• Journal of the Korean Electrochemical Society
• /
• v.23 no.4
• /
• pp.105-112
• /
• 2020

Transition metal oxide, which undergoes a conversion reaction in the negative electrode material for a lithium-ion batteries, has a high specific capacity, but still has several critical problems. In this study, manganese pyrophosphate (Mn₂P₂O₇), nickel pyrophosphate (Ni₂P₂O₇), and carbon composite materials with pyrophosphates as novel negative electrode materials instead of transition metal oxide, are synthesized through simple solid-state reaction. The initial reversible capacity of Mn₂P₂O₇ and Ni₂P₂O₇ are 333 and 340 mAh g^-1, and when the composite materials are composed with carbon, the reversible capacity increases to 433 and 387 mAh g^-1, respectively. The initial Coulombic efficiency is also improved by about 10%. The Mn₂P₂O₇ and carbon composite material has the highest initial capacity and efficiency, and has the best cycle performance. Mn₂P₂O₇ containing polyanion, has a lower specific capacity due to the large mass of polyanion compared to MnO (manganese oxide). However, since Mn₂P₂O₇ shows a voltage curve with a slope, the charging (lithiation) voltage increases from 0.51 to 0.57 V (vs. Li/Li⁺), and the discharge (delithiation) voltage decreases from 1.15 to 1.01 V (vs. Li/Li⁺). Therefore, the voltage efficiency of the cell is improved because the voltage difference between charging and discharging is greatly reduced from 0.64 to 0.44 V, and the operating voltage of the full cell increases because the negative electrode potential is lowered during the discharging process.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.4A
• /
• pp.197-206
• /
• 2012

It is found the first case of broad interpretation of the crash analysis in MASH (Manual for Assessing Safety Hardware, AASHTO, 2009) which is the guideline of roadside safety features in United States. They introduced the procedure of calculating 1,500 kg sedan safety index from the 2,270 kg pick-up truck crash test for crash cushion. First, following MASH's method, calculate 0.9 ton vehicle crash data and safety index using 1.3 ton vehicle crash test data and compare with actual 0.9 ton vehicle crash test data. results show that actual test data and the data calculated by MASH's method have great difference. Second, analyse the cause and develop new method. Proposed method can estimate not only the lighter vehicle (0.9 ton) crash data from the heavier vehicle (1.3 ton) crash test but also heavier vehicle (1.3 ton) data from lighter vehicle (0.9 ton) test. This method is superior to MASH's method and has stronger theoretical foundation. This paper proves the efficiency and the accuracy of new broad interpretation method using crash test data and investigates the principle.

• Journal of Korean Society of Environmental Engineers
• /
• v.34 no.8
• /
• pp.566-573
• /
• 2012

This study examined the removal rate of heavy metals from synthetic control water using red mud and lime stone. Overall, the percent of absorption obtained in this study for the red mud treatment was 94.0% ($Pb^{2+}$), 67.1% ($As^{3+}$), 37.5% ($Cu^{2+}$), and 36.6% ($Cr^{6+}$), while that of lime stone was $Pb^{2+}$ (30.8%), $Cu^{2+}$ (16.5%), $Cr^{6+}$ (11.5%), and $As^{3+}$ (8.9%). The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models, the equilibriuim adsorption of $Cr^{6+}$ and $Pb^{2+}$ obeys Freundlich isotherm model, while the adsorption of $Cu^{2+}$ obeys only Langmuir model. The results also showed that adsorption rate slightly increased with increasing pH from 5 to 9. Interestingly, this trend is similar to results obtained as function of loading amount of red mud. Meanwhile, an unit adsorption rate was slightly decreased. For lime stone, it did not much change in adsorption as function of treatment amount. Consequently, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.

