• 한국세라믹학회지
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• 제30권9호
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• pp.740-746
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• 1993

TiO2-SnO2 fine powders prepared by coprecipitation from TiCl4-SnCl4 aqueous solution, and their crystal structures were studied. All the TiO2-SnO2 fine powders calcined at 180~$700^{\circ}C$ showed the complete solid solution between TiO2(rutile structure) and SnO2(rutile structure). This crystal structure of TiO2-SnO2 powders is thought to be originated mainly from the heterogeneous nucleation of Ti-hydroxde on the Sn-hydroxide with coherent structure.

• 한국재료학회지
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• 제22권7호
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• pp.352-357
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• 2012

$SnO_2$-mixed and Sn-doped $TiO_2$ nanoparticles were synthesized via a hydrothermal process. $SnO_2$-mixed $TiO_2$ nanoparticles prepared in a neutral condition consisted of anatase $TiO_2$ nanoparticles(diamond shape, ~25 nm) and cassiterite $SnO_2$ nanoparticles(spherical shape, ~10 nm). On the other hand, Sn-doped $TiO_2$ nanoparticles obtained under a high acidic condition showed a crystalline phase corresponding to rutile $TiO_2$. As the Sn content increased, the particle shape changed from rod-like(d~40 nm, 1~200 nm) to spherical(18 nm) with a decrease in the particle size. The peak shift in the XRD results and a change of the c-axis lattice parameter with the Sn content demonstrate that the $TiO_2$ in the rutile phase was doped with Sn. The photocatalytic activity of the $SnO_2$-mixed $TiO_2$ nanoparticles dramatically increased and then decreased when the $SnO_2$ content exceeded 4%. The increased photocatalytic activity is mainly attributed to the improved charge separation of the $TiO_2$ nanoparticles with the $SnO_2$. In the case of Sn-doped $TiO_2$ nanoparticles, the photocatalytic activity increased slightly with the Sn content due most likely to the larger energy bandgap caused by Sn-doping and the decrease in the particle size. The $SnO_2$-mixed $TiO_2$ nanoparticles generally exhibited higher photocatalytic activity than the Sn-doped $TiO_2$ nanoparticles. This was caused by the phase difference of $TiO_2$.

• 한국세라믹학회지
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• 제31권2호
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• pp.213-219
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• 1994

The formations of spinel and colors of ZnO-Fe2O3-TiO2-SnO2 system have been researched on the basis of ZnO-Fe2O3 system. Specimens were prepared by substituting Fe3+, with Ti4+ or Sn4+ when mole ratios between Fe3+ and Ti4+ or between Fe3+ and Sn4+ were 0.2 mole. The reflectance measurement and X-ray diffraction analysis of the formation of spinel and the colors of there specimens were carried out. ZnO-Fe2O3 system in which Fe2O3 was substituted with SnO2 and TiO2 was formed the spinel structure of 2ZnO.TiO2, 2ZnO.SnO2, ZnO.Fe2O3. The stable stains which were colored with yellow and brown could be manufactured.

• 한국세라믹학회지
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• 제14권3호
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• pp.187-192
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• 1977

For the purpose researching to the influence of tetrahedral and octahedral preference of cations of $Ni^{2+}$, $Ti^{4+}$ upon the formation and the color development of the $ZnO-SnO_2$ spinel containing $Ni^{2+}$ and $Ti^{4+}$ ions, the gradual substitution of $Ni^{2+}$ ions for $Zn^{2+}$ ions and of $Ti^{4+}$ ions for $Sn^{4+}$ ions of the spinel in NiO-ZnO-$SnO_2$-$TiO_2$ system was carried out. On samples prepared by calcining the oxide and basic cabonate mixtures at $1300^{\circ}C$ for 2 hours, the X-ray analysis, measurement of reflectance and the test of their stabilaity as a glaze pigment were also carried out. The results are summarized as follows 1) Single spinel was formed completely to x=1 in the $xNiO\cdot(2-x)ZnO\cdot{SnO}_2$system, and gave brilliant lightgreen hue. Moreover, $NiO\cdot{ZnO}\cdot{SnO}_2$ formed easily spinel than $NiO\cdot{MgO}\cdot{SnO}_2$ because Zn^{2+}$ ions had more strong tetrahedral preference than $Mg^{2+}$ ions. 2) As the gradual substitution of $Ti^{4+}$ ions for $Sn^{4+}$ ions in $NiO\cdot{MgO}\cdot{SnO}_2$ system, the spinels formed well and was nearly not changed in the hue. 3) The results of glaze test. (1) As the gradual substitution of $Ni^{2+}$ ions for $Zn^{2+}$ ions, the color changed from dull white to graish broun gradually in calcium-zinc glaze and calcium glaze, and from white to beige in tile glaze. (2) As the gradual substitution of $Ti^{4+}$ ions for $Sn^{4+}$ ions in $NiO-ZnO-SnO_2-TiO_2$ system, the color was become dull generally and was not change in tile glaze.

