• Title/Summary/Keyword: 전기적 특성 측정

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Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

A Study on the Stability of Ultra-Thin Film Mixed with Stearic Acid and Phospholipid (스테아르산과 인지질 혼합물의 농도변화에 대한 유기초박막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.789-794
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    • 2015
  • In this study, we investigated the stability with respect to the Langmuir-Blodgett(LB) monolayer films of stearic acid and phospholipid(L-${\alpha}$-dimyristoylphosphatidyl choline, DMPC) mixture. LB films of stearic acid and DMPC monolayer were deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with three-electrode system in $0.05N\;NaClO_4$ solution, -0.3 V initial, 1650 mV switching potential and -1350 mV final potential. As a result, monolayer LB films of stearic acid and phospholipid mixture was appeared on irreversible process caused by the oxidation current from the cyclic voltammogram. Diffusion coefficient (D) of stearic acid and DMPC mixture(molar ratio 1:1, 1:2, 1:3) was calculated $1.4{\times}10^{-3}$, $1.7{\times}10^{-3}$ and $1.6{\times}10^{-3}(cm^2/s)$ in $0.05N\;NaClO_4$ solution, respectively.

The Experimental Study on Characteristics of Valve System using Hole Type Valve Lift Sensor (밸브 거동 특성 파악을 위한 hole 센서의 적용에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Yong-Gyu;Lee, Seong-Jin;Choi, Kyo-Nam;Jeong, Dong-Soo;Park, Sung-Young
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.80-86
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    • 2008
  • Recently, controlled auto ignition(CAI) in gasoline engines are drawing more attentions due to its extremely low level of NOx emissions and potentials in lowering the fuel consumption rate. The one of the key techniques for realizing CAI combustion in engines is the control of valve system. Since the valve linkage system with higher complexity, or even earn-less valve systems, such as electro-hydraulic and electro-magnetic system, are adopted in CAI engines, it is not easy to estimate the valve lift profile from earn profiles. Therefore new measurement techniques for valve lift in CAI engines have been tried and tested. In this paper, hole type valve lift sensor was developed and tested to check the applicability in CAI engines. The valve lifts could be obtained from the sensor signal, which depends on the distance from the sensor to magnet attached to valve. Various engine speeds, ranging from 2,000 to 6,000 rpm, and valve lifts, maximum up to 9.7 mm, were tested. It was found that the sensor output for valve lift had accuracy of 98% in comparison with the basic specifications of valve lift through improvements of sensor driving circuit.

Solution Growth of SiC Single Crystal from Si-Cr-Co Solvent (Si-Cr-Co 용매로부터 SiC 단결정 용액성장)

  • Hyeon, Gwang-Ryong;Tsuchimoto, Naomich;Suzuk, Koki;Kim, Seong-Jong;Taishi, Toshinori
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.113-113
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    • 2018
  • 환경 친화형 전기자동차, 하이브리드 자동차, 전철 등에서는 고내압 및 소형으로 전력손실을 감소시킬 수 있는 파워 디바이스가 필수이다. 최근, 실리콘 카바이드(SiC, silcon carbide)는 기존 실리콘(Si)보다 스위칭 손실의 저감 및 고온환경에서의 동작 특성이 우수하여, 차세대 저 손실 전력반도체 재료로서 기대를 받고 있다. 용액 성장 법에서 고품질 SiC 결정을 만들 수 있다. 그러나 늦은 성장 속도 때문에 SiC의 양산을 어렵게 하고 있다. 현재까지 성장 속도 향상을 위한 Si용매에 Cr을 첨가하여 탄소 용해도를 높이는 방법이 사용되고 안정된 성장을 위한 Si-Cr용매에 Al를 첨가하는 등 다양한 금속을 첨가하는 방법이 이용되고 있다. 선행 연구에서는 다양한 용매인 탄소 용해도를 실측하고 특히 큰 탄소 용해도를 보인 것은 Co이었다. 본 연구에서는 $Si_{0.6}Cr_{0.4}$원료와 Co를 첨가한 $Si_{0.56}Cr_{0.4}Co_{0.04}$의 용매에 의한 SiC용액 성장을 실시하고 결정 성장 속도 및 표면 상태의 변화를 검토했다. on-axis 4H-SiC(000-1)을 사용한 Top-seeded solution growth(TSSG)법과 원자 비율로 $Si_{0.6}Cr_{0.4}$$Si_{0.56}Cr_{0.4}Co_{0.04}$의 용매를 이용하여 SiC 용액 성장을 실시했다. Ar가스에서 저항 가열로 내를 치환 후에 $1800^{\circ}C$까지 가열하고 종자화 후에 120분간 유지하고 결정 성장을 실시했다. 냉각 후에 성장의 표면에 남은 용매를 $HF+HNO_3$에서 제거했다. 광학 현미경을 이용하여 결정면과 두께를 관찰 측정했다. Co를 첨가한 $Si_{0.56}Cr_{0.4}Co_{0.04}$의 경우는 $Si_{0.6}Cr_{0.4}$의 경우보다 결정 성장 속도가 향상됐다. 또한 $Si_{0.6}Cr_{0.4}$보다 step-flow의 성장을 나타낸 결정의 표면이 전반적으로 관찰됐으며 안정된 결정성장을 나타냈다. 본 연구에서 실시한 연구 방법과 결과는 고품질 및 고속의 SiC 용액성장을 위한 매우 유용한 자료로 활용 될 수 있을 것으로 판단한다.

