• Title/Summary/Keyword: 층간온도

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Synthesis of Zeolite A from Natural Bentonite in Korea (국산 천연 벤토나이트로부터 제올라이트 A의 합성)

  • 심미자;김상욱
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.897-902
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    • 1995
  • To get optimum synthetic condition of zeolite A made from Kampo natural bentonite, the effects of reactant mole fraction, reaction temperature, and reaction time were studied. The source of silica was 40% -H₂SO₄ treated natural bentonite and that of alumina was synthesized NaA1O₂. The reactant was mixed at the mole ratio of SiO₂ : Al₂O₃ : Na₂O : H₂O=2 : 1 : 1 : 25 and 2 : : 1 : 37. The mixed reactants were aged at 60℃ for 1hr and reacted at 90℃, 100℃ and 120℃ for 1, 3 and 5hr. The optimum synthetic condition was SiO₂ : A1₂O₃ : Na₂O H₂O=2 : 1 : 1 : 30 at 90℃ for 3hr and the synthetic zeolite A prepared by this optimum condition showed the dehydration temperature at 79.2℃ and lattice trans-formation at 503.3℃. The wright loss of water was 5.9%.

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Dynamic Change of the DO Concentration by Continuous Monitoring in Artificial Lake (인공 호소의 연속모니터링을 통한 DO 동적변화 규명)

  • Choi, Sunhwa;Lee, Seungheon;Park, Hyungseok
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.494-494
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    • 2017
  • 국내의 호소는 대부분이 농업용수 공급을 목적으로 설치된 인공 호소이다. 최근 이상기후 및 유역 오염원 증가로 호소의 수질오염도가 증가 추이에 있으며, 특히 하절기 외기온도 상승과 함께 녹조 대량발생, 어류 집단폐사 등 수질오염사고가 야기되고 있다. 이러한 수질오염사고는 호소의 지역적 특성으로 인한 여러 가지 원인이 있겠지만 직접적인 원인으로는 호소의 산소 고갈에 기인된다. 본 연구에서는 농업용 호소의 수온, DO, EC 등에 대한 일주기 및 계절적 동적변화를 규명하여 호소의 수질개선대책수립에 활용하고자 하였다. 연구대상 지구는 경기도 시흥시에 소재하고 있는 M 농업용 저수지이며, 2015년 6월 4일부터 9월 22일까지 수온, DO, EC을 측정할 수 있는 연속 자동측정장치를 설치하였고, 측정지점은 저수지 수심을 상(바닥층에서 1.5m 상부), 중(바닥층에서 1.0m 상부), 하(바닥층에서 0.5m 상부)로 구분하여 각각 측정하였다. 호소의 수온은 일주기로 수온성층 형성과 대류혼합이 반복되었으며, 상 하층간의 수온 차이가 평균 $1.4^{\circ}C$, 최대 $5.0^{\circ}C$의 차이를 보였다. 또한 강우가 발생한 이후에는 일시적으로 저수지 상 하 층간 수온 차이가 거의 없는 것으로 나타났는데, 이는 강우에 의한 수체의 수직혼합으로 저수지 전체의 물질순환에 영향을 미친 것으로 판단된다. 호내 DO 농도는 일(day) 주기 동안 농도변화가 크게 나타났으며, 여름철 무강우 기간에는 저수지 바닥층의 평균 DO 농도가 약 0.5mg/L로 거의 무산소 상태가 지속되는 것으로 관측되었다. DO는 기온이 낮아지거나 강수가 발생할 때 대류에 의한 수직혼합에 의해 간헐적으로 회복되다가 다시 고갈되는 현상이 반복되는 것으로 나타났다.

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Evaluation of Physical and Mechanical Properties based on Liquid Composite Molding (액상성형공정별 물리적/기계적 특성 비교 평가)

  • Park, Dong-Cheol;Kim, Tai-Gon;Kim, Seung-Hyeok;Shin, Do-Hoon;Kim, Hyeon-Woo;Han, Joong-won
    • Composites Research
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    • v.31 no.6
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    • pp.304-310
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    • 2018
  • Autoclave process has been remaining as one of the most robust and stable process in fabricating structural composite part of aerospace industry. It has lots of advantages, however exhibits some disadvantages or limitations in capital investment and operation. Recently, there have been various Out-of-Autoclave process being researched and developed to overcome those limitations. In this study, laminate specimens were fabricated using LCM (Liquid Composite Molding) process, regarded as one of potential OoA process. DB (Double bagging), CAPRI (Controlled Atmospheric Pressure Resin Infusion), VAP (Vacuum Assisted Process) and Autoclave process were used for laminate specimens. Void content, Thickness, Tg (Glass Transition Temperature), ILSS (Interlaminar Shear Strength) and Flexural strength properties were evaluated for comparison. It is verified that Autoclave based specimen has uniform thickness distribution, the lowest void content and outstanding mechanical properties. And, CAPRI based specimen exhibits relatively good physical and mechanical properties over DB and VAP based specimen and comparable mechanical properties with autoclave based specimen.

