• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.33-39
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• 2024

In this study, the basic properties of cement paste with varying replacement ratio of micro-silica and fumed silica were analyzed to determine the suitability of nanomaterials for use as concrete admixtures. Referring to the ultra-high strength mix, the fluidity of cement paste was evaluated according to the nanomaterial replacement rate and the compressive strength characteristics were compared and analyzed. The related properties of the reactive nanomaterials to the cement hydrate were analyzed using SEM and EDS to observe the microstructure and identify the components of the hydration product. The reactive nanomaterials used in this study had tap densities between 0.061 and 0.264 g/cm³, which were lower than SF. Micro silica exhibited excellent compressive strength properties with increasing replacement ratio, but fumed silica, unlike micro white, obtained excellent compressive strength at replacement ratio of 0.01~0.1 %. The same trend was observed in the hydration characterization.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.290.2-290.2
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• 2013

X-선 튜브는 의료 영상 및 치료, 산업용 제전 장치, 비파괴 X-선 영상 장치 등에서 사용되는데 기존의 열전자원을 이용한 X-선 튜브와는 달리, 냉음극형 X-선 튜브는 빠른 속도의 디지털 구동이 가능하며 전력 소비가 낮은 장점이 있다. 따라서, 최근 많은 연구자들에 의해서 냉음극형 X-선 튜브에 관한 연구가 활발하게 진행되고 있다. 냉음극형 X-선 튜브는 전계 방출을 이용한 전자원을 사용하며, 탄소나노튜브 (CNT), Si, 다양한 종류의 나노선 등이 대표적이다. 그 중에서 CNT는 높은 종횡비로 인해 전계 방출 특성이 우수하여 가장 대표적인 물질이다. CNT를 이용한 전자원을 제작하기 위해서는 직접 성장법, 전기영동법, 스크린 프린팅법, 디핑법 등 다양한 방법이 존재한다. 직접 성장법을 제외한 방법들은 모재료인 CNT와 용매, 금속재료들을 섞어 페이스트나 수용액의 상태를 제작하여야 한다. 이 때, 금속 재료는 기판과 CNT간의 접착 및 전자 전도 통로의 역할을 하는 무기 충전제이며 일반적으로 나노 혹은 수 마이크로미터 크기의 상태로 존재하는 것을 주로 사용한다. X-선 튜브 제작은 일반적으로 외벽을 유리 혹은 세라믹을 주로 사용하는데 아노드 전극 및 캐소드 전극 등과 결합하여 진공 밀봉된 형태가 되어야 한다. 브레이징 방법은 금속과 세라믹을 결합하는데 매우 유용한 방법이며, 그 중에서도 진공 브레이징 방법은 다량의 부품을 한 번에 결합시킬 수 있다. 하지만 진공 브레이징 공정의 온도는 약 $700{\sim}1,000^{\circ}C$이며 이는 금속 재료가 충분히 증발할 수 있는 온도가 된다. 본 발표에서는 고온 진공 상태에서의 무기 충전제의 증발에 대한 현상을 관찰하고 고온진공 상태에서 증발없이 무기 충전제로의 역할을 할 수 있도록 다양한 금속 및 합금에 대한 연구를 수행하였다. 또한, 이 연구를 통해 선택된 무기 충전제를 포함하여 CNT 페이스트를 볼밀링 방법을 이용하여 제작하였으며, 이를 이용한 CNT 에미터가 X-선 튜브의 전자원으로 사용될 수 있는지 확인하기 위해 전계 방출 실험을 함께 실시하였다. 제작된 CNT 에미터가 우수한 전계 방출 특성을 가지고 있음을 확인하였으며, 이는 본 연구를 통해 선택된 금속 및 합금 재료가 무기 충전제로의 역할을 잘 수행하고 있음을 보여준다.

