• Title/Summary/Keyword: 무정형

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Interpretation on Raw Material Characteristics and Manufacturing Techniques of Brown-glazed Stonewares and Roof Tiles from Hong Nang Sida Temple, Laos (라오스 홍낭시다 유적 출토 갈유도기와 기와의 원료특성과 제작기술 해석)

  • Jin, Hong Ju;Jang, Sungyoon;Kim, Su Kyoung;Lee, Myeong Seong;Moon, Dong Hyeok;Chun, Yu Gun
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.4
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    • pp.273-285
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    • 2019
  • This study is aimed to interpret the raw material characteristics and manufacturing technology through physical, mineral and geochemical analysis of the brown-glazed stonewares and roof tiles excavated from the Hong Nang Sida temple in Laos, which was built in the 12th century. The glaze of brown-glazed stoneware is a typical lime serial with CaO content of more than 15 % and they were vitrified. The body is the combination of quartz, mullite and cristobalite, but had not vitrified texture, and therefore, which is assumed to have been fired more than 950 ℃. Meanwhile, The roof tiles are unglazed and its outer color is reddish brown, whitish grey and bluish grey. The bluish gray tiles has sandwich structure, which seem to experience imperfect reducing environment. The tile samples with a number of amorphous iron oxide nodule had a very similar chemical composition. In conclusion, it is assumed that the clay source was made from raw material produced from the same bedrock. The firing temperature of roof tiles were divided into less than 900 ℃, 900~950 ℃ and greater than 950 ℃ according to detection of micas, hercynite and mullite.

THE ERUPTION GUIDANCE OF AN IMPACTED TOOTH ASSOCIATED WITH A COMPLEX ODONTOMA : CASE REPORT (복잡 치아종으로 인한 매복치아의 교정적 견인)

  • Pack, Jung-Ah;Yang, Kyu-Ho;Choi, Nam-Ki;Kim, Seon-Mi
    • Journal of the korean academy of Pediatric Dentistry
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    • v.34 no.4
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    • pp.651-657
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    • 2007
  • Odontomas are the common type of odontogenic tumors and generally are asymptomatic and frequently lead to impaction or delayed eruption of permanent teeth. They are composed of enamel, dentin, cementum and pulp tissue and are divided into compound and complex according to the morphology of the hard tissues. Compound odontomas consist of varying numbers of small toothlike structure and have a predilection for the maxillary anterior regions. Complex odontomas consist of an unorganized mass of odontogenic tissues and comprise approximately 25 percent of all odontomas and have a predilection for the mandibular posterior regions. The etiology of odontomas is uncertain but hypothesized to involve local trauma, infection and genetic factors. Treatment of odontoma is conservative surgical removal and are little probability of recurrence. These two cases were about the patients with delayed eruption of mandibular first molar and mandibular lateral incisor. We surgically removed odontoma, exposed impacted tooth and guided impacted tooth into normal position by orthodontic traction. At the completion of traction, the mandibular first molar and mandibular lateral incisor was positioned fairly within the arch and complications such as root resorption were not observed.

