• Economic and Environmental Geology
• /
• v.29 no.6
• /
• pp.725-732
• /
• 1996

To assess soil distribution patterns of heavy metals in agricultural environments, we have measured the concentrations of six metals from surficial soils of three different groups divided on the basis of the surrounding environment: (1) soil group I-cultivated soils within the purely agricultural regions, (2) soil group II-both cultivated and uncultivated soils near various livelihood facilities, and (3) soil group III-mainly cultivated soils near major polluting sources. The mean concentrations for the three soil groups were found in the range as follows: 0.12~0.15 (Cd), 4.94~6.08 (Pb), 0.05~0.11 (Hg), 2.82~3.50 (Cu), 4.69~7.82 (Zn), and 0.36~0.78 (As) ppm. Examination of data distribution trends indicates that the concentrations determined from the relatively unpolluted soil environs (groups I and II) were comparable not only between each other but also with those reported previously in background soil environs of Korea. The concentration data for the soil group III were however found to be much higher than the rest two groups. Unlike the direct comparison of the magnitudes of concentrations, results of a regression analysis exhibited much different patterns: it was seen that the correlation patterns for soil group I were rather analogous to those of soil group III. The similarities in correlation patterns between groups I and III along with the lack of correlations in soil group II suggest that soil characteristics such as whether being cultivated or not are important factors affecting soil distributions of heavy metals.

• Journal of Environmental Science International
• /
• v.27 no.11
• /
• pp.947-956
• /
• 2018

Trains have been a major means of transport in Korea during these past decades. However, train facilities such as stations and repair shops are contaminated with organic and inorganic substances. There is a high probability of train facility contamination with polyaromatic hydrocarbons (PAHs). This study evaluated the PAH and heavy metal contamination of soil near railroads in the Kyungpook area. A total of 18 soil samples were collected from the railroads and analyzed for 16 PAHs and 6 heavy metal species. The contamination level of the top soil was found to be slightly higher than that of the subsoil for contamination with PAHs. The ratio of carcinogenic PAH concentration to the total PAH concentration was relatively high, with a maximum of 0.9. The toxicity equivalent (TEQ) of the PAHs were 500.6 ng/kg in the topsoil and 355.5 ng/kg in the subsoil. The ratio of low molecular PAHs (LPAHs) to high molecular PAHs (LPAHs) ranged from 6.7 to 29.5; this shows that contamination is primarily due to combustion of fuel rather than due to petroleum. The ratio of phenanthrene to anthracene and the ratio of fluoranthene to pyrene also show that contamination occurred due to combustion for transportation. The heavy metal contamination level was lower than the Korean standard, but higher than the background concentration; this indicates that the soil was affected by the operation of the railways.

• Economic and Environmental Geology
• /
• v.41 no.1
• /
• pp.63-79
• /
• 2008

Physicochemical characteristics of stream water, leachate, mine water and groundwater were investigated to estimate the influences of the tailing and waste rock from the abandoned Uljin mine area. Total extraction analysis and mineralogical studies were carried out to understand sulfide weathering and to determine the distributions of trace elements in the soil affected by mine waste (tailing, waste rock and leachate). The pH and EC value of the leachate from the tailing disposal ranged 2.9-6.0, $99{\sim}3,990{\mu}S/cm$, respectively, and the concentrations of dissolved major (up to 492 mg/l Ca; 83.8 mg/l Mg; 45.2 mg/l Na; 44.7 mg/l K, 50.8 mg/l Si) and trace elements (up to $826,060{\mu}g/l$ Fe; $131,230{\mu}g/l$ Mn; $333,600{\mu}g/l$ Al; $61,340{\mu}g/l$ Zn; $2,530{\mu}g/l$ Cu; $573{\mu}g/l$ Cd; $476{\mu}g/l$ Pb) were relatively high. The stream water showed the variation of dissolved metal concentrations in seasonally and spatially. The dissolved metal contents of the stream water increased by influx the leachate from the tailing disposal, but these of the down stream have been considerably decreased by mixing of dilute tributaries. The dissolved metal concentrations of the stream water at dry season (as February) were lower than these at rainy season (as May and July). These represent that the amounts of the leachate varied with season. However, stream water could not be effectively diluted by confluence with uncontaminated tributaries, because the flux of tributaries and streams reduced at dry season. Thus attenuations by dilution had been dominantly happened in rainy seasons. The order of accumulations of trace element in soils compared with background values revealed Mn>Fe>Pb>Cu>Zn. Sulfide minerals were mainly pyrrhotite, sphalerite and galena and chalcopyrite. Pyrrhotite was rapidly weathered along the edge and fractures, and results in the formation of Fe-(oxy)hydroxides, which absorbed a little amount of Zn.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.2
• /
• pp.177-184
• /
• 2012