• 한국재료학회지
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• 제8권4호
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• pp.312-316
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• 1998

ZnO와 $SnO_2$에$ TiO_2$를 첨가시킨 $ZnO-TiO_2$와$SnO_2$-$TiO_2$세라믹 복합체를 제작하여 1000ppm 일산화탄소에 대한 감응특성을 조사하였다. 상분석을 위해서 X-선 회절 분석을 하였고, 전자 주사 현미경을 이용해서 시편 파단면의 미세구조를 관찰했다. 일산화탄소 감도는 건조공기 분위기에서 측정한 저항($R_{dry air}$ )과 1000ppm 일산화탄소 분위기에서의 저항($R_{co}$ )을 측정하여 각각의 저항값의 비로 정의하였다. $TiO_{2}$첨가에 의한 ZnO의 일산화탄소 감도의 변화는 ZT5의 경우 최대 감도가 약 1.7배 감소하였고, $TiO _{2}$첨가에 의한 $SnO_{2}$의 일산화탄소 최대 감도는 약 2.5배 증가함으로써 비교적 $ZnO-TiO_2$배 증가함으로써 비교적 $ZnO-TiO_2$배 증가함으로써 비교적 $ZnO-TiO_2$복합체 보다는 $SnO_2$- $TiO_2$복합체의 일산화탄소 감응특성이 우수했다.

• 청정기술
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• 제16권1호
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• pp.46-50
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• 2010

본 연구에서는 새집증후군의 대표적 원인물질인 수중 부유 톨루엔을 효율적으로 분해하기 위해 Sn원소를 티타니아 골격에 삽입하여 고온 고압에서 용매열(solvothermal)법으로 Sn-$TiO_2$ 나노 광촉매를 제조하였다. 제조한 Sn-$TiO_2$의 물리적 특성은 X-ray 회절분석법, 투과전자현미경, 주사전자현미경, 자외선-가시선 분광 광도계를 통하여 분석하였다. Sn-$TiO_2$의 광촉매 활성은 수중 부유 톨루엔 광분해반응을 통해 확인하였고, 반응 전후의 수중 부유 톨루엔 농도는 자외선-가시선 분광광도계를 이용하여 측정하였다. 수중 부유 톨루엔 광분해반응 결과 0.01 mol% Sn-$TiO_2$촉매가 순수 $TiO_2$ (anatase) 광촉매보다 활성이 향상되었으며. 500ppm 수중 부유 톨루엔은 300분 이내에 완전히 분해되었다.

• 한국결정성장학회지
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• 제8권3호
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• pp.487-492
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• 1998

ICP(Inductively Coupled Plasma)를 열원으로 출발용액의 농도변화 및 $TiO_2$ 첨가로 $SnO_2$와 $(Sn,Ti)O_2$미분말을 합성하였으며 SnO2 박막을 제조하였다. 각각 합성된 $SnO_2$ 미분말은 모두 tetragonal의 rutile형으로서 입자들의 평균입경은 30nm로 매우 미세하였으며, 좁은 입도분포를 나타내었다. $TiO_2$를 첨가하였을 경우 $SnO_2-TiO_2$ 미분말은 고용체를 이루었으며, 첨가량이 증가함에 따라 결정성은 감소하였다. ICP tail flame으로 fused quartz 기판을 가열하여 (101)면을 주 peak로 하는 $SnO_2$ 박막을 얻었다.

