• Title/Summary/Keyword: 열분석적 특성

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태화강 주변지역 지하수의 수질특성 및 계절별 수질변화 양상

  • Lee Jong-Seong;Kim Do-Sun;Yun Hye-Jeong;Choi Yeong-A;Choi Yeong-Seon;Im Jong-Seon;Yun Han-Jik;Lee Jin-Yeol;Jeong Su-Geun;Ham Yu-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.441-445
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    • 2005
  • 태화강 주변지역 지하수의 계절적 수질 변화를 보고자 현장측정 항목(수온, pH, 알칼리도, 전기전도도), 일반 항목(증발잔류물, 총경도, 과망간산칼륨소비량), 음이온물질$(F^-,\;Cl^-,\;{NO_3}^-,\;{SO_4}^{2-})$, 양이온물질$(Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+)$등으로 구분하여 분석하였으며, 총 70개 지점을 대상으로 2004년 5월, 10월 2회에 걸쳐 실시하였다. 지역별 수질특성을 살펴보면 남구지역은 $Ca-Mg-HCO_3,\;Ca-Mg-HCO_3-Cl,\;Ca-Mg-Na-Cl-HCO_3,\;Na-Cl-HCO_3$의 4가지 유형이 전체 시료의 74%를 차지하였으며, $Ca-Mg-HCO_3$형이 가장 우세하게 나타났고, 중구지역 지하수에서는 $Ca-Mg-HCO_3-Cl,\;Ca-Mg-Na-HCO_3-Cl,\;Ca-Mg-HCO_3$의 3가지 유형이 전체 시료의 60%를 차지하는 것으로 나타났으며, 이중에서 $Ca-Mg-HCO_3-Cl$형이 가장 우세하게 나타났다. 두 지역의 수질 변화를 살펴보면. 전기전도도는 남구는 $731.5{\mu}s/m^3$에서 $529.8{\mu}s/m^3$, 중구는 $752.6{\mu}s/m^3$에서 $621.6{\mu}s/m^3$로 201.7, $131.0{\mu}s/m^3$만큼 작아져 두 지역 모두 같은 양상을 보였으나, Hardness 및 TDS의 경우 남구지역은 5월보다 10월에 평균, 최대값이 모두 낮게 나타났다. 또한 $Cl^-$의 경우 지역적, 계절적으로 큰 차이를 보이고 있으며 남구는 5월 68.2mg/l, 10월에는 61.7mg/l로 다소 감소하였으나 중구의 경우 5월 75.5mg/l, 10월 122.1mg/l로 다소 증가한 것으로 나타났다. 양이온 분포 비율 및 농도는 비슷하게 나타났으며, 계절적으로 5월보다 10월에 모두 높게 나타났다. 두 지역 모두 양이온물질 중 나트륨의 분포비율 및 농도가 5월보다 10월에 다소 높게 나타났다. 연구 지역 지하수의 계절적 수질변화를 살펴보면 두 지역간의 지하수질 및 분포특성에 있어 다소 차이를 보이고 있으며, 특히 중구 지역에서 5월보다 10월에 나트륨과 염소이온의 증가가 다소 나타나는 것으로 관찰되었다. 또한 연구지역 중 특이지점($Cl^-$:1,000mg/l이상)은 남구는 5월에 2개에서 10월에는 3개 지점으로 증가하였으며, 중구는 5월, 10월 모두 4개 지점으로 나타났다.

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A Fundamental Properties of the Concrete Using Coarse Particle Cement and Mineral Admixture (굵은입자 시멘트와 광물질 혼화재를 조합 사용하는 콘크리트의 기초적 특성)

  • Han, Cheon-Goo;Jang, Duk-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.131-138
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    • 2010
  • This research intends to analyze the basic characteristics of cements(hereinafter "CC") with affordable price and particle distribution effective as hydration heat face which are discharged at the outlet of smashing process of ordinary portland cement(hereinafter "OPC") manufacturing process such as fluidity, rigidity, temporary insulation temperature increase amount etc to review the potential of developing "CC" to 3 ingredients low heat cement that substitutes fly ash and blast furnace slag(hereinafter "BS"). As a result of experiment, fluidity tended to decrease with increase in CC substitution rate, and increase with increase in FA+BS substitution rate. Air amount tended to slightly decrease with increase in CC substitution rate, and decrease with increase in FA+BS substitution rate. Condensation characteristics were such that condensation time was delayed with increase in CC and FA+BS substitution rate. As for the temperature rising amount by temporary insulation, peak temperature decreased with increase in CC substitution rate and increase in FA+BS substitution rate in general, and thereafter, temperature tended to decrease slowly. Compressive strength decreased with increase in CC and FA+BS substitution rate, and as aging goes on, long term strength was equivalent to plain or higher. By and large, when FA+BS was substituted to CC, fluidity and air amount tended to decrease, but hydration heat face showed good reduction effects, suggesting possibility of development to 3 ingredients low heat cement.

