• Journal of the Korean Geosynthetics Society
• /
• v.16 no.4
• /
• pp.13-20
• /
• 2017

In this study, laboratory tests were performed to evaluate for new filling materials (ZA-Soil) for bored pile that were developed using by high calcium ash. As a result of laboratory test, the uniaxial compression strength of 2 types of ZA-Soil are shown 68.0% and 64.6% compared to ordinary portland cement. And it have a suitable flowability and environmental stability. Also, after 28days, uniaxial compression strength of material mixed with soil and high strength filling material (ZA-Soil) for bored pile is 1.10-1.23 times bigger than material mixed with ordinary portland cement.

• Resources Recycling
• /
• v.29 no.6
• /
• pp.41-47
• /
• 2020

This study was carried out to utilize the coal bottom ash generated in a circulating fluidized bed combustion boiler as a treatment agent for heavy metal ions, and experiments were conducted to remove heavy metal ions from the acid mine drainage. The batch experiments were conducted to investigate the influence of dosage of ash, initial concentration of solution on the removal capacity of heavy metal ions (Cu, Cd, Cr, Pb). The results of the experiment showed that the total removal capacity of heavy metals was 30.8 mg/L and 46.4 mg/g, respectively, under the condition that the concentration of coal ash was added as 15 g/L of heavy materials and 10 g/L of light materials. After that, a long-term column experiment was performed to determine the maximum removal capacity of heavy metal ions (Cu, Cd, Cr, Pb, As), and the removal capacity for each metal component was investigated. After approximately 60 days of operation, the maximum removal capacity of heavy metals was 23.6 mg/g at pH 9.25.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.8 no.1
• /
• pp.8-16
• /
• 2020

As the circulating fluidized bed combustor(CFBC) boilers system to generate electric power increase in order to reduce environmental pollution, a lot of CFBC fly ashes(CFFA) are produced. CFFA has limited use in concrete because it contains free CaO, which can cause cement expansion and rapid initial hydration. In this study, the microstructure and the initial development of compressive strength characteristics were experimentally analyzed to be used as a stimulant to replace natural gypsum by mixing with CFFA and phosphate gypsum to enhance the initial strength of portland blast furnace slag cement. The recycled gypsum was used as flue-gas desulfurization gypsum and phosphate gypsum. Experimental results show that the initial strength development is relatively lower when CFFA and dihydrate gypsum are mixed, but the strength improvement effect of the mixture with CFFA and anhydrous gypsum as an anhydritedII typed crystalized gypsum is similar to that of natural gypsum. As a result, it w as analyzed to have high possibility of use for stimulant of portland blast furnace slag cement.

• Korean Chemical Engineering Research
• /
• v.47 no.6
• /
• pp.795-800
• /
• 2009

In this study, the $CO_2$ removal characteristics of the Vortex tube type absorbtion apparatus were investigated to enhance the compactness of $CO_2$ absorption process and to reduce the amount of absorbing solution of the $CO_2$ separation process. The Vortex tube with the diameter of 17 mm and the length of 250mm was introduced in the experimental apparatus to treat $20Nm^3/hr$ of $CO_2$ containing flue gas. The flue gases for experiments containing 11~13 vol% of $CO_2$ were supplied from the coal-firing CFBC power plant with 12 ton/hr of steam producing capacity. The mixed solutions of 20 wt% of MEA as base solution with the adding solutions like HMDA, AMP and KOH were used as absorbents. The experiments were executed under the various conditions like the absorbing solution concentrations in the range of 20 to 50 wt%, the flow rate of $CO_2$ containing flue gases in the range of 6 to $15Nm^3/hr$ and the flow rate of absorbing solution in the range of 1.0 to 3.0 l/min. As a results, the $CO_2$ removal efficiency of mixed absorbent of 20 wt% of MEA with HMDA was remarkable. From this study, we concluded that the efficient separation of $CO_2$ from flue gases using the features of the Vortex tube type absorbing unit for gas/liquid contact and the separation of gas/liquid be possible. But more works are needed to increase the $CO_2$ removal efficiency of Vortex tube process.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.1 no.1
• /
• pp.49-57
• /
• 2013

Recently, recycling of industrial by-products and CO2 reduction have been important issues in the world. In this reason, applications and reuse of Fly ash as a binder for concrete, which is generated in thermoelectric power plant, have been one of the effective recycle methods. In order for Fly ash to be applied to concrete, Korean Standard(KS) has selected and managed quality such as $SiO_2$, fineness, specific gravity, ignition loss and activity index. However, there is a limits for activity index, whose test period required is at least 28 days or 91 days. Activity index is the critical indication standard to determine mechanical strength of concrete that contained Fly ash. To complement the disadvantage of test method, this research provided "API test method", which quickly measure Pozzolanic reaction of Fly ash can be considered as a alternative of activity index. Then, the adaptable API test method need to be investigated through comparative analysis with the test result of API, activity index and K-value. The test method can make evaluation of Fly ash quality faster and more accurate. As a result, most Fly ash produced in Korea has not been satisfied in the KS quality standard except water content and specific gravity, and especially fluidized bed boiler ash has its characteristics. Also, API, activity index and K-value have superior interrelationship. The interrelationship between API and activity index and K-value gets increased as the material age gets higher, so API test can be considered as very useful test method for Pozzolanic reaction evaluation of Fly ash.

