• Title/Summary/Keyword: $SO_3$ decomposition

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Activation of persulfate by UV and Fe2+ for the defluorination of perfluorooctanoic acid

  • Song, Zhou;Tang, Heqing;Wang, Nan;Wang, Xiaobo;Zhu, Lihua
    • Advances in environmental research
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    • v.3 no.3
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    • pp.185-197
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    • 2014
  • Efficient defluorination of perfluorooctanoic acid (PFOA) was achieved by integrating UV irradiation and $Fe^{2+}$ activation of persulfate ($S_2O{_8}^{2-}$). It was found that the UV-$Fe^{2+}$, $Fe^{2+}-S_2O{_8}^{2-}$, and UV-$S_2O{_8}^{2-}$ processes caused defluorination efficiency of 6.4%, 1.6% and 23.2% for PFOA at pH 5.0 within 5 h, respectively, but a combined system of UV-$Fe^{2+}-S_2O{_8}^{2-}$ dramatically promoted the defluorination efficiency up to 63.3%. The beneficial synergistic behavior between $Fe^{2+}-S_2O{_8}^{2-}$ and UV-$S_2O{_8}^{2-}$ was demonstrated to be dependent on $Fe^{2+}$ dosage, initial $S_2O{_8}^{2-}$ concentration, and solution pH. The decomposition of PFOA resulted in generation of shorter-chain perfluorinated carboxylic acids (PFCAs), formic acid and fluoride ions. The generated PFCAs intermediates could be further defluorinated by adding supplementary $Fe^{2+}$ and, $S_2O{_8}^{2-}$ and re-adjusting solution pH in later reaction stage. The much enhanced PFOA defluorination in the UV-$Fe^{2+}-S_2O{_8}^{2-}$ system was attributed to the fact that the simultaneous employment of UV light and $Fe^{2+}$ not only greatly enhanced the activation of $S_2O{_8}^{2-}$ to form strong oxidizing sulfate radicals ($SO{_4}^{\cdot-}$), but also provided an additional decarboxylation pathway caused by electron transfer from PFOA to in situ generated $Fe^{3+}$.

Nitrogen Oxides Removal Characteristics of SNCR-SCR Hybrid System (SNCR-SCR 하이브리드 시스템의 질소산화물 제거 특성)

  • Cha, Jin Sun;Park, Sung Hoon;Jeon, Jong-Ki;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.658-663
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    • 2011
  • The SNCR-SCR (selective non-catalytic reduction-selective catalytic reduction) hybrid system is an economical NOx removal system. In this study, the effect of the operating parameters of the SNCR-SCR hybrid system on NOx removal efficiency was investigated. When the SNCR reactor was operated at a temperature lower than the optimum temperature ($900{\sim}950^{\circ}C$), an additional NO removal is obtained basesd on the utilization of $NH_3$ slip. On the other hand, the SNCR reactor operated above the temperature resulted in no additional NO removal of SCR due to decomposition of $NH_3$. Therefore, the SNCR process should be operated at optimum temperature to obtain high NO removal efficiency and low $NH_3$ slip. Thus, it is important to adjust NSR (normalized stoichiometric ratio) so that $SR_{RES}$ can be maintained at an appropriate level.

Optimal Configuration of the Truss Structures by Using Decomposition Method of Three-Phases (3단계(段階) 분할기법(分割技法)에 의한 평면(平面)트러스 구조물(構造物)의 형상(形狀) 최적화(最適化)에 관한 연구(硏究))

  • Lee, Gyu Won;Song, Gi Beom
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.3
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    • pp.39-55
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    • 1992
  • In this research, a Three Level Decomposition technique has been developed for configuration design optimization of truss structures. In the first level, as design variables, behavior variables are used and the strain energy has been treated as the cost function to be maximized so that the truss structure can absorb maximum energy. For design constraint of the optimal design problem, allowable stress, buckling stress, and displacement under multi-loading conditions are considered. In the second level, design problem is formulated using the cross-sectional area as the design variable and the weight of the truss structure as the cost function. As for the design constraint, the equilibrium equation with the optimal displacement obtained in the first level is used. In the third level, the nodal point coordinates of the truss structure are used as coordinating variable and the weight has been taken as the cost function. An advantage of the Three Level Decomposition technique is that the first and second level design problems are simple because they are linear programming problems. Moreover, the method is efficient because it is not necessary to carry out time consuming structural analysis and techniques for sensitivity analysis during the design optimization process. By treating the nodal point coordinates as design variables, the third level becomes unconstrained optimal design problems which is easier to solve. Moreover, by using different convergence criteria at each level of design problem, improved convergence can be obtained. The proposed technique has been tested using four different truss structures to yield almost identical optimum designs in the literature with efficient convergence rate regardless of constraint types and configuration of truss structures.