• Current Research on Agriculture and Life Sciences
• /
• v.1
• /
• pp.27-34
• /
• 1983

This study was conducted to obtain the basic informations on the selection for the early and high-yielding lines in $F_2$ populations of wheat. Two combinations such as Olmil-Saemil cross and Naphal-Cheonggemil cross and their eight populations were used and genetic parameters of genetic variances and path-coefficients for agronomic traits mainly in $F_2$ populations were analyzed. Genetic coefficient of variability in Olmil-Saemil cross was higher in harvest index, grain number, grain yield and plant height in decreasing order, but in Naphal-Cheonggemil cross harvest index, plant height, and 1,000-grain weight were higher in order. Heading and maturing dates, plant height, and harvest index showed high hertability (0.525-0.808) in both crosses, but very low heritabilities were observed in grain numbers per panicle and yield. In both crosses, genetic advances(%) was higher in heading and maturing stage, but lowest in yield. High genetic advance was obtained in 1,000-grain weight of Naphal-Cheonggemil cross. The highly significant correlations between yield and panicle number, yield and grain number per panicle were obtained, and the highest direct effect on yield was obtained in panicle number followed by grain number per panicle number.

• Journal of the Korean Chemical Society
• /
• v.55 no.3
• /
• pp.472-477
• /
• 2011

The concentration of selenium in grain samples was determined using isotope dilution method in ORC-ICPMS. The experimental conditions were optimized to $H_2$ mode and the flow rate was $4.0\;mL\;min^{-1}$. ORC in $H_2$ mode proved to eliminate most of polyatomic interferences except $BrH^+$ when Br is present in sample matrix. Chemical removal of Br was very difficult and the mathematical correction was successfully employed. The fraction of $BrH^+$ generated from Br at the current experimental condition was 14.1%. The signal on m/z 82 was corrected and calculated for isotope dilution. The analytical reliability of the propose method was successfully evaluated by analyzing the certified standard reference material NIST SRM 1566 and 1567. The method was applied to real samples and the results are $0.034{\pm}0.001\;{\mu}g\;g^{-1}$ for white rice, $0.059{\pm}0.002_5\;{\mu}g\;g^{-1}$ for brown rice, $0.029{\pm}0.001_4\;{\mu}g\;g^{-1}$ for black rice, and $0.034{\pm}0.002\;{\mu}g \;g^{-1}$ for barley. The detection limits ($3\sigma$) for Se was $0.012\;ng\;g^{-1}$.

• Analytical Science and Technology
• /
• v.12 no.5
• /
• pp.408-414
• /
• 1999

A selective and sensitive method for the derivatization of total homocysteine (Hcy) and the related compounds in plasma by gas chromatograph (GC)-electron capture detector (ECD) has been developed. To determine total homocysteine, cysteine (Cys), and methionine (Met) in human plasma using GC-ECD, analytes were reduced and converted into their N(O,S)-ethylearbonyl pentafluoropropyl (PFP) ester by derivatization with ethyl chloroformate and pentafluoropropyl alcohol (PFP-OH) in plasma. The best derivatizing agent N(O,S)-ethyl carbonyl PFP ester, was chosen by comparing the sensitivity of derivatized analysis in GC-ECD. The derivatized analytes in plasma were extracted by chloroform, and subsequently back-extracted with hexane and analyzed by GC-ECD. The calibration carves ($R^2$ > 0.990) were linear over the range $5-50{\mu}mol/L$ of Hcy and Met, $40-400{\mu}mol/L$ of Cys spiked in plasma. The detection limit observed by the established method was below $0.5{\mu}mol/L$. This method is highly sensitive and specific in the analysis of Hcy, Cys, and Met. Therefore, we suggest that this method is appropriate in the analysis of trace concentration of Hcy, Cys, and Met in biological fluids.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.13 no.3
• /
• pp.171-180
• /
• 2015

