• 한국방재학회:학술대회논문집
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• 2011.02a
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• pp.195-195
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• 2011

본 연구는 방염성능시험에 의한 필름 및 도료처리 시료를 대상으로 화재 시 발생하는 연소가스 중의 독성에 대하여 NES 713 방법에 의해 분석하고, 독성지수를 확인함으로써 연소 시 인체에 미치는 영향을 간접적으로 확인해 보고자 하였다. 기존 방염제품 중 필름과 도료처리 그리고 도료처리 후 기간이 경과한 시료의 3가지로 실험군을 구분하였으며, NES 713 방법으로 연소가스를 분석하고 독성지수를 평가하였으며, 추가로 기존의 국내 노출기준과의 비교를 수행하였으며, 국내 NES 713 방법을 활용한 선행연구들을 참조하였다. 발암가능 추정물질인 아크릴로니트릴은 총 18개의 시료에서 검출되었으며, 포름알데히드는 9개의 시료에서 검출되었다. 염화수소와 브롬화수소는 각각 5개의 시료들에서 검출된 반면에 도료처리된 시료에서는 각각 1개만이 검출되었다. 그 외 일산화탄소와 이산화탄소 그리고 질소산화물은 모든 시료에서 공통적으로 검출되었다. 독성지수는 최소 3.5에서 최고 9.4의 값을 갖는 것으로 나타났다. 본 연구에서 수행한 NES 713 분석결과와 독성지수 산출 및 기존 국내 노출기준과의 비교를 수행해 본 결과는 다음과 같았다. 첫째, 현행 국내 기준 상 방염제품의 독성시험 등에 관한 기준이 없고, 둘째, 방염제품에 대한 연소가스 독성 등을 평가한 선행연구가 제한적이라는 점에서 의미가 있을 것으로 사료된다. 하지만 독성지수의 적용이 국내에서 이루어지고 있지 않은 현실에서 산출도나 독성지수의 위해정도를 평가하기 어렵고, 시료의 수량이 총 18개로서 많지 않았다는 점에서 전체 방염제품의 연소가스 독성의 잠재적인 위험성을 추정할 수는 있지만 대표성을 갖기에는 문제점이 있다는 한계성을 벗어날 수 없었다. 따라서 향후 후속 연구에서는 보다 많은 방염제품들을 대상으로 무작위 선정을 통한 연구 설계 및 실험 연구가 수행된다면 보다 객관적이고 대표성을 지닌 연구결과를 도출할 수 있을 것으로 기대한다.

• Fire Science and Engineering
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• v.23 no.5
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• pp.66-71
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• 2009

In this study, I evaluated toxicity that analyze performance of flame-retardant about flame-retardant painting wood and combustion gas that is based on the toxicity index. Processing condition of flame retardant solution and treatment method of samples didn't affect greatly to performance of flame retardant. Occurrence of combustion gas showed a almost similar result from the sample which spraying flame retardant solution and toxicity corresponds to high level, Hazard Class III, and the flame retardant solution saturation sample which makes put out Hazard Class II which is a low toxicity relatively.

• Fire Science and Engineering
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• v.23 no.5
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• pp.78-83
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• 2009

17 kinds of fire resistant paint which are currently used were painted on the MDF, to find flame resistance performance and smoking characteristics according to principal ingredient and characteristics of fire resistant paint. 45 degree combustion test and smoke density test were conducted to investigate the flame resistance performance and smoking characteristics. According to the 45 degree combustion test, acrylic resin type fire resistant paint showed the most excellent fire resistance performance. And the water soluble fire resistant paint showed better fire resistance performance compare to the solvent soluble paints. Also gloss paint showed better fire resistance performance than the flat paint. Based on the smoke density test, the smoke generation of fire resistant treated specimen of acrylic resin type was least. And the water soluble fire resistant paint generate little smoke than solvent soluble fire resistant paint.

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.256-260
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• 2014

Interior of the building is used as a MDF plywood if there is a fire in order to delay the ignition, flame retardant paint, flame retardant solution and flame retardant film are being handled by the flame retardant. Combustion characteristics anf flame retardant performance results can be summarized as follows: General film with a sample showed that short of the criteria in terms of carbonation area, and the results of flame retardant paint, flame retardant solution and flame retardant film products satisfied the criteria. Toxic gases generated in the combustion process results in a film samples using a high incidence of carbon monoxide and the creation of a smoke could be seen. This confirm that is estimated that result from incomplete combustion of PVC film that attach, and displays high toxicity index and hazard class relatively.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.124-127
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• 2008

현장방염처리 물품의 방염성능평가시 실내 인테리어 공사가 끝난 후 시험 시료를 채취하여 연소시험을 실시하게 되어있다. 그러나 이러한 절차로 인해 검사 소요시간이 길어지고 여러 민원이 발생하여 이를 대처할 시험 방법이 필요하다. 따라서 연소시험 대신 도막두께 측정 시험 방법을 도입하여 방염성능평가에 따른 문제점들을 해결하고자 한다. 도막두께 측정 시험의 경우 도막두께 측정용 라벨을 방염도료를 칠해야 하는 합판이나 목재 위에 붙이고 도료 작업이 끝나고 나면 관할 소방서에 이 라벨을 떼어서 제출하여 기준 도막 두께와 비교 측정하였을 때 기준 도막두께보다 두꺼우면 방염성능을 인정해주고 만약 기준 도막두께보다 얇게 칠해지면 현장 검사 또는 시료 채취 후 연소시험을 병행하여 검사함으로서 안전하고, 책임 있는 방염성능 시공을 할 수 있도록 관리 감독할 수 있을 것이다.