• 한국재료학회지
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• 제2권3호
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• pp.163-171
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• 1992

$TiO_2$가 5-50wt%첨가된 $SnO_2/TiO_2$ 후막형 감습소자를 스크린 프린팅 법을 이용하여 제조 하였다. 소자의 표면결정구조를 XRD, SEM 그리고 FTIR로 조사하였으며, 전기적 특성에 의한 후막소자의 감습특성을 측정하였다. $SnO_2/TiO_2$ 후막은 $TiO_2$ 결정상 보다 주로$(SnO^2){\cdot}6T$ 결정상으로 나타났으며, $1300^{\circ}C$에서 소결된 후막소자의 평균입경은 $2.0{\mu}m$이었다. 또한 $1300^{\circ}C$에서 소결된 10wt% $TiO_2$가 첨가된 $SnO_2/TiO_2$ 후막소자는 상대습도 20-90%에서 높은 감습특성을 나타내었다.

• Korean Chemical Engineering Research
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• 제53권6호
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• pp.776-782
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• 2015

$TiO_2$ 나노입자의 광촉매 반응을 억제하기 위해 평균 직경 3~5 nm의 $TiO_2-SnO_2$ 나노입자가 titanium tetraisopropoxide(TTIP)와 tin chloride의 가수분해 반응에 의해 합성되었다. 생성된 $TiO_2-SnO_2$ 나노입자를 졸-겔법에 의해 3-glycidoxypropyl trimethoxysilane(GPTMS)과 반응시킴에 의해 유-무기 혼성 코팅 용액이 제조되었다. 그 후 코팅 용액을 기재인 polycarbonate(PC) 시트 위에 스핀 코팅시키고, $120^{\circ}C$에서 열경화 시켜 고굴절률 하드코팅 도막이 제조되었다. $TiO_2-SnO_2$ 나노입자로부터의 코팅 도막은 $TiO_2$ 나노입자로부터 얻어진 코팅 도막의 2H에 비해 증가된 3H의 연필경도를 보였다. 또한 $TiO_2-SnO_2$ 나노입자로부터의 코팅 도막의 굴절률은 Sn/Ti 몰 비가 0에서 0.5로 증가함에 따라 633 nm 파장에서 1.543으로부터 1.623으로 향상되었다.

• 한국세라믹학회지
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• 제13권2호
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• pp.24-30
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• 1976

To observe the influence of tetrahedral and octahedral preference of cations of Ni2+, Ti4+ upon the formation and the color development of the MgO-SnO2 spinel containing Ni2+ and Ti4+ ions, the gradual substitution of Ni2+ ions for Mg2+ ions and of Ti4+ ions for Sn4+ ions of the spinel in NiO-MgO-SnO2-TiO2 system was carried out. On samples prepared by calcining the oxide and basic carbonate mixtures at 130$0^{\circ}C$ for 1.5 hour, the X-ray analysis, measurement of reflectance and the test of their stability as a glaze pigment were also carried out. On samples prepared by calcining the oxide and basic carbonate mixtures at 130$0^{\circ}C$ for 1.5 hour, the X-ray analysis, measurement of reflectance and the test of their stabiality as a glaze pigment were also carried out. The results are summarized as follows. 1) As increasing the amounts of Ni2+ ions in the xNiO.(2-x)MgO.SnO2 system, spinel was not formed easily, and the mixed-spinel was formed in NiO.MgO.SnO2 of x=1 but the spinels was not formed completely in the range of x>1.5 2) The spinels was not more formed in NiO-MgO-TiO2 system than NiO-MgO-SnO2 system. Therefore, Ti4+ ions have strong octahedral preference than Sn4+ ions. The color changed the yellow region little. The mixed-spinel or non-spinel was formed easily NiO.TiO2, MgO.TiO2 of illmenite type as the gradual substitution of Ti4+ ions for Sn4+ ions. 3) The results of glaze test. The color changed from white through graish brown to brown as the gradual substitution of Ni2+ ions for Mg2+ ions in calcium-zinc glaze and calcium glaze, and from white through light yellowish beige to dull beige in tile glaze. Also, the color did not change generally as the gradual substitution of Ti4+ ions for Sn4+ ions in NiO-MgO-SnO2-TiO2 system.