• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.1-8
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• 2003

Three different surfactants, APG, Brij30, and SDS, were tested to study the characteristics of sorption on soil surfaces, washing ability, biodegradability, and electrokinetic removal. Kaolinite and phenanthrene were selected as a model soil and a representative HOC, respectively. Phenanthrene was sorbed on kaolinite up to 2,200 mg/kg dry soil. The APG, Brij30, and SDS were sorbed on soil to 40, 7, and 4g/kg soil, respectively. The washing ability of phenanthrene was in order of Brij30＆gt;SDS＆gt;APG. The biodegradability tested with sludge was in order of APG＆gt;Brij30＆gt;SDS. In the electrokinetic test, the highest removal efficiency was obtained with APG that exhibited the highest electroosmotic flow. To increase the removal efficiency of HOC in the electrokinetic remediation, the most important factor was the selection of surfactant which maximized the electroosmotic flow.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.1
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• pp.16-23
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• 2021

Lithium carbonate recovered from the waste solution generated during the lithium secondary battery manufacturing process contains heavy metals such as cobalt, nickel, and manganese. In this study, the recrystallization of lithium carbonate was performed to remove heavy metals contained in the powder and to increase the purity of lithium carbonate. First, the leaching efficiency of lithium carbonate according to pH in the aqueous hydrochloric acid solution was examined, and the effect on the recrystallization of lithium carbonate according to the equivalent and concentration of sodium carbonate was confirmed. As the equivalent and concentration of sodium carbonate increased, the recovery rate of lithium carbonate improved. And the SEM image showed that the crystal shape was changed depending on the reaction conditions with sodium carbonate. Finally, the high purity lithium carbonate of 99.9% or more was recovered by washing with water.

• Proceedings of the Korea Water Resources Association Conference
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• 2005.05b
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• pp.1083-1087
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• 2005

하수처리장의 침전지는 고형물(SS)을 침전, 제거하여 하수를 정화하는 시설로서 생물학적처리에 의해 발생하는 슬러지와 처리수를 분리하는 것을 주목적으로 한다. 장방형침전지의 경우, 유입된 하수가 침전지의 전 단면에 걸쳐 균일하게 도달하게 하기 위하여 $6\~20\%$ 정도의 유공율을 가진 유공정류벽을 설치하며 유효 침전구역에서의 유속은 0.08 m/sec 이하가 되도록 설계되어야 한다. 지금까지 침전지 유입부의 설계시에는 상기 설계기준만을 참조하여 설계가 진행되고 있는 실정으로 보다 나은 대안을 도출하기 위한 분석은 미흡한 실정이다. 본 연구에서는 3차원 수치모형인 FLOW-3D를 이용하여 침전지의 유입부 설계를 위한 설계인자를 도출하였다. 특히 유공정류벽의 크기, 위치 유공율에 따라서 유입하수의 수리적인 특성을 3차원적으로 분석하였다. 저류벽의 위치에 따른 유량의 분배효과를 검토하기 위하여 저류벽의 폭, W를 2.4 m로 고정하고 유입부에서 저류벽까지의 거리, L을 1.5 m, 2.0 m, 2.5 m로 변화시키며 수치모의를 수행하였다. 그리고 저류벽의 폭에 따른 유량의 분배효과를 검토하기 위하여 L을 고정하고 W를 변화시키며 수치모의를 수행하였다. 유공정류벽의 유공율에 따른 유량의 연직 분배효과를 검토하기 위하여 유공율을 변화시키며 연직위치별 통과유량을 산정하였다 각 모의조건에 대한 통과유량 산정결과, 유공율이 $7\%$일때 통과유량의 표준편차가 가장 작게 발생하며, 유공율이 $7\%$보다 감소하거나 증가하면 표준편차가 증가하고 있음을 알 수 있다. 본 연구에서는 상용 CFD모형인 FLOW-3D를 계획 중인 하수처리장의 침전지 유입부 설계에 적용하였으며 저류벽의 위치와 폭, 유공정류벽의 유공율에 따른 유입하수의 분배효과를 분석하였다. 실험을 수행하여 보다 정밀한 공식으로 개선할 수 있었다.$10,924m^3/s$ 및 $10,075m^3/s$로서 실험 I의 $2,757m^3/s$에 비해 통수능이 많이 개선되었음을 알 수 있다.함을 알 수 있다. 상수관로 설계 기준에서는 관로내 수압을 $1.5\~4.0kg/cm^2$으로 나타내고 있는데 $6kg/cm^2$보다 과수압을 나타내는 경우가 $100\%$로 밸브를 개방하였을 때보다 $60\%,\;80\%$ 개방하였을 때가 더 빈번히 발생하고 있으므로 대상지역의 밸브 개폐는 $100\%$ 개방하는 것이 선계기준에 적합한 것으로 나타났다. 밸브 개폐에 따른 수압 변화를 모의한 결과 밸브 개폐도를 적절히 유지하여 필요수량의 확보 및 누수방지대책에 활용할 수 있을 것으로 판단된다.8R(mm)(r^2=0.84)$로 지수적으로 증가하는 경향을 나타내었다. 유거수량은 토성별로 양토를 1.0으로 기준할 때 사양토가 0.86으로 가장 작았고, 식양토 1.09, 식토 1.15로 평가되어 침투수에 비해 토성별 차이가 크게 나타났다. 이는 토성이 세립질일 수록 유거수의 저항이 작기 때문으로 생각된다. 경사에 따라서는 경사도가 증가할수록 증가하였으며 $10\% 경사일 때를 기준으로 $Ro(mm)=Ro_{10}{\times}0.797{\times}e^{-0.021s(\%)}$로 나타났다.천성 승모판 폐쇄 부전등을 초래하는 심각한 선천성 심질환이다. 그러나 진단 즉시 직접 좌관상동맥-대동맥 이식술로 수술적 교정을 해줌으로써 좋은 성적을 기대할 수 있음을 보여주었다.특히 교사들이 중요하게 인식하는 해방적 행동에 대한 목표를 강조