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Electrochemical Properties of Ti/IrO2/SnO2-Sb-Ni Electrode for Water Treatment (수처리용 Ti/IrO2/SnO2-Sb-Ni 전극의 전기화학적 특성평가)

  • Yang, So Young
    • Journal of Environmental Science International
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    • v.29 no.10
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    • pp.943-949
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    • 2020
  • In this work, we prepared a heterojunction anode with a surface layer of SnO2-Sb-Ni (SSN) on a Ti/IrO2 electrode by thermal decomposition to improve the electrochemical activity of the Ti/IrO2 electrode. The Ti/IrO2-SSN electrode showed significantly improved electrochemical activity compared with Ti/IrO2. For the 0.1 M NaCl and 0.1 M Na2SO4 electrolytes, the onset potential of the Ti/IrO2-SSN electrode shifted in the positive direction by 0.1 VSCE and 0.4 VSCE, respectively. In 2.0-2.5 V voltages, the concentration in Ti/IrO2-SSN was 2.59-214.6 mg/L Cl2, and Ti/IrO2 was 0.55-49.21 mg/L Cl2. Moreover, the generation of the reactive chlorine species and degradation of Eosin-Y increased by 3.79-7.60 times and 1.06-2.15 times compared with that of Ti/IrO2. Among these voltages, the generation of the reactive chlorine species and degradation of Eosin-Y were the most improved at 2.25 V. Accordingly, in the Ti/IrO2-SSN electrode, it can be assumed that the competitive reaction between chlorine ion oxidation and water oxidation is minimized at an applied voltage of 2.25V.

Preparation and Photocatalytic Characteristics of $TiO_2$ by Anodic Oxidation Process (양극산화법에 의한 광촉매용 $TiO_2$제조 및 특성)

  • Jang, Jae-Myeong;Kim, Seong-Gap;O, Han-Jun;Lee, Jong-Ho;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.61-66
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    • 2001
  • $TiO_2$films for photocatalytic reaction were synthesized by anodizing process. The photocatalytic efficiencies of anodized $TiO_2$were evaluated by the rate of decomposition of aniline blue. The properties of photocatalysis on anodic $TiO_2$films have been observed, but the efficiencies of photocatalytic reaction depended on the conditions of films formation. The microstructure of the anodic film formed in $H_2SO_4$ solution differed from that of $TiO_2$films formed in $H_2SO_4+H_3PO_4$ solution. It has been shown that the appropriate applied-voltage for anodizing of titanium for photocatalysis was 180V in both aqueous solutions.

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A Comprehensive Survey of Lightweight Neural Networks for Face Recognition (얼굴 인식을 위한 경량 인공 신경망 연구 조사)

  • Yongli Zhang;Jaekyung Yang
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.46 no.1
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    • pp.55-67
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    • 2023
  • Lightweight face recognition models, as one of the most popular and long-standing topics in the field of computer vision, has achieved vigorous development and has been widely used in many real-world applications due to fewer number of parameters, lower floating-point operations, and smaller model size. However, few surveys reviewed lightweight models and reimplemented these lightweight models by using the same calculating resource and training dataset. In this survey article, we present a comprehensive review about the recent research advances on the end-to-end efficient lightweight face recognition models and reimplement several of the most popular models. To start with, we introduce the overview of face recognition with lightweight models. Then, based on the construction of models, we categorize the lightweight models into: (1) artificially designing lightweight FR models, (2) pruned models to face recognition, (3) efficient automatic neural network architecture design based on neural architecture searching, (4) Knowledge distillation and (5) low-rank decomposition. As an example, we also introduce the SqueezeFaceNet and EfficientFaceNet by pruning SqueezeNet and EfficientNet. Additionally, we reimplement and present a detailed performance comparison of different lightweight models on the nine different test benchmarks. At last, the challenges and future works are provided. There are three main contributions in our survey: firstly, the categorized lightweight models can be conveniently identified so that we can explore new lightweight models for face recognition; secondly, the comprehensive performance comparisons are carried out so that ones can choose models when a state-of-the-art end-to-end face recognition system is deployed on mobile devices; thirdly, the challenges and future trends are stated to inspire our future works.

A study on VFAs recovery from food waste for exterior carbon source of denitrification (탈질화의 외부 탄소원 제공을 위한 음식폐기물의 유기산발효)

  • 장성호;조한진;손영일
    • Journal of environmental and Sanitary engineering
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    • v.15 no.3
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    • pp.15-23
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    • 2000
  • This study's purpose is the investigating the created liquid post-acid fermentation of usability of denitrification as exterior carbon sources by loading capacity of Organic matters. The time of acid fermentation of food waste, the slower loading capacity of organic matter, the faster decomposition fate, but the density of generation $VFA_S$ was weak and, $SBOD_5$ : ST-N rate and $SBOD_5/SCOD_{Cr}$ rate was low. Between TS and VS, VS was decreased to 6th day rast, and then was decreased slowly. Two days after stating the experiments, $SCOD_{Cr}$, $SBOD_5$, STOC and $VFA_S$ was decreased or increased slowly, and then increased fast. And after showing the highest density, it was tended to decreased fast. About 5 days after, because about 5 days later $CH_4$ bacteria activity due to the accumulation of $VFA_S$ was limited, $CH_4$ density was weak. When highest density in the acquisition of VFA, $R_1$ was $10,120mg/{\ell}$, $R_2$ was $11,380mg/{\ell}$, $R_3$was $13,720mg/{\ell}$. So $R_3$ only cut was highest generation. At the time of $SBOD_5$ with the highest density, at $SBOD_5$ : ST-N ratio, $R_1$ was 243:1, $R_2$ was 278:1, $R_3$ was 293:1. All of these were high $SBOD_5$ : ST-N ratios. And $R_3$ was the highest. After studying $SBOD_5$ : ST-N ratio and $SBCD_5/SCOD_{Cr}$ ratio, as a carbon source of biological denitrification it was profitable composition ratio.

