• Title/Summary/Keyword: 영역분해법

Search Result 155, Processing Time 0.03 seconds

Synthesis of Visible-working Pt-C-TiO2 Photocatalyst for the Degradation of Dye Wastewater (염료폐수 분해를 위한 가시광 감응형 Pt-C-TiO2 광촉매의 합성)

  • Hahn, Mi Sun;Yun, Chang Yeon;Yi, Jongheop
    • Clean Technology
    • /
    • v.11 no.3
    • /
    • pp.123-128
    • /
    • 2005
  • Among various metal oxides semiconductors, $TiO_2$ is the most studied semiconductor for environmental clean-up applications due to its unique ability in photocatalyzing various organic contaminants, its chemical inertness, and nontoxicity. $TiO_2$, however, has a few drawbacks to be solved such as reactivity mainly working under ultraviolet irradiation (${\lambda}$ < 387 nm) and electron - hole recombination on $TiO_2$. In this study, to extend the absorption range of $TiO_2$ into the visible range and enhance electron - hole separation, we synthesized platinum (Pt) deposited $C-TiO_2$. The presence of Pt as an electron sink has been known to snhance the separation of photogenerated electron-hole pairs and induce the thermal decomposition. The characterization of as-synthesized $Pt-C-TiO_2$ was performed by Transmission Electron Microscopic (TEM), the Brunuer-Emmett-Teller (BET) method, X-ray Diffractometer (XRD), UV-vis spectrometer (UV-DRS), and X-ray Photoelectron Spectroscopy (XPS). In order to estimate the photocatalytic activity of the synthesized materials, the photoelectron Spectroscopy (XPS). In order to estimate the photocatalytic activity of the synthesized materials, the photodegradation experiment of an azo dye (Acid Red 44; $C_{10}H_7N=NC_{10}H_3(SO_3Na)_2OH$)was carried out by using an Xe arc lamp (300 W, Oriel). A 420 nm cut-off filter was used for visible light irradiation. From the results, Pt-deposited $C-TiO_2$ showed a far superior phothdegradation activity to Degussa P25, the commercial product under the irradiation of visible light and enhanced photocatalytic activity of visible-working $C-TiO_2$. This is a useful result into the application for the purification system of dye wastewater using visible energy of sun light.

  • PDF

A Study of Optimized MRI Parameters for Polymer Gel Dosimetry (중합체 겔 선량측정법을 위한 최적의 자기공명영상 변수에 관한 연구)

  • Cho, Sam-Ju;Chung, Young-Lip;Lee, Sang-Hoon;Huh, Hyun-Do;Choi, Jin-Ho;Park, Sung-Ill;Shim, Su-Jung;Kwon, Soo-Il
    • Progress in Medical Physics
    • /
    • v.23 no.2
    • /
    • pp.71-80
    • /
    • 2012
  • In order to verify exact dose distributions in the state-of-the-art radiation techniques, a newly designed three-dimensional dosimeter and technique has been took strongly into consideration. The main purpose of our study is to verify the optimized parameters of polymer gel as a real volumetric dosimeter in terms of the various study of MRI. We prepared a gel dosimeter by combing 8% of gelatin, 8% of MAA, and 10 mM of THPC. We used a Co-60 gamma-ray teletherapy unit and delivered doses of 0, 2, 4, 6, 8, 10, 12, and 14 Gy to each polymer gel with a solid phantom. We used a fast spin-echo pulse to acquire the characterized T2 time of MRI. The signal noise ratio (SNR) of the head & neck coil was a relatively lower sensitivity than the body coil; therefore the dose uncertainty of head & neck coil would be lower than body coil's. But the dose uncertainty and resolution of the head & neck coil were superior to the body coil in this study. The TR time between 1,500 ms and 2,000 ms showed no significant difference in the dose resolution, but TR of 1,500 ms showed less dose uncertainty. For the slice thickness of 2.5 mm, less dose uncertainty of TE times was at 4 Gy, as well, it was the lowest result over 4 Gy at TE of 12 ms. The dose uncertainty was not critical up to 6 Gy, but the best dose resolution was obtained at 20 ms up to 8 Gy. The dose resolution shows the lowest value was over 20 ms and was an excellent result in the number of excitation (NEX) of three. The NEX of two was the highest dose resolution. We concluded that the better result of slice thickness versus NEX was related to the NEX increment and thin slice thickness.