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Environmental Characteristics of Wedelia prostrata Hemsl. Habitats in Jeju-do (제주도 갯금불초(Wedelia prostrata Hemsl.) 자생지의 환경특성)

  • Kim, Kyung-Ah;Han, Jun-Soo;Cheon, Kyeong-Sik;Yoo, Ki-Oug
    • Korean Journal of Environment and Ecology
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    • v.27 no.1
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    • pp.1-10
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    • 2013
  • The habitats characteristics of Wedelia prostrata were investigated to compile basic data for conservation and restoration. Natural habitats were located at inclinations of $1-40^{\circ}$. Thirty eight vascular plants were identified from 19 quadrats in 7 habitats. The importance value of Wedelia prostrata is 44.77% and 5 highly ranked species such as Vitex rotundifolia(13.32%), Carex pumila(6.75%), Calystegia soldnella(4.24%), Aster hispidus(2.54%) and Artemisa capillaris(2.43%) are considered to be an affinity with Wedelia prostrata in their habitats. Species diversity was 0.79, and dominance and evenness were found to be 0.25 and 0.67, respectively. Average field capacity was 4.51%, the organic matter was 3.37%, pH was 8.17, available phosphorus was $1.33{\mu}g/g$, and electrical conductivity was $802.01{\mu}s/cm$.

Subunits and Composition of Carotenoprotein from Salmo Salar Eggs (연어알에서 분리한 Carotenoprotein의 구조적 특성)

  • Jae-Woong Kim;Tae-Jin Min;Tae-Young Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.377-384
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    • 1988
  • Carotenoprotein from Salmo Salar eggs was purified and characterized by CM-cellulose, 50% $(NH_4)_2SO_4$, DEAE-cellulose and sephadex G-75 column. The chromoprotein had a spectrum with ${\lambda}_{max}$ 409, 540 and 580nm in p-buffer (pH 7.0) at initial step. Molecular weights by sephadex G-200 gel filtration were 50, 200 and 26,000 daltons. SDS-PAGE analysis showed a structure with four identical subunits (12,500 daltons). Its sample retained a small amount of carbohydrates and lipids. Amino acids were analyzed, and mannose, galactose and glucosamine also were identified. Carotenoid extacted with acetone was found to be astaxanthin ester by partition test, epoxy test, iodine test, allylic test, reduction, acetylation, uv/vis, ir and nmr datas. Stearate (47.9%) and palmitate (21.4%) were predominant fatty acids in the astaxanthin ester.

