• Title/Summary/Keyword: 유연소재

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Effect of Amino Modified Siloxane on the Properties of Epoxy Composites for MEMS Adhesives (MEMS 접착제용 에폭시 복합재의 아미노 변성 실록산 첨가에 의한 효과)

  • Lee, Donghyun;Yu, Kihwan;Kim, Daeheum
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.203-207
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    • 2009
  • In the NCAs(non-conductive adhesive) for adhesion of Micro Electro Mechanical System(MEMS), there are some problems such as delamination and cracking, because of the differences of CTE(coefficients of thermal expansion) between NCAs and substrates. Addition of inorganic particle or flexibilizer have been performed to solve those problems. In this study, to improve the flexibility of epoxy adhesive, epoxy/siloxane composites were prepared by adding 1, 3, or 5 phr of amino modified siloxane(AMS). Glass transition temperatures(Tg), moduli and CTE of those composites were measured to confirm effects of siloxane on thermal/mechanical properties of siloxane/epoxy-composites. Tg of AMS/epoxy-composites decreased from $134^{\circ}C$ to $122^{\circ}C$ with increasing AMS contents and moduli decreased from 2,425 MPa to 2,143 MPa with increasing AMS contents. But CTE of AMS/epoxy-composites increased from $67ppm/^{\circ}C$ to $71ppm/^{\circ}C$ with increasing AMS contents. In short, the addition of siloxane is effective for enhancing the flexibility of epoxy but leads to the decrease of Tg.

Investigation on Electrochemical Property of CNT Fibers and its Non-enzymatic Sensing Performance for Glucose Detection (CNT Fibers의 전기화학적 특성 및 비효소적 글루코스 검출 성능 고찰)

  • Song, Min-Jung
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.159-164
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    • 2021
  • As the attachable-type wearable devices have received considerable interests, the need for the development of high-performance electrode materials of fabric or textiles type is emerging. In this study, we demonstrated the electrochemical property of CNT fibers electrode as a flexible electrode material and its non-enzymatic glucose sensing performance. Surface morphology of CNT fibers was observed by SEM. And the electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fibers based sensor exhibited improved sensing performances such as high sensitivity, a wide linear range, and low detection limit due to improved electrochemical properties such as low capacitive current, good electrochemical activity by efficient direct electron transfer between the redox species and the electrode interface. Therefore, this study is expected to be used as a basic research for the development of high performance flexible electrode materials based on CNT fibers.

Laser Transmission Welding of Flexible Substrates and Evaluation of the Mechanical Properties (플렉서블 기판의 레이저 투과 용접 및 기계적 특성 평가)

  • Ko, Myeong-Jun;Sohn, Minjeong;Kim, Min-Su;Na, Jeehoo;Ju, Byeong-Kwon;Park, Young-Bae;Lee, Tae-Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.2
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    • pp.113-119
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    • 2022
  • In order to improve the mechanical reliability of next-generation electronic devices including flexible, wearable devices, a high level of mechanical reliability is required at various flexible joints. Organic adhesive materials such as epoxy for bonding existing polymer substrates inevitably have an increase in the thickness of the joint and involve problems of thermodynamic damage due to repeated deformation and high temperature hardening. Therefore, it is required to develop a low-temperature bonding process to minimize the thickness of the joint and prevent thermal damage for flexible bonding. This study developed flexible laser transmission welding (f-LTW) that allows bonding of flexible substrates with flexibility, robustness, and low thermal damage. Carbon nanotube (CNT) is thin-film coated on a flexible substrate to reduce the thickness of the joint, and a local melt bonding process on the surface of a polymer substrate by heating a CNT dispersion beam laser has been developed. The laser process conditions were constructed to minimize the thermal damage of the substrate and the mechanism of forming a CNT junction with the polymer substrate. In addition, lap shear adhesion test, peel test, and repeated bending experiment were conducted to evaluate the strength and flexibility of the flexible bonding joint.

Fatigue Safe Life Analysis of Helicopter Bearingless Rotor Hub Composite Flexbeam (헬리콥터 무베어링 로터 허브 복합재 유연보 피로 안전수명 해석)

  • Kim, Taejoo;Kee, Youngjoong;Kim, Deog-Kwan;Kim, Seung-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.7
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    • pp.561-568
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    • 2013
  • After we designed Bearingless rotor hub system for 7,000lb class helicopter, flexbeam fatigue analysis was conducted for validation of requirement life time 8,000 hours. sectional structural analysis method applying elastic beam model was used. Fatigue analysis for two sections of flexbeam which were expected to weak to fatigue damage from result of static analysis was conducted. Extension, bending and torsion stiffness of flexbeam section shape was calculated using VABS for structure analysis. S-N curve of two composite material which composed flexbeam was generated using wohler equation. Load analysis of bearingless rotor system was conducted using CAMRAD II and load analysis result was applied HELIX/FELIX standard load spectrum to generate bearingless rotor system load spectrum which was used flexbeam fatigue safe life analysis.

