• Title/Summary/Keyword: 연속추출분석법

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The Distribution Characteristics and Contamination of Heavy Metals in Soil from Dalcheon Mine (달천광산 토양 내 중금속의 존재형태 및 오염도)

  • Suh, Ji-Won;Yoon, Hye-On;Jeong, Chan-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.57-65
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    • 2008
  • The geochemical partitioning of arsenic in contaminated soils from a of wet land and tailing of the abandoned mine is examined. Chemical analysis and sequential extraction method by ultrasound-sonication extraction are applied to investigate the mobility and chemical existence conditions of arsenic as well as heavy metals. The results of this study showed that heavy metals concentration of tailings showed as a following order: Fe > As > Cu > Pb > Cr. The highest metal concentration was recognized in samples less than $63\;{\mu}m$ fraction in their particle sizes. Exchangeable and carbonate fractions in soil samples showed following Cu > As > Pb > Fe > Cr for tailings, and Fe > Pb > Cu > As > Cr for reservoir soils, respectively. Arsenic was bound as exchangeable fraction in tailings and its concentration appeared higher than those of the other metals. Thus, As can be easily dispersed into soil and water environments. The obtained results can be used to design soil remediation plan in the study area and require further detailed study to investigate severe environmental pollution of surface water as well as rivers with respect to heavy metals in terms of speciation analysis of toxic elements such as As and Cr.

The Structure of Korean Consonants as Perceived by the Japanese (일본인이 지각하는 한국어 자음의 구조)

  • Bae, Moon-Jung;Kim, Jung-Oh
    • Korean Journal of Cognitive Science
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    • v.19 no.2
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    • pp.163-175
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    • 2008
  • Twelve Japanese students living in South Korea have been examined for their perceptual identification of an initial consonant in Korean syllables with or without a white noise. A confusion matrix was then subject to analyses of additive clustering, individual difference scaling, and probability of information transmission, the results of which were also compared to those of South Koreans. The Japanese in the present experiment confused /다/and/타/ most frequently, followed by /가/ and /카/, /자, 차, 짜/, /타/ and /따/, and so on. The results of additive clustering analysis of the Japanese significantly differed from those of the South Koreans. Individual difference scaling revealed dimensions of sonorant, aspiration and coronal. While South Koreans showed binary values on aspiration and tenseness dimensions, the Japanese did continuous values on such dimensions. An information transmission probability analysis revealed that the Japanese participants could not perceive very well such larynx features as tenseness and aspiration compared to the South Korean participants. The former group, however, perceived very well place of articulation features such as labial and coronal. The present results suggest that an approach dealing with structures of base representations is important in understanding the phonological categories of languages.

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Accuracy analysis of SPOT Orbit Modeling Using Orbit-Attitude Models (궤도기반 센서모델을 이용한 SPOT 위성 궤도모델링 정확도 분석)

  • Kim, Hyun-Suk;Kim, Tae-Jung
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.4 s.38
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    • pp.27-36
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    • 2006
  • Conventionally, in order to get accurate geolocation of satellite images we need a set of ground control points with respect to individual scenes. In this paper, we tested the possibilities of modeling satellite orbits from individual scenes by establishing a sensor model for one scene and by applying the model, which was derived from the same orbital segment, to other scenes that has been acquired from the same orbital segment. We investigated orbit-attitude models with several interpolation methods and with various parameter sets to be adjusted. We used 7 satellite images of SPOT-3 with a length of 420km and ground control points acquired from GPS surveying. Results of the conventional individual scene modeling hardly introduced differences among different interpolation methods and different adjustment parameter sets. As the results of orbit modeling, the best model was the one with Lagrange interpolation for position/velocity and linear interpolation for attitude and with position/angle bias as parameter sets. The best model showed that it is possible to model orbital segments of 420km with ground control points measured within one scene (60km).

