• Resources Recycling
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• v.30 no.5
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• pp.57-66
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• 2021

In this study, we attempted to separate and recover Cu from low-grade copper ore by a hydrometallurgical process. The leaching sample obtained after crushing and sieving by 0.355 mm of low-grade copper ore contained 1.5% Cu, 4.7% Fe, 1.0% Mn, and 0.3% Zn. The Cu in the oxide ore was very well leached into sulfuric acid and 97% Cu leaching efficiency was achieved at 80℃ and 3 M sulfuric acid (H₂SO₄). From the leaching solution, Cu was separated by solvent extraction from Fe, Mn, and Zn using LIX984N. The separation tendency between Cu and other metals was confirmed through the distribution ratio and separation factor. By plotting the McCabe-Thiele Diagram, the optimum condition for recovering Cu is 5 vol.% LIX984N, 2-stage counter-current solvent extraction, and an O/A ratio of 0.5. Using this method, 99% of the Cu was extracted and a CuSO₄ solution was finally obtained that contained 1.6 g/L Cu after the stripping process using 2 M H₂SO₄.

• Resources Recycling
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• v.30 no.4
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• pp.27-34
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• 2021

In this study, the leaching behavior of vanadium (V) was investigated through CaO roasting and sulfuric acid leaching from domestic V-bearing titanomagnetite (VTM). Changes in the phase according to the amount of CaO added and roasting temperature were analyzed. Regardless of the roasting conditions, perovskite (CaTiO₃) was preferred to form. When the CaO content was increased, the calcium ferrite (CaFeO_x) phase was formed; otherwise, ferrite (Fe₂O₃) was preferred. After CaO was roasted, leaching was performed for 6 h with 1M sulfuric acid at 50℃ and a 10% solid-liquid ratio. Results of leaching revealed that when the roasted product was sintered, V was not sufficiently oxidized, and the leaching efficiency decreased. In addition, when the roasting temperature was low, the leaching efficiency of V decreased due to the influence of unreacted excess CaO. To lower the leaching efficiency of iron and titanium in VTM concentrates, suppressing the formation of CaTiO₃ and CaFeO_x was necessary by minimizing the amount of CaO added. Consequently, a leaching efficiency of 86% V, 4.3% Fe, and 6.5% Ti was obtained when the roasted product of 1150℃ and 10 wt% CaO was leached.

• Journal of the Korean earth science society
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• v.43 no.3
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• pp.430-445
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• 2022

The purpose of this study was to explore the learning effects in elementary school students who participated in a geological field trip conducted under the theme 'minerals and rocks', focusing on novelty space. A total of 10 sixth-grade students participated in this program held at a public elementary school in Seoul as part of after-school club activities. Students observed mineral and rock samples in a classroom and outdoor learning environment. The authors collected activity papers (texts, drawing), researchers' participation notes, video and audio recordings containing the study participants' activities, and post-interview data To analyze the learning effects in the cognitive domain of students, the observation analysis framework for rock classification of Remmen and Frøyland (2020) and the rock description analysis framework of Oh (2020) were used. Additionally, to explore the learning effects of psychological and geographic areas, students' drawings, texts, discourses, and interview data were inductively analyzed. The results showed that the students demonstrated 'everyday' and 'transitional' observations in the classroom learning environment, while in the outdoor learning environment (school playground, community-based activities), they demonstrated 'transitional' and 'scientific' observations. Moreover, as the scientific observation stage progressed, more types of descriptive words for rocks were used. In terms of psychological and geographic aspects, students showed their selection of places to explore familiar outdoor learning environments, positive perceptions of outdoor learning, and aesthetic appreciation. Finally, this study not only discussed novelty space as a tool for analyzing students' learning effects but also suggested the need for an academic approach considering new learning environments, such as learning through virtual field trips.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.259-271
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• 2022

Lattice preferred orientation (LPO), which shows a specific lattice-orientation of minerals, is affected by the deformation conditions of minerals. Because of this reason, LPO is very useful to study the deformation conditions of the minerals and the rocks. In this study, we collected amphibole-rich rocks from the Geumgye Mountain, Chugye-ri, Yugu-eup, Chungcheongnamdo, located in the southwestern part of the Gyeonggi Massif, and analyzed the LPO of amphibole and plagioclase using electron backscattered diffraction. Two types of LPOs of amphibole, type I and type IV, were observed in Yugu amphibole-rich rocks. Our data suggest that the amphibole-rich rocks in Yugu were deformed by rigid body rotation regardless of the LPOs and grain size of amphibole, and the LPOs are considered to have been affected by the degree of deformation (i.e. strain). In the low strained amphibole-rich rock, a strong type I LPO and a large grain size of amphibole were observed. On the other hand, in the highly strained amphibole-rich rocks, a weak type IV LPO and a small grain size of amphibole were observed. The various degree of deformation observed in the Yugu amphibole-rich rocks were also observed in the adjacent peridotites, indicating that the rocks in Yugu experienced various levels of deformation.