• Fire Science and Engineering
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• v.23 no.2
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• pp.111-116
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• 2009

17 kinds of fire resistant paint which are currently used were painted on the MDF(middle density fiber board), which suitable to the regulation of Fire Service Act. And we investigate a ignition delay effect under a exposure condition of radiative heat of fire. Radiative heat flux was controlled from $10kW/m^2$ to $30kW/m^2$ using the cone heater. Ignition time, ignition type and surface temperature of the sample were measured. Based on the experimental result, critical heat flux of the fire resistant paint treated sample was $10kW/m^2$ and there were no ignition delay effect above the $30kW/m^2$. And it was found that it will be difficult to expect the fire resistant effect above $400^{\circ}C$ of sample surface temperature.

• Fire Science and Engineering
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• v.30 no.5
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• pp.124-129
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• 2016

According to the current law, on-site flame resistant-treated interior decorations should pass the flame resistant performance test through a 45 degree combustion test from the district fire department. Although a 45 degree combustion test is the most accurate method for determining the flame resistant performance, it can be unreliable when tested on unauthorized samples. To avoid unauthorized sampling, this study suggests on-site flame resistant inspection by X-ray fluorescence spectrometer. Ten types of flame resistant paint were spread on plywoods and MDFs and the components were analyzed by X-ray fluorescence spectrometer. As a result, due to a difference amounts of substances in each paint, each flame resistant paints showed its own characteristic spectrum and the contents of each substance could be determined. On-site flame resistant inspections can be used efficiently when institutional procedures are created.

• Fire Science and Engineering
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• v.24 no.3
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• pp.52-57
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• 2010

Fire protection countermeasure were considered on the straw thatched roof and wooden structure. For the fire resistant treatment, rice straw was soaked in the fire resistant liquid with different soaking time. After treatment, some rice straw sample was washed with water then the rice straws were tested to check the fire resistance performance. And the wood was soaked in the fire resistant liquid at an atmospheric pressure, vacuum-pressure condition and painted with brush on the surface. To analyse the fire resistant performance of rice straw, ignition delay time was measured under the radiant heat flux of cone heater. And the fire resistant performance of wood samples were tested with 45 degree fire resistant test apparatus and cone heater. Based on the cone heater test, the rice straw which most easily ignitable material shows the longer ignition delay time than not treated ones and even in the water washed straw show a longer ignition delay time than not treated ones. And fire resistant treated woods of vacuum-pressure treated sample showed the most excellent performance on fire resistance. And the fire resistant treated by brush and soaking showed a longer ignition delay time than not treated ones. From this experiment, it was found that a fire resistant treatment of rice straw and wood of the house can be protected from the fire spread.

• Fire Science and Engineering
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• v.12 no.2
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• pp.43-59
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• 1998

It was studied a compared estimation of the fire risk of the three kinds of the interior materials, such as a resist carpet, a resist-after-treatment plywood and sofa leather. Toxic gases, CO, CO2, NOx, SO2, HCN, HCI were detected during the combustion of the samples. A resist-carpet was more combustible than the resist-after-treatment plywood and sofa leather in the combustion characteristics and has a blow-up-combustion of combustion in all the samples. The generation of CO reached the lethal doses in minute after the combustion was begun. NOx and So2 were detected not more than each of the lethal doses, while HCN was detected in the carpet 20.6 times than the sofa leather, and 4.6 times than the resist-after-treatment plywood. HCI was detected in the carpet 4.48 times than the sofa leather and 2.47 times than the resist-after-treatment plywood. It is conclusion that the carpet was the highest in the fire risk among the three kinds of the interior materials.

• Fire Science and Engineering
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• v.25 no.2
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• pp.33-38
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• 2011

This study is a research for analysis the states of flame resistant treatment and its system which important in fire prevention by ignition delay of early stage of fire. Some problems arose in the flame resistant treatment site were analysed through the meeting with fire officer and businessman related with flame resistant treatment, and visiting the flame resistant treatment places. From the meeting, visiting and reviewing the code system we find the following problems. First one is a problem of excessive competition with many company in small market of flame resistant treatment and to reduce the cost, the businessman who have no professional technic do not work along the specification. Second one is the inspection system which do not inspect on site but inspect by sampling the flame resistant treated materials submitted by businessman. And there are some problems arose about the reliability and consistency of flame resistant performance of the sample and the treated site. To solve the above problems, we suggest some countermeasure.