• Title/Summary/Keyword: 비면적 저항

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Effect of CdTe Deposition Conditions by Close spaced Sublimation on Photovoltaic Properties of CdS/CdTe Solar Cells (CdTe박막의 근접승화 제조조건에 따른 CdS/CdTe 태양전지의 광전압 특성)

  • Han, Byung-Wook;Ahn, Jin-Hyung;Ahn, Byung-Tae
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.493-498
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    • 1998
  • CdTe films were deposited by close spaced sublimation with various substrate temperatures, cell areas, and thicknesses of CdTe and ITO layers and their effects on the CdS/CdTe solar cells were investigated. The resistivity of CdTe layers employed in this study was 3$\times$ $10^{4}$$\Omega$cm For constant substrate temperature the optimum substrate ternperature for CdTe deposition was $600^{\circ}C$. To obtain larger grain size and more compact microstructure, CdTe film was initially deposited at 62$0^{\circ}C$, and then deposited at 54$0^{\circ}C$. The CdTe film was annealed at 62$0^{\circ}C$ and $600^{\circ}C$ sequentially to maintain the CdTe film quality. The photovoitaic cell efficiency improved by the "two-wave" process. For constant substrate temperature, the optimum thickness for CdTe was 5-6$\mu m$. Above 6$\mu m$ CdTe thickness, the bulk resistance of CdTe film degraded the cell performance. As the cell area increased the $V_{oc}$ remained almost constant, while $J_{sc}$ and FF strongly decreased because of the increase of lateral resistance of the ITO layer. The optimum thickness of the ITa layer in this study was 300~450nm. In this experiment we obtained the efficiency of 9.4% in the O.5cm' cells. The series resistance of the cell should be further reduced to increase the fill factor and improve the efficiency.

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Fabrication of MEA using gradient catalyst coating method (Gradient catalyst coating 방법을 이용한 MEA 제조)

  • Kim, Kun-Ho;Kim, Hyoung-Juhn;Lee, Sang-Yeop;Lim, Tae-Hoon;Lee, Kwan-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.325-328
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    • 2006
  • 고분자 전해질 연료전지의 전극을 gradient catalyst coating 방법을 이용하여 제조하였다. 촉매 잉크제조 시 나피온 이오노머의 함침 구성비를 다르게 하여 조성 비율이 다른 gradient 구조를 갖도록 하여 전극을 제조하였다. Anode Cathode의 두 전극을 각각 나피온 함량비가 다른 두 개의 gradient 층구조의 촉매층으로 9:1, 8:2, 7:3, 6:4 비율의 조성비로 성능을 측정하였으며, 전극의 전기화학적 반응 면적을 알아보기 위해 순위전위법을 그리고 분극 저항(Polarization resistance) 변화를 알아보기 위해서는 0.7V에서 임피던스 측정법의 전기화학분석법으로 전극 제조법에 따른 성능변화를 확인하였다. 특히 Gradient catalyst coating 방법을 이용하여 제조한 MEA는 종래 방식의 MEA보다 high current $density(1000mA/cm^2)$이상에서 향상된 성능을 보였다.

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1V 2.56-GS/s 6-bit Flash ADC with Clock Calibration Circuit (클록 보정회로를 가진 1V 2.56-GS/s 6-bit Flash ADC)

  • Kim, Sang-Hun;Lee, Han-Yeol;Jang, Young-Chan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.10a
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    • pp.436-439
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    • 2011
  • 본 논문은 클록 보정회로를 가진 1V 2.56-GS/s 6-bit flash analog-to-digital converter (ADC) 제안한다. 제안하는 ADC 구조에서 아날로그 블록은 단일 T/H와 2단의 프리앰프, 그리고 비교기를 사용된다. 2단의 프리앰프와 비교기의 출력에 옵셋의 크기를 줄이기 위하여 저항 평균화 기법을 적용하였다. 디지털 블록은 quasi-gray rom base 구조를 사용한다. 3입력 voting 회로로 flash ADC에서 발생하기 쉬운 bubble error를 제거하였으며, 고속 동작을 위해 단일 클록을 사용하는 TSPC F/F로 구현한다. 제안하는 flash ADC는 클록 듀티 비를 조절할 수 있는 클록 보정회로를 사용한다. 클록 보정 회로는 비교기 클록 듀티 비를 조절하여 리셋 시간과 evaluation 시간의 비율을 최적화함으로 dynamic 특성을 확보한다. 제안한 flash ADC는 1V 90nm의 CMOS 공정에서 설계되었다. Full power bandwidth인 1.2 GHz 입력에 대하여 ADC 성능을 시뮬레이션을 통해 확인하였다. 설계된 flash ADC의 면적과 전력소모는 각각 $800{\times}400\;{\mu}m^2$와 193.02mW 이다.

