• Title/Summary/Keyword: 팽창

Search Result 3,289, Processing Time 0.027 seconds

Preparation and Characterization of Si-loaded Expanded Graphite as Anode Material for Lithium ion Batteries (실리콘이 함유된 팽창흑연의 제조 및 전기화학적 특성)

  • Kim, Eunkyung;Ji, Mijung;Jung, Sunghun;Choi, Byunghyun
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.103.2-103.2
    • /
    • 2011
  • 리튬이차전지의 음극물질로서 상용화되고 있는 탄소재료중 흑연은 전기자동차에 적용하기에는 낮은 용량과 나쁜 출력특성을 갖고 있어 지금보다 두배이상의 용량과 출력특성이 좋은 음극소재의 개발이 필요하다. 또 다른 음극물질로 실리콘은 흑연에 비해 월등히 높은 이론용량을 나타내고 있지만 실리콘이 리튬이온과 만나면 부피가 4배이상 팽창하여 사이클이 진행될수록 충방전 용량이 급격히 감소하게 된다. 그래서 본 연구에서는 이 두 음극소재를 상호보완하기 위해 천연흑연을 산처리 과정을 통해 제조된 팽창흑연을 매트릭스로 사용하여 팽창흑연에 실리콘을 충진 시키는 연구를 진행하였다. 팽창흑연에 실리콘을 충진시킴으로써 1C일 때 약 650mAh/g의 용량을 나타내었으며, 50cycle이 진행된 후에도 비교적 안정한 사이클 특성을 나타내었다.

  • PDF

A Study on Compressive Strength Evaluation of the Function Expansion for Ground Subsidence Emergency Restoration (지반함몰 긴급보수를 위한 팽창기능제의 일축압축강도에 대한 연구)

  • Park, Kwang-Seok;Lee, Sang-Moon;Kim, Ju-Ho;Park, Jeong-Jun
    • Proceedings of the Korean Society of Disaster Information Conference
    • /
    • 2016.11a
    • /
    • pp.319-321
    • /
    • 2016
  • 본 논문에서는 지반함몰이 발생한 현장에 긴급복구를 위한 팽창기능제의 개발에 대한 내용이다. 현재 유동화토에 대한 기준이 없어 공동에 채워지는 채움재와 비슷한 압축강도인 0.3MPa을 기준으로 하여 흙의 일축압축시험 방법을 이용하여 실험을 진행하였다. 팽창기능제의 최적배합 실험과 팽창률에 따른 압축강도를 측정하여 뒤채움재로써의 기능 특성을 평가하였다. 실험결과, 팽창기능제 A의 경우 팽창률 750%이하에서 팽창기능제 B의 경우는 모든 실험체에서 목표 강도를 만족하였다.

  • PDF

A Study on Thermal Behaviors of Expanded Graphite/Erythritol Composites (팽창흑연/에리스리톨 복합체의 열적거동에 관한 연구)

  • Choi, Bo-Kyung;Choi, Woong-Ki;Kuk, Yun-Su;Kim, Hong-Gun;Seo, Min-Kang
    • Applied Chemistry for Engineering
    • /
    • v.25 no.5
    • /
    • pp.463-467
    • /
    • 2014
  • In this paper, the thermal behaviors of expanded graphite(EG)/erythritol composites with different contents of EG were studied. The surface and structure properties of the composites were determined by using scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD), respectively. The thermal properties were investigated by differential scanning calorimetry (DSC) and thermal conductivity (TC). As experimental results, the thermal conductivity of the composites increased with increasing the EG content. However, the latent heat was somewhat decreased in the presence of EG. We could concluded that EG was highly promising materials for improving the heat transfer enhancement and energy storage capacity of phase change materials (PCMs).

