• 제목/요약/키워드: 물리화학적 성분

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Physico-Chemical Pretreatment of Herbaceous Biomass by Organosolv Flow-Through Process (초본계 바이오매스의 물리-화학적 유기용매 전처리 공정)

  • Kim, Jun Seok
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.441-446
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    • 2018
  • Herbaceous biomass is easier at chemical conversion than woody biomass. However, pretreatment must be needed because it has substantially lignin. Organsolv is good at fractionation of enzymatic hydrolysis inhibitors such as lignin and it is reusable by distillation when it has low molecular weight. Flow-through process can prevent recondensation of fractionated components and easily separate liquid from the biomass. In this study, the pretreatment was performed for decreasing additional process by using ethanol without catalyst because this process has a lot of operation expense at bio-alcohol production process. Flow-through pretreatment was performed at $150{\sim}190^{\circ}C$ with 30~99.5 wt% ethanol during 20~60 minutes. Also the phsyco-chemical pretreatment was performed for decreasing reaction time and temperature.

Physicochemical Properties of Whey Protein Isolate (WPI의 물리화학적 특성에 관한 연구)

  • Ahn, Myung-Soo;Kim, Chan-Hee
    • Korean Journal of Food Science and Technology
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    • v.39 no.1
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    • pp.50-54
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    • 2007
  • In this study, the physicochemical properties of cheese whey protein isolate (WPI) were measured. The total amount of amino acids in WPI was 89.5% and the proportion of essential amino acids was 44.6%. Among these, leucine, lysine, isoleucine, and valine were shown in large amounts. At various pHs, the solubility of WPI (82-88%) was higher than that of sodium caseinate, (5-79%). The solubility of WPI was not affected by variation of pH. It was shown that the emulsifying capacity of WPI was higher than that of egg yolk by 1.6 times, but the stabilities of emulsions made with WPI and egg yolk was almost same each other at 65-97% and 60-89%, respectively. The foaming capacity of WPI was higher than that of egg white, at 323.3% and 186.6%, respectively, but the foam stability of WPI was similar to that of egg white.

Concentrations of Heavy Metals in Sediments from the Sea off Jinhae and Masan, Korea (마산, 진해 연안해역 해저퇴적물중의 중금속류 함량에 관한 연구)

  • Lee, Jong Wha;Han, Sang Joon;Youn, Oong Koo
    • 한국해양학회지
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    • v.9 no.2
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    • pp.31-38
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    • 1974
  • Concentration of heavy metals in the sediments from the sea off Jinhae and Masan have been studied. Concentration of the elements varied among the stations as the following: 0.32-0.76% Fe, 0.01-0.06% Mn, 29-120ppm Zn, 1-16ppm Co, 2-38 ppm Ni, 2.5-12.4ppm Pb and 0.2-0.7ppm Cd. General tendency of the concentraion of elements except Mn showed considerably high values at stations in the inner bay. This tendency seemed to be caused by waste water from industrial activities in the adjacent land. It can be thought that the pollution status of the studied area is still limited in the inner part of the day.

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알루미늄 재료기술( II )

  • 황창규
    • Journal of the KSME
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    • v.29 no.2
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    • pp.162-168
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    • 1989
  • 철이나 동은 BC5000~3000년부터 도구류, 장식품 등으로 인류의 역사에 등장하고 있는데 반해 알루미늄 재료는 공업용 재료로써의 기초가 확립된 후 아직 100년이 채 못되고 있지만 건종 성 질이 우수하기 때문에 이러한 특성을 이용해서 항공기용 재료, 전선, 기물, 일반프레스 가공품, 제메이스류, 일반 기계부품, 콘덴서용 및 포장용 상자, 도료 및 잉크 원료 화포 재료, 환원재용 분말, 차량, 건축용 재료 등에 사용되고 있고 이용도는 제 2차대전후에 건축, 차량, 조선, 채광, 교량, 화학, 섬유식품 공예 등과 같은 공업분야에 널리 새로운 용도로 개척이 되어 응용이 되고 있다. 이와 같이 그 용도 분야가 다양화되고 적으로도 철, 다음가는 금속재료로 성장하고 있기 때문에 "알루미늄 재료 기술"이라는 이름으로 각종 자료들을 정리 하다보니 너무나도 그 범위가 광범위하여 본 글에서 제외된 알루미늄 재료의 성분, 선정, 지침, 물리. 화학. 기계성질, 형상과 그의 제작범위, 구조설계, 절삭가공, 접합, 표면처리, 단조 등에 대한 여러 가지 자료는 지면관 계로 별도로 정리를 해서 다음 기회에 소개하고자 한다. 소개하고자 한다.

