• Title/Summary/Keyword: $N_2O/O_2$

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Nitrous oxide and carbon dioxide efflux of cropland soil during fallow season (휴경기간 녹비재배 농경지 토양에서 아산화질소 및 이산화탄소 배출특성)

  • Lee, Sun-Il;Kim, Gun-Yeob;Choi, Eun-Jung;Lee, Jong-Sik;Jeong, Hyun-Cheol
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.4
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    • pp.386-396
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    • 2018
  • Cropland is sources of atmospheric nitrous oxide ($N_2O$) and carbon dioxide ($CO_2$). However, the contribution of the fallow season to emission of these gases has rarely been determined. In this study, a field experiment encompassing three treatments was conducted to determine efflux of $N_2O$ and $CO_2$ in cropland during fallow season. The treatments were hairy vetch (H.V.), rye and control (Con.). The H.V. and rye were sown in middle October and early November, respectively. The soil $N_2O$ efflux among all three treatments in the fallow season (November-April) were $0.014-2.956mg\;N_2O\;m^{-2}{\cdot}d^{-1}$. The cumulative $N_2O$ emissions were $104.4mg\;N_2O\;m^{-2}$ for Con., $85.8mg\;N_2O\;m^{-2}$ for H.V. and $85.0mg\;N_2O\;m^{-2}$ for Rye during the fallow season. The highest $N_2O$ emissions occurred in Con., while H.V. and Rye emissions were similar. Cumulative $CO_2$ emissions were $293.1g\;CO_2\;m^{-2}$ for Con., $242.2g\;CO_2\;m^{-2}$ for H.V., $275.2g\;CO_2\;m^{-2}$ for Rye during fallow season. This study showed that soil $N_2O$ and $CO_2$ average daily emission during fallow season were 28.3% and 27.4%, respectively of the growing season. Our results indicate that $CO_2$ and $N_2O$ emissions from agricultural systems continue throughout the fallow season.

Metal Plasma-Etching Damages of NMOSFETs with Pure and $N{_2}O$ Gate Oxides (게이트 산화막에 따른 nMOSFET의 금속 플라즈마 피해)

  • Jae-Seong Yoon;Chang-Wu Hur
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.2
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    • pp.471-475
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    • 1999
  • The metal plasma-etch damage immunity of nMOSFET with $N{_2}O$ gate oxide is found to be improved comparing to that with regular pure oxide of similar thickness. With increasing the antenna ratio (AR), the characteristics of nMOSFETs with $N{_2}O$ oxide shows tighter initial distribution and smaller degradation under constant field stress, which is explained by the effect of the nitrogen at the substrate $Si/SiO_2$ interface. Also, if $N{_2}O$ gate oxide is used, the maximum allowable size of metal AAR and PAR may be increased to the much larger values. These improvements of nMOSFETs with $N{_2}O$ gate oxide are attributed to the effect of the interface hardness improved by the nitrogen included at the substrate-Si/$N{_2}O$-oxide interface.

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The Synthesis of Sodium Titanate by the Ion Exchange of H+/Na+ from Hydrous Titanium Dioxide and its Phase Transition (Hydrous Titanium Dioxide로부터 H+/Na+의 이온교환에 의한 티탄산나트륨의 합성 및 성전이)

  • Lee, Jin-Sik;Song, Yon-Ho;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.585-590
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    • 1998
  • Fibrous $Na_xTi_nO_{2n+1}$ whisker was prepared by $H^+/Na^+$ ion-exchange on layered hydrous titanium dioxide ($H_2Ti_4O_9{\cdot}nH_2O$). The ion-exchange reaction was proceeded at 0.5~2.0 M NaOH solution. In the ion-exchange at 2.0 M NaOH solution, 73% of sodium was exchanged and the prepared $Na_xTi_nO_{2n+1}$ whisker was a fibrous crystal of about $10{\sim}20{\mu}m$ of length and about $0.7{\mu}m$ of diameter. The phase transition of the ion-exchange phases identified by the thermal analysis. The result showed that the $Na_xTi_nO_{2n+1}$ whisker was decomposed into $Na_2Ti_6O_{13}$ and $TiO_2$ in the temperature of $200{\sim}600^{\circ}C$.

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Effect of Zinc Vacancy on Carrier Concentrations of Nonstoichiometric ZnO

  • Kim, Eun-Dong;Bahng, Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05b
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    • pp.17-21
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    • 2001
  • We proposed that concentrations of cartier electron as well as ionized donor defects in nonstoichiometric ZnO are proportional to $P^{-1/2}_{O_2}$, whenever they ionizes singly or doubly, by employing the Fermi-Dirac (FD) statistics for ionization of the native thermal defects $Zn_i$ and $V_o$. The effect of acceptor defect, zinc vacancy $V_{Zn}$made by the Frenkel and Schottky disorder reactions, on carrier concentrations was discussed. By application of the FD statistics law to their ionization while the formation of defects is assumed governed by the mass-action law, the calculation results indicate; 1. ZnO shows n-type conductivity with $N_D>$N_A$ and majority concentration of $n{\propto}\;P^{-1/2}_{O_2}$ in a range of $P_{O_2}$, lower than a critical value. 2. As the concentration of acceptor $V_{Zn}$ increases proportional to $P^{1/2}_{O_{2}}$, ZnO made at extremely high $P_{O_{2}}$, can have p-type conductivity with majority concentration of p ${\propto}\;P^{-1/2}_{O_{2}}$. One may not, however, obtain p-type ZnO if the pressure for $N_{D}<$N_{A}$ is too high.