An Analytical Study on the Expansion Rates of Mortar-bars (ASTM C 227-90) for Basalt and Various Aggregates (모르타르봉 시험(ASTM C 227-90)에 의한 현무암 골재 등의 팽창률 분석 연구)

  • 정지곤;김경수
    • The Journal of Engineering Geology
    • /
    • v.13 no.3
    • /
    • pp.309-320
    • /
    • 2003
  • Since the concrete covers most structures in modern architecture and it is composed of aggregates of about 75%, the appropriate selection of aggregates is valuable for the durability of concrete. A major cause of the expansion of mortar-bar measured by ASTM C 227-90 has been accounted by the alkali-aggregate reaction. This study carried out designed experiments on some aggregates including basalt and sandstone, to classify the expansion factors into the alkali-aggregate reaction, the increase of the gel pore volume, and the interstitial water that could expand physically the cracks or foliation developed in aggregates itself. The quantitative analyses of expansion by each factor indicated that the interstitial water and/or the alkali-aggregate reaction had major roles in the concrete expansion. Thus, if the supplied aggregates have deteriorated the structural framework, it is important to investigate the exact causes through this suggested method.

The Construction of Superconcentrator Based on Linear Expander Bounds (선형 팽창기 영역에 기초한 초집중기의 구성)

  • Cho Tae-Kyung;Park Byoung-Soo
    • The Journal of the Korea Contents Association
    • /
    • v.5 no.1
    • /
    • pp.179-187
    • /
    • 2005
  • Linear order Concentrators and Superconcentrators have been studied extensively for their ability to interconnect large numbers of devices in parallel, whether in communication systems or in parallel computers. One major limitation on the efficiency of parallel computer designs has been the prohibitively high cost of parallel communication between processors and memories. Linear order concentrators, O(n), can be used to construct theoretically optimal interconnection network schemes. Existing explicitly the defined constructions are based on expanders, which have large constant factors, thereby rendering them impractical lot reasonable sized networks. It demands the construction of concentrator which uses the expander with the smaller expansion constant. This paper introduces an improvement on the method of constructing concentrators using expanders, which reduce the size of resulting concentrator built from any given expander by a constant factor.

  • PDF

An Explicit Superconcentrator Construction for Parallel Interconnection Network (병렬 상호 연결망을 위한 초집중기의 구성)

  • Park, Byoung-Soo
    • The Transactions of the Korea Information Processing Society
    • /
    • v.5 no.1
    • /
    • pp.40-48
    • /
    • 1998
  • Linear size expanders have been studied in many fields for the practical use, which make it possible to connect large numbers of device chips in both parallel communication systems and parallel computers. One major limitation on the efficiency of parallel computer designs has been the highly cost of parallel communication between processors and memories. Linear order concentrators can be used to construct theoretically optimal interconnection network schemes. Existing explicitly defined constructions are based on expanders, which have large constant factors, thereby rendering them impractical for reasonable sized networks. For these objectives, we use the more detailed matching points in permutation functions, to find out the bigger expansion constant from an equation, $\mid\Gamma_x\mid\geq[1+d(1-\midX\mid/n)]\midX\mid$. This paper presents an improvement of expansion constant on constructing concentrators using expanders, which realizes the reduction of the size in a superconcentrator by a constant factor. As a result, this paper shows an explicit construction of (n, 5, $1-\sqrt{3/2}$) expander. Thus, superconcentrators with 209n edges can be obtained by applying to the expanders of Gabber and Galil's construction.