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Pyrolysis Characteristics of CCL(Copper Clad Laminate) Based Paper/Phenolic Resin Composites (종이/페놀수지가 주성분인 동박적층판(Copper Clad Laminate)의 열분해 특성)

  • Song, Jae-Hun;Kim, Seung-Do;Ahn, Hyun-Cheol;Kim, Gyung-Soo;Kim, Sang-Bum;Jung, Jae-Sung;Gong, Sung-Ho;Cho, Young-Gae
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1013-1019
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    • 2007
  • Electronic wastes have increased tremendously. However, any reliable treatment methodologies have rarely been established. Electronic wastes have posed serious disposal problem due to their physico-chemical stability. This paper investigated the application possibility of pyrolysis for the purpose of recycling the p-CCL(phenol based Copper Clad Laminate). Thermogravimetric analysis(TGA) was used to investigate the thermal decomposition pattern of p-CCL. We elucidated the characteristics of pyrolysis by-products at operating temperatures of 280, 350 and $600^{\circ}C$. GC/MS and FT-IR were used to characterize the liquid by-products along with general characterization methods such as Ultimate Analysis, Proximate Analysis and Heating Value, whereas general characterization methods were only introduced for the solid by-products. At a heating rate of $5^{\circ}C$/min, TGA curves exhibited three decomposition stages: (1) low-temperature decomposition region$(<280^{\circ}C)$, (2) medium temperature region$(280\sim350^{\circ}C)$ and (3) high-temperature region$(>350^{\circ}C)$. The major compounds of liquid by-products at low- and medium-temperatures were accounted for by water and phenol, whereas branched phenols and furans were major compounds at high-temperatures. As the temperature increases, volatile quantities decreased but the fixed carbon increased. High heating values of solid by-products($7,400\sim7,600$ kcal/kg) would suggest that the solid by-products could be applicable as fuel. In addition, high fixed carbon but low ash content of the solid by-products offered an implication that they are capable of being upgradable for adsorbent after applying appropriate activating process.

Physiological and Molecular Characterization of NAD(P)H-Nitroreductase from Stenotrophomonas sp. OK-5 (Stenotrophomonas sp. OK-5에서 분리한 NAD(P)H-Nitroreductase의 생리학적 및 분자생학적 특성 연구)

  • Ho Eun-Mi;Kahng Hyung-Yeel;Oh Kye-Heon
    • Korean Journal of Microbiology
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    • v.40 no.3
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    • pp.183-188
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    • 2004
  • Stenotrophomonas sp. OK-5 capable of degrading TNT has been found to have three nitroreductase fractions designated as NTR fractions I, II, and III. NTR in a previous study. This study was attempted to reveal physiological and molecular characteristics of NTR fractions I, II, and III in strain OK-5. Several chemicals (e.g., EDTA, NaCl, dithiothreitol, $\beta$-mercaptoethanol) were tested for their effect on enzyme activity of NTRs, demonstrating that enzyme activities of NTR fractions I, II, and III from OK-5 were inhibited in the presence of $\beta$-mercaptoethanol. Substrate specificity test showed that NTR fractions I, II, and III all have over 70% enzyme activities for nitrobenzene or RDX as a substrate. N-terminal amino acid sequence of NTR fraction I from Stenotrophomonas sp. OK-5 was $^1MSDLLNADAVVQLFRTARDS^20$ and exhibited 70% sequence homology with that of NTR from Xanthomonas campestris. NTR I gene from Stenotrophomonas sp. OK-5 (SmOK5nrI) shared extensive sequence homology in deduced amino acid sequence of PCR product with NTRs from Xanthomonas campestris (81 %), X. axonopodis (75%), Streptomyces avermitilis(30%), whereas they had low homology with that from P. putida KT2440 (pnrB) (16%).

