• Title/Summary/Keyword: 초음파 분해

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Effects of sonication on physicochemical properties and pore formation of maize starch (초음파처리가 옥수수전분의 이화학특성과 기공 형성에 미치는 영향)

  • Choi, Eun-Hee;Lee, Jae-Kwon
    • Korean Journal of Food Science and Technology
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    • v.49 no.5
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    • pp.507-512
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    • 2017
  • The physicochemical properties of maize starch sonicated at various amplitudes (100, 200, and 300 W) and times (10, 30, and 50 min) were examined. The amount of enzyme-susceptible starch increased marginally after sonication. Sonication increased the amount of oil absorbed in the starch although the degree of oil absorption decreased with an extension of the sonication time, implied that different types and extent of damages occurred. Scanning electron microscopy revealed that ultrasound sonication did not form pores on the surfaces, but caused damages such as depression and erosion. Pasting viscosity of starch decreased with an increase in the severity of sonication conditions because of the weakened polymer network. X-ray diffraction suggested that the crystalline domains in starch were not susceptible to sonication and were more resistance to degradation. Sonicated starch formed more pin-holes on the surfaces in the initial glucoamylase reaction; subsequently, as the reaction proceeded, porous starch with enlarged pores was formed and finally, disrupted granular fragments were observed.

The Enhancement of the Acoustic Image by Combining Bases of Support for SFR (Spatial Frequency Response) (공간주파수응답의 기저대역 확장에 의한 초음파영상의 개선)

  • Song, Dae-Geon;Oh, Tong-In;Kim, Hyun;Jun, Kye-Suk
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.5
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    • pp.408-417
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    • 2003
  • In this paper, we have studied the enhancement of the acoustic image by combining bases of support for SFR (Spatial Frequency Response) taken at multi-frequencies. The scanning acoustic microscope system have been constructed using the quadrature detector that is able to measure the amplitude and phase of the reflected signal simultaneously. Both real and quadrature components of reflected signal have been acquired at 4.4 ㎒ to 5.6 ㎒ reliably and accurately. In this experimental result, better depth resolution can be obtained by numerically combining images taken at several different frequencies. Image intensity have been better about 3.4 times at multi-frequency than one at a single frequency.

Ultrasound Transducers in Several Tens MHz Band and Their Applications (수십 MHz 대역 초음파 트랜스듀서와 그 응용)

  • 하강렬;김무준
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.8
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    • pp.622-628
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    • 2003
  • Recently, ultrasound transducers in several tens MHz band, which can give the spatial resolution higher than several tens micrometers, have been intensively studying for applying to medical diagnostic fields of ophthalmology and dermatology. In this paper, the background of the studies, structures and characteristics of the transducers, and images obtained by the transducers are briefly reviewed.

Sintering kinetics of ultrasonic spray pyrolyzed alumina powder (초음파 분무 열분해 알루미나 분체의 소결 동력학)

  • 조경식
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.324-333
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    • 1997
  • Porous alumina specimens with 80~92% relative densities were prepared from ultrasonic spray pyrolyzed alumina Powders by sintering at $1600^{\circ}$~ $1700^{\circ}C$. The exaggerated grain growth appeared to high sintering temperature and long soaking time. The microstructural development during sintering was investigated using image analysis. In the study of grain growth kinetics for sintering for spray prolyzed alumina powder, the activation energy for normal grain growth was 386.77 kJ/mol.

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HPLC-MS/MS Detection and Sonodegradation of Bisphenol A in Water (HPLC-MS/MS를 이용한 Bisphenol A 분석 및 초음파에 의한 분해 특성 조사)