This experiment was carried out to investigate soil properties and the requirement of livestock manure compost in a large-scale environment-friendly agricultural complex (EFAC), Gosan, Wanju-gun, Jeonbuk. Total cultivation area of major crops was 2,353 ha. This complex area included different types of environment-friendly cropping sections (402.9ha) and livestock farming including 21,077 Korean beef cattle, 1,099 dairy cow, and 32,993 hog. Amount of livestock waste carried in to Resource Center for Crop and Livestock Farming (RCCLF) was 32 Mg per day and the production of manure compost was 9,600 Mg per year. The manure contained 1.4% total nitrogen (T-N), 2.7% phosphorus as $P_2O_5$, 2.1% potassium as $K_2O$, 0.9% magnesium as MgO, 2.5% calcium as CaO. Amount of compost used in the EFAC was 6,588 Mg per year. Soil pH values in the EFAC were varied as follows: 78.1% of paddy field soil, 58.2% of upland soil, 60.3% of orchard field soil, and 62.1% of greenhouse soil were in proper range. For the content of soil organic matter, 41.7% of paddy field soil, 46.5% of upland soil, 40.5% of orchard field soil, and 81.4% of greenhouse soil were higher than proper range. The content of available phosphorus was mostly higher than proper value on the different fields except upland soil. The contents of exchangeable $K^+$, $Ca^{2+}$, and $Mg^{2+}$ were also exceeded in the orchard field and greenhouse soils. In addition, microbial population, especially aerobic bacteria, in the EFAC was higher than that in regular farming land.

• Korean Journal of Environmental Agriculture
• /
• v.11 no.1
• /
• pp.77-85
• /
• 1992

Of the cadmium-tolerant 162 bacterial strains isolated from soils, river waters or active sludges of waste-water disposal plants in the Gyeongnam province a strain C1, which showed considerably higher growth rate in the agar plate containing 2000 ppm than any other strains isolated, was identified as a Pseudomonas putida or its similar strain when analyzed by taxonomical characteristics. Optimum pH and temperature for the growth of the P, putida were 7.0 and $30^{\circ}C$, respectively. This strain was resistant to antibiotics(ampicillin, chloramphenicol and streptomycin), and heavy metals(lithium, cupper, lead and zinc). This strain utilized salicylate, naphthalene or xylene as a sole carbon source. The rate of cadmium accumulation in P. putida cell was enhanced at low concentration of Cd in the growth media. The maximum cadmium absorption by this strain grown in 1 and l0ppm of Cd was respectively 78% and 60% 24 hrs after culture, but in 100 ppm Cd, 40% 48 hrs after culture. Addition of a non-ionic surfactant Triton X-100(0.1%) to the medium enhanced the accumulation of cadmium in the P. putida up to approximately 37%.

• Ecology and Resilient Infrastructure
• /
• v.3 no.4
• /
• pp.279-284
• /
• 2016

Mine tailings generated during mining activity often contain high concentrations of heavy metals, with pyrite-containing mine tailings in particular being a major cause of environmental problems in mining areas. Chemical cell technology, or fuel cell technology, can be applied to leach heavy metals in pyrite-containing mine tailings. As pyrite dissolves through spontaneous oxidation (i.e. galvanic oxidation) in the anode compartment of the cell, $Fe^{3+}$, sulfuric acid are generated. A decrease in pH due to the generation of sulfuric acid allows heavy metals to be leached from pyrite-containing mine tailings. In this study, pyrite was dissolved for 4 weeks at $23^{\circ}C$ in an acidic solution (pH 2) and in a galvanic reactor, which induces galvanic oxidation, and total Fe leached from pyrite and pH were compared in order to investigate if galvanic oxidation can facilitate pyrite oxidation. The change in the pyrite surface was analyzed using a scanning electron microscope (SEM). Comparing the total Fe leached from the pyrite, there were 2.9 times more dissolution of pyrite in the galvanic reactor than in the acidic solution, and thus pH was lower in the galvanic reactor than in the acidic solution. Through SEM analysis of the pyrite that reacted in the galvanic reactor, linear-shaped cracks were observed on the surface of the pyrite. The study results show that pyrite dissolution was facilitated through the galvanic oxidation in the galvanic reactor, and also implied that the galvanic oxidation can be one remediation option for pyrite-containing mine tailings.

• Korean Journal of Remote Sensing
• /
• v.37 no.2
• /
• pp.233-243
• /
• 2021

Photovoltaic panels are hazardous electronic waste that has heavy metal as one of the hazardous components. Each year, hazardous electronic waste is increasing worldwide and every heavy rainfall exposes the photovoltaic panel to become the source of heavy metal soil contamination. the development needs a monitoring technology for this hazardous exposure. this research use relationships between SAR temporal baseline and coherence of Sentinel-1 satellite to detected photovoltaic panel. Also, the photovoltaic plant detection tested using the difference between that photovoltaic panel and the other difference surface of coherence. The author tested the photovoltaic panel and its environment to calculate differences in coherence relationships. As a result of the experiment, the coherence of the photovoltaic panel, which is assumed to be a permanent scatterer, shows a bias that is biased toward a median value of 0.53 with a distribution of 0.50 to 0.65. Therefore, further research is needed to improve errors that may occur during processing. Additionally, the author found that the change detection using a temporal baseline is possible as the rate of reduction of coherence of photovoltaic panels differs from those of artificial objects such as buildings. This result could be an efficient way to continuously monitor regardless of weather conditions, which was a limitation of the existing optical satellite image-based photovoltaic panel detection research and to understand the spatial distribution in situations such as photovoltaic panel loss.

