• Title/Summary/Keyword: 탄소수 분포

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Transbilayer Effects of n-Alkanols on the Fluidity of Model Membranes of Total Lipids Extracted from Synaptosomal Plasma Membrane Vesicles (n-Alkanols가 소의 대뇌피질 Synaptosomal Plasma Membrane Vesicles로부터 추출 제제한 총지질 인공세포막 이중층간에 형성된 비대칭적 유동성에 미치는 비대칭적 영향)

  • Yun, Il;Kang, Jung-Sook
    • The Korean Journal of Pharmacology
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    • v.28 no.2
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    • pp.191-199
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    • 1992
  • Selective quenching of 1,6-diphenyl-1,3,5-hexatriene (DPH) by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of model membranes of total lipids (SPMVTL) extracted from synaptosomal plasma membrane vesicles (SPMV). The polarization (P), anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the inner monolayer were 0.031, 0.025, 0.033, and 0.070, respectively, greater than calculated for the outer monolayer of SPMVTL. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the effects of n-alkanols on the individual monolayer structure of SPMVTL. n-Alkanols fluidized the hydrocarbon region of bulk SPMVTL, and the potencies of n-alkanols up to 1-nonanol increased with carbon chain length. It appears that the potencies in bilayer fluidization increase by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further increase in hydrocarbon length resulted in a decrease in pharmacological activity. The n-alkanols had greater fluidizing effects on the outer monolayer as compared to the inner monolayer of SPMVTL, even though these selective effects tended to become weaker as carbon chain length increased. Thus, it has been proven that n-alkanols exhibit selective rather than nonselective fluidizing effects within transbilayer domains of SPMVTL.

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Geochemistry of Shallow gases taken from the core sediments in the southeastern Ulleung Basin (울릉분지 남동부 시추 퇴적물 내에 함유되어 있는 천부가스의 특성)

  • Lee Young joo;Huh Shik;Kwak Young hoon;Kim Hag ju;Chun Jong Hwa;Jun Sang Joon;Yoo Hai Soo
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.35-40
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    • 1999
  • Chemical and isotopic compositions of hydrocarbon gases were analyBed to characterize the properties of the shallow gases distributed in the southeastern part of the Ulleung Basin, offshore Korea. Sediments from the core were also analyzed to determine the characteristics and relationship to shallow gases. Hydrocarbon gases in the sediments consisted of methane (697.9-6054.4 ppm), ethane, propane, butane and hexane. The total carbon content of the sediments ranges from 1.84fe to $5.11{\%}$ and the total organic carbon content ranges from $0.29{\%} \;to\; 2.65{\%}$. High C/N ratio (>10) indicates that input of terrestrial organic matter was prevalent at the time of deposition. The methane content and stable isotopic data indicate that hydrocarbon gases from the sediments are identified to be thermogenic gas and mixture of both biogenic and thermal gases. Based on the Rock-Eval and carbon isotopic data, the level of thermal maturity of organic matter in the sediments $(Tmax<425^{\circ}C)$ is lower than that of gas. It suggests that thermal gases in the sediments migrated from the deeper sediments than the penetrated depth.

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Hyperbaric Oxygen Treatment in Acute CO Poisoning (일산화탄소중독치료(一酸化炭素中毒治療)에 있어 고압산소요법(高壓酸素療法)의 효과(效果)에 관(關)한 연구(硏究))

