\varepsilon$-caprolactone) (PCL) by ring opening polymerization of $\varepsilon$-CL with MPEG as an initiator in the presence of HCl . Et$_2$O. The aqueous solution of synthesized diblock copolymers represented sol phase at room temperature and a sol to gel phase transition as the temperature increased from room temperature to body temperature. To confirm the in vivo gel formation, we observed the formation of gel in the mice body after injection of 20 wt% aqueous solution of each block copolymer. After 2 months, we observed the maintenance of gel without dispersion in mice. In this study, we synthesized diblock copolymers exhibiting sol-gel phase transition and confirmed the feasibility as biomaterials of injectable implantation.n.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.119-127
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• 2014

The application of sulfur polymer emulsion (SPE) as an acrylate substitute for semi-rigid pavement grout was evaluated, and the performance improvement by employing PVA fibers were also evaluated. The result indicated that the filling ratio of semi-rigid pavement material decreased as the fiber content increased, but it was measured to be 92~94% in every mixing condition, which satisfies the target performance, 90%. The maximum Marshall stability value of semi-rigid pavement material was measured to be 25.4 kN, which is about 4.7 times higher than the Korean Standard required for semi-rigid pavement material, 5.0 kN. The dynamic stability evaluation of semi-rigid pavement material indicated that the resistance to deformation from the wheel tracking test was improved by an SPE substitution, and in every mixing condition, the deformation converged to a constant value after 45 minutes with the same dynamic stability of 31,500 times/mm. The strain at the flexural failure was about 0.53%, which shows superior rigidity to asphalt pavements. The examination of abrasion resistance and impact resistance showed that the loss ratio was 9.8~6.0% in every mixing condition, which indicates a good abrasion resistance. Also, when fiber content ratio was 0.3%, the impact resistance was 2.82 times higher compared to plain (i.e., when fibers were not added). In the limited range of this study, an SPE substitution ratio of 30% was found to be an optimal level considering the mechanical and durability performance. In addition, it is thought that semi-rigid pavement material with superior performance could be manufactured if fiber content ratio up to 0.3% is applied depending on the purpose of use.