• Resources Recycling
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• 제13권4호
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• pp.39-45
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• 2004

Solvent extraction experiments of Nd from chloride solution were studied with PC88A. Solvent extraction reaction of Nd with PC88A and the equilibrium constant were evaluated from the extraction experimental data and extraction conditions. Nd$aq^{3+}$ + 1.5 $H_2$$A_2$,org = $NdA_3$,org + 3H/sun $aq^{+}$ , K=0.25 The predicted distribution coefficients of Nd agreed well with the experimental results. The effect of saponification of PC88A on the extraction of Nd and on the change of equilibrium pH was investigated. Saponified PC88A present as a monomer in the organic reaction and enhanced the distribution coefficient of Nd. The initial extraction conditions had a great effect on the equilibrium pH.

• KSCE Journal of Civil and Environmental Engineering Research
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• 제28권5A호
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• pp.737-746
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• 2008

Recently, NDTs (Non-Destructive Techniques) using electromagnetic(EM) properties are applied to the performance evaluation for RC (Reinforced Concrete) structures. Since nonmetallic materials which are cement-based system have their unique dielectric constant and conductivity, they can be characterized and changed with different mixture conditions like W/C (water to cement) ratios and unit cement weight. In a room condition, cement mortar is generally dry so that porosity plays a major role in EM properties, which is determined at early-aged stage and also be affected by curing condition. In this paper, EM properties (dielectric constant and conductivity) in cement mortar specimens with 4 different W/C ratios are measured in the wide region of 0.2 GHz~20 GHz. Each specimen has different submerged curing period from 0 to 28 days and then EM measurement is performed after 4 weeks. Furthermore, porosity at the age of 28 days is measured through MIP (Mercury Intrusion Porosimeter) and saturation is also measured through amount of water loss in room condition. In order to evaluate the porosity from the initial curing stage, numerical analysis based on the modeling for the behavior in early-aged concrete is performed and the calculated results of porosity and measured EM properties are analyzed. For the convenient comparison with influencing parameters like W/C ratios and curing period, EM properties from 5 GHz to 15 GHz are averaged as one value. For 4 weeks, the averaged dielectric constant and conductivity in cement mortar are linearly decrease with higher W/C ratios and they increase in proportion to the square root of curing period regardless of W/C ratios.

• Journal of Korean Society of Steel Construction
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• 제13권5호
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• pp.587-597
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• 2001

The structural system that discreterized continuous shells is frequently used to make dome-type structures and these structures show the unstable phenomena by snap-through or bifurcation when a load level reaches certain critical value. The characteristic structural behaviour of a cable dome shows a strong nonlinearity and very sensitive according to the initial imperfection. In this study the shape finding problem by applying initial tension stress is investigated and using this the unstable phenomena of perfectly shaped and initially imperfected shape model by external forces are examined to grasp the unstable behavior of cable dome using the Geiger-type model.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 한국표면공학회 2015년도 추계학술대회 논문집
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• pp.264-264
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• 2015

전기동도금의 경우 도금후 박막의 구조와 특성이 변화하는 단점이 있다. 공정조건 중 인가전류 밀도에 따른 우선결정성장방위, 미세조직, 혼입불순물 및 인장강도 변화를 조사하였다. 혼입불순물이 적은 저전류 밀도($2A/dm^2$)에서는 동도금후 시간이 지남에 따라 초기 인장강도를 유지하였으나, 고전류 밀도(5, $8A/dm^2$)로 갈수록 혼입불순물이 많아지며 동도금후 인장강도 또한 초기값에 비해 약 60%이상 감소하였다.

• Proceedings of the Korean Society of Computer Information Conference
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• 한국컴퓨터정보학회 2024년도 제69차 동계학술대회논문집 32권1호
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• pp.449-452
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• 2024

본 논문에서는 리튬이온 배터리의 SOC(State Of Charge) 초기 정보의 정확도 향상을 위하여 확장칼만필터(EKF) 방법을 적용한 효율적 SOC 추정 알고리즘을 제안한다. 일반적인 전류적산법을 사용하는 방법은 초기 조건이 부정확한 경우에 오차가 발생하고 시간에 따라 누적 오차가 커지는 단점이 있다. 이러한 문제점 해결을 위하여 초기 SOC 추정값에 EKF 방법을 동시에 적용하는 알고리즘을 제안한다. 제안 알고리즘의 평가를 위한 실험을 통하여 제안 방법이 기존 SOC 추정 방법보다 추정 오차가 개선됨을 확인하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 한국수자원학회 2019년도 학술발표회
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• pp.119-119
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• 2019

