• Journal of Korean Society of Environmental Engineers
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• v.32 no.2
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• pp.201-208
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• 2010

The $SO_2$ and $NO_x$ removal with an activated coke catalyst was conducted by a two-stage reaction which first $SO_2$ was oxidized to $H_2SO_4$ and then $NO_x$ was reduced to $N_2$. But if unreacted sulfur dioxide entered in the second stage, the $NO_x$ reduction was hindered by the reaction with ammonia. In this study, experimental investigations by using lab-scale column apparatus on the product and the reactivity of $SO_2$ with ammonia over coke catalyst which was activated with sulfuric acid was carried out through ultimate analysis DTA, TGA and SEM of catalyst before and after the reaction. Also, the effect of reaction emperature on the reactivity of $SO_2$ with ammonia was determined by means of breakthrough curves with time. The obtained results from this study were summarized as following; Activated cokes were decreased carbon component and increased oxygen and sulfur components in comparison with original cokes. The products over coke catalyst were faced fine crystal of $(NH_4)_2SO_4$, which results in the pressure loss of reacting system. The order of general reactivity in terms of the reaction temperature after breakthrough for $SO_2$ was found to be $150^{\circ}C$ > $200^{\circ}C$ > $100^{\circ}C$. This was related to adsorption amounts of ammonia on the activated cokes.

• Clean Technology
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• v.24 no.3
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• pp.212-220
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• 2018

Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

• JOURNAL OF ELECTRICAL WORLD
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• s.451
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• pp.92-97
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• 2014

국내 최초의 대용량 석탄화력발전소인 삼천포화력본부(본부장 노선만)는 한국남동발전(주)의 핵심 발전소 중 하나이다. 1984년 1호기 준공이래 1998년 6호기 준공까지 약 15년에 걸쳐 총 여섯 호기가 준공되었고, 오늘날까지 30년에 걸쳐 양질의 전기를 생산해내고 있다. 특히 1,2호기는 이미 30년이상 운전하며 1980년대 이후 우리나라의 급격한 경제성장을 뒤에서 든든히 뒷받침한 효자 발전소라 아니할 수 없다. 그런데 사실 발전소가 오래됐다고 하면 환경적인 측면에서 부정적 인식이 발생할 수 있다. 하지만 삼천포화력본부는 1~6호기에 대한 환경설비(탈황 탈질)를 준공함으로써 이러한 우려도 불식시켰다. 여기에 최근에는 친환경 발전소로도 명성이 높다. 해양소수력, 태양광 등 신재생발전설비들을 차례로 준공, 운영하면서 기존 석탄화력발전소의 차세대 운영 모델을 제시하고 있는 것이다. 석탄화력발전소의 바로미터로 떠오른 삼천포화력본부를 소개한다.

• Journal of environmental and Sanitary engineering
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• v.10 no.3
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• pp.99-104
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• 1995

The objective of this study was to investigate the effect on denuclearization and decertification of flue gas by utilizing Mg( OH)$_{2}$ and NaOH as reagents in industrial boiler. We used packed absorber with Tellerette in all cases. And pH of circulation solution, rate of liquid per gas in absorber, COD concentration by pH variation in oxidation basin were inves- tigated. The following conclusions were obtained from experimental results: 1. Concerning running cost for reagents, Mg( OH)$_{2}$ reagent for treatment of flue gas was more economical than NaOH. 2. While Mg( OH )$_{2}$ and NaOH as absorbents were used, then the ratio of denuclearization was 96 and 97% respectively and nitrification was recorded 29 and 25% . 3. In this absorption tests the optimum condition for ratio of liquid per gas, pH and nonregenerable salt concentration of circulation solution were 3.6ℓ /Nm$^{3}$, 6.0, 0.5∼1.0% respectively, 4. Initial COD in oxidation basin was 800 ∼ 1,00099ut after adjusting to pH 7.0, COD of effluent water was less than 20ppm.