• Journal of the Microelectronics and Packaging Society
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• v.29 no.1
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• pp.35-41
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• 2022

In the era of Fifth-Generation (5G), technology requirements such as Artificial Intelligence (AI), Cloud computing, automatic vehicles, and smart manufacturing are increasing. For high efficiency of electronic devices, research on high-intensity circuits and packaging for miniaturized electronic components is important. A solder paste which consists of small solder powders is one of common solder for high density packaging, whereas an electroplated solder has limitation of uniformity of bump composition. Researches are underway to improve wettability through the addition of nanoparticles into a solder paste or the surface finish of a substrate, and to suppress the formation of IMC growth at the metal pad interface. This paper describes the principles of improving the wettability of solder paste and suppressing interfacial IMC growth by addition of nanoparticles.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.96-99
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• 2024

A sintering paste for bonding copper plates was synthesized using Cu formate nanofibers on Cu microparticles, mixed with formic acid. Copper oxide nanofibers of 10 ㎛ grown at 400 ℃ on Cu microparticles on the surface were transformed into copper formate nanofibers through the mixing of formic acid. Compared to Cu bulk particles or nanoparticles, Cu formate on Cu microparticles decomposed into metallic Cu at a lower temperature of 210 ℃, facilitating the sintering of copper paste. The growth of nanofiber on Cu microparticles allowed for an increase in the reaction rate of formation to copper formate, aggregating surface area, and decomposition rate of copper formate, resulting in fast sintering.

• Journal of Welding and Joining
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• v.26 no.2
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• pp.20-24
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• 2008

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.28-34
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• 2021

SiO2/Ag core-shell nanoparticles were synthesized by combining modified Stöber process and reverse micelle method using acetoxime as a reducing agent in water/dodecylbenzenesulfonic acid (DDBA)/cyclohexane reverse micells. The SiO2/Ag core-shells were studied for structure, morphology and size using UV-visible spectroscopy, XRD, SEM and TEM. The size of a SiO2/Ag core-shell could be controlled by changing the [water]/[DDBA] molar ratio (WR) values. The size and the polydispersity of SiO2/Ag core-shells increased with increase of the WR value. The resultant Ag nanoparticles exhibit a strong surface plasmon resonance (SPR) peak at 430 nm over the amorphous SiO2 nanoparticles. The SPR peak shifted to the red side with increase in nanoparticle size. Conductive pastes with 70 wt% SiO2/Ag core-shell were prepared, and the pastes were coated on the PET films using a screen-printing method. The printed paste film of the SiO2/Ag core-shell showed higher surface resistance than the commercial Ag paste in the range of 460~750 µΩ/sq.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.95-96
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• 2022

Carbon nanotubes has a positive effect on the mechanical properties, functionality, and durability of cement-based materials. In this study, carbon nanotube solutions mixed with two different types of superplasticizers were dispersed by high-pressure homogenizer, and used for preparation of cement paste. The 7and 28day compressive strength were evaluated.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.201-202
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• 2021

Currently, the domestic construction industry is trying to expand the range of building materials due to overload of growth. In particular, several studies are being conducted to make up for the weakness of building materials by solving problems such as reduction of tensile strength and brittle behavior of concrete. Among them, efforts to maximize the use of carbon nanotubes (CNT) that has excellent mechanical and electrical conductivity properties are continuing. However, CNT is hydrophobic and have a strong Van der Waals force between particles, making it difficult to obtain an effective dispersion state. Therefore, in this study, various kinds of surfactants like DOC (Sodium Deoxycholate), PVP (Polyvinylpyrrolidone), and PCE (Polycarboxylate ester) were added to improve the dispersibility of CNT, and analyzed the changes in the properties of the cement paste mixed with them.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.174-175
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• 2021

Currently, the construction structures become larger and more high-performance in modern society, demands for ultra-high strength and light weight construction materials are increasing rapidly. Therefore, this study aims to confirm the applicability of nanomixed cement supplemented with physical and mechanical properties using nanomaterials.Changes in compressive strength and properties were analyzed according to the ratio of cement paste and dispersant (PCE) made by ultrasonication of carbon nanotubes (CNT)

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.189-190
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• 2023

In this study, the compressive strength and hydration heat of cement paste mixed with cellulose nanocrystal(CNC) and graphene oxide (GO) were evaluated. The difference was compared by mixing 0.1 vol.% ~0.4 vol.% of CNC and 0.05 wt.% ~ 0.1 wt.% of GO in a cement paste with a water cement ratio of 0.3. As a result, it was confirmed that the compressive strength increased as CNC and GO were mixed respectively, and then the compressive strength decreased when the appropriate mixing rate was exceeded. In the hydration heat measurement, there was no significant difference when only CNC was mixed, but it was confirmed that the hydration heat decreased as the amount of CNC mixing increased when used in combination with GO.