Decomposition of EVA(Ethylene vinyl acetate) used as an adhesion of photovoltaic(PV) module by ultrasonic irradiation in bath-type cleaner (Bath-type 초음파(超音波) 세척기(洗滌器)를 이용(利用)한 태양전지모듈 접착제(接着劑) EVA(Ethylene Vinyl Acetate) 분해특성(分解特性))

  • Kim, Young-Jin;Lee, Jae-Ryeong
    • Resources Recycling
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    • v.20 no.6
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    • pp.50-55
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    • 2011
  • Using ultrasonic irradiation, the separation and recovery of PV cell, made of silicon wafer, from PV module was carried out through selective decomposition of EVA used as an interlaminated binder. The ultrasonic cleaner of bath-type (Output: 130 W, Frequency: 40 kHz) was used as an ultrasonic apparatus in this research. With the fixed distance of 2 cm, from ultrasonic generator to PV cell, the experiment of EVA decomposition was performed in various organic solvents such as Toluene, Trichloroethylene, O-dichlorobenzene, Benzene. And also their concentrations and temperature was changed to survey the optimum conditions. However EVA can be decomposed perfectly at $55^{\circ}C$ within 160 min in 5 M of all kinds of solvent, PV cell may be recovered with being damaged or broken severely. This damage may be resulted from the swelling of EVA in the process of decomposition. Whereas, at the condition of 5 M at $65^{\circ}C$, PV cell can be recovered with the state of minor damage or crack. This implies that the decomposition rate of EVA increases with an increase of temperature, thereby EVA can be decomposed before the swelling of EVA layer. Conclusively, it is possible for PV cell to be recovered within 40 min, at $65^{\circ}C$ in 5 M, with less damage.

Numerical Study on Inverse Analysis Based on Levenberg-Marquardt Method to Predict Mode-I Adhesive Behavior of Fiber Metal Laminate (섬유금속적층판의 모드 I 접합 거동 예측을 위한 Levenberg-Marquardt 기법 기반의 역해석 기법에 관한 수치적 연구)

  • Park, Eu-Tteum;Lee, Youngheon;Kim, Jeong;Kang, Beom-Soo;Song, Woojin
    • Composites Research
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    • v.31 no.5
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    • pp.177-185
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    • 2018
  • Fiber metal laminate (FML) is a type of hybrid composites which consist of metallic and fiber-reinforced plastic sheets. As the FML has a drawback of the delamination that is a failure of the interfacial adhesive layer, the nominal stresses and the energy release rates should be determined to identify the delamination behavior. However, it is difficult to derive the nominal stresses and the energy release rates since the operating temperature of the equipment is restricted. For this reason, the objective of this paper is to predict the mode-I nominal stress and the mode-I energy release rate of the adhesive layer using the inverse analysis based on the Levenberg-Marquardt method. First, the mode-I nominal stress was assumed as the tensile strength of the adhesive layer, and the mode-I energy release rate was obtained from the double cantilever beam test. Next, the finite element method was applied to predict the mode-I delamination behavior. Finally, the mode-I nominal stress and the mode-I energy release rate were predicted by the inverse analysis. In addition, the convergence of the parameters was validated by trying to input two cases of the initial parameters. Consequently, it is noted that the inverse analysis can predict the mode-I delamination behavior, and the two input parameters were converged to similar values.

Burial Diagenesis of Smectite in the Tertiary Marine Basin, Japan (일본 제3기 해성 퇴적분지에서의 스멕타이트 매몰 속성작용)

  • Son, Byeong-Kook
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.221-229
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    • 2006
  • Mineralogical and chemical examinations were performed on interstratified illite-smectite (I-S) minerals that occur in the mudstones from a petroleum exploration well in the Tertiary marine basin, Japan. X-ray diffraction analysis shows that component layers of illite in the interstratified I-S increase with increasing burial depth while those of smectie decrease. In addition, the randomly (R=0) interstratified illite-smectite is changed into Rp1 ordered I-S at a depth of about 4,000 m, which corresponds to the result of organic analysis and indicates a burial temperature of about $100^{\circ}C$. However, the present geothermal gradient shows that the conversion of the random I-S to R=0 ordered I-S is likely to occur at 3,000 m. This discrepancy may be interpreted by the reverse fault at 2,500 m which resulted in a deeper burial of sediments up to 1,000 m. Chemical analysis also shows the compositional variation in I-S with increasing depth: a decrease in Si and an increases in Al and K, indicating that the substitution of Al for Si in tetrahedral sheets is compensated by the addition of K to interlayers. K may be derived from K-feldspar and micas, which is present in the mudstones.

