• Title/Summary/Keyword: 용량비

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Development of Environmentally Friendly Backfill Materials for Underground Power Cables Considering Thermal Resistivity (열 저항특성을 고려한 지중송전관로 친환경 되메움재 개발)

  • Kim, Daehong;Oh, Gidae
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.1
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    • pp.13-26
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    • 2011
  • Because the allowable current loading of buried electrical transmission cables is frequently limited by the maximum permissible temperature of the cable or of the surrounding ground, there is a need for cable backfill materials to be maintained at a low thermal resistivity during the service period. Temperatures greater than $50^{\circ}C$ to $60^{\circ}C$ may lead to breakdown of cable insulation and thermal runaway if the surrounding backfill material is unable to dissipate the heat as rapidly as it is generated. This paper describes the results of studies aimed at the development of backfill material to reduce the thermal resistivity. A large number of different additive materials were tested to determine their applicability as a substitute material. The results of Dong-rim river sand (relatively uniform) show that as water content level increases, thermal resistivity tends to decrease, whereas the thermal resistivity on dry condition is very high value($260^{\circ}C-cm/watt$). In addition, other materials(such as Jinsan granite screenings, A-2(sand and gravel mixture), E-1(rubble and granite screenings mixture) and SGFC(sand, gravel, fly-ash and cement mixture)) are well-graded materials with low thermal resistivity($100^{\circ}C-cm/watt$ when dry). Based on this research, 4 types of improved materials were suggested as the environmentally friendly backfill materials with low thermal resistivity.

Low-voltage Pentacene Field-Effect Transistors Based on P(S-r-BCB-r-MMA) Gate Dielectrics (P(S-r-BCB-r-MMA) 게이트 절연체를 이용한 저전압 구동용 펜타센 유기박막트랜지스터)

  • Koo, Song Hee;Russell, Thomas P.;Hawker, Craig J.;Ryu, Du Yeol;Lee, Hwa Sung;Cho, Jeong Ho
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.551-554
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    • 2011
  • One of the key issues in the research of organic field-effect transistors (OFETs) is the low-voltage operation. To address this issue, we synthesized poly(styrene-r-benzocyclobutene-r-methyl methacrylate) (P(S-r-BCB-r-MMA)) as a thermally cross-linkable gate dielectrics. The P(S-r-BCB-r-MMA) showed high quality dielectric properties due to the negligible volume change during the cross-linking. The pentacene FETs based on the 34 nm-thick P(S-r-BCB-r-MMA) gate dielectrics operate below 5 V. The P(S-r-BCB-r-MMA) gate dielectrics yielded high device performance, i.e. a field-effect mobility of $0.25cm^2/Vs$, a threshold voltage of -2 V, an sub-threshold slope of 400 mV/decade, and an on/off current ratio of ${\sim}10^5$. The thermally cross-linkable P(S-r-BCB-r-MMA) will provide an attractive candidate for solution-processable gate dielectrics for low-voltage OFETs.

Specific Surface Area Characteristic Analysis of Porous Carbon Prepared from Lignin-Polyacrylonitrile Copolymer by Activation Conditions (리그닌-PAN 공중합체로 제조한 다공성 탄소 소재의 활성화 처리 조건에 따른 비표면적 특성 연구)

  • LEE, Hyunsu;KIM, Seokju;PARK, Mi-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.49 no.4
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    • pp.299-314
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    • 2021
  • In this study, we investigated the effect of temperature on specific surface area and electrochemical properties when lignin-based porous carbon (LBPC) with potassium hydroxide (KOH) is activated. After preparing LBPCs using lignin-polyacrylonitrile (PAN) copolymer, which was synthesized by graft polymerizing lignin and acrylonitrile as a precursor, activated LBPCs (KA-LBPC-6, 7, 8, 9) were manufactured by activating LBPC with KOH at 600℃, 700℃, 800℃ and 900℃. To identify the surface characteristics of KA-LBPC, observations were made with a scanning electron microscopy (SEM), and the pore characteristics were identified via specific surface area analysis. The electrochemical properties were analyzed using a three-electrode system. The experiment has shown that micropores formed by activation can be observed in SEM images. KA-LBPC-7 had the best pore characteristics among KA-LBPCs, with a specific surface area of 2480.1 m2/g, a micropore volume of 0.64 cm3/g, and a mesopore volume of 0.76 cm3/g. KA-LBPC-7 showed the best electrochemical properties with a specific capacitance of 151.3 F/g at the scan rate of 2 mV/s.