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Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System (3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향)

  • Khan, Md. Al-Masrur;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.82-92
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    • 2022
  • This study aims to investigate the effect of total electrochemical cell resistance (TECR) on electrochemical impedance (EI) measurements of reinforced concrete (RC) by electrochemical impedance spectroscopy (EIS) using a three-electrode system. A series of experimental study is performed to measure electrochemical behavior of a steel bar embedded in a concrete cube specimen, with a side length of 200 mm, in various experimental conditions. Main variables include concrete dry conditions, coupling resistance between sensing electrodes and concrete surface, and area of the counter electrode. It is demonstrated that EI values remains stable when the compliant voltage of a measuring device is sufficiently great compared to the potential drop caused by TECR of concrete specimens. It is confirmed that the effect of the coupling resistance of TECR is far more influential than other two factors (concrete dry conditions and area of the counter electrode). The results in this study can be used as a fundamental basis for development of a surface-mount sensor for corrosion monitoring of reinforced concrete structures exposed to wet-and-dry cycles under marine environment.

Status and Prospect of Herbicide Resistant Weeds in Rice Field of Korea (한국 논에서 제초제 저항성잡초 발생 현황과 전망)

  • Park, Tae-Seon;Lee, In-Yong;Seong, Ki-Yeong;Cho, Hyeon-Suk;Park, Hong-Kyu;Ko, Jae-Kwon;Kang, Ui-Gum
    • Korean Journal of Weed Science
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    • v.31 no.2
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    • pp.119-133
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    • 2011
  • Sulfonylurea (SU)-resistant weeds include seven annual weeds such as Monochoria vaginalis, Scirpus juncoides and Cyperus difformis, etc., and three perennial weeds of Scirpus planiculmis, Sagittaria pigmaea and Eleocharis acicularis as of 2010 since identification Monochoria korsakowii in the reclaimed rice field in 1998. The Echinochloa oryzoides resistant to acetyl CoA carboxylase (ACCase) and acetolactate synthase (ALS) inhibitors has been confirmed in wet-direct seeding rice field of the southern province, Korea in 2009. In the beginning of occurrence of SU-resistant weeds the M. vaginalis, S. juncoides and C. difformis were rapidly and individually spreaded in different fields, however, theses resistant weeds have been occurring simultaneously in the same filed as time goes by. The resistant biotype by weed species demonstrated about 10- to 1,000-fold resistance, base on $GR_{50}$ (50% growth reduction) values of the SU herbicides tested. And the resistant biotype of E. oryzoides to cyhalofop-butyl, pyriminobac-methyl, and penoxsulam was about 14, 8, and 11 times more resistant than the susceptible biotype base on $GR_{50}$ values. In history of paddy herbicides in Korea, the introduction of SU herbicides including besulfuron-metyl and pyrazosulfuron-ethyl that control many troublesome weeds at low use rates and provide excellent crop safety gave farmers and many workers for herbicide business refreshing jolt. The products and applied area of SU-included herbicides have been rapidly increased, and have accounted for about 69% and 96%, respectively, in Korea. The top ten herbicides by applied area were composed of all SU-included herbicides by 2003. The concentrated and successive treatment of ACCase and ALS inhibitors for control of barnyardgrass in direct-seeded rice led up to the resistance of E. oryzoides. Also, SU-herbicides like pyrazosulfuron-ethyl and imazosulfuron which are effective to barnyardgrass can be bound up with the resistance of E. oryzoides. The ALS activity isolated from the resistant biotype of M. korsakowii to SU-herbicides tested was less sensitive than that of susceptible biotype. The concentration of herbicide required for 50% inhibition of ALS activity ($I_{50}$) of the SU-resistant M. korsakowii was 14- to 76-fold higher as compared to the susceptible biotype. No differences were observed in the rates of [$^{14}C$]bensulfuron uptake and translocation. ALS genes from M. vaginalis resistant and susceptible biotypes against SU-herbicides revealed a single amino acid substitution of proline (CCT), at 197th position based on the M. korsakowii ALS sequence numbering, to serin (TCT) in conserved domain A of the gene. Carfentrazone-ethyl and pyrazolate were used mainly to control SU-resistant M. vaginalis by 2006, the early period, in Korea. However, the alternative herbicides such as benzobicyclone, to be possible to control simultaneously the several resistant weeds, have been developing and using broadly because the several resistant weeds have been occurring simultaneously in the same filed. The top ten herbicides by applied area in Korea have been occupied by products of 3-way mixture type including herbicides with alternative mode of action for the herbicide resistant weeds. Mefenacet, fentrazamide and cafenstrole had excellent controlling effects on the ACCase and ALS inhibitors resistant when they were applied within 2 leaf stage.