• Korean Journal of Environmental Agriculture
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• v.18 no.3
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• pp.292-297
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• 1999

This study was performed to estimate the possibility of use of plant materials as catalytic agents fur the decontamination of waste waters contaminated with organic pollutants by using 2,4-dichlorophenol(2,4-DCP) as a model pollutant. Plant materials containing high peroxidase activity were selected as catalysts for the removal of 2,4-DCP. Peroxidase activity, which plant materials were containing, was measured, and the greatest peroxidase activity was observed in shepherd's purse, followed by turnip, sweet potato, Chinese cabbage and white radish. The peroxidase activity in shepherd's purse was four times higher than that of horseradish purchased in U.S.A. Using shepherd' s purse and turnip, it was investigated the effect of various factors on the decontamination of 2,4-DCP through oxidative coupling. The removal of 2,4-DCP was extremely fast, and a maximal removal could be achieved within 3 min for shepherd' s purse and 15min for turnip. The pH range was from 3.0 to 8.0 and the amount of $H_2O_2$ added was 9mM when maximal removal was achieved(over 90%). No increasing removal of 2,4-DCP was observed due to increasing the amount of $H_2O_2$ added (over 9mM). The initial concentration affected the transformation of 2,4-DCP incubated with plant materials. When turnip was used as catalytic agent, it was observed decreasing transformation of 2,4-DCP due to increasing initial concentration.

• Economic and Environmental Geology
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• v.35 no.3
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• pp.221-227
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• 2002

Column experiments were performed to evaluate the removal efficiency of soil vapor extraction (SVE) iota TCE (trichloroethylene) and toluene in soil. Homogeneous Ottawa sands and real soils collected from contaminated area were used to investigate the effect of soil properties and SVE operation conditions on the removal efficiency. In column teats with two different sizes of Ottawa sand, the maximum effluent TCE concentration in a coarse sand column was 442 mg/L and 337 mg/L in a fine sand column. However, after 20 liter gas flushing, the effluent concentrations were very similar and more than 90% of initial TCE mass were removed from the column. For two real contaminated soil columns, the maximum effluent concentration decreased 50% compared with that in the homogeneous Ottawa coarse sand column, but 99% of initial TCE mass were extracted from the column within 40 liter air flushing, suggesting that SVE is very available to remove volatile NAPLs in the contaminated soil. To investigate the effect of contaminant existing time on the removal efficiency, an Ottawa sand column was left stable for one week after TCE was injected and the gas extraction was applied into the column. Its effluent concentration trend was very similar to those for other Ottawa sand columns except that the residual TCE after the air flushing showed relatively high. Column tests with different water contents were performed and results showed high removal efficiency even in a high water content sand column. Toluene as one of BTEX compounds was used in an Ottawa sand column and a real soil column. Removal trends were similar to those in TCE contaminated columns and more than 98% of initial toluene mass were removed with SVE in both column.

