• Title/Summary/Keyword: 유리조성

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Variation of Frit Size and Firing Conditions for High Transmittance in $P_2O_5$-ZnO-RO Glass System ($P_2O_5$-ZnO-RO 유리계의 고 투과율 특성을 위한 프릿 크기 및 소성조건의 변화)

  • 차명룡;전재삼;정병해;김형순
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.197-197
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    • 2003
  • 현재 PDP(Plasma Display Panel) 투명유전체층은 PbO 계열을 사용하고 있으나 제조공정 시 다량의 중금속 페기물이 방출됨에 따라 환경오염을 야기시킴으로 무연조성이며 저온소성이 가능한 저융점유리인 인산염계 유리에 대한 열적, 화학적, 광학적 특성에 대해 체계적인 연구가 진행되었다. 광학적 특성을 위 한 승온속도, 소성온도, 유지시간의 변화 그리고, 프릿 입도에 따른 광 투광성, 기포의 형성, 그리고 기포의 분포특성을 연구하였다. 열적특성은 DTA와 TMA를 이용하여 유리전이점(Tg) 및 선팽창계수(CTE)와 Littleton softning point (Ts)가 측정되었다. 광학적특성은 스크린프린팅법으로 후막 제조 후 소성하여 UV-visible spectrometer을 이용하여 300~800nm영역에서 투광성을 측정하였으며, FEG-SEM, AFM을 이용해 표면을 관찰하였다. 결과로써, Tg는 440-46$0^{\circ}C$ 와 CTE는 7~8.5$\times$$10^{-6}$K값을 보였고 높은 화학적 내구성과 60-80%의 광투과율을 나타내었다. 프릿의 미세화, 숭온속도의 감소는 기포의 생성을 줄이는데 효과를 보였으며, 그 결과 양호한 광투과율을 얻을 수 있었다. 이러한 결과에 따르면, P$_2$O$_{5}$-ZnO-RO 조성은 PDP용 투명유전체 조성으로써 기존의 PbO계열을 대체할만한 새로운 조성으로 고려된다.

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Analysis of the relationship between composition and viscosity of soda-lime glass bottles (소다석회유리병의 조성과 점도의 상관관계 분석)

  • Seung Min Kang;Chang-Sam Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.7-14
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    • 2023
  • Forty Viscosity data of glass bottles fabricated in a glass bottle manufacturing plant for 4 years were calculated using Lakatos model. The relationship between the glass bottle compositions and viscosities at log η of 3, 6.6, 10 and 12.3 Pa·s was analyzed. MgO that was a component of the glass bottle showed the maximum coefficient of variation of 0.89, but it gave a very small change in the viscosity. CaO that was another component of the glass bottle lowered the isokom temperature because it tended to reduce the number of non-bridging oxygen at temperature below a softening point.

Studies on the Compositions of Amino acid and Fatty acid of Pine caterpillar(Dendrolimus spectabilis) (송충이 단백질의 아미노산과 지방산 조성에 대한 연구)

  • 차월석;신주연김연순
    • KSBB Journal
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    • v.7 no.3
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    • pp.186-190
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    • 1992
  • The compositions of amino acid in the protein and total fatty acid of Dendrolimus spectabilis were analyzed quantitatively by HPLC and GC, respectively. The contents of crude oil and protein from the extracts were 21.00% and 58.47%, respectively. The amount of free amino acids in the protein was 3.65g/100g, and 1.31g/100g of essential amino acids was contained in the free amino acids. The amount of total amino acids in the protein was 41.20g/100g, and 14.75g/100g of essential amino acids were contained in the total amino acid. The compositions of fatty acid in the oil were $C_{18}$=26.81%, $C_{16}$=19.09%, $C_{18:1}$=18.74%, $C_{18:3}$=15.33%, $C_{16:1}$=7.29%, $C_{20}$=5.21% in order, respectively. 45.88% of unsaturated fatty acids were contained in the oil.

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Preparation and Dissolution Properties of the Trace Elements doped ${K_2}O$-CaO-${P_2}{O_5}$ Glasses (미량원소함유 ${K_2}O$-CaO-${P_2}{O_5}$유리의 제조 및 용출 특성)

  • Lee, Hoi-Kwan;Kang, Won-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.2
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    • pp.144-148
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    • 2005
  • At the previous papers, we showed that ${K_2}O$-CaO-${P_2}{O_5}$ glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements of B, Mg, Zn, Fe, Cu, Co, Mo, the needed micronutrients for plants to grow, by a melt-quenching process. The dissolution properties in these glasses were investigated with a pH meter and an ICP analyzer. The trace elements doped glasses showed similar behavior in dissolutions and stability properties with the mother glass without containing trace elements. In addition, the dissolution amount of each trace elements depends on the mother glass composition and the quantity of each trace elements, which determine the dissolving velocity of chemical elements.

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Effect of metal alkoxide ratio and TiO2 composition on the synthesis of crystalline LAS glass by Sol-Gel method (졸-겔법에 의한 LAS계 결정화 유리합성에 미치는 금속 알콕사이드와 TiO2 조성비의 영향)

  • Seo, Kwang-Seok;Chun, Kyung-Soo
    • Analytical Science and Technology
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    • v.26 no.3
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    • pp.205-210
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    • 2013
  • For the synthesis of crystalline LAS glass by sol-gel method, the effect of operation conditions including metal alkoxide ratio, nucleating agent composition and heat treatment on the crystalline properties was experimentally investigated. The gelation time and crystallization temperature were proportionally affected by the mole ratio of TEOS in metal alkoxides solution. The addition of $TiO_2$ had an influence on the increasing of the gelation time, but the crystallization temperature was rarely dependent on the adding of nucleating agent. The crystallinity of LAS glass was improved by the nucleating agent under same heat treatment conditions.