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유리반도체

  • 박창엽
    • 전기의세계
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    • v.24 no.4
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    • pp.6-10
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    • 1975
  • 반도체와 그의 응용소자는 지난 20여년간 눈부식 발전을 이룩하였다. 이는 주로 단결정의 제작기술 진보에 의한 것으로 본다. 그러나 최근 단결정과는 전연 다른 유리질반도체가 국제회의에서도 그 우수성을 의논하기에 이르렀다. 유리질 반도체가 주목을 끌게 된겻은 1968년 Ovshinsky가 "무질서 구조에 있어서 가역적 스위칭현상"이라는 논문이 발표되고 유리질 반도체를 사용한 Ovonic 스위칭 소자의 출현에 기인된다. 유리질 반도체가 전기스위칭 작용, 기억작용을 나타낸다고 하는 Ovshinsky의 발표는 전자제치로서의 응용에 대해 찬반되는 의견이 있었지만 물성적 연구의 교량적인 역할을했다고 할 수 있다. 이런 반도체에 속하는 재료는 호칭도 여러가지로 유리질반도체, 비정질반도체 무정형반도체등으로 불리어진다. 단결정체가 각 격자간에 장거리질서를 갖는 반면 유리질 반도체는 무질서한 구조로 각 격자간에 단거리 질서를 갖는 것이 단결정과는 본질적으로 다른 점이라 본다. 유리 반도체의 종류는 첫째, 원소성 유리반도체로서 Ge, Si, Se, Te 들과 같이 단일원소로 된 겻과, 둘째 IV, V, VI족 원소로 된 공유결합 합금인 As$_{2}$Se$_{3}$-As$_{2}$Te$_{3}$ 계 Ge Si As Te계등의 칼코게나이드 유리등으로 금지대는 어느 것이나 2eV이하이다. 셋째 이론결합인 SiO $Al_{2}$O$_{3}$ Ta$_{2}$O$_{3}$Si$_{3}$N$_{4}$등의 산화물 및 질화물로 대표되는 분자성 비정질 물질로서 금지대는 2eV보다 큰 세종류로 크게 분류할 수 있다. 분류할 수 있다. 한다. 단 개개의 문제에 관한 구체적인 해석 또는 검토에 관하여는 다음 기회에 미루기로하고, 우선 여기서는 당면문제로서 대처하지 않으면 안될 자동주파수제어문제및 계통의 경제운용문제만에 한정하여, 이것을 우리나라의 현상과 관련시켜 개설하고, 이들의 자동화에 관한 기본적인 문제를 간단히 적어 보겠다. 가능하다. 제작완료된 ASIC은 기능시험을 완료했으며 실제 line-of-sight(LOS) 시스템 구현에 적용중이다. 시대를 살아 갈 회원들이다. '컨텐츠의 시대'가 개막되는 것이며, 신세기통신과 SK텔레콤은 선의의 경쟁 과 협력을 통해 이동인터넷 서비스의 컨텐츠를 개발해 나가게 될 것이다. 3배가 높았다. 효소 활성에 필수적인 물의 양에 따른 DIAION WA30의 라세미화 효율에 관하여 실험한 결과, 물의 양이 증가할수록 그 효율은 감소하였다. DIAION WA30을 라세미화 촉매로 사용하여 아이소옥탄 내에서 라세믹 나프록센 2,2,2-트리플로로에틸 씨오에스터의 효소적 DKR 반응을 수행해 보았다. 그 결과 DIAION WA30을 사용하지 않은 경우에 비해 반응 전환율과 생성물의 광학 순도는 급격히 향상되었다. 전통적 광학분할 반응의 최대 50%라는 전환율의 제한이 본 연구에서 찾은 DIAION WA30을 첨가함으로써 성공적으로 극복되었다. 또한 고체 염기촉매인 DIAION WA30의 사용은 라세미화 촉매의 회수 및 재사용이 가능하게 해준다.해준다.다. TN5 세포주를 0.2 L 규모 (1 L spinner flask)oJl에서 세포간의 응집현상 없이 부유배양에 적응,배양시킨 후 세포성장 시기에 따른 발현을 조사한 결과 1 MOI의 감염조건 하에서는 $0.6\times10^6$cell/mL의 early exponential시기의 세포밀도에서 72시간 배양하였을 대 최대 발현양을

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The Electrochemical Property Studies on Polyacenic Semiconductor Anode Material (음극 폴리아센 반도체 재료의 전기화학적 특성연구)

  • Kim Han-Joo;Park Jong-Eun;Son Won-Keun;Lee Hong-Ki;Park Soo-Gil;Lee Ju-Seong
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.134-137
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    • 1999
  • The polyacenic semiconductor material (PAS) electrode prepared by the pyrolytic treatment of phenol-formaldehyde resin is one of useful electrodes. As an anode material of lithium rechargeable batteries, amorphous carbon materials have been studied extensively because of their high electrochemcal performance and cyclicability. Carbon materials do not lead to the formation of lithium dendrite which is one of the most serious problems in applying Li-based materials to an electrode of batteries. The polyacene materials prepared from phenol resin at relatively low temperatures $(550\~750^{\circ}C)$ show a highly Li\doped state up to $C_2Li$ state without liberation of Li cluster. We prepared each polyacene materials at various temperature and investigated electro- chemical properties. We tried to change the mole ratio of [H]/[C] which is $0.24\~0.4$ range. Considering of electrochemical properties of PAS material, the PAS material is one of the most suitable materials for electrodes of a polymer battery.