An Experimental Study on the Stabilizing Effect of Nails Against Sliding (사면에 설치된 쏘일네일링의 활동억지효과에 대한 실험적 연구)

  • Hong Won-Pyo;Song Young-Suk
    • Journal of the Korean Geotechnical Society
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    • v.22 no.2
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    • pp.5-17
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    • 2006
  • In order to investigate the stabilizing effect of nails against sliding, a series of model tests were carried out. The apparatus of model test was designed to perform the model test of soil slope reinforced by nails. The instrumentation system was used to measure the deflection behavior of nails during slope failure. As a result of model tests, the quantity and the occurred position of the maximum bending stress are changed according to the area ratio and the inclination angles of nails. The maximum stabilizing effect against sliding of nails is presented at 0.7$\%$ of the area ratio because the biggest maximum bending stress occurs at this time. But, the stabilizing effect of nails decreases with more than 0.7$\%$ of the area ratio. In the same condition of the area ratio, the stabilizing effect of nails is excellent at -10$^{circ}$ of the inclination angles of nails. The sliding surface can be predicted on the basis of the position of the maximum bending stress in each nails. The shape and depth of sliding surface are changed according to the area ratio and the inclination angles of nails.

Evaluation of Deterioration of Epoxy Primer for Steel Bridge Coating using Image Processing and Electrochemical Impedance Spectroscopy (화상처리 기법과 전기화학적 임피던스 분광법을 이용한 강교 도장용 에폭시 하도 도료의 열화 평가)

  • Lee, Chan Young;Lee, Sang Hun;Park, Jin Hwan
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.53-61
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    • 2009
  • In this study, both evaluations by visual imaging for exterior view of coating and by EIS were executed for epoxy primer coated specimens deteriorated by accelerated test, and comparison and analysis were carried out for 2 evaluation methods. In the comparison between total damaged area ratio acquired by image processing method and deterioration point, higher deterioration points were appeared for rusted specimens than for non-rusted specimens. It is attributed that deterioration point per unit area ratio given for rust is higher than for peeling. In the comparison between total damaged area ratio and EIS result, impedance of coating was largely decreased as about TEX>$10^4{\Omega}{\cdot}cm^2$ or less when rust area ratio is more than about 0.1%, and blistering area ratio is more than about 3%. Charge transfer resistance ($R_{ct}$) and double layer capacitance ($C_{dl}$) values were appeared for all specimens except 2 ones, which shows that water is accumulated and steel substrate is corroded at coated film-steel interface. In the comparison between deterioration point and EIS result, more than 10 points as deterioration point were given for specimens of below $10^6{\Omega}{\cdot}cm^2$ of impedance at low frequency. For specimens deteriorated by NORSOK cyclic test, impedance was lowest of all, though deterioration point was not high. It is thought to be attributed that coating system and accelerated deterioration condition of cyclic tested specimens were different from those of main specimens. From the result, it is thought that coating resistance can be relatively more decreased than deterioration degree estimated from exterior view under more severe corrosion environment or in the present of more complex deterioration factors.