Effects of Parental Attachment on Career Maturity in University Students: Moderating Effect of Career Decision-Making Self-Efficacy and Cognitive Flexibility (대학생의 부모애착이 진로성숙도에 미치는 영향 : 진로결정 자기효능감과 인지적 유연성의 조절효과)

  • Lee, Hoo-Jung;Park, Ji-Yeon;Cho, Kyung-duk
    • The Journal of the Korea Contents Association
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    • v.20 no.3
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    • pp.324-335
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    • 2020
  • This study sought to find out the impact of a university student's parental love on their career maturity and the effect of adjusting their career-setting self-efficiency and cognitive flexibility in their relationship. For this purpose, 362 college students in Daejeon, Chungnam, and Seoul were analyzed, there were significant differences between parental attachment and career-setting self-efficiency depending on gender, according to the study. Second, career-setting self-efficiency had a significant impact on career maturity. Third, the effect of controlling cognitive flexibility and career-setting self-efficiency was seen between parental affections and career maturity. This shows that parents attachment may have different effects on university students' career maturity, depending on the degree of career-setting self-efficiency, cognitive flexibility in the process of parental affection affecting the university students' career maturity. Therefore, it can be used to develop various programs that can help individuals decide their career path with recognizing that there are different internal factors within the university student group.

탄소나노튜브의 스프레이 분사법을 이용한 투명전도성 플렉서블 필름 제작

  • Sin, Ui-Cheol;Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.79-79
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    • 2010
  • 최근, 차세대 디스플레이, 터치스크린, 전자파 차폐 및 흡수 등의 분야에 응용하기 위해서 현재 주로 사용되고 있는 ITO박막을 대체하기 위한 연구가 활발하게 진행 되고 있다. ITO 박막은 희소원소인 인듐에서 기인하는 높은 비용뿐만 아니라 매장량도 한계가 있어 대체 재료의 개발이 시급하게 요구되고 있다. 더구나, 다양한 차세대 응용에 있어서는 투명전도성 뿐만 아니라 휠 수 있는 유연성까지 요구되어 ITO박막을 대체할 새로운 투명전도성 유연 박막의 개발에 관한 연구들이 활발히 이루어지고 있다. 탄소나노튜브(CNT)는 금속을 능가하는 이론적인 전기전도도를 갖고 있으며, 높은 탄성등의 우수한 기계적 성질을 갖고 있어, 전도성 확보 및 유연성 구현이라는 투명전도성 플렉서블 박막소재에 요구되는 사항들을 충족시킬 뿐만 아니라, 최근의 대량 합성법등의 개발로 저가에 공급할 수 있다는 장점들이 있어 ITO대체 재료로서 주목을 받고 있다. 그러나, CNT는 튜브 사이에 강한 반데르발스 인력을 가지고 있어 용매 중에 분산하는데 많은 어려움이 있으며, 액상 분산과정을 통한 CNT기반의 플렉서블 박막 제작에 있어서 큰 과제로 남아있다. 본 연구에서는 플라즈마 기능화 처리를 통하여 CNT에 친수성을 부여하였고, 초음파 처리를 통하여 에탄올 중에 CNT를 균일하게 분산한 후, 스프레이 분사법을 이용해 투명 유연기판인 PET고분자 필름위에 균일 박막을 제작하였다. CNT는 아세틸렌 가스를 이용한 열화학증기증착법으로 1mm 이상의 길이를 갖는 수직배향 CNT를 합성하였으며, 이를 아르곤 및 암모니아 플라즈마로 기능화 처리를 실시하였다. 플라즈마 처리를 통해 기능화 된 탄소나노튜브는 플라즈마 처리되지 않은 탄소나노튜브와 분산 속도에서 현저한 차이를 보였다. 제작한 CNT 기반의 투명전도성 유연박막들은 막두께에 따른 전도도 및 투광도의 관계를 조사하였고, 기판에 분사된 CNT 박막의 표면 특성은 AFM, Raman, 접촉각 실험 등을 통하여 분석하였다.

