• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.522-532
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• 1985

The reactions of p-nitrophenyldiphenylphosphate (p-NPDPP) with anions of benzimidazole (BI) and its 2-alkyl derivatives (R-BI) are strongly catalyzed by the micelles of cetyltrimethyl ammonium bromide (CTABr). On the other hand, the first order rate constants $(k'_{R-BI^-})$ and the second order rate constants $(k_{m(R-BI^-)})$ of the reactions mediated by R-$BI^-$in the micellar pseudophase are much smaller than those mediated by $BI^-$. In order to explain the slower rates of the micellar reactions mediated by R-$BI^-$, we compared the concentration-ratios ([R-$BI^-$]/[$BI^-$]) with the first order rate constant-ratios $(k'_{R-BI^-}/k'_{BI^-})$ and the second order constant-ratios $(k_{m(R-BI^-)}/k_{m(BI^-)})$ for the reactions taking place in the micellar pseudophase. The rate constant-ratios were much smaller than the concentration-ratios. For example in a 5 ${\times}10^{-4}$M butyl-BI solution, the two ratios were 0.089 and 0.430 (for the first order) respectively, and in a $10^{-4}$M butyl-BI solution the former was 0.100 (for the second order). This predicts that the reactivities of R-$BI^-$ in the micellar pseudophase are much smaller than that of $BI^-$. Based on the values of several kinetic parameters measured for dephosphorylation of p-NPDPP mediated by R-$BI^-$, a schemetic model is proposed. Due to the hydrophobicity and the steric effect of the alkyl substituents, these groups would penetrate into the core of the micelle for stabilization by van der Waals interaction with long cetyl groups of CTABr. Consequently, the movements of R-$BI^-$ bound to the micelle should be restricted, leading to decreased collison frequencies between the nucleophiles and p-NPDPP. We refer this as an "anchor effect". This effect became more predominent when a larger alky group in R-BI was employed and when a greater concentration of R-BI was used.

• Journal of Korean Society of Transportation
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• v.18 no.6
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• pp.7-17
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• 2000

The Purpose of this study is to test the effectiveness of Special Transportation Management Zone system (TZ) when it is applied to Dongdaemoon commercial zone located in downtown Seoul. The study consists of two Parts ; the legal components of TZ and the case study on Dongdaemoon district. The case study includes the analysis of current traffic situation on the study zone, the design of implemention alternative for each component of TZ, the framework of impact analysis system, and the analysis results. The study finds, if 2,000 won mandatory parking fee on drivers parking in the buildings only with over 10 parking spaces and over 3.000$m^2$ in floor area, strong illegal parking enforcement, and Pro-hibition of parking passenger cars whose last digit plate number matches with the last digit of date, are implemented in the zone simultaneously, the traffic speed increases to 20.56km/h which is above the target set in the zone. In conclusion, we find that TZ2 can be an effective tool relieving traffic congestion in Seoul, and that it is necessary for introducing TZ in Seoul that relevant laws should be revised and expecting problems should be overcome.

• Journal of the Economic Geographical Society of Korea
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• v.23 no.1
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• pp.93-109
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• 2020

The purpose of this study is to examine the effects of industrialization and urbanization of Gwangyang Bay Region on the change of urban system and spatial structure between triangle-cities located in Gwangyang Bay, Yeosu City, Suncheon City, and Gwangyang City, one of the famous industrial zones in Korea. Large-scale development projects carried out by the central government in the Gwangyang Bay Region such as construction of the Second Oil Refinery in the mid-1960s, completion of the POSCO Gwangyang Steelworks in the mid-1980s, construction of the Gwangyang Port Container Terminal in 1987 and designation of the Gwangyang Bay Area Free Economic Zone in 2003, and EXPO 2012 Yeosu Korea, affected to changes of the urban system and spatial structure between triangle-cities in Gwangyang Bay Region. The above four-development projects transformed the urban and spatial structures between the three cities in the Gwangyang Bay Region from a mononuclear urban system centered on Suncheon to a network city system. Historically, Suncheon has served as an exclusive center in the eastern region of Jeonnam, including the Gwangyang Bay Region. However, the hosting of the 2012 Yeosu Expo Korea is reorganizing the three cities into a network-type spatial structure with the strengthening of connectivity and integration in the region. And this trend is expected to intensify in the future.

• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.5
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• pp.281-302
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• 2021

Railway projects have been consistently increasing in Korea. In relation to this trend, the mechanized tunneling using Tunnel Boring Machine (TBM) is preferably applied for mining urban areas and passing under rivers. The TBM tunneling under difficult grounds like mixed faces with high water pressure could require ground improvements for stable TBM advance or safe cutter head intervention (CHI). In this study, pre-grouting works for CHI in Daegok-Sosa railway project are presented in terms of the grouting zone design, the executions and the results, the lessons learned from the experience. It should be mentioned that the grouting from inside TBM was carried out several times and turned out to be inefficient in the project. Therefore, grouting experiences from the surface are highlighted in this study. Jet grouting was implemented on CHI points on land, while permeation grouting off shore in the Han River, which mostly allow to access the cutter head of TBM in free air with stable faces. The results of CHI works have been analyzed and the lesson learned are suggested.

• Journal of Environmental Policy
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• v.8 no.1
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• pp.31-48
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• 2009

To install and operate the Automatic Noise Monitoring Networks reasonably, which able to monitoring environmental noise continually, is an important issue for making decision to urban environment. Noise level is determined by regional environmental factors, that affected by complex urban environment. Therefore, accurate measurement of environmental noise level has top priority to establish and promote appropriate environmental policies. Currently, Automatic Noise Monitoring System is installed for grasping the environmental noise level and preparing basic data for constructing noise-reduction policies. However, this measurement data is recognized not to be able to reflect a sensory noise. The main reason is the lack of reliable measurement data and unreasonable installation site. The main point of this research ought to be the analysis of installed site of noise monitoring system in Busan.

• Journal of Korea Spatial Information System Society
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• v.7 no.3 s.15
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• pp.25-31
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• 2005

With the recent surge of public interests in real estate markets, public demand on cadastral information including cadastral maps has been increasing rapidly. However, the torrent system that provides cadastral information falls far short of meeting public demand due to its main focus on government users. In order to reduce the gap between public demand and supply of cadastral information, a new business model is needed that fulfills public needs and at the same time generates profits for service providers. The main objective of this paper is to identify a potential business model that satisfies the above conditions. To achieve this objective, we have explored the unmet needs of public users in real estate transactions and examined whether the unmet needs can best be served by the resources and capabilities of Korea Cadastral Survey Corporation. Then, we have crafted a detail business model i.e., Syndication model, that includes value propositions, resource maps, and revenue and cost estimations. Finally, a plan is proposed to serve government users better with the financial surplus from the proposed business model. The results of this study can be useful for other similar areas including GIS, ITS and telematics, academically as well as practically.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.364-364
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• 2023