A Quantitative Study for Hydrothermal Alteration Zones using Short Wavelength Infrared Spectrometry (단파장적외선 분광분석법을 이용한 열수변질대 정량화 연구)

  • Kim, Yong-Hwi;Choi, Seon-Gyu;Ko, Kwang-Beom;Han, Kyeong-Soo;Koo, Min-Ho
    • Economic and Environmental Geology
    • /
    • v.50 no.1
    • /
    • pp.15-26
    • /
    • 2017
  • Advanced argillic, argillic, and phyllic zones are the most important alteration patterns to predict the hidden ore body during exploration of hydrothermal deposits. We examined the quantitative relationship between the spectral absorption characteristics and the mineral content of the synthetic mixtures such as alunite-kaolinite and illite-kaolinite using short wavelength infrared (SWIR) spectroscopy. In the alunite-kaolinite mixtures, the spectral absorption characteristics of the alunite was highly correlated with the Hull quotient reflectance(0.99) and the kaolinite had the highest correlation with the Gaussian peak(0.92). Illite-kaolinite mixtures are essential for Gaussian deconvolution because of the overlap of absorption region. Illite and kaolinite mixtures indicate the high correlation of 0.93 and 0.98, respectively. The error ranges in the alunite-kaolinite(8%) and illite-kaolinite mixtures(5%) derived from SWIR were smaller than the ones(29% and 26%) obtained from X-ray diffraction(Rietveld) analysis. These results show that SWIR spectroscopic analysis is more reliable than XRD Rietveld analysis in terms of quantification of allowed minerals.

Studies on Xylan of Tropical Hardwood (II) -Isolation and Purification of Xylan- (열대산(熱帶産) 광엽수재(廣葉樹材)의 Xylan에 관(關)한 연구(硏究) (II) -Xylan의 단리(單離) 및 정제(精製)-)

  • Lee, Jong Yoon
    • Journal of Korean Society of Forest Science
    • /
    • v.35 no.1
    • /
    • pp.24-32
    • /
    • 1977
  • According to the chlorous salt method, most of holocellulose whose lignin was removed, was obtained. In extracting xylan from holocellulose by the different densities of alkali, 5% KOH was extracted three times but still there remained part of xylan in it and another composite of hemicellulose and cellulose was obtained. The extraction of 10% and 20% KOH showed a desirable result. Rather than the ordinary method to use a large quantity of ethanol in the precipitation isolation of xylan, the method to use a small quantity of ethanol in adopting the dialysis with cellophane-membrane by condensing density to one tenth, made il possible to extract a high purity xylan in a high retrieving rate. In isolating glucomannan, the residue of 5% KOH extraction contained a large quantity of xylan, the residue of 10% and 24% KOH extraction, also showed the same result and the comparison between glucose and mannose was approximately 1 : 1. The purification of Fehling solution made it possible to obtain comparatively pure xylan but the process of oxidation dissolution was complicated and the retrieving rate was low. This was not a good method. The ethanol titration purified a high purity xylan in a high retrieving rate and was a very excellent purifying method, considering its simple and easy process. These two purifying methods, however, could not completely remove the residue of arabinose. This will be examined and reported later.

  • PDF

Extraction of Dimethyl-$\beta$-propiothetin from Enteromorpha intestinalis (창자파래(Enteromorpha intestinalis)로부터 Dimethyl-$\beta$-propiothetin 추출)

  • 배태진;강동수;최옥수
    • The Korean Journal of Food And Nutrition
    • /
    • v.13 no.4
    • /
    • pp.334-341
    • /
    • 2000
  • The DMPT produced by marine algae is the main biogenic precursor of oceanic DMS. Also, DMPT is an efficient stimulant for growth, feeding, and body movement of fish and striped prawn, and appears to play a physiologic role as an osmoprotectant in algae. This study was focused on the extraction of dimethyl-$\beta$-propiothetin as bioactive substance from green seaweed. Identification and quantification of dimethyl-$\beta$-propiothetin were measured by headspace gas chromatography after conversion to dimethyl sulfide by treatment with saturated NaOH solution. Dimethyl-$\beta$-propiothetin was extracted through various processes(solvent extraction, ultrasonication, boiling and autoclaving) from Enteromorpha intesinalis. The content of dimethyl-$\beta$-propiothetin extracted by autoclaving treatment showed higher than those of various extraction methods. Dimethyl-$\beta$-propiothetin content in extract of Enteromorpha Enteromorpha was 311,200ng/g after autoclaving at 121$^{\circ}C$ for 60min. Dimethyl-$\beta$-propiothetin in extract of Enteromorpha intestinalis was comparatively stable under low temperature. The retentions of dimethyl-$\beta$-propiothetin content in extract of Enteromorpha intestinalis were 75.8 ~99.8% by incubation at 10~6$0^{\circ}C$ for 2 hours. Chemical decomposition of dimethyl-$\beta$-propiothetin was observed under laboratory conditions at pH values higher than 9.5.