  • Park, Jong-Sung;Yoon, Yeo-Min;Her, Nam-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.6
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    • pp.639-648
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    • 2010
  • The optimal conditions for the analysis of BPA by HPLC-MS/MS was investigated and the ultrasound degradation capacity of the BPA, with the goal to establish the proper directions for analyzing infinitesimal quantities of BPA by HPLC-MS/MS was examined. The MDL and LOQ of BPA analyzed by HPLC-MS/MS were measured 0.13 nM and 1.3 nM respectively, its sensitivity about 620 and 32 times greater than HPLC-UV (MDL: 81.1 nM, LOQ: 811 nM) and FLD (MDL: 4.6 nM, LOQ: 46 nM). In other words, the new method enables the analysis of BPA with the accuracy up to one 1,180th of the amount specified in U.S. EPA guideline for drinking water. Degradation rate of BPA by ultrasound measured over 95% under 580 kHz and 1000 kHz frequency within 30 minutes of treatment, whereas the rate showed some decrease at 28 kHz frequency. At 580 kHz of ultrasound has proven to be the most effective among others at degradation rate and $k_1$ value, so we concluded that this frequency of ultrasound creates hospitable condition for the combined process of degradation by pyrolysis and oxidization. With the addition of 0.01 mM of $CCl_4$, BPA with the initial concentration of 1 ${\mu}M$ was degraded by more than 98% within 30 minutes, the $k_1$ value measured 5 minutes and 30 minutes into the experiment both showed increases by 1.4 and 1.1 times, respectively, compared with BPA without $CCl_4$. It is also found that the main degradation mechanism of BPA by ultrasound is oxidization process by OH radical, based on the fact that the addition of 10 mM of t-BuOH decreased the rate of BPA degradation by around 60%. However, 33% of BPA degradation rate obtained with the addition of t-BuOH implies further degradation done by pyrolysis or other sorts of radical beside OH radical.

Decomposition of EVA(Ethylene vinyl acetate) used as an adhesion of photovoltaic(PV) module by ultrasonic irradiation in bath-type cleaner (Bath-type 초음파(超音波) 세척기(洗滌器)를 이용(利用)한 태양전지모듈 접착제(接着劑) EVA(Ethylene Vinyl Acetate) 분해특성(分解特性))

  • Kim, Young-Jin;Lee, Jae-Ryeong
    • Resources Recycling
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    • v.20 no.6
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    • pp.50-55
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    • 2011
  • Using ultrasonic irradiation, the separation and recovery of PV cell, made of silicon wafer, from PV module was carried out through selective decomposition of EVA used as an interlaminated binder. The ultrasonic cleaner of bath-type (Output: 130 W, Frequency: 40 kHz) was used as an ultrasonic apparatus in this research. With the fixed distance of 2 cm, from ultrasonic generator to PV cell, the experiment of EVA decomposition was performed in various organic solvents such as Toluene, Trichloroethylene, O-dichlorobenzene, Benzene. And also their concentrations and temperature was changed to survey the optimum conditions. However EVA can be decomposed perfectly at $55^{\circ}C$ within 160 min in 5 M of all kinds of solvent, PV cell may be recovered with being damaged or broken severely. This damage may be resulted from the swelling of EVA in the process of decomposition. Whereas, at the condition of 5 M at $65^{\circ}C$, PV cell can be recovered with the state of minor damage or crack. This implies that the decomposition rate of EVA increases with an increase of temperature, thereby EVA can be decomposed before the swelling of EVA layer. Conclusively, it is possible for PV cell to be recovered within 40 min, at $65^{\circ}C$ in 5 M, with less damage.

Ultrasonic and Alkaline Pre-treatments of Waste Activated Sludge for Enhancing Anaerobic Digestion (혐기성 소화를 위한 폐활성슬러지의 초음파와 알칼리 전처리)

  • Park, In Geun;Son, Han Hyung;Lee, Chae Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.2
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    • pp.53-63
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    • 2018
  • The hydrolysis of organic solid waste, such as sludge, is the rate-limiting step of the anaerobic digestion. The longer rate-limiting step lead to decrease of treatment efficiency and increase hydraulic retention time and anaerobic digester. Therefore, the pre-treatment has been applied for accelerating the hydrolysis step. This study was investigated the effects of pre-treatment of waste activated sludge using ultrasonic and alkaline integrated treatment simultaneously. The results showed the cumulative methane production and the methane production rate increased while the lag phase decreased. Therefore ultrasonic and alkaline integrated pre-treatment of waste activated sludge resulted in acceleration of hydrolysis step in anaerobic digestion.