• Journal of Energy Engineering
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• v.8 no.1
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• pp.150-158
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• 1999

본 연구는 저온플라즈마를 이용하여 배기가스중의 SOx와 NOx를 동시에 처리하는 공정을 개발하는 것으로서, 최적의 반응제 선정과 효율적인 공정의 구성을 위해 SOx, NOx와 반응제와 반응기구를 밝히고자 하였다. 실험은 1.0 N㎥/h의 모사가스를 이용한 기초실험과 20 N㎥/h의 실제 연소가스를 이용한 실험으로 진행되었으며, 반응제로는 NH3와 파리핀계 및 올레핀계 탄화수소를 사용하였다. NH3를 반응제로 한 SO2 제거반응은 비플라즈마 조건에서는 NH4HSO3, 플라즈마 조건에서는 (NH4)2SO4의 생성반응이었고, 두 조건 모두 높은 제거율을 나타냈다. 반응제를 사용하지 않은 플라즈마 조건에서 SO2는 환원반응이 일어나고 O2 농도의 증가는 역반응을 증가시키는 화학평형에 의해 SO2의 제거율이 감소되었다. 플라즈마 조건에서 NO는 O2농도가 낮은 경우는 NO의 환원반응이 주로 일어나고, O2 농도가 높을 경우는 산화반응이 지배적이었다. 올레핀계 탄화수소는 플라즈마 조건에서 NO 산화 반응에 탁월한 효과를 보였을 뿐만 아니라 SO2 제거에도 효과를 보여 최대 40%의 제거율을 나타냈으며, NH3의 사용을 줄일 수 있음을 확인하였다.

• Proceedings of the KIEE Conference
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• 1998.07e
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• pp.1806-1808
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• 1998

Tests of pilot-scale plasma DeSOx-DeNOx system using pulsed streamer corona were carried out. The system consists of the reactor with wire-plate electrodes the $30kW_{max}$. MPC type pulse generator, and $1MW_{th}$ pulverized coal combustor as a flue gas source. $NH_3$ and $C_2H_4$ were used to enhance the removal rate. The experimental result on the removal efficiency of SOx/NOx and on the effect of the additives was presented in this paper.

• Proceedings of the KIPE Conference
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• 2009.11a
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• pp.237-239
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• 2009

This paper presents a new developed 160kV-120kW Class MPC (magnetic pulse compressor) power supply for DeNOx, DeSOx system. The circuit consists of N-series connected CCPS (capacitor charging power supply) and MPC Tank. The MPC power supply developed compared to the conventional LC resonant type has many advantage, it was verified reliability of a product by module, simulator and tank connection test. Now, the developed MPC power supply is installed POSCO sintering plant for DeSOx, DeNOx system.

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.157-159
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• 2008

Generally, Capacitor charging power supply (CCPS) consist of the full-bridge inverter, LC resonant tank and capacitance load. The multi-connection systems are normally used for high voltage or high power application. In this paper, conventional parallel operation resonant type and proposed series operation PWM type CCPS for pulse corona occurrence of DeSOx, DeNOx system using magnetic pulse compressor make a comparison. The effect of proposed CCPS is verified by circuit characteristics analysis of parallel operation resonant type and series operation PWM type, and it is confirmed by simulation result.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1910-1912
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• 1996

This paper presents the results of laboratory experimentals to remove $SO_2$ and $NO_x$ by a pulsed corona discharge in the wire-plate reactor. A rotating spark gap switch was used to generate the pulse by chewing the dc high voltage. Repetition frequency of the pulse was 60Hz and rising time of 50ns. The photo pictures of positive streamer corona taken by ICCD camera, pulse voltage and current were measured using a digital oscilloscope. Simultaneous effects of $C_{2}H_{4}$ injection and heterogeneous chemical reactions on nonthermal plasma process to remove $SO_2$ and $NO_x$ from flue gas were investigated in the present study

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.04a
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• pp.235-236
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• 2000

배기가스의 처리를 위한 펄스 코로나 방전공정은 질소 산화물 및 황산화물을 동시에 제거할수 있는 효율적인 공정으로 알려져 있으며 현재 국내외에서 많은 연구들이 수행되고 있는 공정이다. 플라즈마 상태를 이용하는 펄스 코로나 방전공정에서 운전변수들의 변화는 플라즈마 특성을 변화시켜 공정의 효율성에 영향을 미치게 된다. 특히 플라즈마의 특성에 영향을 미치는 여러 가지 변수들 사이에는 강한 상호의존성을 갖고 있으므로 하나의 운전변수가 미치는 영향에 관한 정확한 규명은 매우 복잡하고 어려운 일이다. (중략)