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Simultaneous analysis of residual glucocorticoids in egg by LC/MS/MS (LC/MS/MS를 이용한 계란 중 잔류 글루코코티코이드의 동시분석)

  • Jang, Mi-Ae;Myung, Seung-Woon
    • Analytical Science and Technology
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    • v.22 no.4
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    • pp.326-335
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    • 2009
  • A specific analytical method able to identify and quantify traces of six glucocorticoids residues in eggs were developed. The extraction and clean-up parameters for simultaneous analysis were evaluated and HPLC and spectrometric conditions were also established. For determination of glucocorticoids, 5 g of egg was transferred into a test tube, adjusted pH 5.2 with acetate buffer and was $\beta$-glucuronidase/arylsulfatase from Helix pomatia added. The mixture was centrifuged and supernatant was extracted twice with 20 mL n-hexane. The extraction was performed with HLB cartridge using methanol, followed by clean-up with silica cartridge using methanol/ethyl acetate (4/6, v/v). The analytes were determined by HPLC/ESI-MS/MS operating in the negative ion mode. Validation studies with fortified egg samples for established method were performed. The result of method validation gave good efficiency, linearity, accuracy and precision. The correlation coefficients ($r^2$) of the calibration curves appeared to be higher than 0.99 in egg, indicating excellent linearity. LOD was ranged 0.09 to $0.17{\mu}g/kg$, and recoveries for most compounds were in the range of 55.7-69.8%. This method can be used to determine ${\mu}g/kg$ levels of glucocorticoids in eggs.

Chemical Speciation of Heavy Metals in Geologic Environments on the Abandoned Jangpoong Cu Mine Area (장풍 폐광산 주변 지질환경에서 중금속의 존재형태)

  • Lee In-Gyeong;Lee Pyeong-Koo;Choi Sang-Hoon;Kim Ji-Soo;So Chil-Sup
    • Economic and Environmental Geology
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    • v.38 no.6 s.175
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    • pp.699-705
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    • 2005
  • In order to identify the speciation of As and trace elements which are contained weathered waste rocks on the abandoned Jangpoong Cu mine area, five fraction sequential extraction was carried out. Concentrations of the extraction solutions which were acquaired each fraction were mesured by ICP-AES. Mineral characters of weathered waste rocks were determinated by XRD. The weathered waste rocks could divide into two types (Type I and type II). Type land type II weathered waste rocks are mainly composed of a quartz and a calcite, respectively. The most dominant speciation of As, Co and Fe is residual phase. Most of the speciation of Cd, Mn and Zn is residual phase for type I and Fe-Mn oxide phase for type II. In case of Cu, residual phase is predominant in type I and sulfide is predominet in type II. The most dominant speciation of Pb for type I and type II is associated with the residual phase and Fe-Mn oxide phase, respectively. At pH 4-7 range, the order of relative mobility considers Zn>Cu>Cd>Pb>Co>AS in type I, and Cd>Cu>Zn>Pb>As>Co in type II.

Investigation on Soil Contamination and Its Remediation System in the Vicinity of Some Metalliferous Mines in Korea (국내 일부 금속광산 주변의 토양오염 조사와 광해방지시스템 연구)

