• Ceramist
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• v.8 no.1
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• pp.50-56
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• 2005

압전재료의 다양한 에너지 변환특성 중 기계-전기 에너지간 변환 특성만을 이용하고자 하는 경우로 한정하고, 압전재료의 물성 및 진동모드, 재료물성 평가 사례들을 요약하여 소개하였다. 그러나 이상에서 설명한 압전특성은 매우 개략적인 개념으로서 우수한 압전 응용부품을 개발하기 위해서는 몇 가지 유의할 사항들이 있다. 압전재료는 보다 기본적으로 열에너지, 기계에너지, 전기에너지, 나아가서 Maxwell 방정식에 의해서 전기장과 연결되는 자기에너지까지도 연결시켜서 상호간에 에너지 변환작용을 일으킬 수 있는 특성을 가진다. 기계적 변형(S) = 탄성변형효과 + 역압전효과 + 열팽창효과 전기적 변위(D) = 압전효과 + 유전효과 + 초전효과 즉, 압전 응용부품이 온도변화 및 자기장이 인가되는 환경에서 순수하게 압전현상만을 이용하고자 한다면, 응용분야 및 주위환경에 따라 압전세라믹 소자가 외부 환경변화에 반응을 하지 않도록 적절한 차단 대책을 수립하여야만 한다. 그러나 압전재료의 외부 자기장의 변화에 대한 반응도는 전기장에 대한 반응도에 비해서 매우 작으므로 통상 무시해도 무방하다고 본다. 그리고 압전재료에서 전기장-기계장의 선형성이 보장되는 크기에는 뚜렷한 한계가 있고, 선형성 영역을 벗어나면 이력특성에 의해 비선형 특성 및 포화상태를 보이게 된다는 점 또한 주의하여야 할 점이다. 또한 압전특성은 Curie 온도이하에서만 존재하고, 그 이상의 온도에서는 쌍극자들의 지나친 운동성에 의해 결정 대칭성이 변하여 압전특성이 소멸되므로 사용 온도 구간에 엄격한 제한을 두어야 함도 응용에 유의하여야 한다.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.633-638
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• 2008

The bunsen reaction, part of IS(Iodine-sulfur) cycle that one of the hydrogen production by the thermochemical water splitting, was investigated. It was observed that $H_2SO_4$ was uniformly generated and generation of $H_2SO_4$ was independent of iodine input. However, generation of HI was decreased with increasing iodine input. It was thought that HI and unreacted iodine were formed complex compound such as $HI_3$ $HI_5$ or $HI_7$. The complex compound accelerated liquid-liquid separation properties in the product. It was also revealed that reaction kinetics was increased with increasing iodine input. Liquid-liquid separation properties were improved with increasing iodine input and reaction temperature. Moreover, no side reaction was occurred at all reaction conditions.

• Analytical Science and Technology
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• v.13 no.5
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• pp.652-658
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• 2000

Chemical degradation of aqueous humic acid by ozonation was studied with respect to the direct reactions of ozone and the indirect reactions due to its preliminary decomposition to secondary oxidant, OH radical. This was characterized by analyzing TOC, $UV_{254}$ and ozone consumption measured in different experimental conditions in which ozone reacted in the presence of various concentrations of $H_2O_2$ and $HCO_3{^-}$ concentrations ranging from 20 to 100 mg/L. and different pH (5-9). The results suggest that the TOC removal is mainly dependent on indirect reactions of OH radical whereas $UV_{254}$ reduction is mainly dependent on direct reactions of ozone with humic acid molecules. It has been also found that ozone consumption was most likely to be affected by pH and alkalinity in the solution.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.487-492
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• 2013

Transesterifications of waste oils mixed with animal tallows and vegetable oil by ultrasonic energy were examined over various catalysts for biodiesel production. Reaction activities of the transesterification were evaluated to the ultrasonic energy and thermal energy. The physicochemical properties of feedstock and products were also investigated to the biodiesels produced from the oils in the reaction using ultrasonic energy. The highest fatty acid methyl ester (FAME) yield was obtained on the potassium hydroxide catalyst in the transesterification by ultrasonic irradiation. The effective reaction conditions by ultrasonic energy were 0.5 wt% catalyst loading and 6:1 molar ratio of methanol to the mixed oils. The reaction rate of the transesterification by ultrasonic energy was faster than that by thermal energy. The highest yields of FAME were obtained as 80% in 5 min and the reaction equilibrium reached at that time.

• Journal of the Society of Disaster Information
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• v.19 no.4
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• pp.950-957
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• 2023

Purpose: The response technology is needed to prevent the spill of highly toxic oil contaminants in advance. Therefore, this paper described the results of an experimental study to predict the engineering properties of the developed reactive material. Method: Compaction tests and spectral information acquisition experiments were conducted on the reactive materials, and the results were evaluated. In addition, the correlation between spectral information and maximum dry unit weight was analyzed to evaluate the possibility of predicting the engineering properties for reactive materials. Result: The compaction test results showed that the maximum dry unit weight was in the range of approximately 9kN/m³ to 10kN/m³. The spectral information confirmed that the maximum reflectance decreased as the polynorbornene decreased. Conclusion: It was confirmed that the maximum dry unit weight of the reactive material for absorbing oil contaminants can be predicted using the maximum reflectance according to the component ratio of the reactive material.