• Economic and Environmental Geology
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• v.51 no.5
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• pp.455-461
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• 2018

The purpose of this study is to compare the expert group's recognition with general people's recognition about the image of the future on geo-technoloies. The survey targeting to 215 experts and to 598 people had been completed from July to August, 2017 by a research firm. The research result showed that energy was selected as the first priority by expert group and climate environment, geologic environment, mineral resources and material, living place, space-earth research, and the fourth industrial revolution were sequence ranked by experts. Also, it was analyzed that climate environment was recognized as the first priority and geologic environment, energy, mineral resources and material, living place, space-earth research, the fourth industrial revolution were ranked in sequence by general people group.

• Journal of Periodontal and Implant Science
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• v.36 no.3
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• pp.601-611
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• 2006

임프란트 식립을 필요로 하는 환자의 수평적 치조제 결손의 증대를 위해 골유도재생술과 병용한 bioactive glass (BG) $(Biogran^{(R)})$ 이식의 골재생 양상을 각기 다른 치유기간을 부여한 4명의 환자에서 평가하였다. 6, 8, 10, 18개월의 치유기간 후 임프란트 식립부위에서 조직절편을 채득하여 골재생을 조직계측학적으로 평가하였다. 임프란트 식립을 위한 surgical reentry시 모든 이식부위는 임상적으로 명확한 수평적 치조제 폭경의 증가를 관찰할 수 있었다. 하지만 조직학적 분석결과 BG는 불량한 골전도성을 나타내었다. 6, 8개월의 치유기간후, 이식부위에서 신생골이 거의 관찰되지 않았으며(2.5%이하), 이식부와 기존 골의 경계부위에서 BG particle에 대한 신생골 성장과 결합양상 또는 관찰할 수 없었다. 10개월의 치유기간후 기존 골조직으로부터 성장한 신생골의 BG particle과의 직접적인 접촉양상을 일부 관찰할 수 있었다. 이식부는 13.2%의 광물화된 신생골조직을 보였고, 대부분의 BG particle은 결체조직으로 둘러싸여 있었다. 18개월의 치유기간이 부여된 환자의 조직절편에서 신생골은 이식부의 10.7%를 차지하여 비교적 낮은 신생골 형성양을 나타내었고, 이식부에 존재하는 잔존BG particle은 대부분은 결체조직으로, 일부분에서 광물화된 골조직으로 둘러싸여 있었다. 6, 8, 10, 18개월에서 잔존 BG particle양은 전체 이식부 면적에 대해서 각기 22.3%, 26.5%, 30.7%, 18.7%로 나타났다. 본 증례보고는 비록 한정적인 4명의 환자에서의 조직계측학적 평가결과이지만, 수평적 치조제 결손의 증대를 위해 골유도재생술과 병용한 bioactive glass이식은 불량한 골전도성으로 인해 효과적인 골재생을 위한 이식재로서는 적절하지 않을 수 있음을 나타낸다.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2002.10a
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• pp.93-101
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• 2002

석회석은 우리나라 광업법 제3조에서 규정한 법정광물로써 백운석, 대리석, 방해석 및 코퀴나 등을 포함하며, 최근 우리나라 전체 광산물 생산량의 $75\%$를 상회하는 단일광종 최대생산량을 나타내고 있는 광종이다. 이외에도 석회석 광은 여러 가지 통계적으로도 국내 최대임을 나타내는데, 즉, 2001년도 우리나라 일반광(66종) 등록광구수 5,242개소 중에서 1,494개소를 차지하여 $28.5\%$를 차지하며, 가행광산 수에서도 320개소 중 109개소$(34\%)$, 근로자 수에서는 4,291명중에서 2,748명$(64\%)$으로 최대의 규모를 가지고 있다. 실제로 석회석 및 관련제품은 오늘날 화학공업이나 환경산업 등 각종의 산업에 널리 이용되고 있으며, 그의 이용 역사에서도 유구한 역사를 가지고 있다. 즉, 고대 유적분석 결과는 이미 신석기 시대에도 석회 재료가 쓰였을 것으로 보고되고 있으며, 성경(신명기 27장 1-5절)에도 소개되고 있고, 우리나라에서의 석회 사용의 역사도 동국여지승람(성종16년), 세종실록, 문종실록 등에 석회 산지가 자세히 조사 기록되어 있으며 소성석회의 제조, 사용에 대하여도 기록하고 있다. 이외에도, 그리이스, 로마, 중국 등지의 역사에서는 건축재, 농업, 표백 및 제혁공업 등에 사용되었다는 사실이 발견되고 있지만, 석회석의 용도가 크게 증가된 것은 역시 산업혁명 이후 20세기가 시작되면서부터 라고 할 수 있다. 석회석은 국가산업구조 및 인간의 삶의 양식에 따라 그의 용도가 다양하고, 광범위하게 변화하는 만큼, 그의 품질 또한 중요하게 취급되어야 하지만, 우리나라의 경우에는 아직도 시장규모가 큰 일부용도이외에 사용자의 요구에 부합되는 다양한 품질의 석회제품을 제조하는 데에는 인색하고, 또한 사용자의 대부분은 용도가 명시되어 있는 외국의 제품을 선호하는 경향에 따라 석회석 및 관련제품의 수입량이 감소하지 않고 있다. 최근 우리나라는 국제통화기금(IMF)이후에, 국내산업을 보호하는 정부의 규제나 지원은 폐지 또는 축소되고, 외국회사의 시장참여에 의한 국제경쟁기반이 약화되고 있는 것도 사실이지만, 고 환율에 의하여 일부제품의 수입은 자제되고, 국내산 대체 방향으로 진행되고 있기 때문에, 안정되고 신뢰할 수 있는 품질의 제품을 제조하는 경우에는 오히려 국내시장의 확장에는 좋은 시기가 될 수도 있다고 판단된다. 이에 본고에서는 최근 국내 석회석 관련제품을 활용하는 사례를 분석하고 향후 유효 이용을 도모하는 데에 참고가 되었으면 하는 마음에서 작성하였다.