Effect of Characteristic Change in Natural Graphite according to Complex Purification Process on Anode Performance for Lithium Ion Battery (복합 정제 공정에 따른 천연 흑연의 물리화학적 특성 변화가 리튬 이온 전지의 음극재 성능에 미치는 영향)

  • Ahn, Won Jun;Hwang, Jin Ung;Im, Ji Sun;Kang, Seok Chang
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.290-298
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    • 2021
  • A purification process was performed for the application of natural graphite as an anode material. The influence of the structural change and impurity content of graphite according to the process on the anode electrochemical characteristics was investigated. Natural graphite was chemically/physically purified by acid-treatment which used different amounts of solution of ammonium fluoride/sulfuric acid in the same ratio and thermal treatment used different temperatures (800~2500 ℃). Acid-treatment had limitation to remove impurities, and identified that all impurity contents was removed except some traces of atom such as Si by after progressed thermal-treatment until 2500 ℃. The anode materials characteristic of graphite treated by purification process was improved, and changes in the structure and impurity contents affected dominantly the capacity, rate property and initial Coulombic efficiency. Consequently, the complex purification process improved the graphite structure and also the performance of lithium ion battery by controlling the excessive formation of solid electrolyte interphase and expanding Li+ insertion space originated from the effective removal of impurities.

Effect of Low Temperature Heat Treatment on the Physical and Chemical Properties of Carbon Anode Materials and the Performance of Secondary Batteries (저온 열처리가 탄소 음극재의 물리·화학적 특성 및 이차전지 성능에 미치는 영향)

  • Whang, Tae Kyung;Kim, Ji Hong;Im, Ji Sun;Kang, Seok Chang
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.83-90
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    • 2021
  • In this study, effects of the physical and chemical properties of low temperature heated carbon on electrochemical behavior as a secondary battery anode material were investigated. A heat treatment at 600 ℃ was performed for coking of petroleum based pitch, and the manufactured coke was heat treated with different heat temperatures at 700~1,500 ℃ to prepare low temperature heated anode materials. The physical and chemical properties of carbon anode materials were studied through nitrogen adsorption and desorption, X-ray diffraction (XRD), Raman spectroscopy, elemental analysis. Also the anode properties of low temperature heated carbon were considered through electrochemical properties such as capacity, initial Coulomb efficiency (ICE), rate capability, and cycle performance. The crystal structure of low temperature (≤ 1500 ℃) heated carbon was improved by increasing the crystal size and true density, while the specific surface area decreased. Electrochemical properties of the anode material were changed with respect to the physical and chemical properties of low temperature heated carbon. The capacity and cycle performance were most affected by H/C atomic ratio. Also, the ICE was influenced by the specific surface area, whereas the rate performance was most affected by true density.

A Study on the Properties of Inventory for Efficient Inventory Control at Small-scale Manufacturing Company (소규모 제조기업의 효율적 재고관리를 위한 재고속성에 관한 연구)

  • Kim, Ki Bum;Nam, Gon;Jeong, Yong Moon;Heo, Se min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.449-455
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    • 2020
  • Inventory management is one of the important business functions for manufacturing companies to determine market responsiveness. Customers' needs are diversifying, and the life cycle of products is decreasing, thus increasing the importance of inventory management. However, for small-scale manufacturing companies, investing in an IT system for inventory management is practically difficult. In this study, we introduce an inventory and warehouse management model that can be applied simply and quickly in small-scale manufacturing companies. Firstly, we introduce the concept of the properties of inventory and provide an analytical methodology based on the age and quantity of the inventory. Secondly, in accordance with the properties of the inventory, we introduce location management rules for warehouse operation. To apply the proposed model, we studied a wallpaper manufacturing company and verified the applicability of the proposed methods in the field. The proposed model can be applied immediately as part of on-site improvement activities by small-scale manufacturing companies, and inventory management activities are expected to reduce bad long-term inventory and further secure storage capacity for warehouses.

Classification of hydropower dam in North-han River based on water storage characteristics (저류특성을 고려한 북한강수계 발전용댐의 유형 구분방안 제시)

  • Choi, Jeongwook;Jeong, Gimoon;Kang, Doosun;Ahn, Jeonghwan;Kim, Taesoon
    • Journal of Korea Water Resources Association
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    • v.54 no.8
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    • pp.567-576
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    • 2021
  • Climate change threatens the security of domestic water resources in South Korea. To overcome the potential water shortage, various approaches are being studied by alterning the operation of dams or by integrated operation of multiple dams and reservoirs. However, most of the related researches were developed and applied for multi-purpose dams, and few studies were conducted for the hydropower dams. The main purpose of the hydropower dam is to generate electric energy; however, the potential water shortage due to prolonged droughts brings the idea to supply water from the hydropower dam in the basin. To that end, it is required to estimate the water supply ability of the hydropower dams. In this study, we proposed a methodology to classify the hydropower dam into a "storage-type" and "run-of-river type" dam. The proposed approach was demonstrated using the hydropower dams located in North-han River basin. The results of this study are expected to contribute for further analysis of the hydropower dams, such as evaluation of water supply capacity and drought mitigation purpose operation of the hydropower dams.

