• Title/Summary/Keyword: 초음파화학

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Electrochemical Characteristics of the Oxygen Electrode for Alkaline Fuel Cells -Impregnation of Silver Catalyst on Carbon Black with Colloidal Method- (알칼리형 연료전지용 산소극의 전기화학적 특성고찰 -콜로이드 방법에 의한 카본블랙상 은촉매담지-)

  • Lee, Hong-Ki;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.701-709
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    • 1992
  • Silver particles were impregnated on carbon black with colloidal method and used as catalyst for oxygen electrode in alkaline fuel cell. With the addition of sodium dodecylbenzenesulfonate in $AgNO_3$ and $NaBH_4$solution, colloidal solution was made and confirmed with electrophoresis test. Effects of particle size on electrode performance were studied and $200{\AA}$ of silver particle size shown the highest value of mass activity. The aggromeration of silver particle was Influenced with surfactant amount, stirring time and heat treatment. Considering the increase of particle size caused of operating temperature, recommendable particle size of silver catalyst for manufacturing the electrode was $100{\AA}$. Dispersity of carbon black was investigated and reagglomeration was appeared after homogenizing 30 sec.

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Clinical and Immunohistochemical Characteristics of Malignant Aortic Body Tumor in a Pekingese Dog (페키니즈에서 발생한 악성 대동맥체 종양의 임상양상과 면역조직화학적 특성)

  • Kim, Won-Jung;Kim, Seung-Gon;Lee, Chang-Min;Kim, Dae-Young;Park, Hee-Myung
    • Journal of Veterinary Clinics
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    • v.31 no.5
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    • pp.407-411
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    • 2014
  • A 12-year-old castrated male Pekingese dog was presented with weakness, exercise intolerance, and an episode of coughing started 2 weeks earlier upon presentation. Physical examination revealed a grade II/VI left systolic heart murmur. Echocardiographic examination revealed a pericardial effusion and a mass at the heart base located beside the left atrium. The mass beside the left atrium was also visible on the thoracic radiograph after drainage of the pericardial effusion. An aortic body tumor was definitely diagnosed based on postmortem histopathological examination and immunohistochemical staining for specific markers. The dog lived 234 days after diagnosis with only medical management and without recurrence of the pericardial effusion.

Medullary Thyroid Carcinoma in a Maltese Dog (말티즈 개에서 발생한 갑상선수질암)

  • Hyun, Hee-Jin;Jung, Soo-Kyo;Kim, Jae-Hoon
    • Journal of Veterinary Clinics
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    • v.31 no.5
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    • pp.435-438
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    • 2014
  • An 11-year-old, 2.67 kg female Maltese dog with 3 weeks history of palpable cervical mass near trachea was submitted to a local animal hospital. Radiography and ultrasonography showed radiopaque mass adjacent trachea and vagus nerve. Surgically excised mass was solitary and approximately $3.5{\times}2{\times}0.8cm$ in size. Histopathologically, there were large neoplastic foci admixed with normal thyroid tissues. These neoplastic foci were composed of small to large packets of the neoplastic cells with plasmacytic morphology, and these packets were divided by fine fibrovascular septa. Immunohistochemically, most neoplastic cells in the thyroid mass showed positive reactions for cytokeratin (AE1/AE3), chromogranin A, neuron specific enolase (NSE) and the negative reaction for vimentin. Based on the gross, histopathologic and immunohistochemical characteristics, this dog was diagnosed as medullary thyroid carcinoma.

A Case of Acute Lung Injury Complicated by Transcatheter Arterial Chemoembolization for Hepatocellular Carcinoma (간세포암의 간동맥 화학색전술 후 발생한 급성 폐손상 1예)