• The Journal of the Petrological Society of Korea
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• v.21 no.2
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• pp.249-261
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• 2012

Olivine is a dominant mineral in the upper mantle and is elastically very anisotropic. When olivine is deformed under stress at high pressure and high temperature, lattice preferred orientation (LPO) is formed. It is known that the LPO of olivine is affected by water, stress, and pressure. In this paper, I reviewed the papers dealing with the effects of water, stress, and pressure on the LPO of olivine, summarized the papers on the LPOs of olivine in natural mantle rocks, and discussed its implications for seismic anisotropy in the upper mantle. In addition, I also described four types of LPOs of orthopyroxene recently found in natural spinel lherzolite.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.493-496
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• 2007

본 연구에서는 국내 암석을 암종별로 총 292개 채취하였으며 열물성 측정 장비를 이용하여 이들 암석의 열물성을 측정하였다. 이와 더불어 암석의 물리적 특성을 측정하였으며 일부 시료의 경우 XRD 정량분석을 실시하였다. 이들 결과를 이용하여 암석의 열물성 특성과 열물성에 영향을 주는 인자를 파악하였다. 암석의 열물성 측정 결과 열전도도와 열확산계수는 화강암에서 가장 낮은 값을 보였으며 퇴적암, 변성암 순으로 나타났다. 또한 암종별 열물성 값의 범위를 살펴보면 변성암과 퇴적암에서 넓게 분포한다. 암석의 물성과 열물성과의 상관성 분석 결과 공극률이 증가함에 따라 열전도도와 열확산계수가 감소하나 상관성은 미약한 것으로 나타났다. XRD 분석 결과 암석의 열전도도는 석영($SiO_2$)의 함량에 따른 선형의 비례관계를 보였다. 이로써 암석의 열전도도는 암석을 이루는 광물의 종류에 의하여 영향을 받음을 알 수 있다. 차후 암석의 구성 광물입자의 배열 상태에 따른 열물성 특성과 퇴적암 및 변성암 시료에 대한 이방성 실험을 통해 편리, 층리 및 엽리 등에 따른 열물생의 이방성 정도를 분석할 예정이다.

• Economic and Environmental Geology
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• v.50 no.1
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• pp.1-14
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• 2017

The analytical conditions including surface state, moisture effect, and device condition were investigated for applying Short Wave Infrared(SWIR) spectroscopy to the field survey. Among the three surface state of samples (exposed surface, cutting face and powder), both spectra from the exposed surface and cutting face are almost identical whereas spectral variation was detected in powder sample. Over 24-hours-dryring of the wet sample at room temperature, the samples show a similar spectrum with that of dry condition. The result suggests that outcrop samples mighty be dried for 24 ~ 48 hours depending on the wetness of outcrop. The bright minerals could produce stable spectra with 10 times measurements as default value of the device under SWIR spectroscopy but the dark minerals would require about 10 seconds, which corresponds to 100 times measurements to get the reliable spectra. The position and shape 2,160 ~ 2,330 nm and/or other spectral features of hydrothermal alteration minerals by SWIR spectroscopy could be used for a classification of hydrothermal alteration zone in the field. Absorption peaks in 2,160 ~ 2180 nm are useful for identifying (advanced) argillic zone by spectral characteristics of kaoline, dickite, pyrophyllite, and alunite. Absorption peaks in 2,180 ~ 2,230 nm are able to define muscovite, sericite, and smectite, which are key alteration minerals in phyllic zone. Absorption peaks in 2,230 ~ 2,270 nm can be used to recognize prophylitic zone where chlorite and epidote occur. Absorption peaks of other principle minerals such as talc, serpentine, amphibole, and carbonate group are mainly detected within the wave length of 2,270 ~ 2,330 nm. This result indicates that the spectra of these minerals need to be carefully interpreted.