• Resources Recycling
• /
• v.15 no.5 s.73
• /
• pp.3-10
• /
• 2006

The solvent extraction for the separation of platinum group metals from the leach liquor of spent automotive catalysts has been studied. Tri-n-butyl phosphate (TBP), tri-n-octylamine (TOA) and di-n-hexyl sulfide (DHS) were used as extractants and kerosene as a diluent. The extraction behavior of platinum, palladium and rhodium has been investigated as functions of different kinds of extractants and their concentrations. In addition, the extraction behavior of the major metal impurities such as cerium, lead, iron, magnesium and aluminum has been investigated. Platinum and palladium were extracted with TBP. And platinum, palladium and rhodium were extracted with TOA. Platinum was co-extracted with palladium into the organic phase by solvent extraction using SFI-6 of DHS extractant, but only palladium was selectively extracted with SFI-6R. The selective extraction of palladium with SFI-6R was found better than that with SFI-6, but the kinetics of extraction with SFI-6R was found poor in comparison to SFI-6. The metal impurities extracted simultaneously during the extraction of platinum group metals should be removed in scrubbing and stripping processes. A suitable process has been proposed for the separation of platinum group metals from the leach liquor of spent automotive catalysts. Initially palladium was extracted with SFI-6R, followed by the separation of platinum with TBP or TOA leaving rhodium in the raffinate.

• Resources Recycling
• /
• v.25 no.2
• /
• pp.33-41
• /
• 2016

A scale up tests (380 kg/day) using a continuous solvent extraction and electro-winning system was carried out to separate and recover cobalt from a solution containing 1.91 g/L Co and 14.65 g/L Ni. The solution was obtained during a process including solvent extraction and precipitation stages for removal of Cu and Fe from a synthetic sulfuric acid solution of manganese nodule matte. The optimal condition for solvent extraction was : solvent concentration of 0.22M Na-Cyanex 272 (45% saponified with NaOH) and O:A phase ratios of 1:1.5, 10:1 and 1.5:1 used in extraction, scrubbing and stripping stages, respectively. The extraction and stripping efficiencies were found to be 99.8% and 99.88%, respectively. The stripped solution contained 40.27 g/L Co with 4 ppm Ni. Cobalt metal of 99.963% purity was yielded with current efficiency of 67% and current density of $0.563A/dm^2$ during the electro-winning process.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.1
• /
• pp.81-88
• /
• 2009

This study has shown the tendency to enhance Sand Flux, a device of separating screening the foreign matter, for the recycling of construction waste possible to improve the quality of wet type production system meaningfully as part of research. As a result of experiment on the basic material properties, this study had a tendency to improve the quality and performance significantly in case of absolute surface dried density, 0.08mm sieve throughput, volume of clay lumps, and content of organic foreign matter. In addition, as a result of examining the quality characteristics of mortar, this study has shown the tendency that the flow and compressive strength more increased than the mortar using RS-II by utilizing RS-VI recycled sand produced finally through the device Sand Flux. As for the shrinkage properties, this study has shown the character the generation rate of crack of mortar using RS-IV recycled sand produced finally through the device Sand Flux.

• Economic and Environmental Geology
• /
• v.37 no.2
• /
• pp.185-193
• /
• 2004

A physical model experiment was conducted using a sand and gravel-filled tank model, to investigate the influence on the GPR response of LNAPL vapor phase effects in the unsaturated zone and of residual phase of LNAPL trapped in the saturated zone. Background measurements of GPR were made with only water in the tank using a fluctuating water table model. Gasoline was, then, injected into the bottom of the model tank to simulate a subsurface discharge from a leaking pipe or tank at depth, obtaining GPR data with rising and lowering of water table. Results from the experiment show the GPR sensitivity to the changes in the moisture content in the vadose zone and its effectiveness for monitoring minor fluctuation of the water table. The results also demonstrate a potential of GPR for monitoring possible vapor phase effects of volatile hydrocarbons in the vadose zone as a function of time, and for detecting the effects of residual phase of hydrocarbons in the water saturated system. In addition, the results provide the basis for a strategy that has the potential to successfully detect and delineate residual LNAPL contamination in the water-saturated system at field sites where the conditions are similar to those simulated in the physcial models described herein.