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3D Bioprinting Technology in Biochemical Engineering (바이오화학공학에서 3D 바이오프린팅 기술)

  • Eom, Tae Yoon
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.285-292
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    • 2016
  • Three-dimensional (3D) printing is driving major innovation in various areas including engineering, manufacturing, art, education and biosciences such as biochemical engineering, tissue engineering and regenerative medicine. Recent advances have enabled 3D printing of biocompatible materials, cells and supporting components into complex 3D functional tissues. Compared with non-biological printing, 3D bioprinting involves additional complexities which require the integration of technologies from the fields of biochemical engineering, biomaterial sciences, cell biology, physics, pharmaceutics and medical science.

Treatment of Textile Wastewater by Membrane-Bioreactor Process (막-생물반응조 공정을 이용한 염색폐수의 처리)

  • 강민수;김성수;황규대;강종림
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.60-61
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    • 1996
  • 염색폐수를 처리하기 위하여, 일반적으로 물리.화학적 공정과 호기성 생물학적 공정을 조합한 방법들을 사용하고 있다. 하지만 호기성 생물학적 공정은 난분해성 물질의 제거능력이 낮고, 염색폐수의 주된 오염원인 염료분자가 호기성 미생물에 대한 에너지원으로 적합하지 않아 분해되기 어려우며, 물리.화학적 공정을 이용한 처리방법으로도 높은 처리효율을 얻을 수가 없다. 이러한 문제점을 극복하기 위하여 염색폐수 처리에 혐기-호기공정을 이용하며, 혐기성 공정에서 생물학적으로 분해되기 어려운 고분자 물질들을 가수분해하여 생물학적으로 분해가능한 저분자물질로 전환시키고, 호기성 공정에서 저분자 물질을 효과적으로 처라할 수 있기때문에 기존의 염색폐수 처리공정에 비하여 훨씬 높은 처리효율을 얻을 수 있다. 특히, 혐기성 미생물은 호기성 미생물에 비하여 난분해성 물질에 대한 분해력이 높고, 생물독성 물질에 대한 내성이 강하기 때문에 수중생물에 유해한 염료를 함유한 염색폐수의 색도제거에 효과적인 것으로 기대된다. 또한, 막분리 공정은 유기물 및 미생물이 막표면에 축적, 증식함으로써 막세공에 막힘현상을 초래하여 역세척 등의 물리적인 방법이나 화학약품을 이용한 화학적 세척 방법으로도 투과플럭스의 회복이 불가능한 상태를 유발함으로 막의 수명을 단축시키는 원인이 된다. 따라서, 혐기-호기공정과 조합하면 색도성분 제거 및 막 오염의 원인이 되는 유기물 및 용존성 고형물을 제거하고, 막 오염의 억제를 통한 후 수염의 연장은 물론, 처리수의 수질향상에 활용될 수 있을 것으로 사료된다.1로 강구와 함께 공구강 vial에 장입 후, Spex mixer/mill을 이용하여 기계적 합금화 하였다. 기계적 합금화 공정으로 제조한 분말에 대한 X-선 회절분석과 시차 열분석으로 합금화 정도를 분석하였다. (Bi1-xSbx)2Te3 및 Bi2(Te1-ySey)3 합금분말을 10-5 torr의 진공중에서 300℃∼550℃의 온도로 30분간 가압소결하였다. 가압소결체의 파단면에서의 미세구조를 주사전자현미경으로 관찰하였으며, 상온에서 가압소결체의 열전특성을 측정하였다. (Bi1-xSbx)2Te3의 기계적 합금화에 요구되는 공정시간은 Sb2Te3 함량에 따라 증가하여 x=0.5 조성에서는 4 시간 45분, x=0.75 조성에서는 5 시간, x=1 조성에서는 6 시간 45분의 vibro 밀링이 요구되었다. n형 Bi2(Te1-ySey)3 합금분말의 제조에 요구되는 밀링시간 역시 Bi2Se3 함량 증가에 따라 증가하였으며 Bi2(Te0.95Se0.05)3 합금분말의 제조에는 2시간, Bi2(Te0.9Se0.1)3 및 Bi2(Te0.85Se0.15)3 합금분말의 형성에는 3시간의 bivro 밀링이 요구되었다. 기계적 합금화로 제조한 p형 (Bi0.2Sb0.8)2Te3 및 n형 Bi2(Te0.9Se0.1)3 가압 소결체는 각기 2.9x10-3/K 및 2.1x10-3/K 의 우수한 성능지수를 나타내었다.ering)가 필수적이다. 그러나 침전법에서 얻게 되는 분말은 매우 미세하여 colloid를 형성하게 되며, 이러한 colloid 상태의 미세한 침전입자가 filte