최근 환경부에서 발표한 「제3차(2021~2025) 강우유출 비점오염관리 종합대책(2020)」에 의하면, 우리나라는 지난 50년간 급격한 도시화, 산업화 과정을 거치면서 불투수면적이 전 국토의 약 22.4%에 달한다고 보고되고 있다. 특히 전체 소권역의 6%에 해당하는 51개 소권역의 경우 불투수 면적률 25%를 넘어서고 있는 것으로 조사되었다. 이러한 불투수면의 증가는 기후변화에 의한 영향으로 토양 침투량과 기저유출량을 감소, 갈수기 하천건천화 심화, 우기 표면유출수 증가를 가중시키며 이로인한 비점오염물질 유입 증가, 수질 악화의 원인으로 작용 될 수 있다. 이에 정부에서는 저영향개발(Low Impact Development, LID) 사업 및 친환경그린인프라(Green Infrastructure, GI) 기술요소를 적용하여 도시지역 기후위기 대응 수단의 일원으로 우수유출 저감, 물순환 구조 개선, 비점오염원을 관리하고자 '그린빗물인프라(Green Stormwater Infrastructure, GSI) 조성 사업'을 추진하여 공공청사를 중심으로 학교, 도서관, 체육시설, 공원 등 적용 범위를 확대하고 있다. 이에 본 연구에서는 기후변화에 가장 취약한 해안도시지역인 경상남도에 위치하고 있으며, 불투수면적이 높고 노후화된 소규모 청사 2곳을 시범 구역으로 선정하였다. 각 시범 구역별 GSI 시설 적용이 가능한 주차장, 화단, 옥상 등의 개선방안을 제시하였으며, 적용 규모를 달리하여 물순환·물 환경 개선 효과를 검증하였다. 검증에는 국내에서 개발된 K-LIDM 모형을 활용한 우수유출저감 및 직접유출체적 산정결과를 통해 물순환 효과를, 국립환경과학원에서 제시되고 있는 '토지계 지목별 발생부하원단위', 수질환경개선 보고서에서 제시된 침투형, 식생형 비점오염저감시설의 저감효율을 활용하여 물순환 저감효과를 분석하여 비교하였다.

• Journal of Korea Port Economic Association
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• v.23 no.1
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• pp.163-193
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• 2007

Jeon-buk is well equipped for the growth of the logistics industry as it is the center of inland and marine traffic. However, it was not activated because of the infrastructure insufficiency. This paper surveyed the logistics industry facilities, interviewed people who are engaged in its business, researched into their business difficulties and the problem of the logistics industry of Jeon-buk. As a result of research, this paper makes an alternative plan for the development of the logistics industry of Jeon-buk area.

• Journal of Korea Port Economic Association
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• v.23 no.3
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• pp.53-77
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• 2007

This paper is designed to look for a specialized strategies by drawing the special features of Busan New Port from both a comparative analysis of major factors of harbor competitiveness and a SWOT analysis of Busan New Port and Yangshan Port, one of the biggest competitive ports in Northeast Asia, so that Busan New Port may preoccupy a status as the hub port of the area. The researcher would like to suggest the following measures to make Busan New Port serve as the central port of Northeast Asia on the basis of the findings; Korea should push ahead with creating a railroad transportation linking with Eurasia Contient, secure the amount of goods and resources with the help of the early development of the surrounding complex of the port, make a considerable progress in the level of port service, come up with a differentiation strategies for harbor marketing activities and improve its productivity.

• Asia-Pacific Journal of Business Venturing and Entrepreneurship
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• v.13 no.4
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• pp.117-128
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• 2018

Various government support policies are being promoted in order to stimulate growth of SMEs. The government is striving to provide effective support through direct methods of tax, finance and indirect methods through support programs. However, the view on the government's startup policy is still tense. We are sympathetic with the need for support, but discussions continue to be made on the effectiveness of support projects and support projects. Therefore, this study evaluates the importance and satisfaction of the government start-up support project. For this purpose, we conducted questionnaires on ICT start-ups who have experienced government start-up support projects. Of these, 128 were analyzed for GAP analysis and ISA. As a result of the GAP analysis of the government start - up support project, the degree of satisfaction (4.408) was lower than the degree of importance (5.221), confirming that the beneficiary's evaluation on the start-up support project was negative. As a result of the importance-satisfaction analysis, 'R&D' and 'commercialization' are located in the maintenance area, and 'government funding', 'marketing, overseas advancement' projects are included in the concentrated area. In the low-ranking areas, there are 'entrepreneur events and networks' items. Finally, there are 'facilities and spaces', 'mentoring and consulting', and 'entrepreneurship education' in the surplus areas. As a result of multiple regression analysis, it was found that 'R&D', 'entrepreneurial education', and 'government funding' influenced satisfaction. Based on the results of this study, it is expected that it will contribute to improving the quality level of the government start-up support project by establishing the support policy for the ICT start-up enterprises and improving the system.