  • Yun, Dork-Ro;Cho, Soo-Hun
    • Journal of Preventive Medicine and Public Health
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    • v.16 no.1
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    • pp.153-156
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    • 1983
  • 1950년(年) 이후(以後) 무연탄(無煙炭)으로 만든 연탄(煉炭)을 취사(炊事), 난방용(煖房用)으로 가정(家庭)에서 광범위(廣範圍)하게 사용(使用)하게 되면서 연탄(煉炭)가스내(內)의 일산화탄소(一酸化炭素)로 인(因)한 중독사고(中毒事故)가 빈발(頻發)하여 심각(深刻)한 국민보건(國民保健)의 문제(問題)가 되어왔다. 저자(著者)들의 실태조사(實態調査)(1975년도(年度))에 의(依)하면 서울특별시일원(特別市一圓)에 있어 일산화탄소중독(一酸化炭素中毒)의 년간발생(年間發生)은 인구(人口), 10만당(萬當) 경증(輕症) 260명(名), 혼수상태(昏睡狀態)의 중증중독(重症中毒) 45명(名), 사망(死亡) 1명(名)으로 위험인구(危險人口)를 3,000만명(萬名)으로 하였을 때 전국적(全國的)으로 일산화탄소중독(一酸化炭素中毒)의 추정발생수(推定發生數)는 년간(年間) 경증(輕症) 78만명(萬名), 중증(重症) 13만(萬) 5천명(千名), 사망(死亡) 3,000명(名)으로 그 피해(被害)의 규모(規模)가 100만을 육박(肉薄)하는 가공(可恐)할 수자(數字)를 보여주고 있다. 저자(著者)들은 이러한 심각(深刻)한 국민보건(國民保健)의 문제(問題)를 우선(于先) 실천가능(實踐可能)한 제이차예방(第二次豫防)에 역점(力點)을 두어 고압산소요법(高壓酸素療法)을 보급(普及)할 목적(目的)으로 일인용고압산소장치(一人用高壓酸素裝置)를 개발(開發)하고 1969년(年) 1월(月)에 서울대학교병원(大學校病院)에 고압산소치료실(高壓酸素治療室)을 개설(開設)하여 급성일산화탄소(急性一酸化炭素) 중독환자(中毒患者)에 대(對)한 응급치료(應急治療)를 실시(實施)하여 1978년(年)까지 10년간(年間)의 치료결과(治療結果)를 요약(要約)한바 다음과 같다. 1. 총치료환자수(總治療患者數)는 2,242명(名)이고 회복(回復)된 수(數)는 2,202명(名)으로 98.2%의 회복률(回復率)을 보였다. 2. 계절적(季節的)으로 10월(月)에서 4월(月)까지가 연중최성기(年中最盛期)이나 5월(月)에서 9월(月)까지도 적지않은 환자(患者)의 발생(發生)을 볼 수 있었다. 3. 연령별분포(年齡別分布)를 보면 15세(歲)${\sim}29$세군(歲群)이 전체환자(全體患者)의 반이상(半以上)인 52.7%를 차지하고 있고 $0{\sim}14$세군(歲群)은 인구비(人口比)에 대해 발생(發生)이 훨씬 적은 결과(結果)를 보이고 있다. 4. 도착시간별(到着時間別) 입원율(入院率)은 오전(午前) 10시이후(時以後) 도착군(到着群)서부터는 입원율(入院率)이 급증(急增)하는데 이는 병원도착(病院到着)이 늦일수록 당일회복(當日回復)이 되지못하고 입원가료(入院加療)하게 됨을 나타내주는 결과(結果)라 할 수 있다. 5. 병발증(倂發症)으로는 급성욕창, 폐렴(肺炎) 및 신경학적(神經學的) 이상등(異常等)의 소견(所見)을 많이 볼 수 있었다.

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Influences of Water Level and Vegetation Presence on Spatial Distribution of DOC and Nitrate in Wetland Sediments (수심의 정도와 식생의 유무에 따른 인공습지 토양 내 유기탄소와 질산염의 공간적 분포)

  • Seo, Ju-Young;Song, Keun-Yea;Kang, Ho-Jeong
    • Journal of Wetlands Research
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    • v.12 no.2
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    • pp.59-65
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    • 2010
  • Wetlands are a well known ecosystem which have high spatial-temporal heterogeneity of chemical characteristics. This high heterogeneity induces diverse biogeochemical processes, such as aerobic decomposition, denitrification, and plant productivity in wetlands. Understanding the dynamics of dissolved organic carbon (DOC) and inorganic nitrogen in wetlands is important because DOC and inorganic nitrogen are main factors controlling biological processes in wetlands. In this study, we assessed spatial distribution of DOC and inorganic nitrogen with relation to the different hydrology and vegetation in created wetlands. Both DOC and nitrate contents were significantly higher in vegetated areas than open areas. Different water levels also affected DOC contents and their quality. Average DOC contents were $0.37mg{\cdot}g^{-1}$ in deep riparian (DR) and $0.31mg{\cdot}g^{-1}$ in shallow riparian (SR). These results appeared to be related to the interaction between carbon supply by vegetation and microbial decomposition. On the other hand, inorganic nitrogen contents were not affected by water level differences. This result indicates that presence/absence of vegetation could be a more important factor than hydrology in the spatial dynamics of inorganic nitrogen. In conclusion, we observed that vegetation and hydrology differences induced spatial distribution of carbon and nitrogen which are directly related to biogeochemical processes in wetlands.