Effects of Ultrasound and Ascorbic acid Cotreatment on Browning of Fresh-cut 'Tsugaru' Apples (초음파 및 Ascorbic acid 병용처리가 신선절단 '쓰가루' 사과의 갈변에 미치는 영향)

  • Cho, Jeong-Seok;Jeong, Moon-Cheol;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.19 no.3
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    • pp.323-327
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    • 2012
  • The effects of ultrasound and ascorbic acid cotreatment on the browning inhibition and microbial growth of fresh-cut Tsugaru apples were investigated. The prepared samples were dipped in distilled water (Cont) or 1% (w/v) ascorbic acid solution (AA) and were then ultrasonicated in distilled water (US) or 1% (w/v) ascorbic acid solution (AA+US). The samples were then packed in a 0.04mm polypropylene bag ($20{\times}15$ cm) and were stored at $10^{\circ}C$ for eight days. The AA+US treated samples showed high $L^*$ and low $a^*$, $b^*$ values as well as inactivated PPO activity. The growth of the total aerobic bacteria also inhibited the AA+US treated samples more. The physicochemical properties were not different among all the samples. It was demonstrated in this paper that the ultrasonication treatment with ascorbic acid prevented the enzymatic browning of and microbial growth in fresh-cut Tsugaru apples.

다중주파수 초음파처리를 이용한 하수슬러지의 탈수성 및 침강성의 변화에 관한 연구

  • Kim, Ju-Ho;Kim, Bu-Gil
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.11a
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    • pp.385-389
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    • 2006
  • 다중주파수 초음파를 이용한 하수슬러지의 전처리시 탈수성와 침강성에 관한 실험을 실시하여 다음과 같은 결론을 얻었다. 1. CST 변화량은 조사시간 80분까지 증가하다가 이후에는 감소하는 경향을 보여 탈수성이 개선될 수 있음을 보였다. 또한 삼중주파수가 이중주파수 일때보다 더 큰 영향을 끼쳤다. 2. $SV_{30}$의 변화량은 초음파 조사와 동시에 급격히 변화하여 침강성의 악화를 가져왔다. 또한 삼중주파수가 이중주파수 일때보다 침강속도를 더 빨리 악화시켰다. 3. 수온은 상승하였고, pH의 변화는 거의 일어나지 않았다. 본 실험에서 다중주파수를 사용하였을때, 단일주파수를 사용했을때보다 효율이 높았다. 그러나 다중주파수를 이용한 초음파 처리시 정확한 탈수성과 침강성 평가를 위해 ECP, 여과비저항(SRF), 입도분도, 점도 등 다양한 후속연구를 진행해야 할 것이다.

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Mechanical, Electrical Characteristics of Epoxy/Organoclay_93A Nanocmposites according to Power Ultrasonic Application Time (Epoxy/Organoclay_93A 나노콤포지트 기계적, 전기적 특성연구)

  • Park, Jae-Jun;Cho, Hee-Su;Cho, Sung-Min;Hwang, Byung-Joon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1213-1215
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    • 2008
  • 분산능력은 나노콤포지트의 제반적인 물성에 큰 영향을 준다. 그러나 유기용매를 사용한 분산능력은 전기적 절연특성에 불순물케리어로 작용되는 경우가 있어 오히려 절연성능 즉, 결합이 약하게 작용되는 결과를 가져오게 된다 이런 이유로 물리적인 분산법인 강력초음파법을 이용하여 Epoxy/Organoclay_93A 나노콤포지트를 제조하였다. 최적의 초음파 적용시간을 연구하기위해 강력초음파를 15,30,60,120분 각각에 대해 적용하였다. 적용시간은 기계적,전기적인 물성에 독립적인 특성을 나타내었다. 그러나 전반적인 물성의 비교에서 최적의 초음파 적용시 60분의 경우가 가장 양호한 결과를 얻었다. 기계적, 전기적인 물성에서 1차경화만으로 측정자료로 최적의 2차 경화를 가져가하면 더욱 높은 물성을 가져오게 될 것이다.

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