• Economic and Environmental Geology
• /
• v.53 no.4
• /
• pp.337-346
• /
• 2020

This study was carried out to evaluate the applicability of the soil washing process to remediation mercury-contaminated mine tailing or solid material (soil and sediments etc.) around abandoned mines. First, the physicochemical characteristics of mine tailing were analyzed through particle size analysis and sequential extraction. Secondly, laboratory scale washing experiments were performed using hydrochloric acid, nitric acid, potassium iodide and sodium thiosulfate. As a results of particle size analysis, mine tailing particle were concentrated below 40 mesh and the particle size below 200 mesh was the most analyzed. As a result of sequential extraction, elemental mercury fraction was analyzed as the highest with 69.12%, with strongly bound fraction 15.25% and residual and HgS fractions 11.97%, respectively. Laboratory scale washing experiments showed low applicability for nitric acid and sodium thiosulfate solutions. In case of hydrochloric acid solution, it was analyzed that mercury removal was possible at particle size of 200 mesh or more. Therefore, it is considered to be performed together with the physical sorting process. Potassium iodide solution was analyzed to have high washing efficiency at all concentrations and particle sizes. In particular, the mercury removal efficiency is high in the micro particles, and thus the applicability of the washing technology is the highest.

• Economic and Environmental Geology
• /
• v.48 no.6
• /
• pp.467-475
• /
• 2015

The Deokjin Pond is one of the places representing Jeonju City's history but has the poor water quality. The pond has a storage of $88,741m^3$ and a drainage area of $3.77km^2$. It has been maintained only by the groundwater pumped from the upstream wells and the direct rainfalls on the water surface since the old streams replenishing the pond were turned into a part of the sewer system due to indiscreet urbanization. The lack of replenishing water as well as the organic-rich bottom sediment were suggested as two main causes deteriorating the water-ecosystem. In this study, possible measures obtaining waters for restoration of Deokjin Pond ecosystem are discussed. It is estimated that the present pond can be replenished about 32 times a year by the runoff when the drainage system in the watershed is recovered to a state before urbanization. To support this, the drainage system is compared with that of nearby Osong Pond, which shows relatively better water-ecosystem. Even though Osong Pond has a drainage area one-seventh of that of Deokjin Pond, its storage is more than the half of it. It is because its watershed has a near natural drainage system where the rain mostly infiltrates into soil and slowly discharges into the pond. Therefore, it is believed that the low impact development (LID), which is known as a technique restoring the water circulating system to a condition before development, would be helpful in obtaining waters required for Deokjin Pond ecosystem management.

• Korean Journal of Plant Resources
• /
• v.23 no.4
• /
• pp.261-273
• /
• 2010

This study intended to investigate the environmental factors including soil and vegetation in order to understand the environmental and ecological characteristics of seven different habitats of Viola websteri. These habitats, according to investigations, are mostly located on the slope of mountains facing north at an altitude of 343 m to 991 m above sea level with angle of inclination from 1 degree to 33 degrees. The type of soil is mostly sandy loam and the average field capacity of soil is 28.97%. Their average organic matter is 16.63%, soil pH 5.62, and available phosphorus is 14.75%. A total of 133 vascular plants are identified in 18 quadrates of seven habitats. Dominant species of woody plants in seven habitats are represented as Acer pictum subsp. mono and Quercus mongolica in tree layer, and Acer pictum subsp. mono in subtree layer. Importance value of Viola websteri is 9.66%, as regards the herbaceous layer, and five highly ranked species such as Meehania urticifolia(8.53%), Pseudostellaria heterophylla(6.51%), Hylomecon vernalis(5.15%), Oxalis obtriangulata (4.52%), and Pseudostellaria davidii(4.15%) are considered to be an affinity with Viola websteri in their habitats. The degree of their average species diversity is 1.32, and that of dominance and evenness are 0.08 and 0.89, respectively. Correlation coefficients analysis based on environmental factors, vegetation and soil analysis shows that the coverage of Viola websteri is correlated with silt and sand ratio, and coverage of tree layers are correlated with species richness and altitude. Cluster analysis based on vegetation structure of each habitats are forms a three groups.

