• Title/Summary/Keyword: 사이클변화

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Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

An Experimental Study on the Durability of Recycled Aggregate Concrete (재생골재 콘크리트의 내구특성에 관한 실험적 연구)

  • Seo Chi-Ho;Kim Byung-Yun
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.385-392
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    • 2005
  • The object of this study is to prove the quality and reliability of recycled aggregate concrete by finding a way to improve the durability of the material through the experiment on the accelerated carbonation, freezing and thaw, and drying shrinkage, analysing the influence on the durability to Promote more active use of recycled aggregate concrete. The result of study as follows. (1) Resistibility to the freeze and thaw of the recycled aggregate concrete showed relative dynamic modulus of elasticity over $90\%$ which is very good, and all cycles show $99.2{\~}91.0\%$ dynamic modulus of elasticity which is improved compared with the $97.5{\~}90.6\%$ relative dynamic modulus of elasticity of ordinary concrete made of broken stone. (2) Carbonated thickness of the recycled aggregate concrete and the normal concrete was similar or it appeared with the tendency which it diminishes more or less. (3) Length change rate in drying contraction of the recycled aggregate concrete made of the recycled aggregate was lower than the ordinary concrete made of the broken stone by $18.5{\~}3.9\%$ in all blending.

Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

Poly(phenanthrenequinone)-Poly(acrylic acid) Composite as a Conductive Polymer Binder for Submicrometer-Sized Silicon Negative Electrodes (서브마이크로미터 크기의 실리콘 음극용 폴리페난트렌퀴논-폴리아크릴산 전도성 고분자 복합 바인더)

  • Kim, Sang-Mo;Lee, Byeongil;Lee, Jae Gil;Lee, Jeong Beom;Ryu, Ji Heon;Kim, Hyung-Tae;Kim, Young Gyu;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.87-94
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    • 2016
  • In order to improve performances of submicrometer-sized Si negative electrode which shows larger volumetric change than nano-sized Si, composite binders are introduced by blending between poly(phenanthrenequinone) (PPQ) conductive polymer binder and poly(acrylic acid) (PAA) having good adhesion strength due to its carboxyl functional group. Blending between PPQ and PAA shows an effect that the adhesion strength of the Si electrode with the composite conductive binder is greatly improved after blending and this makes its better stable cycle performance. Blending ratios between PPQ and PAA in this work are 2:1, 1:1, 1:2 (by weight) and the best capacity retention at 50th cycle is observed in the electrode with the blending ratio 2:1 (named QA21). This is because that PPQ plays a role of conductive carbon among the Si particles or between Si particles and Cu current collector and PAA binds effectively the particles and the current collector. According to this synergetic effect, the internal resistance of the Si electrode with the blending ratio 2:1 is the smallest value. In addition, the Si electrode with PPQ-PAA composite binder shows the better stable cycle performance than the electrode with conventional super-P conductive carbon (20 wt.%).

Radix-4 Trellis Parallel Architecture and Trace Back Viterbi Decoder with Backward State Transition Control (Radix-4 트렐리스 병렬구조 및 역방향 상태천이의 제어에 의한 역추적 비터비 디코더)

  • 정차근
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.40 no.5
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    • pp.397-409
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    • 2003
  • This paper describes an implementation of radix-4 trellis parallel architecture and backward state transition control trace back Viterbi decoder, and presents the application results to high speed wireless LAN. The radix-4 parallelized architecture Vietrbi decoder can not only improve the throughput with simple structure, but also have small processing delay time and overhead circuit compared to M-step trellis architecture one. Based on these features, this paper addresses a novel Viterbi decoder which is composed of branch metric computation, architecture of ACS and trace back decoding by sequential control of backward state transition for the implementation of radix-4 trellis parallelized structure. With the proposed architecture, the decoding of variable code rate due to puncturing the base code can easily be implemented by the unified Viterbi decoder. Moreover, any additional circuit and/or peripheral control logic are not required in the proposed decoder architecture. The trace back decoding scheme with backward state transition control can carry out the sequential decoding according to ACS cycle clock without additional circuit for survivor memory control. In order to evaluate the usefulness, the proposed method is applied to channel CODEC of the IEEE 802.11a high speed wireless LAN, and HDL coding simulation results are presented.