Management performance analysis using the DEA model of the food waste recycling facility (음식물류 폐기물 자원화 시설 DEA모형을 활용한 경영성과 분석)

  • Jeoung, IlSeon;Kim, Youngkyun
    • Journal of Korea Society of Industrial Information Systems
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    • v.27 no.4
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    • pp.105-114
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    • 2022
  • As the national income level is improving, housing urbanization and economic speed are progressing rapidly, household waste and food waste are rapidly increasing. The "Waste Management Act" (founded in 1991) introduced the volume-based household waste system in 1995, and even after implementation, the odor of food waste and the prompt disposal process continue to be a social problem.For this reason, the food waste recycling business is attracting attention. In this paper, regarding the role of resource recycling such as feed, compost, and other resources of food waste, this thesis aims to reduce the inefficiency of the recycling process. Data Envelopment Analysis (DEA) of the relationship between inputs and outputs of 33 facilities nationwide, excluding facility data (insufficient) among 394, (238 public, and 156 private ones), as of the end of 2020, which is running a domestic resource recycling project This study was conducted to investigate the important role in the relative management performance of food waste recycling facilities.It was hypothesized that the influence of business history, facility capacity, capital, and machinery of a company running a food waste recycling business on sales was tested.

Assessments of Dissolved Rare Earth Elements and Anthropogenic Gadolinium Concentrations in Different Processes of Wastewater Treatment Plant in Busan, Korea (부산 하수처리장에서 공정별 용존 희토류 원소의 농도 및 인위적 기원 가돌리늄의 배출량 평가)

  • Lim, Ijin;Ryu, Jong-Sik;Lee, Joonyeob;Lee, Jun-Ho;Cho, Hyung-Mi;Kim, Taejin
    • Journal of the Korean earth science society
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    • v.43 no.2
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    • pp.303-311
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    • 2022
  • Gadolinium, commonly used as a contrast agent for magnetic resonance imaging (MRI), is discharged into aquatic environments without removal after treatment in wastewater treatment plants (WWTPs) because of its high stability. In this study, we collected water samples from Suyeong WWTP, Busan, to investigate the dissolved rare earth element (REE) removal capacity of each wastewater treatment process and to evaluate the discharge of anthropogenic Gd (Gdanth) from effluents. As wastewater passed through each stage of treatment, the concentrations of light REEs (La-Eu) decreased, whereas those of heavy REEs (Tb-Lu) were relatively consistent. Negative Sm anomalies (<1) were observed in several samples, indicating that Sm can be removed by adsorption onto particles or phosphate during the biological removal process. Positive Gd anomalies (149±50, n=9) were observed in all samples. The ratios of Gdanth concentrations to measured Gd concentrations in all wastewater treatment processes were higher than 97%. This indicates that Gdanth was discharged to the Suyeong River without removal during the wastewater treatment process. Considering the daily treatment capacity in each process, the total flux of Gdanth was estimated to be 259 mmol/day. Our results suggest that mid- and/or long-term monitoring of Gd is needed because Gdanth is continuously discharged into Suyeong Bay through WWTPs.

Effect of Nitrogen Plasma Surface Treatment of Rice Husk-Based Activated Carbon on Electric Double-Layer Capacitor Performance (질소 플라즈마 표면처리가 쌀겨 기반 활성탄소의 전기 이중층 커패시터 성능에 미치는 영향)

  • Lee, Raneun;Kwak, Cheol Hwan;Lee, Hyeryeon;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.71-77
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    • 2022
  • To increase biomass utilization, rice husk-based activated carbon (RHAC) followed by nitrogen plasma surface treatment was prepared and the electric double-layer capacitor performance was investigated. Through nitrogen plasma surface treatment, up to 2.17% of nitrogen was introduced to the surface of RHAC, and in particular the sample reacted for 5 min with nitrogen plasma showed dominant formation of pyrrolic/pyridine N functional groups. In addition, mesopores were formed on the RHAC material by the removal of silica, and the surface roughness of the carbon material increased by nitrogen plasma surface treatment, resulting in the formation of many micropores. As a result of cyclic voltammetry measurement, at a scan rate of 5 mV/s, the specific capacitance of the RHAC treated with nitrogen plasma increased up to 200 F/g, showing an 80.2% improvement compared to that of using untreated RHAC (111 F/g). This is attributed to the synergetic effect of the introduction of pyrrolic/pyridine-based nitrogen functional groups and the increase of the micropore volume on the surface of the carbon material. This study has a positive effect on the environment in terms of recycling waste resources and using plasma surface treatment.