Study of the Mitigation of Algae in Lake Uiam according to the Operation of the Chuncheon Dam and the Soyang Dam (춘천댐 및 소양강댐 운영에 따른 의암호 조류 저감 연구)

  • Lee, Dong Yeol;Baek, Kyong Oh
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.2
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    • pp.171-179
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    • 2022
  • In this study, the characteristics of algae mitigation according to dam operation were quantitatively analyzed for Uiam Lake, where the Chuncheon Dam is located upstream of the main stream, Uiam Dam is located downstream, and Soyang Dam is located in the tributary stream. Nine dam operation scenarios were applied to the event of the summer of 2018 (at that time an algae alert occurred) using the EFDC model, which is capable of calculating three-dimensional hydrodynamics and water quality levels such as those associated with chlorophyll-a. The dam operation scenarios were set to generate a flushing effect via discharges in the form of pulse waves from the upstream dams and by lowering the water level at the downstream dam. At Uiam Lake, the flushing effect was different depending on the operation of the dam, and the amount of algae reduction at each point was different owing to topographic characteristics and the different base water temperatures from BukHan River and Soyang River. With regard to a point located on the left bank, it was predicted that the peak level of chlorophyll-a would be reduced by approximately 50 % or more upon pulsed discharge at 50 m3/s for three days at Soyang Dam. However, for the right bank, the amount of discharge from Soyang Dam had little effect on algae mitigation. Therefore, an appropriate dam operation could be effective for algae mitigation at specific points in the water body where large dams exist upstream and downstream, such as at Uiam Lake, in an emergency situation in which algal blooms rapidly.

Analysis of Hydrodynamics in a Directly-Irradiated Fluidized Bed Solar Receiver Using CPFD Simulation (CPFD를 이용한 태양열 유동층 흡열기의 수력학적 특성 해석)

  • Kim, Suyoung;Won, Geunhye;Lee, Min Ji;Kim, Sung Won
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.535-543
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    • 2022
  • A CPFD (Computational particle fluid dynamics) model of solar fluidized bed receiver of silicon carbide (SiC: average dp=123 ㎛) particles was established, and the model was verified by comparing the simulation and experimental results to analyze the effect of particle behavior on the performance of the receiver. The relationship between the heat-absorbing performance and the particles behavior in the receiver was analyzed by simulating their behavior near bed surface, which is difficult to access experimentally. The CPFD simulation results showed good agreement with the experimental values on the solids holdup and its standard deviation under experimental condition in bed and freeboard regions. The local solid holdups near the bed surface, where particles primarily absorb solar heat energy and transfer it to the inside of the bed, showed a non-uniform distribution with a relatively low value at the center related with the bubble behavior in the bed. The local solid holdup increased the axial and radial non-uniformity in the freeboard region with the gas velocity, which explains well that the increase in the RSD (Relative standard deviation) of pressure drop across the freeboard region is responsible for the loss of solar energy reflected by the entrained particles in the particle receiver. The simulation results of local gas and particle velocities with gas velocity confirmed that the local particle behavior in the fluidized bed are closely related to the bubble behavior characterized by the properties of the Geldart B particles. The temperature difference of the fluidizing gas passing through the receiver per irradiance (∆T/IDNI) was highly correlated with the RSD of the pressure drop across the bed surface and the freeboard regions. The CPFD simulation results can be used to improve the performance of the particle receiver through local particle behavior analysis.

Effects of Crosslinking Agent and Flame Retardant on the Dielectric Properties of Poly(phenylene ether)-based Polymer Substrate Material (폴리페닐렌에테르계 고분자 기판 소재의 유전특성에 대한 가교제 및 난연제의 영향)

  • Kim, Dong-Kook;Park, Seong-Dae;Yoo, Myong-Jae;Lee, Woo-Sung;Kang, Nam-Kee;Lim, Jin-Kyu;Kyoung, Jin-Bum
    • Polymer(Korea)
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    • v.33 no.1
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    • pp.39-44
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    • 2009
  • Polymer substrates were fabricated by using poly (phenylene ether) as a base resin, N,N'-m-phenylenedimaleimide (PDMI) as a crosslinking agent and decabromodiphenylethane as a flame retardant. The effects of crosslinking agent and flame retardant on physical properties such as dielectric property of the substrate were investigated. Thermal curing feature of PDMI with or without an initiator was analyzed by DSC, and then, PPE-PDMI test compositions were designed based on this result. Composite sheets were cast by film coater, laminated under vacuum and pressure, and then, the changes of dielectric constant, dielectric loss, peel strength, solder heat resistance and inflammability according to increasing amount of PDMI and flame retardant were evaluated, Dielectric constant and dielectric loss showed increasing trend with increasing amount of PDMI and flame retardant, but solder heat resistance and inflammability were improved. Peel strength was obtained higher than 1 kN/m when PDMI above 10 wt% was added, but slightly decreased as the amount of flame retardant increased. From the measured gel contents, the reaction mechanism of PPE-PDMI system was deduced to the formation of network structure by crosslinking PDMI with PPE rather than the formation of semi-IPN structure. In conclusion, the polymer composite substrate materials with dielectric constant of 2.52$\sim$2.65 and dielectric loss below 0.002 at 1 GHz were obtained and they will be proper for high frequency applications.