Organic carbon behavior and distribution in the Mankyoung River Estuary (만경강 하구역의 유기탄소 거동 및 분포)

  • Park Jun-Kun;Kim Eun-Soo;Kim Kyung-Tae;Cho Sung-Rok;Park Yong-Chul
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.3
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    • pp.131-140
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    • 2006
  • Suspended particulate matter and organic carbon were measured in the Mankyoung river estuary in February, May, July and August 2003. There was a large variance in river discharge between the dry season of February and May and the wet season of July and August. The influx of dissolved organic carbon into the estuary was $8.16{\times}10^2tonC\;month^{-1}$ in the dry season and $5.77{\times}10^3tonC\;month^{-1}$ in the wet season. The influx of particulate organic carbon was $9.37{\times}10^2tonC\;month^{-1}$ and $3.14{\times}10^4tonC\;month^{-1}$ in the dry and wet seasons, respectively. Especially, dissolved organic carbon in the northern part of the site inside the dike was increased in July when torrential rainfall was high. In the research, the distribution of dissolved organic carbon showed conservative behavior with the salinity gradient in the estuary, suggesting that physical mixing between seawater and freshwater dominates the distribution pattern of the dissolved organic carbon in the system. However 60 to 90% of the particulate organic carbon introduced into the estuary was removed from the surface water at the upper estuarine mixing zone of low salinities, showing non-conservative behavior similar with suspended particulate matte r. The completion of the Saemangum Dike is likely to inhibit the exchange of materials between open sea and the Mankyoung estuary. This suggests that the oxidation of organic carbon in the bottom of the estuary may exhaust dissolved oxygen in the confined environment.

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Investigation on the Distribution of Native Oxide in GaAs Wafer Using Angle-resolved X-ray Photoelectron Spectroscopy (각분해 X-선 광전자 분광기를 이용한 GaAs 자연 산화막의 분포연구)

  • Sa, Seung-Hun;Gang, Min-Gu;Park, Hyeong-Ho;O, Gyeong-Hui;Seo, Gyeong-Su
    • Korean Journal of Materials Research
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    • v.7 no.6
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    • pp.484-491
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    • 1997
  • 본 연구에서는 비파괴적 분석 기법인 각분해 X-선 광전자 분광기(Angle-Resolved X-ray Photoelectron Spectros-copy)를 이용하여 GaAs 표면 자연 산화막의 깊이에 따른 화학적 결합 상태 및 조성 분석을 수행하였다. GaAs의 벽개면 및 Ar이온으로 식각된 면을 기준시료로 하여 각 원자의 광전자 강도(intensity)를 보정해주는 인자인 ASF(atomic sensitivity factor)의 최적값을 구하였다. 이륙각에 따라 발생되어지는 각 원소의 피이크 분해와 정확한 ASF의 보정을 통한 각 원소의 실험적인 결과를 이용하여 깊이 방향으로의 조성 분포 모델을 세웠으며, 이론적인 강도와의 상호비교로부터 표면 오염층의 구조는 표면으로부터 탄소층, Ga-oxide와 As-oxide로 이루어진 oxides층, As-As결합의 elemental As층 및 GaAs기판의 순으로 존재함을 알 수 있었다. 또한 GaAs 표면에 존재하는 오염층은 35.8$\pm$3.3 $\AA$이었다. 또한 위 결과로부터 분석깊이 영역에서 원자수의 비로써 정의되는 의미로서의 실질조성을 구하였는데 단지 특정 이륙각에 따라 일반적인 ASF로 보정된 표면조성 결과는 표면 상태를 명확히 표현해주지 못함을 확인할 수 있었다.

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Analysis of Electric Field Distribution of PVDF Electrospinning According to Electrospinning Conditions (전기방사 조건에 따른 PVDF 방사의 전기장 분포 해석)

  • Yonjo Jung;Minsang Lee;Honggun Kim
    • Journal of The Korean Institute of Defense Technology
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    • v.5 no.4
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    • pp.9-15
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    • 2023
  • In this study, electric field analysis was conducted for each process as a preliminary step in the design of the electrospinning device to apply the electrospinning PVDF nanofibers to increase the filtering effect of insect screens. In the electrospinning analysis using a single nozzle, it was confirmed that there was a decrease in the electrostatic field strength as the tip's size decreased, an increase in the voltage, and no effect depending on the TCD distance. In addition, it was confirmed that the closer the distance between tips, the more electric field interference occurs, and this was found to have a more significant effect on the tip located in the center with tips on both sides. Therefore, based on these analytical results, it is believed that an increase in production speed can be expected by establishing an efficient process line by confirming the radiating area of the collector and designing the spacing between multi-nozzles through actual experiments.