• Proceedings of the IEEK Conference
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• 2003.07b
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• pp.722-726
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• 2003

본 논문에서는 Porous poly-silicon cold cathode에 의해 전자를 방출하는 Ballistic electron surface-emitting display(BSD)의 전계방출 특성을 실험했다. BSD는 nanocrystalline을 둘러싼 산화막을 multi-tunneling한 전자에 의해 발광이 되는 mechanism이기 때문에 산화막의 두께를 변수로 두어 특성을 실험했다. 900℃에서 1시간에서 3시간까지 30분 간격으로산화 반응을 진행하였으며, leakage current와 emission current의 비로 효율을 나타내었을 때 1시간 30분 동안 산화 반응을 한 시료가 가장 좋은 특성을 나타내었다.

• Journal of the Mineralogical Society of Korea
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• v.17 no.3
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• pp.277-288
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• 2004

Alkali-silica reaction (ASR) is a chemical reaction between alkalies in cement and chemically unstable aggregates and causes expansion and cracking of concrete. In the Present study, we studied the effects of metakaolin, which is a newly introduced mineral admixture showing excellent pozzolainc reaction property, on the inhibition of ASR. We prepared mortar-bars of various replacement ratios of metakaolin and conducted alkali-silica reactivity test (ASTM C 1260), compressive strength test and flow test. We also carefully analyzed the mineralogical changes in hydrate cement paste by XRD qualitative analysis. The admixing of metakaolin caused quick pozzolanic reaction and hydration reaction that resulted in a rapid decrease in portlandite content of hydrated cement paste. The expansion by ASR was reduced effectively as metakaolin replaced cement greater than 15%. This resulted in that the amounts of available portlandite decreased to less than 10% in cement paste. It is considered that the inhibition of ASR expansion by admixing of metakaolin was resulted by the combined processes that the formation of deleterious alkali-calcium-silicate gel was inhibited and the penetration of alkali solution into concrete was retarded due to the formation of denser, more homogeneous cement paste caused by pozzolanic effect. Higher early strength (7 days) than normal concrete was developed when the replacement ratios of metakaolin were greater than 15%. And also, late strength (28 days) was far higher than normal concrete for the all the replacement ratios of metakaolin. The development patterns of mechanical strength for metakaolin admixed concretes reflect the rapid pozzolanic reaction and hydration properties of metakaolin.

• Korean Journal of Food Science and Technology
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• v.35 no.3
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• pp.417-422
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• 2003

The onions are considered to be a favorable functional source of beverage because they contain much sugar and various nutrients, and they are juicy vegetable. Recently, consumers have a new trend to take functional foods with health benefits. To meet this need, this study was the basic research to establish a manufacturing process of functional onion beverage by glucose oxidase. Glucose oxidase catalyzes reaction of glucose oxidation and makes generation of gluconic acid. Kinetics of the reaction was also investigated, and maximum glucose consumption rate $(V_{max})$ of $26.1{\times}10^{-2}\;g/L{\cdot}min$ and $K_m$ of 5.84 g/L were obtained. Optimum conditions were obtained when the glucose oxidase catalyzed reaction was carried out at temperature of $25^{\circ}C$, agitation rate of 450 rpm and aeration rate of 4 vvm in a 2.5 L jar fermentor. Finally, the enzyme reactor was 10-times scaled up and a similar glucose oxidation performance was achieved in the scaled-up reactor.

• Journal of the Korean Magnetics Society
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• v.6 no.3
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• pp.151-157
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• 1996

Magnetic properties and microstructures of FeTaNC thin films, which were deposited by magnetron reactive sputtering rrethod, were investigated as a function of $CH_{4}$ and $N_{2}$ gas partial pressures. Magnetic properties of FeTaNC films depended on total reactive gas pressure as well as $CH_{4}/N_{2}$ pressure ratios. For reactive gas partial pressures of 5~10 %, optimum magnetic properties were observed in the FeTaNC films with proper $CH_{4}/N_{2}$ ratio. On the other hand, at 15% of gas partial pressure, FeTaN and FeTaC films showed superior properties to FeTaNC films. Above 15%, the magnetic properties of films rapidly degraded due to an excess incorporation of C and/or N atoms. Excellent soft magnetic properties of 17 kG of Bs, 0.3 Oe of He, and 4000 of $\mu'$(at 5 MHz) were obtained in the FeTaNC films. High permeabilities of FeTaNC films could be explained by the Fe lattice distortion caused by N atoms, hence reduction of magnetic anisotopy. While precipitated TaN and TaC particles effectively supress the growth of $\alpha-Fe$ grains leading to a good soft magentic properties, FeN and FeC phases such as $Fe_3N$, $Fe_4N$, FexC have detrimental effects.

• Proceedings of the KSEEG Conference
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• 2007.04a
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• pp.70-71
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• 2007