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Dissolution Characteristics of Iron Ion in Soil by the Decontamination Solution (제염용액에 의한 토양 중 철 성분 용해 특성)

  • 원휘준;김계남;정종헌;최왕규;박진호;오원진
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.676-680
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    • 2003
  • Dissolution of magnetite powders by 0.05 M citric acid was investigated at $50^{\circ}C$. All the tests were performed in the pH range between 2.0 to 5.0, which was adjusted using nitric acid or sodium hydroxide. Concentration of each of the dissociated chemical species of citric acid under various solution pHs was calculated using the ionization constants. Variation of zeta potential of magnetite with pH changes was also investigated. The dissolution reaction was explained by comparing the concentration of the dissociated chemical species of citric acid with the zeta potential. Longer than 3 h of induction time was required to dissolve the magnetite. The dissolution behaviour of magnetite was well described by the equation. The physical meaning of each parameter was explained successfully from the model equation.

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Environmental Pollution and Reclamation in the Abandoned Mines in Korea (국내 폐 광산 환경오염 실태 및 처리 현황)

  • Cheong Young-Wook;Min Jeong-Sik
    • 한국지구물리탐사학회:학술대회논문집
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    • 2001.09a
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    • pp.75-89
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    • 2001
  • There are 334 coal mines and about 900 metal mines abandoned. The environmental problems such as acid mine drainage from adits etc. and the subsidence has occurred in the abandoned mines. In addition, soil has been contaminated by tailings. According to analysis of mine drainages, some of them from adits in the abandoned coal and metallic mines were acidic and polluted by heavy metals. Especially, water quality of coal mine drainages were different by areas. Treatment of mine drainage by conventional chemical treatment has the drawback because the operating cost is very expensive. The treatment system used in mine drainage is the natural treatment system such as anoxic limestone drain in adits and the constructed wetland. The method of reclamation for abandoned waste rocks and tailings impoundments are mainly landfilling.

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Physicochemical Properties of Insoluble Mineral Substances in Food Additives (식품첨가물중 불용성광물성물질의 물리화학적 특성)

  • Kim, Hee-Yun;Lee, Young-Ja;Hong, Ki-Hyoung;Kwon, Yong-Kwan;Kim, So-Hee;Kim, Hyun-Jong;Lee, Chul-Won;Kim, Kil-Saeng;Lee, Sang-Hoon
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1188-1195
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    • 1999
  • This study was conducted to determin basic mineral compositions, chemical components, description of particle size distribution and whiteness for 32 items of insoluble mineral substances, i.e., 3 items of diatomaceus earth, 1 item of kaolin, 10 items of bentonite, 13 items of acid clay, 3 items of talc and 2 items of perlite. The chemical components and XRD (X-Ray diffractometer) for insoluble mineral substances, were similar with those of the reported references except kaolin. However, whiteness was determined in 90% level for talc, diatomaceus earth and kaolin. The contents of heavy metals in insoluble mineral substances were determined as follows : Pb, $nd{\sim}23.10$ ppm ; Cd, $nd{\sim}0.67$ ppm ; Hg, $nd{\sim}0.58$ ppm ; As, $nd{\sim}1.42$ ppm ; Cu, $nd{\sim}39.35$ ppm. These data were significanty lower than the references.

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Analysis of Physical and Chemical Properties of CFBC Fly Ash in Vietnam for Solidification (고화재 활용을 위한 베트남 CFBC 플라이애시의 물리적·화학적 특성 분석)

  • Min, Kyongnam;Lee, Jaewon;Lee, Dongwon;Kim, Jinhee;Jung, Chanmuk
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.245-253
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    • 2017
  • Vietnam CFBC fly ash has high CaO content and can be used as a solidification agent for soft ground improvement. However, most fly ash is treated as landfill or waste. In order to utilize fly ash as a solidification agent for soil improvement, the characteristics of fly ash must be accurately determined. In this study, laboratory tests were conducted on fly ash from four CFBC power plants to evaluate the utility of Vietnam fly ash as a solidification agent. As a result of analyzing the physical properties, it was analyzed that all four samples were suitable as material for solidification agent and have suitable particle size for the improvement of soft ground. As a result of analysis of chemical characteristics, it was analyzed that the fly ash of one place could be used as a solidification agent because of the high content of free-CaO. The remaining three fly ash was not suitable for use as a solidification agent due to low Free-CaO content. However, it has a chemical composition similar to that of general fly ash in Korea, so it can be recycled in various ways.