• Korean Journal of Plant Resources
• /
• v.23 no.4
• /
• pp.360-367
• /
• 2010

The genetic diversity and structure of P. tongkangensis in 5 populations from 3 regions was investigated using 56 markers derived from 6 ISSR primers. Genetic diversity at the species level (P=94.6, SI=0.377, h=0.240) was substantial considering the limited distribution and small size of populations. Genetic differentiation among regions (12%) and among populations (13%) in the region was not clearly evident, which suggested a moderate level of gene flow among adjacent populations. The Mantel test revealed a significant correlation between genetic differentiation (${\Phi}_{ST}$) and geographic distance among populations. This was supported by cluster analysis and principal coordinate analysis (PCoA). The significant difference in marker band frequency at many loci and their fixation in opposite directions in the smallest and most isolated population SC were considered due to genetic drift. Therefore, the genetic diversity of P. tongkangensis could be compromised if the distribution area or the size of the population was further reduced. In particular, small and isolated populations could be at great risk of extinction. Considering this, the unique habitats of P. tongkangensis should be protected and the reduction of population size should be closely monitored. Conservation efforts including the seeding and planting of seedlings should be done carefully based on their genetic and ecological traits. Our data support the argument that establishing an integrated management system for the efficient conservation of P. tongkangensis is critical.

• Korean Journal of Plant Resources
• /
• v.25 no.2
• /
• pp.246-256
• /
• 2012

This study intended to investigate the distribution of natural habitats, and the environmental factors, vegetation and soil analysis at 22 different sites of 9 regions in order to understand the environmental characteristics of $Adoxa$ $moschatellina$ in Prov. Gangwon-do. Natural habitats are confirmed at 44 regions of 14 cities and counties except for Donghae-si, Sokcho-si, Gosung-gun and Yanggu-gun in Prov. Gangwon-do. Natural habitats were located at altitudes of 99-1,084 m with slope inclinations of $0-25^{\circ}$. A total of 215 vascular plant taxa are identified from 22 quadrates. Importance value for members of the herbaceous (H) layer were as follows: $Adoxa$ $moschatellina$ 32.8%; $Meehania$ $urticifolia$ 7.5%; $Cardamine$ $leucantha$ 5.1%; $Scopolia$ $japonica$ 3.8%; $Corydalis$ $remota$ 3.3%. The importance value of the last four species are high, so they are at affinity with $Adoxa$ $moschatellina$ in their habitats. Species diversity of investigated sites ranged 0.4870-0.9848, and that of evenness and dominance are 0.4525-0.7601 and 0.1335-0.4191, respectively. Cluster analysis based on importance value appeared the high relations with differences of dominance species. Field capacity of investigated sites ranged 4.29-38.45%, and the soil pH and organic matter were 4.61-5.98 and 2.44-20.21, respectively.

• Korean Journal of Plant Resources
• /
• v.28 no.5
• /
• pp.665-674
• /
• 2015

The final goal of this research is to develop a botanical biofiltration system, which combines green interior, biofiltering, and automatic irrigation, which can purify indoor air pollutants according to indoor space and the size of biofilter. The biofilter used in this experiment was designed as an integral form of water metering pump, water tank, blower, humidifier, and multi-level planting space in order to be more suitable for indoor space utilization. This study was performed to compare indoor air quality between the space adjacent to a botanical biofilter and the space away from the biofilter (control) without generation of artificial indoor air pollutants, and to evaluate plant growth depending on multiple floors within the biofilter. Each concentration of indoor air pollutants such as TVOCs, monoxide, and dioxide in the space treated with the biofilter was lower than that of control. Dracaena sanderiana ‘Vitoria’ and Epipremnum aureum ‘N Joy’ also showed normal growth responses regardless of multiple floors within the biofilter. Hence, it was confirmed that the wall-typed botanical biofilter suitable for indoor plants was effective for indoor air purification.