Studies on the Physico-chemical Properties of Vitrified Forms of the Low- and Intermediate-level Radioactive Waste (${\cdot}$저준위 방사성폐기물 유리고화체의 물리${\cdot}$화학적 특성 연구)

  • Kim, Cheon-Woo;Park, Byoung-Chul;Kim, Hyang-Mi;Kim, Tae-Wook;Choi, Kwan-Sik;Park, Jong-Kil;Shin, Sang-Woon;Song, Myung-Jae
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.839-845
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    • 2001
  • In order to vitrify the Ion-Exchange Resin(IER), Dry Active Waste(DAW), and borate concentrate generated from the commercial nuclear facilities, the glass formulation study based on the their compositions was performed. Two glasses named as RG-1 and DG-1 were formulated as the candidate glasses for the vitrification of hte IER and DAW, respectively. A glass named as MG-1 was also formulated as a candidate glass for the vitrification of the mixed wastes containing the IER, DAW, and borate concentrate. The process parameters, product qualities, and economics were evaluated for the candidate glasses and confirmed experimentally for the some properties. The glass viscosity and electrical conductivity as the process parameters were in the desired ranges. the product qualities such as glass density, chemical durability, phase stability, etc. were satisfactory. In case of vitrifying the wastes using our developed glass formulation study, the volume reduction factors for the IER, DAW and mixed wastes were evaluated as 21, 89 and 75, respectively.

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Changes of Fatty acids and Free Amino Acids in Raw and Salted-dried Red Tongue Sole During Cooking (생.건 참서대의 조리방법별 지방산과 유리아미노산 함량변화)

  • 신애숙;홍정훈;김경자
    • Korean journal of food and cookery science
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    • v.14 no.5
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    • pp.535-540
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    • 1998
  • Changes in fatty acids and free amino acids of raw .ed tongue sole (RRT) and dried red tongue sole (SRT). were analyzed after steaming, boiling, or baking. 1. RRT was composed of moisture 78.4%, ash 1.2%, crude lipid 1.1%, and crude protein 18.3%. 2. The main fatty acid of RRT and SRT were palmitic acid (21.5%) and lignoceric acid (43.1%) which cover 64.5% of total fatty acid. Steamed RRT or SRT had higher content of fatty acids than boiled or baked ones. 3. The main free amino acids of RRT or SRT were glutamic acid (14.9%), aspartic acid (12.2%), Iysine (10%), leucine (8.4%), and arginine (6.8%) covering more than 52.3% of total free amino acids.

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Composition of Free Amino Acids and Essential Oils in Root of Anthriscus sylvestylis (전조 뿌리의 유리 아미노산과 정유 성분 조성)

  • 김상국;권태용;민기군;이승필;최부술;이상철
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.5
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    • pp.521-525
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    • 1996
  • The study was carried out to find compositions of proximate components, free amino acid, and essential oils from root of Anthriscus sylvestylis. Proximate component contents were 7.69% for protein, 1.74% for fat, 2.44% for fiber, and 3.76% for ash. Extract content was 27.68% in fresh root. The compositions of free amino acids consisted 16 kinds. Phenylalanine content was the highest in composition of free amino acids. The essential oils of the root of Anthriscus sylvestylis was examined. $\alpha$-pinene, campreol, ,$\beta$-pinene, sabinene, myrcene, phellandrene, $\alpha$-terpinolene, d-limone, ${\gamma}$-terpinene, p-cymene, $\alpha$-terpinolene, carboxaldehyde, 3-cyc1ohexen-l-carboxaldehyde, 2-nonenal, isobornyl acetate, 4-terpineol, $\beta$-bisabolene, cis-piperitol, p-cymen-8-ol, BHT, methyl eugenol and 2-methoxy-4-vinyl-phenol were identified from the diethylether layers. Recovery yield of essential oils of Anthriscus sylvestylis of root was 0.58%. As a result, it was considered that the plant is worthy of cultivating as spice and medicinal crops.

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A Study on Improvement of Chemical Durability in the $Na_2O$-CaO-$SiO_2$ System Glass ($Na_2O$-CaO-$SiO_2$ 계 유리의 내화학적 성질 향상에 관한 연구)

  • Kim, Jong-Ock;Park, Won-Kyu;Lim, Dae-Young;Kim, Moon-Ki
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.111-118
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    • 1996
  • In order to improve the chemical durability of glass in the $Na_2O$-CaO-$SiO_2$ system, it was investigated in the effect of $B_2O_3$ and ZnO addition and changing amount of each composition, $Na_2O$, $Al_2O_3$, $Li_2O$. In this minimize the change of softening point of glass was as follow.(wt%)$B_2O_3$:3.36%, ZnO:2.88%, $Na_2O$:9.93%, $Al_2O_3$, $Li_2O$:0.19%, $SiO_2$:70.56%, CaO:11.22%, $K_2O$:0.14%

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