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Investigation of Pollution of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Soil near Railway Rails

철도레일 부근 토양의 다환방향족 탄화수소 및 중금속 오염도 조사

  • Choi, Hyun-Kyung (GyeongSangBukdo Goverment Public Institute of Health and Environment) ;
  • Yoon, In-Ju (GyeongSangBukdo Goverment Public Institute of Health and Environment) ;
  • Shin, Tae-Cheon (Department of Environmental Engineering, Andong National University) ;
  • Kim, Young-Hun (Department of Environmental Engineering, Andong National University)
  • 최현경 (경상북도 보건환경연구원) ;
  • 윤인주 (경상북도 보건환경연구원) ;
  • 신태천 (안동대학교 환경공학과) ;
  • 김영훈 (안동대학교 환경공학과)
  • Received : 2018.05.08
  • Accepted : 2018.07.10
  • Published : 2018.11.30

Abstract

Trains have been a major means of transport in Korea during these past decades. However, train facilities such as stations and repair shops are contaminated with organic and inorganic substances. There is a high probability of train facility contamination with polyaromatic hydrocarbons (PAHs). This study evaluated the PAH and heavy metal contamination of soil near railroads in the Kyungpook area. A total of 18 soil samples were collected from the railroads and analyzed for 16 PAHs and 6 heavy metal species. The contamination level of the top soil was found to be slightly higher than that of the subsoil for contamination with PAHs. The ratio of carcinogenic PAH concentration to the total PAH concentration was relatively high, with a maximum of 0.9. The toxicity equivalent (TEQ) of the PAHs were 500.6 ng/kg in the topsoil and 355.5 ng/kg in the subsoil. The ratio of low molecular PAHs (LPAHs) to high molecular PAHs (LPAHs) ranged from 6.7 to 29.5; this shows that contamination is primarily due to combustion of fuel rather than due to petroleum. The ratio of phenanthrene to anthracene and the ratio of fluoranthene to pyrene also show that contamination occurred due to combustion for transportation. The heavy metal contamination level was lower than the Korean standard, but higher than the background concentration; this indicates that the soil was affected by the operation of the railways.

