• Title/Summary/Keyword: 물리적 제거

Search Result 934, Processing Time 0.033 seconds

Determination of Operational Parameters for TCE Degradation in Photocatalytic Oxidative Reactors (TCE의 분해를 위한 광촉매 산화반응조의 운전인자 도출에 관한 연구)

  • Hur, Joon-Moo;Cheon, Seung-Yul;Kim, Jong-Soo
    • Korean Journal of Environmental Agriculture
    • /
    • v.22 no.2
    • /
    • pp.124-129
    • /
    • 2003
  • The objectives of this study are to manufacture an efficient $TiO_2$, photocatalyst and to delineate optimum operational parameters for TCE (trichloroethylene) degradation in a photocatalytic oxidative reactor. The $TiO_2$ photocatalyst irradiated by 365 nm UV light is expected to increase degradation of TCE in solution by a series of photocatalytic oxidations in the reactor. A new membrane $TiO_2$ photocatalyst wns eventually developed by coating a mixture of Davan-C(0.24 wt%) and PVA(0.16 wt%) on the surface of slips using the slip-casting method. Results show that increase in the number of coating of $TiO_2$ sol on surface of photocatalysts and in the surface thickness improved the endurance and photocatalysts, but these physical modifications caused significant decrease in the overall degradation efficiency of TCE. Pre-aeration or recirculation of the influents to the reactors containing TCE increased degradation efficiency of TCE. The optimum operational conditions far the surface area of photocatalysts and UV light intensity appeared to be $1.47\;mL/cm^2$ and $225\;W/cm^2{\times}100$, respectively, in the reactor. Based on the overall experimental results, the photocatalytic oxidation of TCE with the new membrane $TiO_2$ photocatalyst is found to be very effective under the operational conditions delineated in this study.

A Case Study on the TEMAZ Explosion Accident in Semiconductor Process (반도체 공정에서 TEMAZ폭발사고 사례연구)

  • Yang, Won-Baek;Rhim, Jong-Kuk;Hong, Seong-Min
    • Journal of the Korean Institute of Gas
    • /
    • v.21 no.6
    • /
    • pp.52-60
    • /
    • 2017
  • In diffusion process exhaust line during semiconductor manufacturing process, In order to improve the transportation efficiency in the piping by removing "The reaction by-product, $ZrO_2$ and The unreacted material, TEMAZ, TMA, $O_3$, etc" and "Powder being deposited", the piping temperature was raised to $80^{\circ}C$ or more by using the heater jacket, and the bellows at the rear end of the vacuum pump ruptured. So conducted a case study and try to prevent the similar accidents from occurring through case studies. The causes of the accident were analyzed as follows: the inflow of outside air due to the generation of a gap on the suction side of the vacuum pump and heating the pipe with the heater jacket resulted in the overpressure in the pipe due to the volumetric expansion of the gas generated by decomposition of the unreacted TEMAZ, It can be assumed that the most vulnerable bellows of the piping has been ruptured. In order to prevent such accidents, This study is aimed to identify the cause of pipeline rupture accident and to establish safety measures for the prevention of similar accidents by evaluating physical hazards of TEMAZ, which is assumed to be the cause of pipe rupture accident.

Study on the control of marine biofouling developed on the surface of porous ceramics (세라믹 다공체 표면에 발생하는 해양 생물 오손 억제에 관한 연구)

  • Kang, Jimin;Kang, Seunggu;Kim, YooTack
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.25 no.5
    • /
    • pp.218-224
    • /
    • 2015
  • Recently, removing methods of red tide has been attempted by filtering the organisms using the ceramic porous bodies. However, the marine biofouling could be developed on the surfaces of porous ceramic body after use for more than one month, and it might decrease the function of the specimen. In this paper, a method of inhibiting marine biofouling by changing the physical properties or surface-modification of ceramic porous body was studied. After experiment with six different ceramic porous bodies, it was found that the specimen of lower porosity and water absorption showed the least amount of biofouling. In addition, by increasing the surface roughness with silica particles bonded to the surface of specimen, the amount of biofouling caused by large marine life such as barnacle and mussel could be decreased. On the other hand, when the surface of specimen was coated and fused by glass powder, the amount of biofouling was rather increased. This might be due to eluted inorganic ions from the glass which can promote the growth of the microorganism. In conclusion, the environmental-friendly methods to reduce the amount of marine biofouling, such as controlling the physical properties and the surface roughness of the porous ceramics, can be possible without the use of dangerous substances. So it is expected for the results obtained to be applicable to a marine structure.

