• Title/Summary/Keyword: 분리용매

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A Study on stability of membrane in O/W/O emulsion liquid surfactant membrane separation (O/W/O 유화형 액막분리에 있어서 막의 안정성에 관한 연구)

  • Kim, Ju-Duck
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.1
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    • pp.5-26
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    • 1996
  • O/W/O(oil in water in oil)형 유화액막에 의한 2성분 탄화수소 혼합물인 toluene-cyclo hexane의 분리에 있어서 투과율, 막의 안정성과 분리계수에 미치는 영향을 계면활성제 농도, emulsion과 용매와의 교반속도 등을 변수로 하여 실험하였다. 계면활성제의 농도가 증가함에 따라 투과율은 증가하는데 0.5wt% 이상에서는 증가율이 둔화 되었다. 막 파괴율은 0.1wt%에서 가장 낮게 나타났으며, 그 이상에서는 농도가 증가하면서 파괴율도 증가하였다. 또한 분리계수는 계면활성제의 농도가 0.5wt%에서 가장 높게 나타났다. 에멀젼 제조 시 교반속도 변화에서는 투과율이나 막 파괴율에 큰 영향을 미치지 않는 것으로 나타났다. 막 강화제의 농도가 증가함에 따라 투과율은 감소하였고, 에멀젼과 용매의 접촉 시 교반속도가 증가 할수록 막 파괴율도 증가하였다.

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A Study on the Purification of Crude Phosphoric acid using Solvent Extraction Method (용매 추출법을 이용한 조인산 정제에 관한 연구)

  • Yoon, Yu-Mi;Kim, Ju-Yup;Shin, Chang-Hoon;Kim, Hyun-Sang;Ahn, Jae-Woo
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.168-172
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    • 2005
  • 초산, 질산 및 인산이 함유된 폐혼산에서 초산과 질산을 1차 분리하고 남은 조인산으로부터 정제인산으로 회수한 후 에칭액의 원료로 재활용하기 위하여 용매 추출 기술을 검토하였다. 알루미늄(Al) 및 몰리브덴(Mo) 불순물이 함유된 조인산을 인산염 추출제를 이용하여 인산을 추출한 후 세정공정과 탈거공정을 거쳐 알루미늄과 몰필브덴을 분리하기 위한 최적 분리조건을 도출하고자 하였다. 실험 결과 추출공정과 세정공정, 그리고 탈거 공정을 통하여 알루미늄 및 몰리브덴의 함량을 1ppm이하로 분리 제거하여 정제 인산으로 회수가 가능하였다.

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Separation of Molybdenum and Tungsten from Sulfuric acid Solution by Solvent Extraction with Alamine 336 (황산용액에서 Alamine 336에 의한 용매추출로 몰리브덴과 텅스텐의 분리)

  • Nguyen, Thi Hong;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.1
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    • pp.16-23
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    • 2016
  • The separation behaviour of Mo and W from sulfuric acid solution by solvent extraction with Alamine 336 was investigated as a function of solution pH and extractant concentration. Selective extraction of Mo over W by Alamine 336 was obtained in the pH range of 3-5 with low amine concentration. The mixture of Alamine 336 and acidic extractants improved the separation factor between Mo and W and was in the following order: D2EPHA > PC88A > Decanol > Versatic acid. The stripping efficiency of Mo and W from the loaded mixture of Alamine 336 and D2EHPA was very poor, while complete stripping of Mo and W was possible from the mixture of Alamine 336 and Decanol by using a mixture of $NH_4OH$ and $NH_4Cl$.

An Investigation into Ultrasonic Flotation Separation of Spent MgO-C Refractories Using Acetic Acid (아세트산을 활용한 폐 마그카본(MgO-C) 내화물의 초음파 부상 분리에 관한 연구)

  • Yunki Byeun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.40-46
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    • 2024
  • A novel approach is presented to address issues associated with the use of strong acidic solutions for the leaching of magnesium oxide (MgO) from spent magnesia-carbon refractories. An ultrasonic flotation and separation process is employed, with a mildly acidic solvent, acetic acid, used to selectively chelate MgO from the spent refractories. When using 2 M acetic acid as a solvent, the recovery of the graphite exhibited 99.7 % with high purity of 72.7 %, showing a significant improvement compared to using water as the solvent. Furthermore, the technology presented in this study offers a method for producing magnesium acetate through the reaction of MgO in spent refractory with acetic acid, providing a means for the purification and separation of graphite.

