• Proceedings of the Korean Fiber Society Conference
• /
• 2001.04b
• /
• pp.55-58
• /
• 2001

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.6
• /
• pp.730-739
• /
• 2015

Various cellulose nanofibers (CNF) with different morphology and chemical properties were prepared for the reinforcement of sheet of paper mulberry bast fiber. Lignocellulose nanofiber (LCNF), Holocellulose nanofiber (HCNF), alkali-treated HCNF (AT-HCNF), TEMPO-oxidated nanofiber (TEMPO-NF) and cellulose nanocrystal (CNF) were prepared and their addition effect on the properties of sheet of paper mulberry bast fiber were investigated. Air permeability, surface smoothness, and tensile properties were improved by increasing CNF addition. Its improvement may be due to the CNF deposited between and on paper mulberry bast fibers, which was confirmed by SEM observation.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2003.04a
• /
• pp.78-82
• /
• 2003

셀룰로오스계 재생섬유 중 가장 먼저 개발된 Viscose rayon은 셀룰로오스 펄프를 17-18%의 가성소다 수용액에 팽윤시켜 알칼리 셀룰로스를 만든 뒤 이황화탄소(CS$_2$)에 반응시킨 후 방사하여 제조하며 흡습성, 제전성, 드레이프성 및 광택이 우수한 쾌적성 섬유이다. 그러나 탄성 회복율이 좋지 않으며 강력이 적고 특히 습윤시의 강력 저하의 단점이 있을 뿐만 아니라 제조과정에서 사용하는 이황화탄소의 환경 유해성이 큰 문제점으로 지적되고 있어 선진국들이 점차 설비를 폐쇄하거나 개도국으로 이전하고 있는 실정이다. (중략)

• KSBB Journal
• /
• v.20 no.1 s.90
• /
• pp.50-54
• /
• 2005

Tar is often produced during the carbonization of cellulose that limits the formation fibrous structure of the carbonized sample. This problem was reduced by applying a high temperature $(up\;to\;800{\circ}C)$ during carbonization process. Alternatively, dry cellulose was immersed in toluene and ultrasonicated prior to carbonization. In both cases, complete fibrous structures were not achieved. The formation of tar was reduced by the heat treatment of cellulose in the presence of HCI vapor before carbonization process. Such treatment before carbonization yielded mostly the fibrous structures of the carbonized sample as evident from SEM analysis. Similar results were found when the cellulose was subjected to a heat treatment in an inert condition followed by the removal of tar by the oxidation process prior to the carbonization.

• Microbiology and Biotechnology Letters
• /
• v.45 no.1
• /
• pp.1-11
• /
• 2017

In this review, we focus on one of the most attractive biomaterials, microfibrillated cellulose (MFC). MFC, a type of nanocellulose, mainly originates from cellulose in lignocellulosic biomass. MFC represents one of incredible important natural resources due to its abundancy, renewability, and sustainability. MFC is produced through mechanical pretreatment, and it is composed of various sizes of microfibers, ranging from a few nanometers to a few micrometers. Because of the heterogenetic compositions of MFC, it possesses superior properties as a material, such as high surface area, high aspect ratio, and peculiar insolubility as a biomaterial. These properties allow MFC to be used in various bio-industries, from the traditional pulp industry to the high-tech food/bio/chemical/medical industries. However, it is difficult to use MFC on a commercial scale owing to the high energy input required during its production and the challenge of controlling its reactivity. Therefore, future studies should be focused on accurately characterizing MFC's surface morphologies, regulating its characteristics in a desirable direction, and standardizing proper guidelines for the analysis of surface morphologies its analysis.