A Study on Reactivity of Zinc-Based Sorbents (아연계흡수제의 반응특성 규명연구)

  • 연장희;이영우;이창근
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.24-34
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    • 1998
  • In this research, effects of the types and amounts of binders and additives on desulfurization and regeneration reactivities of zinc titanate were investigated. Bentonite and kaolinite were used as binders and Mo-based, Ni-based, and Cu-based compounds were used as additives. A thermogravimetric analyzer (TGA) was utilized to investigate reactivities of desulfurization and regeneration for each sorbent. Two-cycle reactions of desulfurization-regeneration were performed in the TGA reactor. Results of XRD analysis showed that all sorbents had the crystalline phases of $Zn_2TiO_2$ and $Zn_2Ti_3O_8$ irrespective of the type and amount of binder and additive. Kaolinite-bound sorbents gave higher surface areas than bentonite-bound ones and the surface areas and pore volumes of sorbents increased with amount of binder increased. It was found that the most suitable temperatures for desulfurization and regeneration were 680$^{\circ}$C and 730$^{\circ}$C, respectively, and the sorbent prepared by the addition of 3 mol% CuO showed the best performance in terms of desulfurization and regeneration. Nio-added sorbents had good regenerability whereas $MoO_3-based$ sorbents showed poor performance. In cycle experiments in a fixed bed reactor 3 mol% CuO-added sorbents showed high reactivity.

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A study on an instantaneous angular velocity and torque fluctuation for marine diesel engine (선박용 디젤 기관의 순간 각속도와 토크 변동에 관한 연구)

  • Jung, Gyun-sik;Lee, Ji-woong
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.722-728
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    • 2015
  • The demand for shipboard energy management is expected to gradually increase based on ship energy efficiency management plans (SEEMPs), which have been in use since January 1, 2013. Therefore, the fuel consumption of the main engine, which occupies the greatest portion of the energy used, along with elements related to the engine power, should be strictly monitored. There are many different methods for indicating the engine power. However, this study performed an experiment to monitor the status of a ship's engine power in real time using an encoder and a proximate switch, which are economical to purchase and easy to install. In the experiment, the angular velocity during one cycle of a two-stroke low-speed engine was measured, and the measured data were converted to the torque fluctuation. The angular velocity during an abnormal firing condition in the cylinder was also measured, and the torque fluctuation as a result of a misfire was considered. The results were compared with sea trial data to determine the reliability. In this study, the status of the engine power was determined using the torque fluctuation of the main engine in an operating ship.

The evaluation of applicability for agricultural reservoir of CAT(Catchment hydrologic cycle Assessment Tool) (CAT 모형의 농업용 저수지 유역에 대한 적용성 평가)

  • Jang, Cheol-Hee;Kim, Hyeon-Jun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.121-121
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    • 2011
  • 도시유역 물순환 해석 모형(Catchment hydrologic cycle Analysis Tool, CAT)은 기존의 개념적 매개변수 기반의 집중형 수문모형과 물리적 매개변수 기반의 분포형 수문모형의 장점을 최대한 집약하여, 도시유역 개발 전/후의 장/단기적 물순환 변화특성을 정량적으로 평가하고 물순환 개선시설의 효과적인 설계를 지원하기 위한 물순환 해석 모형이다. 이 모형은 수문학적으로 균일하게 판단되는 범위를 소유역으로 분할하여 지형학적 요인에 의한 유출 특성을 객관적으로 반영할 수 있으며, 개발 공간 단위별로 침투, 증발, 지하수 흐름 등의 모의가 가능하도록 하는 링크-노드 방식으로 개발되었다. 모형의 UI(User Interface)는 사용자가 손쉽게 모형을 적용/관리하고, 여러 시나리오를 동시에 효과적으로 모의하여 분석할 수 있도록 설계되었다. 또한, 모든 입/출력 자료를 엑셀이나 텍스트 형식과 연동되도록 하여 프로젝트별 매개변수 관리가 용이하도록 개발하였다. 특히 본 모형에서는 사용자의 목적에 맞는 다양한 물순환 개선시설(침투시설, 저류지, 습지, 빗물저장시설, 리사이클 및 외부급수 등)의 구현 및 모의가 가능하도록 개발하였다. CAT은 수자원의지속적확보기술개발사업(2008 ~ 2011)의 연구 성과로서 한국건설기술연구원에서 개발하였다. 2008년 말에 모형의 기본구조가 개발되었고, 2009년에는 세부 알고리즘인 증발산, 침투, 유역 유출, 지하수 유거, 하도추적 등의 모듈과 사용자 편의시스템이 개발되었다. 2010년에는 우리나라 논의 특성을 반영한 논 유출 해석 모듈 및 저류지, 침투시설, 습지, 빗물이용시설 및 하천에서의 취수와 도수 등과 같은 물순환 개선시설을 평가할 수 있는 모듈을 추가하여 개발하였으며 2010년 3월에 도시유역 물순환 해석 모형 1.0 베타 버전을 출시하였다. 2010년 12월 에는 1.0 베타 버전에 침투해석모듈(Green&Ampt, Horton), 논에서의 개량물꼬 배수, 침투녹지(Bioretention) 및 차집관거 기능을 추가하였고, 기타 GUI의 업그레이드 및 추가를 통하여 1.5 베타 버전을 출시하였다. 현재까지 여러 자연유역과 신도시 개발지역에 대한 적용을 통하여 모형의 적용성을 평가하였다. 본 연구에서는 기존의 자연유역과 신도시 개발지역 외에 농업용 저수지와 논 관개지구가 위치한 유역을 대상으로 모형의 적용성을 평가하고자 하였다. 대상유역은 농업용수 지구이며 농업수리시설의 종류와 규모가 다양할 뿐만 아니라 농촌유역으로써의 대표성을 가지고 기존의 관측자료가 풍부한 점 등을 고려하여 경기도 평택의 이동유역을 선정하였다. 이동유역은 행정구역으로는 경기도 용인시 이동면, 남사면 일원이며 서쪽은 경기도 오산시, 남쪽은 평택시, 안성시 그리고, 북쪽은 용인시와 인접하고 있다. 이동유역 내 주요시설로서 유역면적 $94.4km^2$의 이동저수지와 상류에 용덕저수지($12.41km^2$)와 미산저수지($4.39km^2$), 노곡저수지($2.00km^2$)의 3개 저수지가 위치하며 2개의 유입하천(진위천, 송전천)에 의해 이동저수지로 유입된다.