A Study on the Possibility of Using Fire-Retardant Working Cloth Made from Silicon Carbide (SiC) Composite Spun Yarns (Silicon Carbide (SiC) 복합방적사로부터 제조된 원단의 방화복 활용 가능성에 관한 연구)

  • Kang, Hyun-Ju;Kang, Gun-Woong;Kwon, Oh-Hoon;Kwon, Hyeon-Myoung;Hwang, Ye-Eun;Jeon, Hye-Ji;Joo, Jong-Hyun;Park, Yong-Wan
    • Science of Emotion and Sensibility
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    • v.24 no.4
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    • pp.149-156
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    • 2021
  • The mechanical properties of a woven fabric made of SiC (silicon carbide) fibers were determined in this study using the KES-FB system. The woven fabric is used in high heat settings above 1500℃. Composite spun yarns were used to create SiC fibers. By analyzing the wearing properties, we studied the prospect of using the textiles as fire-retardant work clothes. Mechanical properties determine the wearing attributes. Therefore, the tensile linearity (LT), tensile resilience (RT), and shear stiffness (G) values of the fabric varied according to the yarn type (filament or spun yarn). The thickness, weight per square meter, and density of the fabric were found to have an effect on the shear hysteresis (2HG) and compression resilience (RC) values. In terms of wearable clothing qualities, the fabric qualities of the SiC composite yarn demonstrated the highest ratio of compressive energy to thickness (WC/T), which indicates bulkiness. The fabric manufactured from SiC composite yarns passed the KFI criteria for carbonation length and cumulative flame time in the flame-retardant test. Therefore, we discovered that the material can be used as a fire-resistant work cloth.

A Study on Microclimate Change Via Time Series Analysis of Satellite Images -Centered on Dalseo District, Daegu City- (위성영상의 시계열 분석을 통한 미기후변화 분석 -대구시 달서구를 대상으로-)

  • Baek, Sang-Hun;Jung, Eung-Ho
    • Journal of the Korean Association of Geographic Information Studies
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    • v.12 no.2
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    • pp.34-43
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    • 2009
  • Based on previous research on ways of reducing an urban heat island phenomenon via an introduction of wind corridors, I conducted this study to see what influence a change in land cover arising of or going through urbanization has on wind corridors of urban space. As a target place, I chose Daegu city where is a representative extreme heat place in Korea and has been also largely expanded in size by incorporating its neighboring areas since the 1980s, expecially Dalseo District whose surface temperature gap is large. The population of Dalseo District has been sharply increased since its creation as a new administrative district in 1988. I studied on the urban microclimate change for a 20-year period by using satellite images on summer months in 1987, 1997 and 2007 in time frames. The finding of this study found that a reduction of natural land cover and an increase of artificial land cover serves as a disadvantageous factor for cold air creation and flowing and strikingly lowers the amount and height of cold air in the downtown area. It seemed that the cold air creation and flowing functions are influenced by land cover. In order to steadily create cold air and secure its flowing, it is thought that urban development or urban regeneration should be implemented by analysing the characteristics of the space surrounding the city. By doing so, a pleasant and healthy city could be formed.

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Analysis of Global Shipping Market Status and Forecasting the Container Freight Volume of Busan New port using Time-series Model (글로벌 해운시장 현황 분석 및 시계열 모형을 이용한 부산 신항 컨테이너 물동량 예측에 관한 연구)

  • JO, Jun-Ho;Byon, Je-Seop;Kim, Hee-Cheul
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.10 no.4
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    • pp.295-303
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    • 2017
  • In this paper, we analyze the trends of the international shipping market and the domestic and foreign factors of the crisis of the domestic shipping market, and identify the characteristics of the recovery of the Busan New Port trade volume which has decreased since the crisis of the domestic shipping market We quantitatively analyzed the future volume of Busan New Port and analyzed the trends of the prediction and recovery trends. As a result of analyzing Busan New Port container cargo volume by using big data analysis tool R, the variation of Busan New Cargo container cargo volume was estimated by ARIMA model (1,0,1) (1,0,1)[12] Estimation error, AICc and BIC were the most optimal ARIMA models. Therefore, we estimated the estimated value of Busan New Port trade for 36 months by using ARIMA (1, 0, 1)[12], which is the optimal model of Busan New Port trade, and estimated 13,157,184 TEU, 13,418,123 TEU, 13,539,884 TEU, and 4,526,406 TEU, respectively, indicating that it increased by about 2%, 2%, and 1%.