최근 기후변화와 이상기후의 영향으로 국지성 호우 및 가뭄, 홍수, 태풍 등 재해 발생 규모가 커지고 그 빈도 또한 많아지고 있다. 이러한 자연재해 및 이상현상에 대한 피해를 예방하고 빠르게 대처하기 위해서는 정확한 강우량 추정 및 강우의 시간적 예측이 필요하다. 이러한 강우의 불확실성을 해결하기 위해서 기상청 등에서는 단일 수치예보가 가지는 결정론적인 예측의 한계를 보완한 초기조건, 물리과정, 경계조건 등이 다른 여러 개의 모델을 수행하여, 확률적으로 미래를 예측하는 앙상블 예측 시스템을 예보기술에 응용하고 있으며 기존 수치모델의 정보와 예보 불확실성에 대한 정보를 동시에 제공하고 있다. 그러나 다양한 자연조건에 대한 불완전한 물리적 이해와 연산 능력 등의 한계로 높은 불확실성이 내포되어 있으므로 불확실성을 최소화하기 위한 편의보정이 수행될 필요가 있다. 강우분석의 적용 이전에 해당 자료의 타당성과 신뢰도의 분석이 필요하다. 본 연구에서는 LENS(Local ENsemble prediction System) 예측값과 시강우 관측값을 단기예측모델에 맞추어 3시간 누적하여 비교하였다. 비교 기간은 호우가 집중되는 2016년 10월로 선정하였으며 대상지역은 울산중구로 선정하였다. LENS를 대상 지역의 관측소 지점값과 행정구역 면적값을 따로 추출한 후, 불확실성을 최소화하기 위해 활용되고 있는 CF 기법과 QM 기법을 이용하여 LENS 모델을 재가공하고 이에 따른 편의보정 기법에 따른 LENS 모델을 과거의 실제강우 관측값과의 비교분석을 이용해 적용성을 검토 및 평가하였다.

• KSBB Journal
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• 제17권6호
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• pp.543-548
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• 2002

The enantioselective esterification of racemic ibuprofen catalyzed by a Candida rugosa lipase was studied according to reaction conditions such as a lipase concentration, reaction temperature, alcohol chain length and alcohol concentration. The S-(+)-ibuprofen alkyl esters prepared were converted to S-(+)-ibuprofen by hydrolysis with sulfuric acid as a catalyst. High conversions in the esterifications were obtained at 60$^{\circ}C$ and an equimolar ratio of octanol to ibuprofen. The initial reaction rate of the esterification decreased with increasing octanol concentration. Conversion and initial reaction rate increased with increasing alcohol chain length. Values of enantiomeric excess(ee) according to esterification reaction conditions did not change below 60$^{\circ}C$. On the other hand, values of conversion and ee for the chemical hydrolysis of S-(+)-ibuprofen alkyl esters were independent of alcohol alkyl chain length. Optical resolution of racemic ibuprofen was achieved by lipase catalyzed esterification and chemical hydrolysis. The separation method provided a high yield and enantioselectivity for the production of S-(+)-ibuprofen from racemic ibuprofen.

• Journal of Korean Association for Spatial Structures
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• 제11권1호
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• pp.77-85
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• 2011

In this study, micro genetic algorithm is used to find an optimum cross section of grid structures with pretension. Design optimization of trusses consists of arriving at optimum sizes of cross-section and prestressing force parameters, when weight of the truss is minimum, satisfying a set of specified constraints. The present approach is verified by ten-bar truss example showing good agreements with previous results. Features of the proposed method, which help in modeling and application to optimal design of pretensioned truss structures, are demonstrated by solving a problem of seventy two bar truss structures. The minimum weight design of seventy two bar truss is performed for various magnitudes of pretension and optimal prestressing forces are also found for various configurations of pretensioned truss structures.

• KSCE Journal of Civil and Environmental Engineering Research
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• 제33권6호
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• pp.2369-2379
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• 2013

The Soil-Water Characteristics Curve (SWCC) is affected by the initial density of soil under unsaturated condition. Also, the characteristic of hydraulic conductivity is changed by the initial density of soil. To study the effect of initial density of unsaturated soil, SWCC and the Hydraulic Conductivity Function (HCF) of Jumoonjin sand with various relative densities, 40%, 60% and 75% were measured in both drying and wetting processes. As the results of SWCC estimated by van Genuchten (1980) model, the parameter related to Air Entry Value(AEV), ${\alpha}$ in the wetting process is larger than that in drying process, but the parameters related to the SWCC slope, n and the residual water content, m are larger than those in wetting process. The AEV is increased or Water Entry Value (WEV) is decreased with increasing the relative density of sand. The AEV is larger than the WEV at the same relative density of sand. As the results of HCF estimated by van Genuchten (1980) model which is one of the parameter estimation methods, the unsaturated hydraulic conductivity maintained at a saturated one in the low level of matric suctions and then suddenly decreased just before the AEV or the WEV. The saturated hydraulic conductivity in drying process is larger than that in wetting process. The saturated hydraulic conductivity is decreased with increasing the relative density of sand in both drying and wetting processes. Also, the hysteresis in unsaturated HCFs between drying and wetting process was occurred like the hysteresis in SWCCs. According to the test results, the AEV on SWCC is decreased and the saturated hydraulic conductivity is increased with increasing the initial density. It means that SWCC and HCF are affected by the initial density in the unsaturated soil.

• Journal of the Institute of Electronics Engineers of Korea SP
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• 제47권1호
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• pp.1-8
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• 2010

Some methods employing the Active Contour Model have been widely used to extract face contour. Their performance, however, depends on the initial position of the model and the coefficients of the energy function which should be reconsidered whenever illumination and environmental condition of an input image is changed. Additionally, the number of points in the contour model should increase drastically in order to extract a fine contour. In this paper, we thus propose a novel approach which extracts face contour by segmenting the face region with threshold values obtained by a histogram analysis technique in the separated region of input image. The proposed method shows good performance under various illumination and environmental condition since it extracts face contour by considering the characteristics of the input image.