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Study on the Estimation of Long Life Cycle and Reliability Tests for Epoxy Insulation Busway System (에폭시 박막 절연형 버스웨이 시스템의 장기 수명 및 신뢰성 평가에 관한 연구)

  • Jang, Dong-Uk;Park, Seong-Hee;Lee, Kang-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.261-268
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    • 2018
  • The use of electric cable was limited due to the installation time and large space as the increase of power demand and load quantity in side line. In order to solve these problems, the application of busway system which can supply the large current was increasing. But it was lack of methods of performance tests to evaluate the reliability and results of test for busway system. In this paper, we presented items to evaluate the reliability test for epoxy coated busway system with reference to IEC 61349-6. In addition, we proposed items to evaluate the reliability and long term life cycle test for the epoxy coated busway system. The combined acceleration deterioration test that reflects actual conditions of the survey as much as possible was conducted considering both thermal and electrical stresses. The deterioration condition was selected to satisfy fifty years life expectation and the insulation performance verification test of the busway system confirmed the long term life prediction. Furthermore, as test items for reliability assessment of compliance with the environment for the use of temperature, humidity and load current where busway system was installed, thermal overload test, water immersion test, cold shock temperature test and thermal cycle test were performed. And we examined changes in characteristics and abnormality after tests. From results, the test items presented to evaluate performance and reliability of the epoxy insulated busway system were confirmed to be appropriate in this paper, and the performance of the product was also confirmed to be excellent for reliability tests.

An XML based Mobile Information Visualization System for Mobile Devices using Information layout Techniques (Rectangle Layout을 이용한 XML 기반 모바일 정보 시각화 시스템)

  • Yoo Hee-Yong;Cheon Suh-Hyun
    • Journal of KIISE:Software and Applications
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    • v.33 no.9
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    • pp.776-786
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    • 2006
  • This paper proposes XML based mobile information visualization system using rectangle layout to show effectively XML based information to user on mobile devices which do not have a rich display feature. We define XML schema that can describes information in graph with cycle as well as information in tree form. It suggests using rectangle layout method that is an improvement of the traditional method of the radial layout because the specificity of the mobile display should be considered when XML information is rendered on the screen. And then, it applies DOI of fisheye view algorithm to information on the rectangle layout to represent all and user interest information. And it also suggests an effective method considering capability of mobile devices to decrease user's confusion and improve awareness of user when a user Interest target selected. The proposed information visualization system in the form of focus+context supports an effective interface for information retrieval via mobile devices, such as PDA, cellular phone and smart phone, that usually have less power of CPU than that of PC and the constraints of display and memory. In this paper, it performs experiments and makes an evaluation comparing information visualization method between the traditional radial layout and the proposed rectangle layout.