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온도분포가 이동하는 액체금속로 원통용기의 열적 라체팅 해석

  • Lee, Hyeong-Yeon;Kim, Jong-Beom;Lee, Jae-Han;Koo, Kyung-Hoe;Yoo, Bong;Gwak, Dae-Yeong;Im, Yong-Taek
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.235-240
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    • 1996
  • 본 연구에서는 고온의 천이 열하중을 받는 304 SS 재질의 액체금속로 원통용기에 대하여 진행성 변형기구인 열적 라체팅(thermal ratcheting) 변형거동을 해석하였다. 재료의 반복 소성을 나타내는 구성식으로서 Chaboche모델을 이용하였으며 이 모델의 적용을 위하여 ABAQUS의 사용자 프로그램을 개발하였다. 열천이 과정이 반복되는 동안에 축방향의 온도분포 이동에 따른 탄소성 해석을 수행한 결과 소성변형이 각 싸이클마다 누적되어 점진적 변형이 일어났으며 이 해석결과를 시험치와 비교함으로써 해석의 타당성을 검토하였다. 반복 소성거동에 대한 Chaboche 모델을 이용하면 천이 열하중을 받는 304 SS. 재질의 고온구조물에 대하여 라체팅 거동을 정량적으로 평가 할 수 있는 것으로 나타났다.

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Comparison of Three Kinds of Methods on Estimation of Forest Carbon Stocks Distribution Using National Forest Inventory DB and Forest Type Map (국가산림자원조사 DB와 임상도를 이용한 산림탄소저장량 공간분포 추정방법 비교)

  • Kim, Kyoung-Min;Roh, Young-Hee;Kim, Eun-Sook
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.4
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    • pp.69-85
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    • 2014
  • Carbon stocks of NFI plots can be accurately estimated using field survey information. However, an accurate estimation of carbon stocks in other unsurveyed sites is very difficult. In order to fill this gap, various spatial information can be used as an ancillary data. In South Korea, there is the 1:5,000 forest type map that was produced by digital air-photo interpretation and field survey. Because this map contains very detailed forest information, it can be used as the high-quality spatial data for estimating carbon stocks. In this study, we compared three upscaling methods based on the 1:5,000 forest type map and 5th national forest inventory data. Map algebra(method 1), RK(Regression Kriging)(method 2), and GWR(Geographically Weighted Regression)(method 3) were applied to estimate forest carbon stock in Chungcheong-nam Do and Daejeon metropolitan city. The range of carbon stocks from method 2(1.39~138.80 tonC/ha) and method 3(1.28~149.98 tonC/ha) were more similar to that of previous method(1.56~156.40 tonC/ha) than that of method 1(0.00~93.37 tonC/ha). This result shows that RK and GWR considering spatial autocorrelation can show spatial heterogeneity of carbon stocks. We carried out paired t-test for carbon stock data using 186 sample points to assess estimation accuracy. As a result, the average carbon stocks of method 2 and field survey method were not significantly different at p=0.05 using paired t-test. And the result of method 2 showed the lowest RMSE. Therefore regression kriging method is useful to consider spatial variations of carbon stocks distribution in rugged terrain and complex forest stand.

Combustion Synthesis of Fibrous Silicon Carbide (고온연소합성을 이용한 섬유형 탄화규소의 합성)

  • Choi, Yong
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.551-559
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    • 1998
  • 장경비가 큰 탄화규소를 탄소와 규소간의 고온연소반응으로 제조하기 위하여 공정변수에 따른 연소거동과 미세조직의 변화를 조사하였다. 연소합성된 생성물은 주로 $\beta$-SiC이며 연소반응이 충분히 진행되지 못하였을 경우에는 미량의 잔류 반응물과 $\alpha$-SiC가 관찰되었다. 생성된 탄화규소의 평균입도는 약 5$\mu\textrm{m}$로 작았으며, $1300^{\circ}C$ 이상의 예열 조건에서 장경비가 30이상인 탄화규소를 합성할 수 있었다. 압분 강도가 69MPa인 분말의 성형체에서 평균 연소 온도와 평균 전파 속도는 각각 약 $1425^{\circ}C$와 2.1mm/sec 범위이며, 연소 온도는 흑연 분말을 사용하였을 경우가 탄소 섬유를 사용한 경우보다 약 $10^{\circ}C$ 높았다. 연소 반응을 임의로 중단시킨 시편의 계면을 EDX와 Auger 전자 현미경으로 분석한 결과 상호 확산층이 관찰되지 않았다. 이는 탄화규조의 연소합성이 용해-석출 모델에 의하여 진행됨을 시사한다. 예열 온도에 따른 연소 반응 중의 온도 분포를 유한 요소법으로 해석함으로써 $2500^{\circ}C$의 초기 연소 개시 온도에 대하여 예열 온도 $300^{\circ}C$에서는 연소파가 거의 전파할 수 없으며 예열 온도가 $1300^{\circ}C$에서는 시료 내부에 자체 전파가 가능한 $2000^{\circ}C$이상의 온도 구역이 존재함을 알았다.

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