• Journal of Environmental Impact Assessment
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• v.25 no.5
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• pp.333-344
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• 2016

In this study, the efficiency of natural attenuation was evaluated through the hydrogeological characteristics such as monitoring and analyses, tracer tests, chemical composition analysis of the groundwater at a military site contaminated by petroleum hydrocarbon in korea. Also, based on the results, the natural attenuation rate by distance and the expressed biodegradation capacity(EBC) was evaluated. The regression slope of -0.0248($K/V_x$) and bulk attenuation rate of $1.7{\times}10^{-3}/day$ were calculated respectively. The range of total expressed biodegradation capacity(EBC) of BTEX was shown from 9.1 mg/L to 10.0 mg/L(average 9.7 mg/L). It was confirmed that the denitrification which was expressed about 63.6% in the total EBC is the largest influence redox process. Consequently, the biodegradation capacity is considered to be sufficient for remediation in the BTEX average concentration of 1.326 mg/L.

• KSBB Journal
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• v.14 no.4
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• pp.503-510
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• 1999

In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

• Journal of Korea Water Resources Association
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• v.30 no.5
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• pp.459-465
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• 1997

The possibility of NAPL removal from contaminated soil was studied using the steam injection technique. Both single (octane, toluene and xylene) and composite NAPL (gasoline) were used as contaminant. Soils used in this study were Chumunjin fine sand and weathered granitic soil, both of which are commonly found in Korea. Experimental results showed that with 1 pore volume steam injection, the NAPL removal rate was in the range of 66∼78% for sand and 45∼73% for weathered granitic soil. The steam injection technique seems to have high potential for soil remediation with advantages of relatively short operating time and no side-effect. Rise in the background temperature led to the delay of steam condensation and the increase of NAPL mobility, which resulted in the improvement of removal efficiency. In addition, water flooding after steam injection turned out to be a very efficient way of removing NAPL residual in the soil pores.

• Journal of Korea Water Resources Association
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• v.36 no.5
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• pp.787-797
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• 2003

The characteristics of concentrations and loads of Total Nitrogen(T-N), Total Phosphorus(T-P), and Chemical Oxygen Demand (COD) in mountain stream water were examined from September 2000 through August 2001. The 92.5-ha study watershed in Chungbuk Province consists of 59% mixed forest and 30% coniferous forest. Streamflow was measured and water samples were collected at about 10 day intervals for dry days and at 2-6 hour intervals for a storm event at the study watershed outlet. The mean concentration of COD in streamflow for rainy days was significantly (p < 0.05) higher than for dry days. The mean concentrations of T-N and T-P in vegetation growing season (May to October) were lower than those in vegetation dormant season (November to April). Low concentrations of pollutants during vegetation growing season are likely due to the heavy demand for nutrients by the vegetation and biological activity associated with a warming of soil. The ratios of pollutants loads during storm periods to annual pollutants loads were 87% for T-N, 83% for T-p, and 87% for COD. The unit loads of pollutants for study area were estimated at 5.9 kg/ha $\cdot$ yr for T-N, 0.15 kg/ha $\cdot$ yr for T-p, and 23.9 kg/ha $\cdot$ yr for COD. The removal efficiency of pollutants in study area were 24% for T-N, 58% for T-P and 66% for COD, indicating that a study area shows water purification function.

• Economic and Environmental Geology
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• v.41 no.6
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• pp.709-717
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• 2008

Rhizofiltration for cesium uptake by sunflowers (Helianthus annuus L.) and beans (Phaseolus vulgaris var.) was investigated for groundwater contamination. The cesium removal by sunflowers was greater than 98% of the total cesium in solution, and the uptake by beans was also greater than 99% within 24 hours of the rhizofiltration, showing that the rhizofiltration has a great capability to remove cesium from the contaminated water system. Experiments at various pH of solution indicated that a solution of pH $5{\sim}9$ yielded very high cesium accumulation in two plants. From the results of the analysis for cesium accumulation in plant parts, about 80% of cesium transferred into the plant from solution was accumulated in the root part and less than 20% of cesium existed in the shoot part (including leaves). Results suggest that only the roots of the fully grown plant used for rhizofiltration should be disposed or post-treated and thus the cost and time to treat massive amounts of grown plants could be dramatically reduced when sunflower and bean are used in the real field. The results of SEM and EDS analyses indicated that the most of cesium were accumulated in the root surface as a ionic phase rather than a soil precipitation phase.