• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.317-322
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• 2012

The microstructures were examined by SEM, FT-IR spectra, tensible properties mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly industries have led to the development of solvent-free formulations that can be cured. We had synthesized the polyurethane resin having the ability to protect stainless steel against corrosion. Compared with general packing materials and coatings, this resin is highly stronger in intensity and longer durability. Polyurethane resins were composed of polyols, IPDI, silicone surfactant, catalyst and crosslink agent. Moreover, thermal fillers such as $Al_2O_3$, fume silica and $ZrO_2$ not only accelerated the curing rate but also improved the physical property as thermal barriers. The rigid segments of polyurethane in mechanical properties were due to crosslink agent and the increase of [NCO/OH]. In conclusion, the polyurethane microstructure with crosslink agent can be good material for themoset coating of metal substrates such as stainless steel.

• Journal of the Mineralogical Society of Korea
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• v.27 no.4
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• pp.293-299
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• 2014

The bentonite, a buffer material, is essential for the deep geological disposal of HLW (high-level radioactive waste), and it is important to know its characteristic long-term evolution in the underground environment. With an assumption that the concentration of aqueous copper ions will increase if copper-coated materials on a metal canister are corroded, we examined some characteristic ion-exchanges and cation release phenomena occurring in the bentonite clay (montmorillonite) interacted with aqueous Cu cations. During the interaction between dissolved copper and bentonite, Na rather than Ca cations in the expandable clay were preferentially replaced by Cu ions in the experiment. In addition, the Cu-exchanged montmorillonite was characterized by an asymmetric X-ray diffracted pattern with relatively collapsed interlayers compared to the raw sample. These results indicate that the gradual change of the original bentonite property may occur in a underground disposal condition. We are going to further study the characteristic chemical and mineralogical changes of the bentonite buffer to be used for the disposal site by conducting additional experiments.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.23-27
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• 1998

To protect the underground pipeline from the mechanical damage and to enhance the cathodic protection effect, the river sand has been backfilled traditionally around the buried pipeline. However, river sand became depleted and expensive. One has to seek for the economic alternative materials. Crashed stone is a good candidate for the backfill material. In this study, how much the particle size and shape of the crashed stone can effect on the gas pipeline coating was examined. A series of laboratory and field test was performed. In the Lab, the increasing loads were applied to the coated pipeline surrounded by the crashed stone, where no significant damage was observed.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.6
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• pp.569-575
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• 1984

The characteristics of the stress corrosion cracking of SUS 304 stainless steel weldments were studied with the speciments of the constant displacement type under the environment of 42% MgC $l_{2}$ boiled solution (143.+.-.2.deg.C). The susceptibility of initiation and propagation of the stress corrosion crack was quantitatively inspected in the weld metal, heat affected zone and heat affected zone with including the reinforcement shape, respectively. Also, those susceptibility were discussed in connection with the change of mechanical and microstructural characteristics caused by heating cycle of welding. Main results obtained are as follows: (1)Stress corrosion cracking is easiest to initiate and propagate in the heat affected zone of weldment. (2)The susceptibility of stress corrosion cracking of the weldment is largely improved by eliminating the reinforcement part of the weld bead. (3)The dominant factor of the cracking susceptibility of the heat affected zone appeared to be the phenomenon of softening and sensitizing caused by welding heat cycle. (4)Under the low loading conditions, the behavior of stress corrosion cracking of the SUS 304 steel weldment is largely influenced by the pitting phenomenon in the front region of the main crack.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.265-269
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• 2016

Ammonia gas as a hydrogen source has received great attention since the importance of hydrogen gas as a clean energy source increased. However, ammonia is toxic and corrosive to metal such that the absorbent that can store and transport ammonia became an important issue. As an effort to solve this, a large pored covalent organic framework, COF-10 was proposed as an adsorbent for storage and safe transportation of ammonia. During the ammonia adsorption process, boron in COF-10 structure can act as a Lewis acid site and bind with ammonia. In this study, COF was synthesized and its structure was identified by BET, XRD and FT-IR. The adsorption characteristics of COF were investigated by TPD and adsorption isotherm. The COF-10 showed an excellent adsorption capacity for ammonia (9.79 mmol/g) which could be utilized as an ammonia adsorbent.

• Composites Research
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• v.31 no.4
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• pp.145-150
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• 2018

Various structural health monitoring (SHM) systems have been suggested for aerospace industry in order to increase its life-cycle and economic efficiency. In the case of aircraft structure madden with metal, a major concern was hot spots, such as notches, bolts holes, and where corrosion or stress concentration occurs due to moisture or salinity. However, with the increasing use of composites in the aerospace industry, further advanced SHM systems have been being required to be applied to composite structures, which have much complex damage mechanism. In this paper, a method of acoustic emission localization for composite structures using Q-switched laser and multiple Amplifier-integrated PZTs have been proposed. The presented technique aims at localization of the AE with an error in distance of less than 10 mm. Acoustic emission simulation and the localization attempt were conducted in the composite structure to validate the suggested method. Localization results, which are coordinates of detected regions, grid plots and color intensity map have been presented together to show reliability of the method.