Keywords

References

  1. Badawy, M. I,, Al-Mujainy, I. S., Hernnadez, M. D., 1993, Petroleum derived hydrocarbons in water, sediment and biota from the Mina-Al-Fahal Coastal waters. Mar Pollut Bull.
  2. Choi, Y. J., Yoo, E. H., Kim, M. H., 2012, Characteristics of Polycyclic Aromatic Hydrocarbons (PAHs) distribution in Busan Soils, The Annual Report of Busan Metropolitan city Institute of Health & Environment, 22(1), 216-234.
  3. Debajyoti, R., Abhijit, C., 2017, Polycyclic aromatic hydrocarbons over a tropical urban and a high altitudeHimalayan Station in India: Temporal variation and source apportionment, Atmospheric Research, 197, 331-341. https://doi.org/10.1016/j.atmosres.2017.07.010
  4. Hassan, A., Moustafa, Y. M., Agrama, A., 2006, Environmental Studying of Polynuclear Aromatic Hydrocarbons (PAHs) in the South Area of Manzala Lake Water, 2nd International Conference for Environmental Science and Technology, National water research center Egypt.
  5. Helfrish, J., Armstrong, D. E., 1986. Polycyclic aromatic hydrocarbons in sediments of southern basin of Lake Michigan, J Great Lake Res.
  6. IARC, 1987, verall evaluation of carcinogenicity: an updating of IARC monographs, 1-42.
  7. IARC, 1989, IARC Monographs on the Evauatioin of Caecinogenic Risks to Humans. Diesel and Gasoline Engine Exhausts and Some Nitroarenes, Monographs, 56, 41-57.
  8. Jung, W. S., Park, D. S., Yang, J. W., 2003, A Basic study on the remediation of railroad oil-contamination soil, Korean Society for Railway, 484-490.
  9. Kang, H. H., Lee, I. S., Huh, I. A., Shin, W. S., Hwang, I. S., Kim, Y. H., Hur, J., Shin, H. S., Kim, J. H., Oh, J. E., 2010, Assessment of Distribution Patterns and Sources for PAHs, OCPs, and Co-PCBs in the Surface Sediments from the Nakdong River Basin, Korea, Korean Society of Environmental Engineers, 32(7), 656-664.
  10. Kim, H. M., 2009, Experimental Study on the Treatment of Combined Pollution of Oil and Heavy Metals in Railway Site, Journal of Soil and Groundwater Environment, 307-308.
  11. Kim, P. H., Kim, M. J., Jo, M. R., Lee, D. S., Song, K. C., Byun, H. S., Cho, K. C., Park, K. J., Jun, J. C., Yoon, H. D., 2010, Polycyclic Aromatic Hydrocarbons Hazard Assessment of Shellfish due to Oil Spill Accidents, Korean journal of fisheries and aquatic sciences, 43(3), 211-216. https://doi.org/10.5657/kfas.2010.43.3.211
  12. Kim, T. S., Park, J. G., Yoon, K. J., Eom, I. C., Chung, I. R., Sihn, S. K., Park, J. S., Lee, K. Y., An, Y. J., 2007, Establishment of the Soil Quality Standards for Organic Pollutants(II), National Institute of Environmental Research.
  13. Larsen, J. C., Larsen, P. B., 1998, Chemical carcinogens. In: Hester, R. E., Harrison, R. M.(Eds.), Air Pollution and Health. Royal Society of Chemistry, Cambridge, UK, 33-56.
  14. Lee, D. S., Shin, Y. S., Jo, G. T., 2000, Responding to international joint regulation of persistent organic pollutants, News & Information for Chemical Engineers, 18(5), 543-550.
  15. Ministry of Environment, 2016, Soil Environmental Conservation Act.
  16. Ministry of Environment, 2016, Soil official testing method in Korea.
  17. Nisbet, I. C. T., LaGoy, P. K., 1992, Toxic equivalency factors (TEFs) for polycyclicaromatic hydrocarbons (PAHs), Regulatory Toxicology and Pharmacology 16, 290-300. https://doi.org/10.1016/0273-2300(92)90009-X
  18. Noh, H. J., Yoon, J. K., Yun, D. G., Yu, S. J., Kim, T. S., Lee, J. Y., 2014, The Influence of Land Use on the Concentration Levels and Distribution Characteristics of Polycyclic Aromatic Hydrocarbons (PAHs) in Korea, J. Soil Groundw. Environ, 19(6), 59-71. https://doi.org/10.7857/JSGE.2014.19.6.059
  19. Oa, S. W., Lee, T. G., 2009, Investigation of Soil Pollution Status for Railroad Depot, Journal of the Korean Society for Reilway, 12(5), 788-792.
  20. Shin, K. H., 2015, Case study on environmental impact assessment of soil in road and railway projects, Korea Environment Institute.
  21. UNEP, 2003, Stockholm Convention for the International Regulation of Persistent Organic Pollutants, United Nations Environment Programme.
  22. United States Environmental Protection Agency, US EPA, 1993, Provisional Guidance for Quantitative Risk Assessment of Polycyclic Aromatic Hydrocarbons, EPA/600/R- 93/089.
  23. WHO, 1987, polynuclear aromatic hydrocabons, In: Air quality guidelines for Europe, Copenhagen, World Health Organization Rerional Office for Europe, 105-117.
  24. WHO, 1997, on-heterocyclic polycyclic aromatic hydrocarbons, Geneva, International program on chemical safety.
  25. WHO, 1998, elected non-heterocyclic polycyclic aromatic hydrocarbons, Geneva, World Health Organization (Environmental Health Criteria No. 202).