  • 정명채;전효택;안주성
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1997.05a
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    • pp.17-20
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    • 1997
  • 이 연구에서는 국내에 산재되어 있는 금속광산들에 대한 토양환경오염을 조사하고 적절한 환경처리를 위한 기초자료를 제공하기 위하여 대표적인 연-아연광산, 동광산 및 금-은광산을 대상으로 As. Cd, Cu, Pb, Zn 등의 오염규모와 분산정도를 규명하고자 하였다. 연구대상지역으로 삼보 연-아연강산, 달성 동-텅스텐광산 그리고 구봉, 삼광, 금왕 금-은광산을 선정하여 이들 광산 주변에서 토양을 채취하여 화학분석을 실시하였다. 그리고 연속추출법을 이용하여 토양중에 존재하는 중금속의 존재형태를 규명하였으며 화학분해방법에 따른 중금속의 추출정도를 고찰하기 위하여 강산을 이용한 분해방법과 토양환경보전법에 제시된 방법을 비교하였다. 화학분석 결과, 삼보광산 주변의 상부토양 (0-15cm 심도)에서는 평균 11.8 $\mu\textrm{g}$/g Cd, 208 $\mu\textrm{g}$/g Cu, 2,700 $\mu\textrm{g}$/g Pb, 8,300 $\mu\textrm{g}$/g Zn이 검출되었으며 일부 농경지에서는 토양환경보전법의 우려기준을 초과하는 중금속이 검출되어 광산활동에 의한 토양오염이 심각함이 조사되었다. 달성광산 주변 토양에서도 다량의 중금속이 검출되었으며 (평균 4.4 $\mu\textrm{g}$/g Cd, 1,950 $\mu\textrm{g}$/g Cu, 1,030 $\mu\textrm{g}$/g Pb, 419 $\mu\textrm{g}$/g Zn) 특히 As (평균 2,500 $\mu\textrm{g}$/g)의 오염이 심각하였다. 그리고 대표적인 금은광산인 구봉, 삼광 및 금왕광산에서는 광미와 선광장 주변에서 다량의 중금속과 As가 검출되었다. 이 연구 결과, 이들 점오염원에 대한 오염정도가 심각하므로 이를 적절하게 처리할 수 있는 오염복구사업이 실시되어야할 것으로 판단된다.

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The Predicting Environmental Fate of Cd, Cu, and Pb by Sequential Fractionation in Mine Tailings and Agricultural Soils

  • Lee, Do-Kyoung;Chung, Doug-Young;Park, Mi-Sun;Lee, Seung-Kil
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.195-200
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    • 1998
  • 토양내에 있어 중금속의 총량 분석만으로는 오염 토양에 대한 환경 평가를 위한 충분한 자료가 되지 못한다. 또한 중금속의 토양내 위해성은 중금속과 토양과의 화학적 상호작용에 의해 결정되기 때문에 중금속의 화학적 형태를 규명하는 것은 토양 환경에 있어서 그들의 이동성과 거동 특성을 평가하는데 중요한 자료가 된다. 연속 추출법은 구봉 광산의 광미로 부터 Cd, Cu, Pb을 화학적 형태에 따라 분리하고, 인위적으로 중금속을 포화시킨 광미와 두밭토양에 있어 중금속의 토양내 거동 특성을 예측하기 위하여 이용되었다. 광미중 Pb의 대부분은 Fe-Mn oxide, carbonate의 결합 형태로 존재하였으며, Cu와 Cd은 각각 71.8%와 42.9%가 유기물, carbonate의 결합형태로 존재하였다. 상당량의 Cd(94.9%), Cu(95.1%), 그리고 Pb(85.8%)은 토양내 잠재적으로 이동 가능한 형태로 존재하였다. 유성과 논산의 밭토양 에 가해진 Cd는 대부분 이동성이 가장 높은 치환태로 존재하였으며, 유성과 논산 토양에서 각각 67.9%와 93.2%가 치환태로 존재하였다. 토양에 가해진 Cd, Cu, Pb은 대부분 이동이 용이한 형태로 존재하였으며, 토양과의 결합세기는 Pb > Cu > Cd 순으로 감소하였다.