Magnetoresistive heads with dual exchange bias using $NiFe/TbCo/Si_3N_4$ thin films (자기 저항 헤드의 이중 자기 교환 바이어스를 위한 $NiFe/TbCo/Si_3N_4$ 박막제조)

  • 김영채;오장근;조순철
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.239-243
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    • 1994
  • $NiFe/TbCo/Si_3N_4$ thin films were fabricated, which can be employed as dualOongitudinal and transverse) biased magnetoresistive elements utilizing surface magnetic exchange at the interface of NiFe/TbCo films. When Tb area percent was 36 % and substrate bias was not applied, magnetic exchange fields of 100~180 Oe were obtained. The thicknesses of NiFe, TbCo and $Si_3N_4$(Protective layer) were $470\;{\AA},\;2400\;{\AA}\;and\;600\;{\AA}$, respectively. Magnetoresistance ratio of 1.45 % was obtained using NiFe films fabricated with 1000 W power and 2.5 mTorr of Ar pressure. The MR ratio of microstructured elements was reduced to 1.31 % and the MR response curves were shown not to saturate due to demagnetizing fields of the elements. When elements were fabricated with $36^{\circ}$ of misalignment with respect to the exchange field direction using films having 150 Oe exchange field, MR response curve was shifted by 85 Oe, and the operating point of the device shifted to the linear region of the response. Also, the Barkhausen noise was eiminated due to longitudinal bias field originating from the exchange field.

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A Comparative Study on Skid Resistance Performance Evaluation Methods for Maintenance of Skid Resistance Pavement (미끄럼방지포장 유지관리를 위한 미끄럼저항 성능평가방법 비교 연구)

  • Hyun-Woo Cho;Sang-Kyun Noh;Bong-Chun Lee;Yoon-Seok Chung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.6
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    • pp.79-85
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    • 2023
  • Skid resistance pavement is an accessory to the road and is a facility for the safe driving of cars by increasing the skid resistance of road pavement. In particular, in bad weather conditions such as snow, rain, and black ice, the skid resistance performance of skid resistance pavement greatly affects the safety of road traffic and drivers. However, BPT(British Pendulum Tester) has a test area of only 0.009 m2, making it difficult to represent the overall packaging surface. A reliable method of evaluating slip resistance performance is needed for maintaining non-slip packaging. In this study, the conventional BPT test and the skid resistance performance evaluation method of the PFT(Pavement Friction Tester) and µGT(Micro Grip Tester) tests were compared through guidelines and standard investigations and applied to the field skid resistance performance evaluation. In addition, skid resistance pavement with different skid resistance performance was installed at the test-bed and actual road demonstration sites to compare BPN(British Pendulum Number), SN(Skid Number), GN(Grip Number), and to derive correlations for each performance evaluation method. As a result of the experiment, SN and GN showed similar skid resistance performance, and the GN value was derived similar to BPN × 0.01.

Cone Resistivity Penetrometer for Detecting Thin-Layered Soils (협재층 탐지를 위한 선단비저항 콘)

  • Yoon, Hyung-Koo;Jung, Soon-Hyuck;Kim, Rae-Hyun;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.26 no.8
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    • pp.15-25
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    • 2010
  • The thin-layered sand seam in clay affects the soil behavior. Although the standard cone penetrometer (A: $10cm^2$) have been used to evaluate the thin-layered soil, the smaller diameter cone penetrometer have been commonly recommended because of the high resolution. The purpose of this study is the development and application of the Cone Resistivity Penetrometer (CRP), which detects qc, fs, and electrical resistivity at cone tip for the evaluation of thin layered soils. Two sizes of the CRP are developed for the laboratory and field test. The projected areas of CRP for the laboratory and field tests are $0.78cm^2$ (d: 1.0 cm) and $1.76cm^2$ (d: 1.5 cm), repectively. The length of friction sleeve is designed in consideration of ratio of the projected area to the friction sleeve area. The application tests are carried out by using the artificially prepared thin-layered soils in the laboratory. In addition, the field tests are conducted at the depth of 6 to 15 m in Kwangyang. In the laboratory test, the measured electrical resistivity and cone tip resistance detect the soil layers. Moreover, in the field test the CRP investigates the three thin-layered soils. This study suggests that the CRP may be a useful tool for detecting thin-layered in soft soils.