  • PDF

Total Cross Sections for Kilovolt Neutrons of Even-Odd Nuclei in the Region of the 3s Strength-Function Resonances

  • Mann-Cho;Bak, Hae-Ill;F.H. Frohner;K.N. Muller
    • Nuclear Engineering and Technology
    • /
    • v.2 no.4
    • /
    • pp.241-248
    • /
    • 1970
  • Neutron total cross sections of seperated isotopes were measured with the time-of-flight spectrometer at the 3 MeV Karlsruhe Van do Graaff Accelerator. The neutron energy ranged from 10 to 250 keV. The energy resolution was between 0.2 and 0.5 nsce/m. The measured cross sections were-shape-analyzed in terms of an R-matrix multilevel formula. Thus neutron widths and spins for up to 50 resonances per isotope could be determined. Average neutron widths, level densities and strength functions were derived. The spin dependence of strength functions and the distribution of widths and spacings were investigated.

  • PDF

Comparison of EMD and HP Filter for Cycle Extraction with Korean Macroeconomic Indices (순환성분 추출을 위한 EMD와 HP 필터의 비교분석: 한국의 거시 경제 지표에의 응용)

  • Park, Minjeong;Seong, Byeongchan
    • The Korean Journal of Applied Statistics
    • /
    • v.27 no.3
    • /
    • pp.431-444
    • /
    • 2014
  • We introduce the empirical model decomposition (EMD) to decompose a time series into a set of components in the time-frequency domain. By using EMD, we also extract cycle and trend components from major Korean macroeconomic indices and forecast the indices with the components combined. In order to evaluate their efficiencies, we investigate volatility, autocorrelation, persistence, Granger causality, nonstationarity, and forecasting performance. They are then compared with those by Hodrick-Prescott filter which is the most commonly used method.

Characterization and Isolation of Bacteria Producing Cellulose (Cellulose 생합성 세균의 분리 및 특성)

  • Lee, Seung-Jin;Yoo, Ju-Soon;Chung, Soo-Yeol;Choi, Yong-Lark
    • Applied Biological Chemistry
    • /
    • v.40 no.2
    • /
    • pp.101-106
    • /
    • 1997
  • A screening was performed to isolate the cellulose-producing microorganisms from vinegar in Korea. The isolated strain was identified as Acetobacter sp. with respect to physiological and biochemical characteristics and designated as Acetobacter CBI-2. Cellulose production of Acetobacter CBI-2 was equal with the well known cellulose-producing bacteria, A. xylinum. The result of separation on thin layer chromatography(TLC) was consistent with the degradation product of native cellulose. The presence of genes required for the cellulose biosynthesis in Acetobacter CBI-2 was confirmed by Southern hybridization.

  • PDF

Development of Weakly Nonlinear Wave Model and Its Numerical Simulation (약비선형 파랑 모형의 수립 및 수치모의)

  • 이정렬;박찬성
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.12 no.4
    • /
    • pp.181-189
    • /
    • 2000
  • A weakly nonlinear mild-slope equation has been derived directly from the continuity equation with the aid of the Galerkin's method. The equation is combined with the momentum equations defined at the mean water level. A single component model has also been obtained in terms of the surface displacement. The linearized form is completely identical with the time-dependent mild-slope equation proposed by Smith and Sprinks(1975). For the verification purposes of the present nonlinear model, the degenerate forms were compared with Airy(1845)'s non-dispersive nonlinear wave equation, classical Boussinesq equation, andsecond¬order permanent Stokes waves. In this study, the present nonlinear wave equations are discretized by the approximate factorization techniques so that a tridiagonal matrix solver is used for each direction. Through the comparison with physical experiments, nonlinear wave model capacity was examined and the overall agreement was obtained.

  • PDF

Nano Scale Compositional Analysis by Atom Probe Tomography: II. Applications on Electronic Devices and Nano Materials (Atom Probe Tomography를 이용한 나노 스케일의 조성분석: II. 전자소자 및 나노재료에서의 응용)

  • Jung, Woo-Young;Bang, Chan-Woo;Jang, Dong-Hyun;Gu, Gil-Ho;Park, Chan-Gyung
    • Applied Microscopy
    • /
    • v.41 no.2
    • /
    • pp.89-98
    • /
    • 2011
  • Atom Probe Tomography (APT) can provide 3-dimensional information such as position and chemical composition with atomic resolution. Despite the ability of this technique, APT could not be applied for poor conductive materials such as semiconductor. Recently APT has dramatically developed by applying the laser pulsing and combining with Focused Ion Beam (FIB). The invention and combination of these techniques make possible site-specific sample preparation and permit the investigation of various materials including insulators. In this paper, we introduced the recently achieved state of the art applications of APT focusing on Si based FET devices, LED devices, low dimensional materials.