The Necessary Conditions and Deterring Factors of Good Care (좋은 돌봄의 필요조건과 저해요인에 관한 연구 - 노인돌봄을 중심으로 -)

  • Seok, Jaeeun;Noh, Hyejin;Lim, Jeonggi
    • Korean Journal of Social Welfare
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    • v.67 no.3
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    • pp.203-225
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    • 2015
  • Social care service has grown much with the introduction of Long-Term Care Insurance, but it remains difficult to answer in the affirmative to the question: are we providing sufficiently good care? This study has its purpose in figuring out what conditions are necessary to realize good care in our society. The study has used focus group interview (FGI) as a way to acquire realistic knowledge on the conditions that create good care and its deterring factors. The focus group interview, which targeted long-term care workers and facility heads, was conducted three times from January through March 2014, with each session taking about 3 hours. The analysis showed that the components of good care were mutual understanding and recognition through active interaction, making a good relationship based on mutual trust and respect, professionalism of care worker with flexible judgment that provides customized services, professionalism of center manager with appropriate intermediation, and the tripartite partnership among family, elderly, and care worker. Meanwhile, the deterring factors of good care were identified as devaluation of care labor, ambiguous job description and abuse, unprofessionalism of care worker and manager, inappropriate interference and indifference of family, and the structural constraints on long-term care environment.

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Immobilization of Late Transition Metal Catalyst on the Amino-functionalized Silica and Its Norbornene Polymerization (아미노-기능화된 실리카 위 후전이 금속 촉매 담지 및 이를 이용한 노보넨 중합)

  • Pacia, Rose Mardie P.;Kim, So Hui;Lee, Jeong Suk;Ko, Young Soo
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.313-318
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    • 2016
  • In this study, an amorphous silica was functionalized with aminosilane, N-[(3-trimethoxysilyl)propyl]ethylenediamine (2NS) and the late transition metal catalysts including ($(DME)NiBr_2$ and $PdCl_2$(COD)) were subsequently immobilized on the functionalized amorphous silica for norbornene polymerization. Effects of the polymerization temperature, polymerization time, Al/Ni molar ratio, and type of co-catalyst on norbornene polymerization were investigated. Unsupported late transition metal catalysts did not show any activities for norbornene polymerization. However, the $SiO_2$/2NS/Ni catayst with MAO system, with increasing polymerization temperature, increased the polymerization activity and decreased the molecular weight of the polynorbornene (PNB). Furthermore, the catalyst when increasing polymerization temperature caused the decrease in both the polymerization activity and molecular weight of PNB. This confirmed that the stability of $SiO_2$/2NS/Ni at a high temperature was greater than that of $SiO_2$/2NS/Pd. Also the longer polymerization time resulted in the higher conversion of norbornene for both catalysts. When the Al : Ni molar ratio was 1000 : 1, the highest activity (15.3 kg-PNB/($({\mu}mol-Ni^*hr$)) but lowest molecular weight ($M_n$ = 124,000 g/mol) of PNB were achieved. Also $SiO_2$/2NS/Ni catalyst with borate/TEAL resulted in diminishing the polymerization activity and molecular weight of PNB with increasing the polymerization temperature.

Physical, Morphological, and Chemical Analysis of Fly Ash Generated from the Coal Fired Power Plant (석탄 화력발전소에서 발생되는 석탄회 특성과 형성 분석에 관한 연구)

  • 이정언;이재근
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.146-156
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    • 1998
  • Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A physical, morphological, and chemical characteristic of fly ash has been analyzed. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, ash recycling and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution and gravimeter. Morphological characteristic of fly ash is performed using a scanning electron micrograph and an optical microscope. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry (ICP). The distribution of fly ash size was ranged from 15 to 25 $\mu$m in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, relative opacity, coloration, cenosphere and plerosphere. The spherical fly ash might be generated at the condition of complete combustion. The size of fly ash was found to be increased the with particle-particle interaction of agglomeration and coagulation. Fly ash consisted of $SiO_2\;Al_2O_3\;and\;Fe_2O_3$ with 85% and carbon with 3~10% of total mass.

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Adsoptive Properties of Cellulose Thermally Treated at Low Temperature and Its Solubility to Water (저온 열처리 셀룰로오스의 염기성가스 흡착과 용해특성)