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진공 플라즈마 용사 코팅 조건에 따른 초고온 세라믹 코팅의 미세구조

  • Yu, Yeon-U;Jeon, Min-Gwang;Nam, Uk-Hui;Byeon, Eung-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.135-135
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    • 2016
  • 차세대 가스터빈 엔진 및 초음속 항공기 내 고온부의 온도가 증가함에 따라, 기존의 초내열합금 기반 소재를 사용하기 어려워지고 있다. 초고온 세라믹스는 높은 기계적 물성, 화학적 안정성 등 우수한 고온 특성을 가지고 있어 기존의 초고온 소재를 대체 할 수 있는 물질로 부상되고 있다. 하지만 기존의 금속 기반 소재 대비 높은 밀도로 인하여 초고온 세라믹 단일체를 비행체 부품에 적용하기에는 어려움이 있다. 이에 초고온 세라믹스와 탄소섬유를 포함하는 세라믹 복합체(Ceramic Matrix Composite, CMC)를 제작하여 동등한 기계적 물성을 보이면서 무게를 감소시키는 연구들이 진행 중에 있다. 초고온 세라믹스가 함침 된 세라믹 복합체의 경우 우수한 내삭마, 내산화 특성을 보이지만, 장시간 고온에 노출되어 탄소 섬유가 드러나게 되면 급격한 산화로 인해 소재 특성의 열화가 진행되는 단점을 가지고 있다. 따라서, 탄소 섬유가 드러나지 않도록 복합체 표면에 코팅층을 형성하여 세라믹 복합체 모재를 보호하는 방법이 활발히 연구되고 있다. 본 연구에서는 진공 플라즈마 용사 공정을 이용하여 다양한 공정조건 하에서 초고온 세라믹 코팅층을 형성하였다. 수십 마이크론 크기 분포를 갖는 HfC 분말을 Ar 유송 가스를 이용하여 플라즈마 화염 내부로 투입하였다. 플라즈마 화염 가스는 Ar 과 H2를 혼합하여 구성되었으며, 분위기 가스로는 N2를 사용하였다. 코팅에 사용된 모재로는 ZrB2 단일체와 SiC가 미량 포함된 HfC 단일체를 사용하였다. 다양한 공정 조건하에서 형성된 HfC 코팅층의 두께, 미세 조직구조를 SEM을 이용하여 관찰하였으며, XRD를 이용하여 형성된 HfC 코팅층의 결정구조를 분석하였다.

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Next-Generation Neuromorphic Hardware Technology (차세대 뉴로모픽 하드웨어 기술 동향)

  • Moon, S.E.;Im, J.P.;Kim, J.H.;Lee, J.;Lee, M.Y.;Lee, J.H.;Kang, S.Y.;Hwan, C.S.;Yoo, S.M.;Kim, D.H.;Min, K.S.;Park, B.H.
    • Electronics and Telecommunications Trends
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    • v.33 no.6
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    • pp.58-68
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    • 2018
  • A neuromorphic hardware that mimics biological perceptions and has a path toward human-level artificial intelligence (AI) was developed. In contrast with software-based AI using a conventional Von Neumann computer architecture, neuromorphic hardware-based AI has a power-efficient operation with simultaneous memorization and calculation, which is the operation method of the human brain. For an ideal neuromorphic device similar to the human brain, many technical huddles should be overcome; for example, new materials and structures for the synapses and neurons, an ultra-high density integration process, and neuromorphic modeling should be developed, and a better biological understanding of learning, memory, and cognition of the brain should be achieved. In this paper, studies attempting to overcome the limitations of next-generation neuromorphic hardware technologies are reviewed.

Fabrication of Flexible Passive Matrix by Using Silicon Nano-ribbon (실리콘 나노리본을 이용한 유연한 패시브 매트릭스 소자 제작)

  • Shin, Gun-Chul;Ha, Jeong-Sook
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.338-341
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    • 2011
  • Thin silicon ribbon was used for fabricating flexible silicon p-i-n junction devices, consisting of 100${\times}$100 arrays of pixels in 1 inch on the diagonal. Those passive matrix devices exhibited the rectification ratio $>10^{4}$ owing to smaller cross-talking current than that of p-n junction devices. P-i-n devices fabricated on silica/silicon substrates are easily detached by treatment with hydrofluoric acid and are subsequently transferred onto both PDMS and flexible PET film.

Materials and Compartments for Flexible Dye Sensitized Solar Cell (유연 염료감응 태양전지 소재 및 요소기술 동향)

  • Jung, In-Soo;Park, Byung-Wook;Lee, Jae-Joon
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.86-94
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    • 2015
  • In order to solve incoming environmental crisis and an energy crunch caused by the consumption of fossil fuels, lots of investigations and developments for solar cell application are getting a spotlight in various aspects. Amongst many solar cells, a flexible dye sensitized solar cell is an attractive research field from fundamentals to commercialization. In this manuscript, we introduce materials and available techniques for the future scientific research and technical developments in commercialization.