• Journal of Adhesion and Interface
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• v.2 no.3
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• pp.16-24
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• 2001

The curing behavior of a phenolic resin (F/p: 1.3, 1.9, 2.5 for resol resin, F/P: 0.5, 0.7, 0.9 for novolac resin) has been studied by FT-IR spectroscopy. In this study is to synthesis of resol and novolac type phenolic resin with different F/P molar ratios and to compare the level of cure at different curing temperature conditions ($130^{\circ}C$, $160^{\circ}C$, $180^{\circ}C$ for resol resin, $160^{\circ}C$, $170^{\circ}C$, $180^{\circ}C$ for novolac resin) for 3, 5, 7, 10, 20, and 60 (min.), respectively. The conversion (${\alpha}$) was determined by the ratio of the peak area with time to the peak area of non-baked phenolic QH ($3300cm^{-1}$) at spectra. It is concluded that the initial curing rate of resol and novolac resin was increased as the molar ratio of formaldehyde/phenol increased and as the curing temperature of resin increased. According to the analysis was by the homogenous first-order model, the initial curing rate of resol and novolac resin was increased as the molar ratio of formaIdehyde/phenol increased at specific curing temperature.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.05a
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• pp.377-384
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• 2004

지구환경 문제가 대두되면서 자동차 경량화를 위한 재료의 고강도화는 필수적인데, 재료의 고강도화는 성형성의 감소를 야기한다. 이러한 문제점은 가공방법으로 해결할 수 있는데, 그 대표적인 것이 프레스 경화(Press Hardening)공정이다. 프레스 경화 공법이란 성형성이 좋은 고온$(900^{\circ}C)$에서 성형하면서 성형 중 프레스에서 고강도를 부설하는 공법이다. 프레스 경화 공정은 스웨덴의 SSAB자회사인 프라냐에서 1973년에 개발된 공법으로 초기에는 높은 경도가 필요한 산업용 설비 (톱 등)에 적용되다가 1990년대부터 Bumper와 Door Impact Beam등의 자동차 부품으로 개발을 하여 적용되기 시작하였으며, 현재 그 적용 영역을 보다 넓혀나가고 있는 상태이다. 본 발표에서는 프레스 경화 공정의 대표 부품인 범퍼 임펙트을 개발하기 위해 관련한 성능해석을 수행하였다. 수행한 결과에 의하면 기존 소재 대비하여 $30\%$이상 경량화가 가능함을 알수 있었다.

• Korean Journal of Materials Research
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• v.7 no.3
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• pp.244-250
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• 1997

본 연구에서는 에폭시/산무수물계에 경화촉진제를 첨가한 시료를 몰드(mold)내에서 등온 경화시킬 때 시료 내부의 온도변화를 측정하여 얻어진 온도-시간 곡선(temperature-time profile)을 조사하였다. 실험에 사용한 경화촉진제의 종류는 1-cyanoethy1-2-ethy1-4-methy1 imidazole(1E4MZ-CN), N,N-dimethy1 benzy1 amine(BDMA), 2,4,6-tris(dimethy1-aminomethy1)-phenol(DMP-30)이며 그들의 농도(c)는 1.0,1.5,2.0,2.5,phr그리고 경화온도(T$_{cure}$ )는 65,70,85,95$^{\circ}C$로 하였다. 경화가 진행되는 동안 시료내부의 온도는 초기에 경화온도로 상승한 후 본격적인 경화 반응이 일어나기 시작하여 온도가 급격히 상승하였다가 다시 감소하는 양상을 보였다. 온도-시간 곡선상에 나타나는 온도가 최고로 상승되는 시점(t$_{peak}$ )과 그 때의 온도(T$_{peak}$ )는 촉진제의 종류와 농도 그리고 경화온도에 의하여 영향을 받았다. 사용한 경화촉진제중에 DMP-30이 가장 짧은 t$^{peak}$ 값을 가져 가장 우수한 촉진 효과를 갖는 것으로 나타났으며, T$_{peak}$ 는 촉진제의 농도와 경화온도가 증가할수록 상승하였다. 그리고 경화촉진제의 농도와 경화온도의 변화에 따른 t$_{peak}$ 과 T$_{peak}$ 의 변화를 보면 촉진제 농도와 경화온도가 낮을 때 그 변화가 민감하여 2E4MZ-CN 이 가장 민감한 촉진제로 나타났으며 또한 T$_{peak}$ 에 영향을 주는 여러가지 요소들을 본 연구에서 얻어진 결과로부터 자세히 살펴보았다.