• Journal of the Korean Geotechnical Society
• /
• v.34 no.6
• /
• pp.17-24
• /
• 2018

In this study, static load test and dynamic load test were performed to evaluate pile-filling material (ZA-Soil) of soil-cement injected precast pile method which was developed by using the ash of circulating fluidized boiler as a stimulant for alkali activation reaction of blast furnace slag. As a result of the static load test, the allowable bearing capacity of pile was 1,350 kN, which was the same as the result of using ordinary portland cement. And total settlement was 6.97 mm, and net settlement was 1.48 mm. These are similar to the total settlement, 7.825 mm, and net settlement, 2.005 mm of ordinary portland cement. As a result of the dynamic load test and CAPWAP analysis, the skin friction was 375.0 kN, the end bearing capacity was 3,045.9 kN, and the allowable bearing capacity was 1,368.36 kN. These results are similar to the results of using ordinary portland cement as pile-filling material.

• Resources Recycling
• /
• v.29 no.1
• /
• pp.43-52
• /
• 2020

The objectives of this study were to identify the optimal mix of foam concrete with the low-strength and high-flow for the repairing ground subsidence situation emergently by utilizing a large amount of industrial by-products and evaluate the possibility by applying it to the site. The factors of the experiment were the mixing ratio of mixing water and a foaming agent and the mixing ratio of foam over paste volume. The optimal mix identified by the experiment was applied to the field and basic properties were evaluated. The results of the experiment showed that the optimal mixing ratio of mixing water and the foaming agent was 10%. Moreover, when the mixing ratio of pre-foam over paste volume was 170%, it satisfied the target. However, to ensure stable quality when applying to the field, the foam mixing ratio was set 140% for the field application. The field application test of foam concrete with the low-strength and high-flow using an eco-friendly binder satisfied all target performances. Therefore, the possibility of using it as a mixture and construction method for a ground repair system is confirmed. However, there was a quality deviation between the upper part and the lower part due to the separation between foam and paste. Consequently, further studies are needed to improve it.

• Resources Recycling
• /
• v.29 no.1
• /
• pp.53-61
• /
• 2020

This study aimed to develop a foam concrete material for a ground repair system that has low strength and low fluidity by using an eco-friendly binder, which substitutes industrial by-products for more than 90% of cement. Basic properties were evaluated after substituting a small amount of calcium sulfo aluminate (CSA) for the binder to improve the sinking depth rate and volume change, commonly found when it had a large amount of industrial by-products. The substitution rates of CSA for the eco-friendly binder used for the foam concrete were 2.5, 5, and 10%. Fresh properties, hardened properties, pore structure, and hydrates were analyzed. Experimental results showed that using only 2.5% of CSA could improve the deep sinking depth which occurred when using an eco-friendly binder. As a result, the weight difference between the upper, middle, and lower parts of cast specimens was improved even after being hardened. The addition of CSA also contributed to the formation of small, uniformly sized closed pores and improved initial strength. However, when the proportion of CSA increased, the long-term strength decreased. However, it satisfied the target strength when 5% or less of CSA was used. The results of this study revealed that it was possible to manufacture foam concrete with low strength and high fluidity for repairing ground satisfying target qualities by adding 2.5% of CSA to the eco-friendly binder containing a large amount of industrial by-products.

• The Journal of Engineering Geology
• /
• v.27 no.3
• /
• pp.245-253
• /
• 2017

Vietnam CFBC fly ash has high CaO content and can be used as a solidification agent for soft ground improvement. However, most fly ash is treated as landfill or waste. In order to utilize fly ash as a solidification agent for soil improvement, the characteristics of fly ash must be accurately determined. In this study, laboratory tests were conducted on fly ash from four CFBC power plants to evaluate the utility of Vietnam fly ash as a solidification agent. As a result of analyzing the physical properties, it was analyzed that all four samples were suitable as material for solidification agent and have suitable particle size for the improvement of soft ground. As a result of analysis of chemical characteristics, it was analyzed that the fly ash of one place could be used as a solidification agent because of the high content of free-CaO. The remaining three fly ash was not suitable for use as a solidification agent due to low Free-CaO content. However, it has a chemical composition similar to that of general fly ash in Korea, so it can be recycled in various ways.

• Korean Chemical Engineering Research
• /
• v.48 no.1
• /
• pp.58-67
• /
• 2010

Combustion of the Korean Anthracite and wood-pellet was characterized in air atmosphere with variation of heating rate(5, 10, 20 and $30^{\circ}C/min$) in TGA. The results of TGA have shown that the combustion of the wood-pellet occurred in the temperature range of $200{\sim}620^{\circ}C$ which is much lower than that of Korean anthracite. Activation energies of the wood-pellet and Korean anthracite, determined by using Friedman method were 44.12, 21.45 kcal/mol respectively. Also, their reaction orders(n) and pre-exponential factors(A) were 5.153, 0.7453 and $4.01{\times}10^{16}$, $1.39{\times}10^6(s^{-1})$ respectively. In order to find out the combustion mechanism of the wood-pellet and Korean anthracite, twelve solidstate mechanisms defined by Coats Redfern Method were tested. The solid state combustion mechanisms of the woodpellet and Korean anthracite were found to be sigmoidal curve A3 type and a deceleration curve F1 type respectively. Also, from iso-thermal combustion($300{\sim}900^{\circ}C$) of their char, the combustion characteristics of their char was found. Activation energies of the their char were 27.5, 51.2 kcal/mol respectively. Also, pre-exponential factors(A) were $2.55{\times}10^{12}$, $1.49{\times}10^{10}(s^{-1})$ respectively. Due to the high combustion reactivity of wood-pellet compared with Korean anthracite, combustion atmosphere will be improved by co-combustion with Korean anthracite and wood-pellet.