• Polymer(Korea)
• /
• v.37 no.3
• /
• pp.362-372
• /
• 2013

During extruder processing to manufacture cellulose fiber and film using cellulose-NMMO pre-dope produced by a new method, it seems to occur the changes of molecular weight and ${\alpha}$-cellulose content of cellulose upon thermal and mechanical degradation. In an extruder making cellulose solutions from the pre-dope obtained by high-speed mixer, the changes of cellulose molecular weight and ${\alpha}$-cellulose content resulted with the variations of processing temperature, concentration of cellulose, and residence time. The molecular weight and ${\alpha}$-cellulose content of cellulose decreased with decreasing cellulose concentration and increasing processing temperature. At 15% concentration and short residence time region, the change of ${\alpha}$-cellulose content was so high due to high-shear with an increase in temperature. From these processing conditions, the variations of ${\alpha}$-cellulose content and molecular weight showed different behaviors, and these processing conditions for making cellulose solution were found to be important factors.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.44 no.1
• /
• pp.89-94
• /
• 2018

In this study, water-dispersed biocellulose nanofibers (TC) were prepared via an oxidation reaction using 2,2,6,6-tetramethyl-1-piperidine-N-oxy radical (TEMPO) as a catalyst. The TC retained their unique structure in water as well as in emulsion. TC adhered to the skin surface while maintaining nanofibrous structures, providing inherent functions of biocellulose, such as high tensile strength and high water-holding capacity. When gelatin gels as model skin were coated with TC, the hardness representing the elasticity was increased by 20% compared to untreated gelatin gel because TC could tightly hold the gelatin structure. When porcine skin was treated with TC and TC-contained O/W emulsion, the initial water contact angles of TC were lower than other materials, and dramatically decreased over time as water penetrated the fibrous structure of the TC film. Characterization of TC on the skin surface offered insight into the function of nanofibers on the skin, which is important for their applications with respect to fiber-cosmetics.

• Korean Journal of Food Science and Technology
• /
• v.33 no.2
• /
• pp.216-220
• /
• 2001

This study was conducted to examine the effect of oxidized cellulose that had been selectively oxidized with TEMPO(2, 2, 6, 6-tetramethyl-1-piperidine oxoammonium ion), NaBr and NaOCl substituting for 10% of the wheat flour in a yellow layer cake formula. Physicochemical and sensory characteristics of a cake containing oxidized cellulose were compared with a control cake and a cake containing non-oxidized cellulose(CNC). The cake sample with oxidized cellulose(COC) had smaller L and a values and greater b value than the control, with a greater cake volume. Results of sensory evaluation showed that grittiness of COC was about the same as that of the control, but weaker than that of CNC, and COC was more moist and less hard than the control. These observations indicated the possibility that the oxidized cellulose could be used as a dietary fiber in a cake without causing detrimental effect on textural characteristics.

• 보존과학연구
• /
• s.34
• /
• pp.20-29
• /
• 2013

Paper, textile and wood materials are mainly consisted of cellulose. Cellulose is high molecule and make up the strong crystalline structure by hydrogen bonds. In particular, the polymerization degree of cellulose are closely related to the strength of fiber, and the permanence. the useful life of fiber, also depends on the degradation of this substance. The viscosity of cellulose is considered to be an important indicator of fiber damage in high molecule polymers. The viscosity measurements with CED solution is used to measure the molecular weight and the degree of polymerization of cellulose. Cellulose viscosity of wood fibers is measured with TAPPI standard method T230. However, TAPPI standard method T230 is difficult to completely dissolving the cellulose of high molecular weight and large degree of polymerization, such as Korea traditional papers and fabrics made with mulberry, ramie, cotton fibers. In this study, The high viscosity of hanji and fabric was measured with TAPPI standard method T254. T254 method is that the cellulose specimen with the proper amount of weaker (0.167M CED) solution, and completely dissolved with the stronger (1.0M CED) solution. It was found that cellulose with high degree of polymerization was dissolved more easily in general CED method.

• Proceedings of the Korean Fiber Society Conference
• /
• 1998.10a
• /
• pp.129-132
• /
• 1998

지금까지 면직물의 DP가공에 가장 많이 쓰여온 가교제로는 셀룰로오스의 히드록시기와 ether결합을 형성하는 DMDHEU(dimethyloldihydroxyethylene urea) [1] 이나, 인체에 암을 유발시킬 수 있는 포름알데히드를 발생하기 때문에 그 사용이 제한되고 있으며 현재는 셀룰로오스의 히드록시기와 ester형의 가교를 형성하는 polycarboxylic acid와 같이 포름알데히드를 발생하지 않는 가교제에 대한 연구가 활발히 진행되고 있다. (중략)