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Comparison of hypertonic saline treatment in meningitis with cerebral edema (뇌수막염에서 발생한 뇌부종 치료에서 고장성 식염수 비교)

  • Kim, Hyung Su;Kim, Hee Ra
    • Clinical and Experimental Pediatrics
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    • v.49 no.12
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    • pp.1275-1281
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    • 2006
  • Purpose : Cerebral edema in meningitis is a potentially complication. Hypertonic saline of various concentrations are frequently used to treat cerebral edemas in meningitis. We analyzed the safety and efficacy of osmotic therapy in cerebral edema by comparison of various hypertonic saline concentrations and mannitol. Methods : The medical records of 42 patients, who were followed up in the Department of Pediatrics, Busan Medical Center, from Jan. 2002 to Oct. 2005, were analyzed retrospectively. We measured intracranial pressure, mean flow velocity, and various laboratory parameters. Results : In cerebral edema developed in meningitis, intracranial pressure and symptoms were improved in treatment of hypertonic saline and mannitol. Serial bolus infusion of 3 percent hypertonic saline resulted in the best outcome. There was not a statistically considerable difference on the mean values of the intracranial pressure gap. On transcranial doppler, mean flow velocity was increased and pulsatilty index was decreased. Laboratory findings (osmolarity, Na, Cl, pH, lactic acid, Ca) were diffenent during the treatment period as opposed to K, Hb, bicarbonate, base excess. There was not a specific form of hypertonic saline used in meningitis treatment with cerebral edema. Conclusion : The therapy for cerebral edema in meningitis remains largely empirical. Serial bolus infusion of 3 percent hypertonic saline is better than other hypertonic salines. Various concentrations and different infusion methods of hypertonic saline statistically does not influence the result of treatment. More research aimed at improving cerebral edema treatment is needed to identify new, effective forms of treatment.

The Aroma Components of Duchung Tea and Persimmon Leaf Tea (두충차와 감잎차의 향기성분)

  • Choi, Sung-Hee
    • Korean Journal of Food Science and Technology
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    • v.22 no.4
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    • pp.405-410
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    • 1990
  • The aroma components of duchung tea and persimmon leaf tea were collected simultaneous distillation and extraction method. Those were analyzed and identified by GC-MS using a fused sillica capillary column. Seventy seven components, including 17 alcohols, 3 hydrocarbons, 15 ketones, 16 aldehydes, 8 esters,8 acids, 8 heterocyclic compounds and 2 phenols were confirmed in duchung tea. Seventy one components, including 17 alcohols, 10 hydrocabrons, 11 ketones, 13 aldehydes, 8 esters, 6 acids, 5 heterocyclic compounds and 1 phenol were confirmed in persimmon leaf tea. The most abundant components of duchung tea were aldehydes(23.31%) including 2-pentenal and heterocyclic compounds(16.71%) including $epoxy-{\beta}-ionone$. The most abundant components of persimmon leaf tea were alcohols(25.57%) including linalool and aldehydes(19.45%) including hexanal and hydrocarbons(10.40%) including ${\alpha}-copaene$.

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The application of fuzzy spatial overlay method to the site selection using GSIS (GSIS를 이용한 입지선정에 있어 퍼지공간중첩기법의 적용에 관한 연구)

  • 임승현;조기성
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.17 no.2
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    • pp.177-187
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    • 1999
  • Up to date, in many application fields of GSIS, we usually have used vector-based spatial overlay or grid-based spatial algebra for extraction and analysis of spatial data. But, because these methods are based on traditional crisp set, concept which is used these methods. shows that many kinds of spatial data are partitioned with sharp boundary. That is not agree with spatial distribution pattern of data in the real world. Therefore, it has a error that a region or object is restricted within only one attribution (One-Entity-one-value). In this study, for improving previous methods that deal with spatial data based on crisp set, we are suggested to apply into spatial overlay process the concept of fuzzy set which is good for expressing the boundary vagueness or ambiguity of spatial data. two methods be given. First method is a fuzzy interval partition by fuzzy subsets in case of spatially continuous data, and second method is fuzzy boundary set applied on categorical data. with a case study to get a land suitability map for the development site selection of new town, we compared results between Boolean analysis method and fuzzy spatial overlay method. And as a result, we could find out that suitability map using fuzzy spatial overlay method provide more reasonable information about development site of new town, and is more adequate type in the aspect of presentation.

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