• Conservation Science in Museum
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• v.16
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• pp.32-45
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• 2015

The bronze incense burner, discovered in Chungung-dong, Hanam, Gyeonggi-do in 1971, is a hanging incense burner dating from the Goryeo period. The incense burner was covered with a thick layer of clay. The object was in a severely deteriorated state, affected by bronze disease which resulted in extensive corrosion. Numerous cracks were present across its surface, and some parts had been broken off. To preserve and display the bronze incense burner in a stable condition, deposits of foreign material were removed from the surface, and the weakened metal was strengthened. Cracked and broken areas were reinforced using woven glass fiber, followed by the application of epoxy resin to restore the shape. To investigate the method of production, a chemical analysis was performed, and the microstructure was examined. The chemical analysis revealed that the body of the incense burner as well as the ear, loop, lid and the knob were cast in a ternary alloy of Cu-Sn-Pb. Moreover, copper nails with high copper content were used to securely join the ear to the body of the incense burner. The microstructure was mainly α-phase, and non-intermetallic inclusions composed of Cu and S were detected.

• Journal of Powder Materials
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• v.22 no.4
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• pp.271-277
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• 2015

As wrought stainless steel, sintered stainless steel (STS) has excellent high-temperature anti-corrosion even at high temperature of $800^{\circ}C$ and exhibit corrosion resistance in air. The oxidation behavior and oxidation mechanism of the sintered 316L stainless was reported at the high temperature in our previous study. In this study, the effects of additives on high-temperature corrosion resistances were investigated above $800^{\circ}C$ at the various oxides ($SiO_2$, $Al_2O_3$, MgO and $Y_2O_3$) added STS respectively as an oxidation inhibitor. The morphology of the oxide layers were observed by SEM and the oxides phase and composition were confirmed by XRD and EDX. As a result, the weight of STS 316L sintered body increased sharply at $1000^{\circ}C$ and the relative density of specimen decreased as metallic oxide addition increased. Compared with STS 316L sintered parts, weight change ratio corresponding to different oxidation time at $900^{\circ}C$ and $1000^{\circ}C$, decreased gradually with the addition of metallic oxide. The best corrosion resistance properties of STS could be improved in case of using $Y_2O_3$. The oxidation rate was diminished dramatically by suppression the peeling on oxide layers at $Y_2O_3$ added sintered stainless steel.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.75-81
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• 2015

A deposited metal specimen of ER2594 which is a super duplex steel welding wire used to investigate the effect of sigma(${\sigma}$) phase on electrochemical corrosion characteristics was prepared by gas tungsten arc welding. Aging treatment was conducted for the specimen at the temperature range of $700^{\circ}C$ to $900^{\circ}C$ for 5 to 300 minutes after annealing at $1050^{\circ}C$. Corrosion current density has decreased a little with an increase of aging time over 60 minutes at $700^{\circ}C$ to $900^{\circ}C$ and the uniform corrosion of deposited metal had more influence on the precipitation of ferrite than the precipitation of sigma phase. Therefore, the precipitation of sigma phase did not have much effect on the uniform corrosion. Pitting potential representing pitting corrosion has shown decreasing tendency as the precipitation of sigma phase increased. The degree of sensitization representing intergranular corrosion has shown increasing tendency as the precipitation of sigma phase increased at $700^{\circ}C$ to $800^{\circ}C$, while it has decreased at $900^{\circ}C$ for 60 to 300 minutes.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.16-16
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• 2009

Alloy 82/182로 용접된 원자력 발전소 주기기의 이종 금속 용접부는 장기간 운전 후 응력부식균열(SCC : Stress Corrosion Cracking)에 의한 결함이 나타나게 된다. 2000년대 이후로 원자력 주기기 Alloy 82/182 용접부에서 PWSCC(Primary Water Stress Corrosion Cracking)에 의한 Degradation이 급격히 증가하는 추세를 보이고 있으며, 국내에서도 이와 관련하여 원자력 발전소의 안전성에 대한 Issue 및 대비책에 대한 관심이 고조되고 있다. 이러한 Alloy 600 용접부에 대한 결함을 예방하기 위한 대표적인 기술로써 수명연장 오버레이 기술이 있다. 원자력 주기기 노즐부는 저탄소강으로 제작되어 있으며, 저탄소강에는 제작 시 용접후열처리가 적용된다. 후열처리를 하는 주된 이유는 Tempering을 통해 열영향부의 인성 및 연성의 회복과 강도를 감소시켜 모재와 동등 또는 이 이상의 물성을 갖도록 하는 데 그 목적이 있다. 그러나 수명연장 오버레이의 경우 현장 작업 시에 후열처리가 어렵기 때문에, 이를 대체하기 위한 기술로 템퍼비드 용접을 적용할 경우 후열처리를 면제해 주고 있다. 본 연구에서는 수명연장 오버레이 기술 개발의 일환으로써 저 탄소강에 대한 템퍼비드 용접 기술을 확립하였다. 실험에 사용된 모재는 원자력 주기기의 노즐에 사용되는 SA508 Gr.3 Cl.1을 사용하였으며, 용가재는 Alloy 52 및 52M을 사용하였다. 최적 조건 도출을 위해서 실험 매트릭스를 이용하여 기본 실험을 수행하였으며, 실험에는 자동 GTAW 용접을 적용하였다. 기본 실험을 통해 얻은 최적 조건을 사용하여 PQ 시험을 수행하여 WPS를 확보하였다. 분석은 용접 후 조직 및 경도 시험, 물리시험(인장시험, 굽힘시험 및 충격시험)을 수행하였다.