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High Temperature Desulfurization over ZnO-Fe2O3 Mixed Metal Oxide Sorbent (ZnO-Fe2O3 복합금속 산화물을 이용한 고온에서의 황화수소 제거에 관한 연구)

  • Lee, Jae-Bok;Lee, Young-Soo;Yoo, Kyong-Ok
    • Journal of Environmental Health Sciences
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    • v.20 no.1
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    • pp.62-67
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    • 1994
  • Introduction : Recently, water and environmental pollution becomes serious social problem and high technology makes this pollution accelerate. Hydrogen sulfide, the main subject of our research, is one of the most dangerous air pollutant like SO$_x$ and NO$_x$. The major contaminant in coal gasification is H$_2$S, which is very toxic, hazardous and extremely corrosive. Therefore, control of hydrogen sulfide to a safe level is essential. Although commercial desulfurization process called liquid scrubbing is effective for removal of H$_2$S, it has drawbacks, the loss of sensible heat of the gas and costly wastewater treatment. Many investigations are carried out about high-temperature removal ol H$_2$S in hot coal-derived gas using metal oxide or mixed metal qxide sorbents. It was reported that ZnO was very effective sorbent for H2S removal, but it has big flaw to vaporize elemental zinc above 600\ulcorner \ulcorner As alternative, metal oxides such as CaO, $Fe_2O_3$, TiO$_2$ and CuO were added to ZnO. Especially, different results are reported for $Fe_2O_3$ additive. Tamhankar et al. reported SiO$_2$ with 45 wt% $Fe_2O_3$ sorbent is favorable for removal of H$_2$S and regeneration.

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Evaluation of Tracking Performance: Focusing on Improvement of Aiming Ability for Individual Weapon (개인화기 조준 능력 향상 관점에서의 추적 기법의 성능평가)

  • Kim, Sang Hoon;Yun, Il Dong
    • Journal of Broadcast Engineering
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    • v.18 no.3
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    • pp.481-490
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    • 2013
  • In this paper, an investigation of weapon tracking performance is shown in regard to improving individual weapon performance of aiming objects. On the battlefield, a battle can last only a few hours, sometimes it can last several days until finished. In these long-lasting combats, a wide variety of factors will gradually lower the visual ability of soldiers. The experiments were focusing on enhancing the degraded aiming performance by applying visual tracking technology to roof mounted sights so as to track the movement of troops automatically. In order to select the optimal algorithm among the latest visual tracking techniques, performance of each algorithm was evaluated using the real combat images with characteristics of overlapping problems, camera's mobility, size changes, low contrast images, and illumination changes. The results show that VTD (Visual Tracking Decomposition)[2], IVT (Incremental learning for robust Visual Tracking)[7], and MIL (Multiple Instance Learning)[1] perform the best at accuracy, response speed, and total performance, respectively. The evaluation suggests that the roof mounted sights equipped with visual tracking technology are likely to improve the reduced aiming ability of forces.

The viterbi decoder implementation with efficient structure for real-time Coded Orthogonal Frequency Division Multiplexing (실시간 COFDM시스템을 위한 효율적인 구조를 갖는 비터비 디코더 설계)

  • Hwang Jong-Hee;Lee Seung-Yerl;Kim Dong-Sun;Chung Duck-Jin
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.42 no.2 s.332
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    • pp.61-74
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    • 2005
  • Digital Multimedia Broadcasting(DMB) is a reliable multi-service system for reception by mobile and portable receivers. DMB system allows interference-free reception under the conditions of multipath propagation and transmission errors using COFDM modulation scheme, simultaneously, needs powerful channel error's correction ability. Viterbi Decoder for DMB receiver uses punctured convolutional code and needs lots of computations for real-time operation. So, it is desired to design a high speed and low-power hardware scheme for Viterbi decoder. This paper proposes a combined add-compare-select(ACS) and path metric normalization(PMN) unit for computation power. The proposed PMN architecture reduces the problem of the critical path by applying fixed value for selection algorithm due to the comparison tree which has a weak point from structure with the high-speed operation. The proposed ACS uses the decomposition and the pre-computation technique for reducing the complicated degree of the adder, the comparator and multiplexer. According to a simulation result, reduction of area $3.78\%$, power consumption $12.22\%$, maximum gate delay $23.80\%$ occurred from punctured viterbi decoder for DMB system.