MOCVD를 이용한 자발성장 InAs 양자점의 적층 성장 시 발생하는 파장변화량 제어

  • Choe, Jang-Hui;An, Seong-Su;Yu, Su-Gyeong;Lee, Jong-Min;Park, Jae-Gyu;Lee, Dong-Han;Jo, Byeong-Gu;Han, Won-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.150-151
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    • 2011
  • 양자점 Laser Diode(LD)는 낮은 문턱전류, 높은 미분 이득을 갖으며 또한 온도변화에도 안정적이기 때문에 광통신분야에서 광원으로 양자점 LD를 사용하기 위한 연구가 계속되고 있다. 양자점은 fill factor가 낮기 때문에 양자점의 밀도를 높이거나 양자점을 적층 성장하여 fill factor를 높인다. 그러나 양자점을 적층 성장하면 각 층간의 응력, 수직적 결합, 전기적인 결합이 생기며 이는 양자점의 전기적, 광학적 특성에 영향을 미친다. 본 연구에서는 metal organic chemical vapor deposition (MOCVD)을 이용하여 InP기판 위에 자발성장 법으로 InAs 양자점을 다주기 성장하였으며 photoluminescence (PL)을 이용하여 광학적 특성을 분석하였다. precursor는 trimethylindium (TMI), trimethylgalium (TMGa), $PH_3$, $AsH_3$를 사용하였으며 carrier gas는 $H_2$를 사용하였다. InAs 양자점은 1100 nm의 파장을 갖는 InGaAsP barrier 위에 성장하였고, InAs와 InGaAsP의 성장온도는 $520^{\circ}C$이며 InAs 양자점 성장시 V/III 비는 3.66으로 일정하게 유지하였다. 그림 1은 양자점 성장시간을 0.11분으로 고정하여 3주기(A), 5주기(B), 8주기(C) 성장한 구조이며 그림 2는 양자점 성장시간을 3주기마다 0.01분씩 줄여가며 3주기는 0.11분${\times}$3(D), 6주기는 0.11분${\times}$3+0.10분${\times}$3(E), 9주기는 0.11분${\times}$3+0.10분${\times}$3+0.09분${\times}$3(F) 으로 성장한 성장구조이다. 각 성장한 시료는 PL을 이용하여 파장과 반치폭을 측정하였다. 그림 3은 양자점 성장시간을 고정한 시료 A, B, C의 PL파장과 PL반치폭 데이터이다. PL파장은 A, B, C 시료 각각 1504 nm, 1571 nm, 1702 nm이며 반치폭은 각각 140 meV, 140 meV, 150 meV이다. PL파장과 반치폭은 각각 3주기에서 6주기로 증가할 때 67 nm, 0 meV 6주기에서 9주기로 증가할 때는 131 nm, 10 meV 증가하였다. 다음 그림4는 양자점 성장시간을 조절하여 성장한 양자점 시료 D, E, F의 PL파장과 PL반치폭 데이터이다. PL파장은 D, E, F 시료 각각 1509 nm, 1556 nm, 1535 nm이며 반치폭은 각각 137 meV, 138 meV, 144 meV이다. PL파장과 반치폭은 각각 3주기에서 6주기로 증가할 때 47 nm, 1 meV 증가하였고, 6주기에서 9주기로 증가할 때는 21 nm 감소, 6 meV 증가하였다. 양자점 성장시간을 고정하여 다주기를 성장하였고 또 3주기마다 양자점 성장시간을 달리하여 다주기를 성장하였으며 PL을 이용해 광학적 특성을 연구하였다. 성장된 양자점의 PL 파장과 PL 반치폭 변화를 통해 적층구조에서 성장 주기가 늘어날수록 양자점의 크기가 증가하는 것을 확인하였고 또한 적층성장을 할 때 양자점 성장시간을 줄임으로써 양자점의 크기 변화를 제어 할 수 있었다.