  • Jo, Tae-Su;Ahn, Byung-Jun;Choi, Don-Ha;Akihiko, Miyakoshi
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.63-70
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    • 2005
  • The purpose of this study was to investigate how to modify the physical properties of cellulose after thermal treatment. Cellulose was treated between $225^{\circ}C$ and $325^{\circ}C$ for 3 hrs under air flow, and then the thermally treated cellulose was measured to specific surface area, constitute elements, consumption ofacid and base, as well as the adsorption capacity of ethylamine vapor. The higher was the treating temperature from $225^{\circ}C$ to $325^{\circ}C$, the lower was the total yield of cellulose. Elemental analysis revealed that carbon content in thermally treated cellulose was gradually increased in proportion to temperature increment. The amount of acidic functional groups tended to increase up to $300^{\circ}C$, after then to be lowered slightly. In principle, no alkaline functional groups were found in thermally treated cellulose. In case of treatment with $325^{\circ}C$, only a few amount of alkaline functional groups were detectable. Specific surface area of thermally treated cellulose are determined to $1.9m^2/g$, which value can become higher when the treated temperature rises. The thermally treated cellulose at $275^{\circ}C$ shows the highest adsorption capacity of ethylamine at $40^{\circ}C$ for 4 hrs. Solubility of those two celluloses with WPG (Weight Percent Gain) value of 113% and 108%, respectively, was determined to almost 100%. X-ray diffractogram of thermally treated cellulose suggested that the crystalline structure of cellulose began to be destroyed at the temperature of $275^{\circ}C$. As a conclusion, changes of such a physical properties make it possible to weaken inter and/or intra hydrogen bond in crystal region of cellulose macromolecules. When thermally treated cellulose adsorbs ethylamine, it turns to be well soluble to water.

Maker Movement and the Possibility of Citizen Science (메이커 운동과 시민과학의 가능성)

  • Kim, Dongkwang
    • Journal of Science and Technology Studies
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    • v.18 no.2
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    • pp.95-133
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    • 2018
  • Since the beginning of the millennium, 'Maker Movement' has been active throughout the world. Today, there is a maker fair every year in major cities of the world including Seoul, and the number of attendees is increasing day by day, so it can be seen as a kind of maker 'phenomenon'. The positive implication of the maker's movement is that it attempts to break down the monopoly of manufacturing and to restore the rights and capabilities of citizens as makers. Today, highly developed industrial capitalism has a tendency to structurally paralyse citizens, to tie their hands and feet, and to degenerate into consuming entities only. Therefore, it can be said that the maker movement has structural tensions in the relationship of neoliberal manufacturing culture. This study is an attempt to actively interpret the maker movement in terms of "critical making". The maker movement can trace its origins to "counterculture" and "new communalism" that emerged in the United States in the 1960s and 1970s. On the other hand, there is criticism that the maker movement can fall into another technology utopianism and function as an area of consumer society, and mobilize it in the direction of activating consumerism. Although the maker's movement is amorphous due to its characteristics and it is currently in progress, it is difficult to make crude definition yet. However, as the citizens who have been defined only as consumers of science and technology, are newly emerging as producers of makers, there have been great changes in the topography of science and technology and civil society. So the scientific implication of the maker movement is great in that it shows the possibility of causing it.

Solvent Effects on the Charge Transport Behavior in Poly(3,4-ethylenedioxythiophene) Synthesized with Iron (III) -p-toluenesulfonate (Iron(III)-p-toluenesulfonate로 합성된 Poly(3,4-ethylenedioxythiophene)의 전하전달현상에 미치는 유기용매의 영향)

  • Park, Chang-Mo;Kim, Tae-Young;Kim, Won-Jung;Kim, Yun-Sang;Suh, Kwang-S
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.363-367
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    • 2005
  • The effects of organic solvent on the charge transport behavior of poly (3,4-ethylenedioxythioph one)/p-toluene-sulfonate(PEDOT-OTs) are investigated. The use of different organic solvents during the oxidative chemical polymerization of 3,4-ethylenedioxythiophene (EDOT) with Iron(III) -tosylate can greatly vary the DC conductivity of PEDOT-OTs along with molecular structure and doping concentration. For example, PEDOT-OTs prepared from methanol shows the conductivity of 19.5 S/cm, which is an increase by a factor of $10^8$ compared to PEDOT-OTa prepared from acetone. From the X-ray diffraction (XRD) experiments, it was found that PEDOT-OTs with ketone is amorphous state, while PEDOT-OTs with alcoholic solvent shows the better defined crystalline structure in which the charge transport along and between the PEDOT chains are promoted. Chemical analysis employing X-ray photoelectron spectroscopy (XPS) revealed that the doping concentration of PEDOT-OTs with alcoholic solvent is much higher than that of PEDOT-OTs with ketones. It is proposed that the interactions between the organic solvent and doping anion can cause the variation in doping concentration and, therefore, result in the PEDOT-OTs of different conductivities and chain structures.