  • Cho, Se-Haeng;Kim, Joo-Hang;Kim, Byung-Soo;Jang, Joon
    • Tuberculosis and Respiratory Diseases
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    • v.42 no.5
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    • pp.781-786
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    • 1995
  • Transcatheter arterial chemoembolization(TACE) was performed in a 61 year old male patient with hepatocellular carcinoma with 10 cc of Lipiodol and 50 mg of doxorubicin. Three days later, he complained of dyspnea and dry cough. The arterial blood gas study revealed moderate hypoxemia and hypocarbia. The chest PA showed acute pulmonary edema with bilateral pleural effusion. To rule out the possibilities of acute respiratory failure caused by infection, pulmonary embolism or congestive heart failure, we performed several laboratory studies. The blood and sputum culture studies revealed negative results for bacterial growth. The echocardiogram was normal. The abdominal CT scan and MR imaging revealed no thrombus or mass lesion in the inferior vena cava. So we concluded pulmonary oil embolism induced by lipiodol as the cause of acute lung injury. Four weeks later, clinical symptoms and chest x-ray were markedly improved with conservative care. We report a case of acute lung injury after TACE with lipiodol and doxorubicin, with review of literatures.

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Dispersion Behavior of Graphene with Different Solvents and Surfactants (용매와 분산제의 종류에 따른 그래핀의 분산 거동)

  • Perumal, Suguna;Lee, Hyang Moo;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.20 no.2
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    • pp.53-60
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    • 2019
  • Stable graphene dispersions in various organic solvents and in water were achieved via noncovalent functionalization of graphene surfaces using different types of commercially available surfactants. Stable dispersions were obtained in short time sonication, 3 h. In NMP, graphene with Tween and Span series, and with Pluronic surfactants showed stable dispersions. In ethanol, nitrogen based surfactants showed stable dispersions. In water and dichloromethane partially stable graphene dispersions were obtained using poly(4-vinyl pyridine) and sodium dodecyl sulfonate surfactants. Large scale productions of stable dispersions were successful using poly(4-vinyl pyridine), poly(vinyl pyrrolidone), and poly(2-(dimethylamino)ethyl methacrylate). Thus, this work will serve as a library to select the surfactants for different solvent systems.

Recent Research Trend in Lateral Flow Immunoassay Strip (LFIA) with Colorimetric Method for Detection of Cancer Biomarkers (암 바이오마커 검출용 비색법 기반 측면 흐름 면역 크로마토그래피 분석법(LFIA) 스트립의 최신 연구 동향)

  • Lee, Sooyoung;Lee, Hye Jin
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.585-590
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    • 2020
  • Successful early diagnosis of cancer diseases such as lung, prostate, liver and adrenocortical carcinoma is a key step in determining the cost of treatment, survival rate, and cure rate. Most of current cancer diagnosis systems including biopsy, computed tomography (CT), positron emission tomography (PET)-CT, magnetic resonance imaging (MRI), ultrasonography, etc., require expensive and complicated equipment with highly trained human resources. Global medical and scientific communities have thus made numerous efforts on developing effective but rapid disease management system via introducing a wide spectrum of point-of-care medical diagnosis devices. Among them, a lateral flow immunoassay strip technique has gained a great attention due to many advantages such as cost-effectiveness, short inspection time, and user friendly accessibility. In this mini-review, we will highlight recent research trend on the development of colorimetry based LFIA strips for cancer diagnosis and discuss the future research direction and potential applications.

Decomposition of Eco-friendly Liquid Propellants over Platinum/Hexaaluminate Pellet Catalysts (백금/헥사알루미네이트 펠렛 촉매를 이용한 친환경 액체 추진제 분해)