Salt Accumulation and Desalinization of Rainfall Interception Culture Soils of Rubus sp. in Gochang-gun, Jeollabuk-do (복분자 비가림 하우스 토양 중 염류집적 요인과 물리적 제염효과)

  • Chung, Byung-Yeoup;Lee, Kang-Soo;Kim, Myung-Kon;Choi, Young-Hee;Kim, Moo-Key;Cho, Jae-Young
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.41 no.5
    • /
    • pp.310-317
    • /
    • 2008
  • This study was carried out to investigate the factors of desalinization of the rainfall interception culture soils of Rubus sp. in Gochang-gun, Jeollabuk-do. Soil samples were collected from 85 different sites of the rainfall interception culture soils of Rubus sp. in Gochang-gun, Jeollabuk-do. The electrical conductivity in paste saturation of rainfall interception culture soils ranged from $1.0\sim28.4dS\;m^{-1}$ (average: $4.8dS\;m^{-1}$) and salt affected soil which EC was higher than $4dS\;m^{-1}$, covered nearly 55% of all field surveyed. Salts in rainfall interception culture soils were accumulated by increasing the cultivation period. Electrical conductivity in rainfall interception culture soils was positively correlated with water soluble anions such as chloride ion ($r=0.85^{**}$), nitrate ion ($r=0.94^{**}$), phosphate ion ($r=0.88^{**}$), and sulfate ion ($r=0.84^{**}$), respectively. As a result of desalinization experiments carried out by water management practices, the rinsing method was more effective than leaching method.

Improved Performance of Direct Carbon Fuel Cell by Catalytic Gasification of Ash-free Coal (무회분탄 연료의 촉매 가스화에 의한 직접탄소연료전지의 성능 향상)

  • Jin, Sunmi;Yoo, Jiho;Rhee, Young Woo;Choi, Hokyung;Lim, Jeonghwan;Lee, Sihyun
    • Clean Technology
    • /
    • v.18 no.4
    • /
    • pp.426-431
    • /
    • 2012
  • Carbon-rich coal can be utilized as a fuel for direct carbon fuel cell (DCFC). However, left-behind ash after the electrochemical oxidation may hinder the electrochemical reactions. In this study, we produced ash-free coal (AFC) by thermal extraction and then tested it as a fuel for DCFC. DCFC was built based on solid oxide electrolyte and the electrochemical performance of AFC mixed with $K_2CO_3$ was compared with AFC only. Significantly enhanced power density was found by catalytic steam gasification of AFC. However, an increase of the power density by catalytic pyrolysis was negligible. This result indicated that a catalyst activated the steam gasification reactions, producing much more $H_2$ and thus increasing the power density, compared to AFC only. Results of a quantitative analysis showed much improved kinetics in AFC with $K_2CO_3$ in agreement with DCFC results. A secondary phase of potassium on yttria-stabilized zirconia (YSZ) surface was observed after the cell operation. This probably caused poor long-term behavior of AFC with $K_2CO_3$. A thin YSZ (30 ${\mu}m$ thick) was found to be higher in the power density than 0.9 mm of YSZ.

Physical Properties of Dredged Sand Treated by Washing and Sorting Dredged Soil (하천준설토를 세척 선별한 준설모래의 물리적 특성)

  • Lee, Yun-Seong;Lee, Sang-Soo;Song, Ha-Young;Bae, Kee-Sun;Lee, Sung-Bok;Lee, Do-Heun
    • Land and Housing Review
    • /
    • v.1 no.1
    • /
    • pp.35-42
    • /
    • 2010
  • Most of the dredged sand generated from the sewage pipe maintenance project and the government's four-river project are disposed depending on abandonment and filling-up. This is caused by the lack of related recycling technology using dredged sand appropriately and high absorption rate and micro-particles of dredged sand producted from existing sand production system. Thus, this study carried out a quality assessment for the dredged sand produced through the optimum washing and sorting system supplementing problems of existing dredged sand production system as a part of research to examine performance of removing micro-particles and foreign substances. As a result of the assessment, the dredged sand produced through the cleaning and sorting system showed a wide quality improvement effect in absorption rate, 0.08 mm sieve pass amount, clay lump volume and organic impurity content, and it turned out to satisfy both the quality standards of this study, KS F 2573(recycled aggregate for concrete) and KS F 2526(aggregate for concrete) so it could be confirmed that it would be able to be used as an aggregate for concrete in the future.

Affinity Filtration Chromatography of Proteins by Chitosan and Chitin Membranes: 1. Preparation and Characterization of Porous Affinity Membranes (키토산 및 키틴 막에 의한 단백질의 친화 여과 크로마토그래피: 1. 다공성 친화 막의 제조와 특성 평가)

  • Youm Kyung-Ho;Yuk Yeong-Jae
    • Membrane Journal
    • /
    • v.16 no.1
    • /
    • pp.39-50
    • /
    • 2006
  • Porous chitosan and chitin membranes were prepared by using silica particles as porogen. Membrane preparation was achieved via the following three steps: (1) chitosan film formation by casting an chitosan solution containing silica particles, (2) preparation of porous chitosan membrane by dissolving the silica particles by immersing the film into an alkaline solution and (3) preparation of porous chitin membrane by acetylation of chitosan membrane with acetic anhydride. The optimum preparation conditions which could provide a chitosan and chitin membranes with good mechanical strength and adequate pure water flux were determined. To allow protein affinity, a reactive dye (Cibacron Blue 3GA) was immobilized on porous chitosan membrane. Binding capacities of affinity chitosan and chitin membranes for protein and enzyme were determined by the batch adsorption experiments of BSA protein and lysozyme enzyme. The maximum binding capacity of affinity chitosan membrane for BSA protein is about 22 mg/mL, and that of affinity chitin membrane for lysozyme enzyme is about 26 mg/mL. Those binding capacities are about $several{\sim}several$ tens times larger than those of chitosan and chitin-based hydrogel beads. Those results suggest that the porous chitosan and chitin membranes are suitable in affinity filtration chromatography for large scale separation of proteins.