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Mechanical Milling of Lithium with Metal Oxide and its Reactivity with Gases

  • Yokoi, Tomomichi;Yamasue, Eiji;Okumura, Hideyuki;Ishihara, Keiichi N.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.959-960
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    • 2006
  • Li reacts with $N_2$ at room temperature. In order to activate Li, the mechanical milling of Li with stable metal oxide, namely, $Al_2O_3$ and MgO, using a high energy vibrating ball mill was performed. In the case of Li-MgO system, it reacts with $N_2$, but hardly reacts with $O_2$. The reaction with $N_2$ generally produces $Li_3N$, while for some vigorous reactions the $Mg_3N_2$ is produced as the major phases. In the case of $Li-Al_2O_3$ system, reactivities with both $N_2$ and $O_2$ are high. The difference is explained in terms of the reaction mechanism and the Li state.

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Separation of Hydrogen-Nitrogen Gases by PDMS-SiO2·B2O3 Composite Membranes (PDMS-SiO2·B2O3 복합막에 의한 수소-질소 기체 분리)

  • Lee, Suk Ho;Kang, Tae Beom
    • Membrane Journal
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    • v.25 no.2
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    • pp.115-122
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    • 2015
  • $SiO_2{\cdot}B_2O_3$ was prepared by trimethylborate (TMB)/tetraethylorthosilicate (TEOS) mole ratio 0.01 at $800^{\circ}C$. PDMS[poly(dimethysiloxane)]-$SiO_2{\cdot}B_2O_3$ composite membranes were prepared by adding porous $SiO_2{\cdot}B_2O_3$ to PDMS. To investigate the characteristics of PDMS-$SiO_2{\cdot}B_2O_3$ composite membrane, we observed PDMS-$SiO_2{\cdot}B_2O_3$ composite membrane using TG-DTA, FT-IR, BET, X-ray, and SEM. PDMS-$SiO_2{\cdot}B_2O_3$ composite membrane was studied on the permeabilities of $H_2$ and $N_2$ and the selectivity ($H_2/N_2$). Following the results of TG-DTA, BET, X-ray, FT-IR, $SiO_2{\cdot}B_2O_3$ was the amorphous porous $SiO_2{\cdot}B_2O_3$ with $247.6868m^2/g$ surface area and $37.7821{\AA}$ the mean of pore diameter. According to the TGA measurements, the thermal stability of PDMS-$SiO_2{\cdot}B_2O_3$ composite membrane was enhanced by inserting $SiO_2{\cdot}B_2O_3$. SEM observation showed that the size of dispersed $SiO_2{\cdot}B_2O_3$ in the PDMS-$SiO_2{\cdot}B_2O_3$ composite membrane was about $1{\mu}m$. The increasing of $SiO_2{\cdot}B_2O_3$ content in PDMS leaded the following results in the gas permeation experiment: the permeability of both $H_2$ and $N_2$ was increased, and the permeability of $H_2$ was higher than $N_2$, but the selectivity($H_2/N_2$) was decreased.

Preparation and Characterization of N-doped Na2Ti6O13@TiO2 Composites for Visible Light Activity (가시광 활성을 위한 N-doped Na2Ti6O13@TiO2 복합체 제조 및 특성 연구)

  • Duk-Hee, Lee;Kyung-Soo, Park
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.492-498
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    • 2022
  • N-doped Na2Ti6O13@TiO2 (denoted as N-NTO@TiO2) composites are successfully synthesized using a simple two-step process: 1) ball-milling of TiO2 with Na2CO3 followed by heat treatment at 900℃; 2) mixing of the prepared Na2Ti6O13 with titanium isopropoxide and calcining with urea at 500℃. The prepared composites are characterized using XRD, SEM, TEM, FTIR, and BET. The N-NTO@TiO2 composites exhibit well-defined crystalline and anatase TiO2 with exposed {101} facets on the external surface. Moreover, dopant N atoms are uniformly distributed over a relatively large area in the lattice of the composites. Under visible light irradiation, ~51% of the aqueous methylene blue is photodegraded by N-NTO@TiO2 composites, which is higher than the values shown by other samples because of the coupling effects of the hybridization of NTO and TiO2, N-doping, and presence of anatase TiO2 with exposed {101} facets.