  • Jo, Hyeonmin;You, Dalsan;Kim, Munjeong;Woo, Jaegyu;Jung, Kyeong Youl;Jo, Young Min;Jeon, Jong-Ki
    • Clean Technology
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    • v.24 no.4
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    • pp.371-379
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    • 2018
  • The objective of this study is to develop a platinum/hexaaluminate pellet catalyst for the decomposition of eco-friendly liquid propellant. Pellet catalysts using hexaaluminate prepared by ultrasonic spray pyrolysis as a support and platinum as an active metal were prepared by two methods. In the case of the pellet catalyst formed by loading the platinum precursor onto the hexaaluminate powder and then adding the binder (M1 method catalyst), the mesopores were well developed in the catalyst after calcination at $550^{\circ}C$. However, when this catalyst was calcined at $1,200^{\circ}C$, the mesopores almost collapsed and only a few macropores existed. On the other hand, in the case of a catalyst in which platinum was supported on pellets after the pellet was produced by extrusion of hexaaluminate (M2 method catalyst), the surface area and the mesopores were well maintained even after calcination at $1,200^{\circ}C$. Also, the catalyst prepared by the M2 method showed better heat resistance in terms of platinum dispersion. The effects of preparation method and calcination temperature of Pt/hexaaluminate pellet catalysts on the decomposition of liquid propellant composed mainly of ammonium dinitramide (ADN) or hydroxyl ammonium nitrate (HAN) were investigated. It was confirmed that the decomposition onset temperature during the decomposition of ADN- or HAN- based liquid propellant could be reduced significantly by using Pt/hexaaluminate pellet catalysts. Especially, in the case of the catalyst prepared by the M2 method, the decomposition onset temperature did not show a large change even when the calcination temperature was raised at $1,200^{\circ}C$. Therefore, it was confirmed that Pt/ hexaaluminate pellet catalyst prepared by M2 method has heat resistance and potential as a catalyst for the decomposition of the eco-friendly liquid propellants.

A Study on the Factors Affecting Entrapment Efficiency and Particle Size of Ethosomes (Ethosomes의 포집효율과 입자크기에 영향을 주는 인자에 관한 연구)

  • Jin, Byung Suk;Lee, Sang Mook;Lee, Kwang Hee
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.138-143
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    • 2006
  • Ethosome is a liquid crystalline vesicle prepared by hydration of ethanol-dissolved lecithin with a solution containing hydrophilic components. Investigation of factors affecting the entrapment efficiency and particle size of ethosomes was carried out, because the high entrapment efficiency and small particle size are prerequisite in developing ethosomes as a drug delivery system. The variations of properties of ethosomes with constituent composition and preparation method were examined using a calcein as a hydrophilic marker. It was observed that the amount of ethanol and calcein solution, phosphatidyl choline content in lecithin, preparation temperature, stirring rate, and PBS addition method had a considerable effect on the properties of ethosome. Sonication treatment resulted in the reduction of entrapment efficiency of ethosome, which was due to the release of entrapped components in the vesicles by strong sonication vibration.

The Modified Method of Splenic Irradiation (초음파를 이용한 비장의 조준법)

  • Chung, Su-Mi;Jang, Hong-Seok;Choi, Ihl-Bohng;Kim, Choon-Yul;Bahk, Yong-Whee
    • Radiation Oncology Journal
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    • v.6 no.2
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    • pp.259-262
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    • 1988
  • Splenic irradiation in chronic myelogenous leukemia is reserved for patients who have painful splenemegaly despite chemotherapy and/or inoperable splenomegaly because of huge size. The role of splenic irradiation is diminution of painful splenomegaly and indirect effect of splenic irradiation on unirradiated hematopoietic and lymphoreticular tissue such as reduction of leukocyte count and increase of hemoglobin level. We report on a useful clinical method for splenic irradiation in chronic myelogenous leukemia. We have used sonography as the tool of simulation. The portal size using modified method is smaller than the field size of conventional simulation, and so this method suggests that useful to irradiation of huge splenomegaly, effective shielding of critical organ and the downfall of complication during irradiation of spleen.

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Pigment Analysis and Nondestructive Deterioration Diagnosis of the Wall Paintings in Gwanyongsayaksajeon (Yaksajeon Hall of Gwanyongsa Temple), Changnyeong, Korea (창녕 관룡사 약사전 벽화의 안료분석 및 비파괴 훼손도 진단)

  • Chun, Yu-Gun;Kim, Won-Kuk;Jo, Young-Hoon;Han, Doo-Roo;Kim, Sun-Duk;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.25 no.4
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    • pp.383-398
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    • 2009
  • We have investigated chemical properties of the pigments and carried out the deterioration diagnosis using nondestructive techniques of the wall painting in Yaksajeon Hall of Gwanyongsa Temple. As the results of pigments analysis, it was unusual that the cobalt was detected in the blue and green colors used to traditional paint background. According to the deterioration diagnosis, ultrasonic measurement and infrared thermography, dominant cracks and exfoliation caused by high content of moisture. Therefore, it should be devised effective plan to prevent penetration of water for the long term this wall painting.

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