• Polymer(Korea)
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• v.35 no.3
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• pp.196-202
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• 2011

The cure kinetics of a bisphenol A epoxy resin and polyoxypropylene diamine curing agent system are investigated in both dynamic and isothermal conditions by differential scanning calorimetry (DSC). In dynamic experiments, the shift of exothermic peaks obtained at different heating rates is used to obtain activation energy of overall cure reaction based on the methods of Ozawa and Kissinger. Isothermal DSC data at different temperatures are fitted to an autocatalytic Kamal kinetic model. The kinetic model is in a good agreement with the experimental data in the initial stage of cure. A diffusion effect is incorporated to describe the later stage of cure, predicting the cure kinetics over the whole range of curing process. Also, dynamic mechanical analysis is performed to evaluate the storage modulus and average molecular weight between crosslinkages.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.101-110
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• 2014

Expansion agent is a very effective admixture for prevention of cracking due to autogenous/drying shrinkage and this can induce internal chemical prestress to embedded reinforcement. In this paper, tension-softening and hardening in cement mortar with steel and CSA expansion agent are experimentally evaluated. Cement mortar with steel reinforcement is prepared and tensile strength test is performed for evaluation of cracking and tensile behavior. In spite of slightly reduced strength and elasticity in CSA mortar, significantly increased tension-hardening behavior is evaluated in CSA mortar with induced chemical prestress. Furthermore previous tension softening models are compared with the test results and improvement are proposed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1997.04a
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• pp.215-220
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• 1997

본 연구는 추진제 연소관 내부에 도포 되는 내열재 라이닝 공정을 최적화하기 위해 라이너 Premix 반응성을 실험하고 그결과를 토대로 Premix 저장조건을 설정하였다. HX-계열의 Bonding agent를 사용하는 LH-2, LH-5, LH-6 라이너를 선택하여 각각 20, 30, $40^{\circ}C$하에서 5주간 저장후 경화제와 경화촉매를 주입하고 초기점도를 측정하여 반응성을 예측하였다. 그 결과 Bonding agent로 HX-868을 사용하는 LH-5, LH-6 라이너가 HX-752를 사용하는 LH-2보다 반응성이 빠르며, 경화제와 경화촉매로 DDI와 T-12를 사용하는 LH-5 라이너가 IPDI와 $Fe(AA)_3$를 사용하는 LH-6 라이너 보다 반응성이 빠르게 나타났다. 이러한 저장온도와 기간에 따른 반응성을 토대로 공정 적용시 급격한 점도 상승에 의한 작업의 불안정성을 피하기 위해 일정 점도를 초과하지 않는 라이너 Premix 저장조건을 설정하였고, 향후에는 Bonding agent로. HX-868을 사용하는 LH-5, LH-6 라이너는 보다 공정성이 양호한 HX-752로 바꾸어 주는 것이 바람직 할 것이다.

• Geotechnical Engineering
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• v.10 no.3
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• pp.17-32
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• 1994

To model the anisotropic behavior of soils in the case of reverse loading, an anisotropic hardening description is proposed on the basis of generalized isotropic hardening(GIH) rule. There is a core of the GIH rule in the allowance of the concept that the center of homology of isotropic hardening can be any proper stress states inside a yield surface. The plastic deformations could be represented for the condition of reverse loading, and an explicit constitutive relationship was formulated by utilizing a simple hardening function. The proposed hardening description has been compared with other anisotropic hardening models. For verification three sets of triaxial test results have been predicted for the drained and undrained behavior of overconsolidated clays and Ko consolidated clays.

• Journal of the Korea Institute of Building Construction
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• v.13 no.4
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• pp.407-415
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• 2013

The purpose of this research is to verify the performance of hardening accelerator in cement paste through mechanical performance evaluation and micro structure analysis on hardening accelerator for development of super high early strength concrete. The research results showed that hardening accelerator produced $Ca(OH)_2$ when hydrated with cement, enhancing the degree of saturation of Ca ion by using differential thermal analysis. Moreover, porosity was reduced rapidly as capillary pores were filled by hydration products of $C_3S$. According to the experiment using hydration measurement testing, when 1% and 3% of accelerator were mixed, hydration rate increased toward the second peak point compared to high early strength cement, before the first peak point disappeared. It turned out that adding accelerator accelerated the hydration rate of cement, especially $C_3S$. The shape of C-S-H is shown depending on the amounts of accelerator added and the production and age of $Ca(OH)_2$ by using SEM to observes hydration products. Therefore, it's evident that hardening accelerator used in this research increases amounts of $Ca(OH)_2$ and accelerates $C_3S$, it is effective for the strength development on early age.

• Proceedings of the Korean Society of Developmental Biology Conference
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• 2005.07a
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• pp.54-54
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• 2005

• Geotechnical Engineering
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• v.10 no.1
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• pp.103-118
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• 1994

A series of drained triaxial testis was performed on a Band by use of cubical triaxial apparatus, in which three principal stresses could be applied independently. The stress -strain behavior on the same stress path with cubical triaxial test was analyzed with application of the isotropic single hardening constitutive model presented by Lade. The behavior predicted by the constitutive model presented good coincidence with experimental results during poi mary loading. However, the predicted Mo윤ding and reloading behavior wan much different from results of cubical triaxial testy. That is, the softening part of the prediction might result in a rough approximation, since the plastic work parameters of single hardening model were based on the hardening portion of the data.