• Korean Journal of Environmental Agriculture
• /
• v.16 no.4
• /
• pp.394-398
• /
• 1997

Changes of nutrient material and heavy metals of irrigation water and natural supplies by irrigation water into 1.0ha of paddy field during the rice cultivation was investigated pH of irrigation water ranged 6.458.34 and electrical conductivity showed $110{\mu}S/cm$ in the first irrigation period and commonly showed $90{\mu}S/cm$. The content of T-N, NH4-N and $NO_3-N$were 3.09~12.36, 0.17~1.34 and 2.70~10.72mg/L respectively. The content of T-P was 0.09~0.22mg/L and ortho-P was not detected. The content of $Ca^{++},\;Mg^{++},\;Na^+\;and\;K^+$ showed 0.89~5.12, 1.12~2.76, 1.74~4.52 and 1.34~4.18mg/L regardless of irrigation season respectively. Only Cu and Zn of heavy metals were detected 0.001~0.009 and 0.007~0.091mg/L, but Pb, Cd, Cr and Ni were not detected When supplied $4,250m^3$ of an irrigation water into 1.0㏊ of paddy field, natural supplies of nutrient materials were 29.67㎏ of T-N, 1.80㎏ of $NH_4-N$, 24.57kg of NO3-N and 0.51kg of T-P. Also $Ca^{++},\;Mg^{++},\;Na^+,\;K^+,\;Cl^-\;and\;SO_4\;^{2-}$ were supplied 9.42, 7.09, 13.34, 9.08, 40.27 and 41.38kg respectively. Only Cu and Zn of heavy metals were supplied 0.017kg of Cu and 0.133kg of Zn, Pb, Cd, Cr and Ni were not supplied

• Journal of Food Hygiene and Safety
• /
• v.27 no.2
• /
• pp.152-160
• /
• 2012

The objective of this study was to analyze hazards for the growing stage of 6 tomato farms (A, B, C; soli farms, D, E, F; Nutriculture farms) located in Gyeongsangnam-do to establish the good agricultural practices (GAP). A total of 144 samples for analyzing hazards collected from cultivation environments (irrigation water, soil, nutrient solution, and air) and personal hygiene (hands, gloves, and cloths) were assessed for biological (sanitary indications and major food borne pathogens) and chemical hazards (heavy metals). Total bacteria, coliform, and fungi were detected at levels of 0.2-7.2, 0.0-6.1, and 0.0-5.4 log CFU/g, mL, hand or 100 $cm^2$, respectively. Escherichia coli were only detected in the soil sample from B farm. In case of pathogens, Bacillus cereus was detected at levels of 0.0-4.4 log CFU/(g, mL, hand or 100 $cm^2$), whereas Staphylococuus aureus, Listeria monocytogenes, E. coli O157, and Salmonella spp. were not detected in all samples. Heavy metals as a chemical hazard were detected in soil and irrigation water, but levels of them were lower than the permit limit. In conclusion, chemical hazard levels complied with GAP criteria, but biological hazards at the growing stage of tomato farms were confirmed. Therefore a proper management to prevent microbial contamination is needed.

• Korean Journal of Environmental Agriculture
• /
• v.23 no.4
• /
• pp.203-210
• /
• 2004

This study was conducted to assessment organic compound and bioassay (density of inhabited animal, fluctuation of predominant fungi, and survival ratio of earthworm) for finding damage on red pepper by heavily amount application of sludges in soil, which was treated with 3 pharmaceutical byproducts and a cosmetic industry wastewater sludge as raw materials of compost, and for establishing estimation method. HEM contents in the soil treated with pharmaceutical byproducts sludge2 (PS2) and cosmetic sludge (CS) were 0.51, 1.10 mg/kg respectively. PAHs content of PS2 treatment in the soil was 3406.8 ug/kg on July 8. In abundance of soil faunas, the pharmaceutical byproducts sludge2 treatment was the most highest. The next was decreased in the order of pig manure (PM) and the cosmetic sludge treatment. However the other pharmaceutical sludge treatments were remarkably reduced populations of soil inhabited animals. In upland soil treated with organic sludges, the numbers of bacteria and fungi of the pharmaceutical sludge treatment were 736, 909 cfu/g and those of the cosmetic sludge treatment were 440, 236 cfu/g, respectively. The pharmaceutical sludge treatments and the cosmetic sludge treatment in identification of predominant bacteria were not any tendency to compare with non fertilizer and pig manure treatments, but they had diverse bacteria than NPK treatment. In microcosm tests, the survival of the tiger earthworm in five soil samples was hardly affected against the soil of PSI (20%) after three months treated in the upland But after six months, survival of PS1 was 80%. At present, raw material of compost was authorized by contents of organic matter, heavy metal (8 elements), and product processing according to 'The specified gist on possible materials of using after analysis and investigation among raw materials of compost', however, for preparing to change regulation of raw material of compost and for considering to possibility of application, this study was conducted to investigate toxic organic compound and bioassay methods using inhabited animal, fungi, and earthworm without current regulation.