Solvent Extraction Separation of Re (VI) from Hydrochloric Acid Leaching Solution of Spent Super Alloy by Alamine 304-1 (폐 초내열합금 염산침출 용액으로부터 Alamine304-1을 이용한 레늄의 용매추출분리)

  • Ahn, Jong-gwan;Jung, Hee-Kyeoung;Jang, Jae-Young;Kim, Min-Seuk
    • Resources Recycling
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    • v.24 no.5
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    • pp.56-62
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    • 2015
  • Solvent extraction experiments for the separation and recovery of Re from hydrochloric acid leaching solution of spent super alloy by Alamine 304-1 were carried out. The effects of some variables, such as the nature and concentration of the extractants, HCl concentration, and the presence of impurities were investigated. The synthetic solutions of Re were prepared by dissolving ammonium perrhenate (APR), Alamine304-1, Cyanex272 and $D_2EHPA$ were used solvent extractants distilled in kerosene. The extraction percentage of Re by Alamine304-1 was higher than the other extractants as Cyanex272 and $D_2EHPA$ and the percentage is about 99%. Only 99% of Re was extracted in the presence of Al, Co and V in HCl solution.

An Effective Method of Isolating Immunoglobulins from Bovine Plasma Proteins (도축혈액으로부터 면역단백질의 효과적인 분리법)

  • Choi, In-Wook;Lee, Hyun-Jung
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.1067-1070
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    • 1997
  • Imunoglobulins from bovine plasma proteins were isolated by IMAC which $Cu^{2+}$ was chelated on a chelating sepharose fast flow gel. Most plasma proteins were eluted by 1st (0.01 M $Na_2HPO_4$, 0.5 M NaCl, pH 4.0) and 2nd elution buffers (0.01 M imidazol). According to the reverse phase HPLC analysis, it was found that proteins which were eluted by 1st elution buffer were mainly composed of serum albumin, while most IgG and transferrin were eluted by 2nd elution buffer. When protein fractions obtained by 2nd elution buffer was applied to ultra filtration system (molecular weight cut off: 100 kD), IgG was further purified. These results indicate that IMAC is an excellent tool for isolating imunoglobulins from plasma proteins.

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Control of Nano-Structure of Ceramic Membrane and Its Application (세라믹 멤브레인의 나노구조 제어 및 응용)

  • Lee, Hye-Ryeon;Seo, Bong-Kuk;Choi, Yong-Jin
    • Membrane Journal
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    • v.22 no.2
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    • pp.77-94
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    • 2012
  • Amorphous ceramic membranes have been developed for gas phase separation and liquid phase separation (water treatment, wastewater treatment and separation of organic solvent or compounds) because of their thermal stability and solvent resistance. In this paper, ceramic membranes were categorized by membrane pore size and materials, and summarized for hydrogen separation, carbon dioxide separation, membrane reactor, pervaporation and water treatment with membrane structure and properties.

Separation of Cobalt and Nickel from Aqueous Solution (수용액(水溶液)에서 코발트와 니켈 분리(分離))

  • Liu, Yang;Lee, Manseung
    • Resources Recycling
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    • v.22 no.1
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    • pp.11-19
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    • 2013
  • Recovery of pure cobalt and nickel from diverse resources is important due to the increased demand for these metals. In order to get cobalt and nickel with high purity, separation of them from other metal ions is necessary. In this review, several methods to obtain pure cobalt or nickel solution, such as solvent extraction, ion exchange, precipitation were introduced and compared. For solvent extraction, the advantage and disadvantage of the separation process together with detailed process conditions were investigated.

Effects of Solvents and Salts on the Separation of Fructose from Glucose-Fructose Mixture (과당.포도당 혼합물로 부터 과당의 분리에 따른 염과 유기용매의 영향)

  • Chang, Jin-Ho;Chang, Ho-Nam
    • Korean Journal of Food Science and Technology
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    • v.15 no.1
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    • pp.70-76
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    • 1983
  • Separation of fructose from glucose-fructose mixture was studied by utilizing the solubility differences of both sugars in the mixed solvents of water and alcohols with or without the presence of NaCl and $CaCl_2$. Better separation of fructose was obtained in ethanol-water solvent than other solvent-water systems. The addition of NaCl to the ethanol-water solvent system improved the separation factor based on the relative composition of two sugars in the supernatant by twice. The change in feed composition from 50-50 mixture of glucose and fructose resulted in a worse separation factor. It was found in the present studies that the best separation of fructose (fructose 75%, glucose 25%) was achieved when NaCl and ethanol was slowly added to the solution containing 20% water, 40% fructose and 40% glucose to make up the final solution with the parts of ethanol 36 ml, water 4 ml, glucose 8 gm, fructose 8 gm and NaCl 0.25gm.

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