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Studies on the Patterning of Polyimide LB Film and Its Application for Bioelectronic Device (폴리이미드 LB 필름을 이용한 패터닝 및 생물전자 소자로의 응용에 관한 연구)

  • 오세용;박준규;정찬문;최정우
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.634-643
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    • 2002
  • Ultrathin film of polyamic acid having benzene and sulfonyloxyimide moieties was prepared using the Langmuir-Blodgett (LB) technique, and then photosensitive polyimide LB film was obtained by the thermal treatment of precursor polyamic acid multilayers at 200$\^{C}$ for 1 hr. The polyamic acid was synthesized by condensation polymerization under THF and pyridine cosolvent. All monomers and polymers were identified through elemental analysis, FT-IR and $^1$H-NMR spectroscopic measurements. The microarray patterning of photosensitive polyimide LB film on a gold substrate was generated with a deep UV lithography technique. The well-characterized monolayer of cytochrome c was immobilized on the microarray patterns using two different self-assembly processes. Physical and electrochemical properties of the self-assembled cytochrome c monolayer were investigated based on cyclic voltammetry and atomic force microscopy (AFM). Also, its application in bioelectronic device was examined.

Energy Conversion Efficiency of TiO2 Dye-sensitized Solar Cells with WO3 Additive (WO3가 첨가된 TiO2 염료감응형 태양전지의 에너지 전환 효율)

  • Lee, Sung Kyu;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.26-30
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    • 2011
  • In order to improve the energy conversion efficiency of dye-sensitized solar cell (DSSC), the photoelectrode was manufactured by using $TiO_2$ and $WO_3$ on combination effects of two conduction bands. The smash procedure of $TiO_2$ and $WO_3$ was carried out by using a paint shaker to enlarge the contact area of semiconductor with dye and electrolyte. The energy conversion efficiency of prepared DSSC was improved about two times from current-voltage curve based on effects of $WO_3$ and smash. The mechanism was suggested that the conduction band of $WO_3$ worked for prohibiting the trapping effects of electrons in conduction band of $TiO_2$. This result is attributed to the prevention of electron recombination between electron in conduction band of $TiO_2$ with dye and electrolyte. Impedance results indicate the improved electron transport at interface of $TiO_2$/dye/electrolyte.

Design of a Free-form Mueller Matrix Ellipsometer with Imperfect Compensators (불완전한 보정기를 적용한 자유형 뮬러행렬타원계의 설계)

  • Kim, Sang Youl
    • Korean Journal of Optics and Photonics
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    • v.33 no.2
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    • pp.59-66
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    • 2022
  • A free-form Mueller matrix ellipsometer (MME) based on independent control of the azimuthal angle of each polarizing element is introduced. The azimuthal angles of the polarizer and the matching compensator which generate the optimum Stokes vectors of an incident beam are investigated for the polarization state generator, where the spectral responses of the retardation angle and transmittance ratio of a nonideal compensator are taken into account. Similarly, the azimuthal angles of the analyzer and the corresponding compensator are investigated for the polarization-state detector, to unambiguously determine the Stokes vector of the outcoming beam from the sample, and explicit expressions for the Stokes elements are derived. Since the suggested technique enables one to utilize a nonideal quarter-wave plate as the compensator for an MME, it will contribute to the construction and application of a Mueller matrix spectroscopic ellipsometer (MMSE) operating over a wide spectral range from deep ultra-violet to near infrared.

Extraction of Cole-Cole Parameters from Time-domain Induced Polarization Data (시간영역 유도분극 자료로부터 Cole-Cole 변수 산출)

  • Kim, Yeon-Jung;Cho, In-Ky
    • Geophysics and Geophysical Exploration
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    • v.24 no.4
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    • pp.164-170
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    • 2021
  • Frequency-domain and time-domain induced polarization methods can provide spectral information about subsurface media. Analysis of spectral characteristics has been studied mainly in the frequency-domain, however, time-domain induced polarization research has recently become popular. In this study, assuming a homogeneous half-space model, an inversion method was developed to extract Cole-Cole parameters from the measured secondary potential or electrical resistivity. Since the Cole-Cole parameters of chargeability, time constant, and frequency index are not independent of each other, various problems, such as slow convergence rate, initial model problem, local minimum problem, and divergence, frequently occur when conventional nonlinear inversion is applied. In this study, we developed an effective inversion method using the initial model close to the true model by introducing a grid search method. Finally, the validity of the developed inversion method was verified using inversion experiments.