This study was performed on the removal of Cs, one of the main high- radioactive nuclides contained in the high-radioactive seawater waste (HSW), by adsorption with IE911 (crystalline silicotitanate type). For the effective removal of Cs and the minimization of secondary solid waste generation, adsorption of Cs by IE911 (hereafter denoted as IE911-Cs) was effective to carry out in the m/V (ratio of absorbent weight to solution volume) ratio of 2.5 g/L, and the adsorption time of 1 hour. In these conditions, Cs and Sr were adsorbed about 99% and less than 5%, respectively. IE911-Cs could be also expressed as a Langmuir isotherm and a pseudo-second order rate equation. The adsorption rate constants (k₂) were decreased with increasing initial Cs concentrations and particle sizes, and increased with increasing ratios of m/V, solution temperatures and agitation speeds. The activation energy of IE911-Cs was about 79.9 kJ/mol. It was suggested that IE911-Cs was dominated by a chemical adsorption having a strong bonding form. From the negative values of Gibbs free energy and enthalpy, it was indicated that the reaction of IE911-Cs was a forward, exothermic and relatively active at lower temperatures. Additionally, the negative entropy values were seen that the adsorbed Cs was evenly distributed on the IE911.

• Journal of Food Hygiene and Safety
• /
• v.34 no.6
• /
• pp.519-525
• /
• 2019

The Ministry of Food and Drug Safety (MFDS) is amending its test methods for health functional foods (dietary food supplements) to establish regulatory standards and specifications in Korea. In this regard, we are continuing our research on analytical method development for the items listed in the Korean Health Functional Food Codex. In this study, we have developed a sensitive and selective test method that could simultaneously separate and determine coenzyme Q10 based on liquid chromatographic-tandem mass spectrometry (LC-MS/MS). Calibration curves showed linearity with a correlation coefficient (R²) of > 0.999 and the limits of detection (LODs) and limits of quantitation (LOQs) were in the range of 26.0 ㎍/L and 78.9 ㎍/L, respectively. The recovery results ranged between 98.6-107.0% at 3 different concentration levels with relative standard deviations (RSDs) less than 5%. The proposed analytical method was characterized with high resolution of the coenzyme Q10 and the assay was fully validated as well.

• Applied Chemistry for Engineering
• /
• v.8 no.5
• /
• pp.790-795
• /
• 1997

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuransfurans are the archetype of toxic chemicals. So it has absorbed public attention. The majors primary sources of PCDDS and PCDFs are chemical, thermal and photochemical reactions. Municipal solid waste incinerator facilities has been reported as the major contributors of dioxins to the environment. In this paper, Dioxins and furans were examined emission gas and fly ash produced during combustion in municipal solid waste incinerator. More effective method for sampling, extraction was described. The sample was extracted using a soxhlet method and purified using silicagel, alumina and carbon fibre HPLC to remove interfering compound. The extract was then analyzed by HRGC/HRMS. The result of this study showed recovery standard was good and the data resembled those of thermal processes. Total dioxins and furans were $1076.20pg/Nm^3$ and $1452.34pg/Nm^3$ respectively. The amount of highly chlorinated compound was more than that of lowly chlorinated compound. The 2,3,7,8-substituted TCDD was Just 0.34% of the total dioxins/furans amount.

• Journal of the Korean GEO-environmental Society
• /
• v.15 no.12
• /
• pp.109-115
• /
• 2014

The purpose of this study is to estimate the sediment volume concentration of the liquified-solid mixture which is included fine sediment fractions, according to the variance of the channel slope and the water supply. The numerical model was performed by using the Finite Differential Element Method (FDM) based on the equation for the mass conservation, momentum conservation and the equation of coarse sediment an fine sediment. In comparison of varying the channel slope, the deeper the channel slope, the inflection point of the sediment concentration was occurred rapidly. In comparison of variance of the water supply, as the water supply increases fluctuation with high sediment concentration. In this situation, debris flow changes to the turbulent flow and the sediment becomes to be floated. In comparison varying the length paved saturated sediment, the longer the length, the high concentration of sediment occurred, for the safety of the slope it is needed to check the possibility of the erosion in the slope by debris flow. The results of this study will provide useful information in predicting of the disaster by the liquified-solid mixture and in prevention of the debris flow with various the slope in the mountain side.