  • PDF

Flame Retardancy and Physical Properties of Polyurethane Foam with Expandable Graphite (팽창 흑연을 포함한 폴리우레탄 폼의 난연 및 물성 변화 연구)

  • Bae, Sung-Jun;Park, Ji-Hyeon;Go, Jae-Wang;Choi, Pil-Jun;Lee, Jae-Yeon;Sur, Suk-Hun
    • Journal of Adhesion and Interface
    • /
    • v.20 no.3
    • /
    • pp.96-101
    • /
    • 2019
  • In this study, the flame retardant and physical properties of the expandable graphite/polyurethane foam composites were considered by the addition of expandable graphite. The tensile strength of expandable graphite/polyurethane foam composites decreased with the content of the expandable graphite and the analysis of cell shape by SEM has shown that as the expandable graphite content increases, the cell becomes uneven and collapses. As the results of the compressive strength, density and air permeability tests, it was found that density and as the content of the expandable graphite increased, the compressive strength of the composites increased but air permeability decreased. When the amount of expandable graphite was added at 10 phr or higher, the foam has excellent flame retardation performance. Analysis of the degree of diffraction by X-ray diffraction (XRD) showed that as the content of the expandable graphite increased, the crystal peak of the graphite appeared near $2{\theta}=26^{\circ}$.

Experimental Study on the Isobaric Thermal Expansion Coefficient Density and Zero-shear-rate Viscosity of Viscoelastic Fluid (점탄성 유체의 정압 열팽창계수, 밀도 및 전단속도 0에서의 점동에 대한 실험연구)

  • 최민구
    • The Korean Journal of Rheology
    • /
    • v.7 no.3
    • /
    • pp.181-191
    • /
    • 1995
  • 점탄성유체의 물성치들 중 정압열팽창계수 및 밀도는 자연대류 열전달 연구에 전단 속도 0에서의 점도는 점탄성유체에 대한 모델들 사용 시 필요하다. 본 연구에서는 점탄성유 체이며 마찰 감소 첨가제, 유전자 분리용액동으로 사용하는 Separan AP-273 용액의 정압열 팽창계수, 밀도 및 전단속도 0에서의 점도에대한 농도 및 온도의 영향을 조사하였다. 작동유 체의 물성치들은 10~6$0^{\circ}C$의 온도범위와 100~20,000wppm의 농도범위에서 측정되었다. 작 동유체의 물성치들에 미치는 열주기와 노화의 영향을 조사하기 위해서 정압열팽창계수와 전 단속도 0에서의 점도를 교대로 두 번씩 측정했다. 정압열팽창계수 및 밀도를 측정하는 장치 의 측정 정밀도는 증류수에 대한 측정치와 문헌에 나타난 자료를 비교하여 얻었고 이는 $\pm$ 2%이내였다. Separan AP-273용액의 정압열팽창계수 및 밀도는 증류수의 값들로 대치될수 있다. 작동유체의 정압열팽창계수와 밀도는 열주기와 노화의 영향을 받지 않았다. 낙하식 점 도계를 사용해 측정한 겉보기점도 값들을 나타내느 flow curve에서 전단속도가 0이 되는방 향으로 겉보기점도를 외삽시켜 Separan AP-273용액에 대한 전단속도0에서의 점도를 얻었 다. 정압열팽창계수 측정 전후에 측정한 작동유체에 대한 전단속도 0에서의 점도는 열주기 와 노화로 인해 퇴화되었다.

  • PDF

Thermally-Expandable Molding Process for Thermoset Composite Materials (열팽창 치공구를 이용한 열경화성 복합재료의 성형연구)

  • 이준호;금성우;장원영;남재도
    • Polymer(Korea)
    • /
    • v.24 no.5
    • /
    • pp.690-700
    • /
    • 2000
  • In this study, an elastomer-assistered compression molding process was investigated by experiments as well as modeling for the long-fiber reinforced thermoset composites. The consolidation pressure generated by fixed-volume and variable-volume conditions was thermodynamically derived for both elastomer and curing prepregs, and was compared with the pressure measured during curing of epoxy matrix. Exhibiting non-linear viscoelastic characteristics in the compressive stress-strain tests, the measured stress was well compared with a modifed KWW (Kohlrausch-Williame-Watts) equation, which is based on the Maxwell viscoelastic model. Using the developed model equations, the consolidation pressure generated by the elastomer was successfully predicted for the compression molding process of thermoset composite materials in tile closed mold system.

  • PDF