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Effect of Vapor-dam Treatment and End-coating Treatment on the air Circulating oven Drying Characteristics of Green Stocks for Korean Traditional Double-headed Drum (수증기댐처리 및 엔드코팅처리가 장고용 초갈이재의 송풍오븐건조 특성에 미치는 영향)

  • Lee, Nam-Ho;Jung, Hee-Suk;Hayashi, Kazuo;Li, Cheng-Yuan;Zhao, Xue-Feng;Hwang, Ui-Do
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.17-26
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    • 2007
  • This study was conducted to investigate the effects of End-coating (CO) treatment and Vapor-dam (V) treatment on the air circulating oven drying characteristics of green stock (Paulownia tomentosa) for drum. The reduction of the weight of specimens was greatly displayed in order of control (C-NC) treatment, End-coating (C-CO) treatment, Vapor-dam (V-NC) treatment and Vapor-dam/End-coating (V-CO) treatment after the beginning of drying. The V-CO treated specimen showed smoother temperature gradient compared with the V-NC treated specimen throughout whole drying stage and there was little temperature gradient between the inner and outer part of the cylindrical stock. The C-CO treated specimen showed higher value of vapor pressure in both the inner and outer part of the cylindrical stock until the middle stage of drying, while after the middle stage of drying only the inner part of the cylindrical stock presented higher value compared with the C-NC treated specimen. The distribution of the absolute vapor pressure of the V-CO treated specimen was similar to that of the V-NC treated specimen during the initial stage of drying. However, the former showed a large distribution in order of the hollow, the outer part, the inner part of the cylindrical stock after the initial stage of drying, which was entirely different model of distribution from that of the V-NC treated specimen. Surface checks and ring failures were not observed for all of the specimens, while end checks were severely occurred for the C-NC treated specimen and the V-NC treated specimen.

CFD-based Fire Accident Impact Analysis in Clean Room for semiconductor PR Process (반도체 PR 공정의 클린룸내 CFD 기반 화재 사고 영향 분석)

  • Chun, Kwang-Su;Yi, Jinseok;Park, Myeongnam
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.35-44
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    • 2021
  • The PR (Photo Resist) process in the semiconductor process is a process that uses a mixture of flammable substances. Due to the process equipment is installed in a clean room and when flammable substances leak, there is a high risk of suffocation, fire, and explosion. It is necessary to analyze the impact of accidents that may occur during operation and to evaluate whether the safety of workers can be guaranteed. In this study, the value of radiant heat and temperature change at the monitor point set up virtual inside the clean room was confirmed through CFD simulation of 10 leak and fire scenarios using the FLACS CFD - Fire Module. A fire that occurs inside a clean room transfers high radiant heat to the inter-story structure, but its scope is quite limited, and it is unlikely that it will collapse in a single fire accident. There was no scenario in which two stairs leading to the exit were exposed to high radiant heat at the same time due to a fire accident, therefore workers were able to escape in case of a fire. In addition, it was confirmed that the level of radiant heat and temperature rise rapidly decreased as they moved downstairs. According to the API 520 standard, workers exposed to 6.31 kW/m2 of radiant heat that workers can withstand for 30 seconds were confirmed that it was possible to sufficiently escape from the inside.

Synthesis and Characterization of Layered Copper Hydroxides in Highly Concentrated Solution (고농도 용액에서 Layered Copper Hydroxides의 합성 및 특성)

  • Nam, Dae-Hyean;Choi, Choong-Lyeal;Kim, Kwang-Seop;Seo, Young-Jin;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.872-879
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    • 2010
  • Layered copper hydroxides [LCHs, $Cu_2(OH)_3{\cdot}NO_3$] has the agricultural potentials as a fungicide because of its high crystallinity, excellent anion exchange capacity, and its regular layered particle size. The study, for the first time, has synthesized LCHs in highly concentrated solution and evaluated its physicochemical properties including the crystallinity and suspension stability. Optimal synthetic condition of LCHs was determined by crystallinity and stability of suspension as follow; 1) concentrations of $Cu(NO_3)_2$ and NaOH solutions were 3.0 M respectively, 2) reaction temperature and solution pH were $25^{\circ}C$ and 6.0, respectively, and 3) aging time after reaction was 2hr. Crystallinity of LCHs enhanced with increase in pH up to 9.0. Whereas, stability of suspension was decrease by increase in crystal size. Especially, increase in reaction temperature decreased stability of suspension. XRD patterns and SEM images exhibited that LCHs had regular layered particle size with 0.2~0.8 ${\mu}m$ and high crystallinity in optimal synthetic condition. The particle size was increased with increase in reaction temperature and pH. These results showed that LCHs synthesized in highly concentrated solution exhibited high stability of suspension as well as high crystallinity suitable to their potential as a fungicide.