A syudy on electrochemical charcteristic of $Li_{1-x}Mn_{2}O_{4}$(0$\leq$x$\leq$0.075) ($Li_{1-x}Mn_{2}O_{4}$(0$\leq$x$\leq$0.075)의 전기화학적 특성연구)

  • 박종광;고건문;김민기;이남재;임석진;한병성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.444-447
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    • 2000
  • The spinel L $i_{1-x}$ M $n_2$ $O_4$has been synthesized by the solid-state reaction. L $i_{l-x}$M $n_2$ $O_4$which includes a mixture of LiOH . $H_2O$ and Mn $O_2$prepared by preliminary heating at 35$0^{\circ}C$ for 12hr. L $i_{l-x}$M $n_2$ $O_4$fired at temperature range from 75$0^{\circ}C$ for 48hr. The structure and the electrochemical characteristics of spinel to L $i_{1-x}$ M $n_2$ $O_4$which is fabricated by changing sintering condition from starting materials are investigated. The cyclic voltammetric measurement was performed using 3 electrode cells. Electrode specific capacity and cycle life behavior were tested in a 3.0~4.2V range at a constant current density of 0.45mA/c $m^2$. To improve the cycle performance of spinel L $i_{l-x}$M $n_2$ $O_4$as the cathode of 4V class lithium secondary batteries, spinel phases L $i_{1-x}$ M $n_2$ $O_4$were Prepared at various lithium. The results showed that discharge capacity of L $i_{l-x}$M $n_2$ $O_4$varied at lithium quantity decrease with increasing lithium add quantity. The discharge capacities of L $i_{0.925}$M $n_2$ $O_4$and LiM $n_2$ $O_4$revealed 108 and 117mAh/g, respectively.spectively.y.

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Space-economical rank and select of two dimensional bit strings (2차원 비트스트링의 공간 효율적 rank와 select)

  • Kim, Tae-Seong;Na, Joong-Chae
    • Proceedings of the Korean Information Science Society Conference
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    • 2012.06a
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    • pp.385-387
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    • 2012
  • Succinct 표현은 n개의 이산 객체를 정수 값으로 표현하는 대신 이진화하여 표현하는 방법으로 o(n) bit만을 사용하는 공간 효율적인 방법이다. Succinct 표현을 위한 1차원 비트스트링은 이산 객체의 저장 위치에 접근하기 위해서 rank와 select 함수를 필요로 하며, 다양한 연구들에 의해 현재 rank와 select 함수는 o(n) 비트를 사용하여 O(1) 시간에 수행되고, 실용적인 구현이 가능하다. 또한, 2차원 비트 스트링에 대한 연구도 진행되어, 현재 O($n^2$) bit를 사용하여 O(logn) 시간에 rank를, O($log^2n$) 시간에 select를 수행할 수 있다. 본 논문에서는 2차원 비트스트링 상에서의 rank 및 select 함수를 새롭게 정의하고 o($n^2$) 비트만을 사용하여 O(logn) 시간에 rank 질의를, 그리고 O($log^2n$)시간에 select 질의를 수행할 수 있는 방법을 제안한다.

Design and Fabrication of Sputter Coating System for Ophthalmic Lens (안경렌즈코팅용 소형 Sputter Coating System 설계 및 제작에 관한 연구)

  • Park, Moonchan;Jung, Boo Young;Kim, Eung Sun;Lee, Jong Geun;Joo, Kyung Bok;Moon, Hee Sung
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.1
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    • pp.53-58
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    • 2008
  • Purpose: To design and fabricate the small sputter coating system for the Ophthalmic lens. Methods: The design of sputter target was done using macleod program for AR coating and mirror coating of Ophthalmic lens with Si target and then the sputter system was fabricated. Results: The optimum condition of AR coating with Si target was [air|$SiO_2$(81.3)|$Si_3N_4$ (102)|$SiO_2$(19.21)|$Si_3N_4$(15.95)|$SiO_2$(102)|glass], for blue color mirror coating [air|$SiO_2$(56.61)|$Si_3N_4$(135.86)|$SiO_2$(67.64)|$Si_3N_4$(55.4)|$SiO_2$(53.53)|$Si_3N_4$(51.28)|glass], for green color coating [air|$SiO_2$(66.2)|$Si_3N_4$(22.76)|$SiO_2$(56.58)|$Si_3N_4$(140.35)|$SiO_2$(152.35)|$Si_3N_4$(70.16)|$SiO_2$(121.87)|glass], for gold color [air|$SiO_2$(83.59)|$Si_3N_4$(144.86)|$SiO_2$(11.82)|$Si_3N_4$(129.93)|$SiO_2$(90.01)|$Si_3N_4$(88.37)|glass]. Conclusions: In the fabrication of sputtering coating apparatus, Dual cathode with same Ti target were coated at the same time on both sides of Ophthalmic lens to lessen the time of coating on Ophthalmic Lens and save the cost of the lens. The distance of target-substrate of cathode was variable from 12.5 cm to 20 cm. Turbo pump was used to take the whole coating process about 15 min. instead of diffusion pump. The lens holder was made to coat 2 pairs lens every coating and was rotated to get the uniformity of thin film.

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