A Field Study on the Enhancement of Landfarming Performance Using Oil-degradable Microbes Adapted to Various Temperature Range (생장 온도 범위별 최적의 유류분해 미생물을 이용한 토양경작 정화기술의 효율성 제고에 관한 현장 적용성 연구)

  • Yu, Jae-Bong;Kim, Jeong-Ho;Kim, Guk-Jin;Oh, Seung-Taek;Lee, Cheol-Hyo;Park, I-Kyong;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
    • /
    • v.14 no.5
    • /
    • pp.10-17
    • /
    • 2009
  • Bioremediation has been applied as a proven technology in remediation of TPH contaminated soil. However, the efficiency of biodegradation is dependent on temperature as microbial activity is depressed at lower temperature ranges ($30^{\circ}C{\sim}80^{\circ}C$). The objective of this study was to develop microbes with enhanced activities at the stated temperature conditions and to evaluate the remediation effectiveness of these microbes in TPH contaminated soil. Experiments were conducted to isolate hydrocarbon degradable microbial consortia cultured under different temperature conditions. It was found that there were 5 strains of mesophilic ($30^{\circ}C$) and 3 strains of psychrophilic ($80^{\circ}C$) microbes. The TPH concentration was reduced from 4,044 mg/kg to 1,084 mg/kg, (73.2%) in 10 days by using mesophilic microbial consortia and from 5,427 mg/kg to 1,756 (67.6%) in 50 days with psychrophilic microbial consortia in laboratory cultures under controlled conditions. This rate determination excluded physical degradation such as venting and dilution. A field study was then performed to examine the feasibility of applying these microbes in the land-farming process. In this case, 87.1% of the 2,560 mg/kg TPH contaminated soil was degraded in 56 days. The biodegradation rate coefficient (k) was $0.0374\;day^{-1}$. Findings of this study provide viable options for applying microbes for bioremediation of TPH in lower temperature conditions.

A Study on the Evaluation for Performance of Body Armor Vest using ANOVA (분산분석을 이용한 방탄조끼의 방탄성능 평가에 관한 연구)

  • Park, Jae Woo;Byun, Kisik;Cho, Sung-Yong;Kim, Suk Ki;Yeo, Yongheon;Kwon, Jae Wook
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.22 no.1
    • /
    • pp.372-378
    • /
    • 2021
  • A body armor vest is a form of munition related directly to the safety and life of combatants. Therefore, it must meet the requirements for ballistic resistance. The ROK demands the performance of body armor vest meet the Level IIIA specified by the NIJ STD-0101.06 published by the US National Institute of Justice. This study performed acceptance tests on body armor vests. The factors for evaluating the ballistic resistance evaluated were not only whether it penetrates when shooting but also whether the BFS (Backface Signature) depth does not exceed 44 mm when it does not penetrate. The factors were assessed to determine if they were consistent or not. The BFS depth is affected by various test factors, such as the physical properties of the backing material and the changes in the amount of impact with the bullet velocity. In this study, an analysis of the bulletproof performance was performed by extracting the data with the same conditions using ANOVA to remove the influence of these external factors. The analysis revealed a correlation between the BFS depth, bullet velocity, vest conditions, and protection area. The mass production process was analyzed by estimating the Interval of BFS on each lot. Through this, a new methodology for ballistic resistance evaluation and paradigm for future quality assurance is suggested.

Dynamic Threshold Determination Method for Energy Efficient SEF using Fuzzy Logic in Wireless Sensor Networks (무선 센서 네트워크에서 통계적 여과 기법의 에너지 효율 향상을 위한 퍼지논리를 적용한 동적 경계값 결정 기법)

  • Choi, Hyeon-Myeong;Lee, Sun-Ho;Cho, Tae-Ho
    • Journal of the Korea Society for Simulation
    • /
    • v.19 no.1
    • /
    • pp.53-61
    • /
    • 2010
  • In wireless sensor networks(WSNs) individual sensor nodes are subject to security compromises. An adversary can physically capture sensor nodes and obtain the security information. And the adversary injects false reports into the network using compromised nodes. If undetected, these false reports are forwarded to the base station. False reports injection attacks can not only result in false alarms but also depletion of the limited amount of energy in battery powered sensor nodes. To combat these false reports injection attacks, several filtering schemes have been proposed. The statistical en-routing filtering(SEF) scheme can detect and drop false reports during the forwarding process. In SEF, The number of the message authentication codes(threshold) is important for detecting false reports and saving energy. In this paper, we propose a dynamic threshold determination method for energy efficient SEF using fuzzy-logic in wireless sensor networks. The proposed method consider false reports rate and the number of compromised partitions. If low rate of false reports in the networks, the threshold should low. If high rate of false reports in networks, the threshold should high. We evaluated the proposed method’s performance via simulation.