• Title/Summary/Keyword: $MgO-P_2O_5$

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Degradation of p-nitrophenol by Gamma Irradiation

  • Lee, O Mi;Kim, Tae-Hun;Yu, Seungho;Jung, In-ha;Lee, Myunjoo
    • Journal of Radiation Industry
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    • v.5 no.4
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    • pp.353-357
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    • 2011
  • Degradation of p-nitrophenol has been carried out using only gamma irradiation or gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$. Effects of different operating parameters such as initial concentration ($50mg\;l^{-1}$, $100mg\;l^{-1}$, $200mg\;l^{-1}$, $300mg\;l^{-1}$, $400mg\;l^{-1}$, $500mg\;l^{-1}$ and $600mg\;l^{-1}$) on the extent of degradation has been investigated. At 5 kGy, $50mg\;l^{-1}$ p-nitrophenol was completely degraded, and the radiolytic degradation of p-nitrophenol was described by the pseudo-first-order kinetic model. The combination of gamma irradiation with $H_2O_2$ or $Na_2S_2O_8$ leads to an enhanced effect, which remarkably increased the degradation efficiency of p-nitrophenol and TOC removal. However, at high $H_2O_2$ concentration, the efficacy of p-nitrophenol degradation is reduced because ${\cdot}OH$ radicals are scavenged by $H_2O_2$ and $Na_2S_2O_8$.

Effect of MgO-P2O5 Sintering Additive on Microstructure of Sintered Hydroxyapatite (HAp) Bodies and Their In-Vitro Study

  • Lee, Byong-Taek;Youn, Hyeong-Chul;Lee, Chi-Woo;Song, Ho-Yeon
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.100-106
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    • 2007
  • The effects of $MgO-P_2O_5$ based sintering additive on the microstructure and material and biological properties of hydroxyapatite $(HAp,\;Ca_{10}(PO_4)_6(OH)_2)$ ceramic were investigated using XRD, SEM and TEM techniques. The $MgO-P_2O_5$ sintering additive improved the material properties and increased the grain size in the sintered HAp bodies. As the content of sintering additive increased over 4 wt%, a small amount of the HAp phase was decomposed and transformed to ${\beta}-TCP$. In the 2 wt% $MgO-P_2O_5$ content HAp sintered body, the maximum values of density and hardness were respectively about 3.10 gm/cc and 657 HV. However, the maximum fracture toughness in the HAp body containing 8 wt% $MgO-P_{2}O_{5}$ was about $1.02MPa{\cdot}m^{1/2}$ due to the crack deflection effect. Human osteoblast like MG-63 cells and osteoclast like raw 264.7 cells were well grown and fully covered all of the HAp sintered bodies. The osteoblast cells were grown with spindle-shaped and the osteoclast cells had a grape-like round shape.

Studies on the Citric Acid Fermentation with Fungi (Part IV) Citric Acid Fermentation from Soluble Starch and Molasses (사상균에 의한 구연산발효에 관한 연구 (제IV보) 가용성전분 및 당밀에 의한 구연산발효)

  • 성낙계;김명찬;심기화;정덕화
    • Microbiology and Biotechnology Letters
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    • v.8 no.3
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    • pp.199-206
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    • 1980
  • Some experiments on the citric acid production were carried out from soluble starch and molasses as raw materials. When soluble starch was used as substrate for the fermentation of citric acid by the strain M-80 which had assimilating ability of soluble starch in surface culture, the optimal culture media was 120g of soluble starch, 3.0g of (N $H_4$)$_2$S $O_4$, 2.0g of K $H_2$P $O_4$, 0.2g of MgS $O_4$.7$H_2O$, 1.5mg of F $e^{++}$, 1mg of Z $n^{++}$ and 20ml of methanol were added to 1 liter and optimal pH was 5.5. In about 8 days 61.8mg/ml of citric acid was produced. When treated molasses with potassium ferrocyanide was used as substrate for the fermentation of citric acid by the strain of M-315, the optimal condition in surface culture was 250g of molasses, 0.3g of N $H_4$N $O_3$, 0.05g of K $H_2$P $O_4$, 0.01g of MgS $O_4$.7$H_2O$, 0.5g of Potassium ferrocyanide and 30ml of methanol were added to 1.0 liter. On the other hand, the optimal condition in submersed culture was 250g of molasses, 0.3g of N $H_4$N $O_3$, 0.1g of K $H_2$P $O_4$, 0.01g of MgS $O_4$.7$H_2O$, 0.5g of potassium ferrocyanide, and 30m1 of methanol were added to 1.0 liter and optimal pH was all 5.0. After 9 days culture, 69.4mg/ ml, 39.6mg/ml of citric acid were separately produced in surface and submerged culture media.dia.

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Studies on the Chemical Contents for Soybean Breeding I. Phenotypic and Genotypic Correlations between Various Chemical Contents (대두의 성분육종에 관한 연구 제2보 화학성분의 표현형상관과 유전상관)

  • Kwon-Yawl Chang
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.1
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    • pp.7-10
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    • 1977
  • Positive correlations were observed between protein content and $\textrm{K}_2\textrm{O}$, protein and ash, protein and moisture content, and $\textrm{P}_2\textrm{O}_5$ and ash in soybean seeds. On the contrary, negative correlations were observed between fat and CaO, fat and ash, $\textrm{K}_2\textrm{O}$ and moisture content, CaO and moisture content, and MgO and ash content in soybean seeds.

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Effects of Nutritional Sources on Degradation of Polychlorinated Biphenyls (PCBs) by Pseudomonas sp. P2 (Pseudomonas sp. P2에 의한 Polychlorinated Biphenyls(PCBs) 분해에 대한 영양원의 영향)

  • 최상기;금정호
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.611-617
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    • 1996
  • The effects of nutritional sources on growth of Pseudomonas sp. P2 were investigated in medium containing biphentyl as a carbon source. To determine characterization of Pseudomonas sp. P2, the incubation time was determined to 100 h of the log phase in the growth curve. The optimal compositions for the growth of Pseudomonas sp. P2 degrading polychlorinated biphenyls (PCBs) were 1000 mg/L $NH_4NO_3$, 1000mg/L KH_2PO_4$, 100mg/L MgSO_4$.$7H_2O$, 30mg/L $CaCl_2$.$2H_2O$, 200mg/L NaCl, and 10mg/L $FeSO_4$.$7H_2O$. Pseudomonas sp. P2 showed the degradability of 59.3%, 57.6%, 51.4%, and 48.7% at 500mg/L, 1000mg/L, 1500mg/L, and 2000mg/L of the PCBs within insulating oil after 100 h incubation under the optimum conditions, respectively.

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Effects of Addition of Inorganic Germanium, GeO2 on the Growth, Germanium and Saponin Contents of Ginseng Adventitious Root in Submerged Culture (무기 게르마늄 GeO2의 첨가가 액체 배양 중 인삼 부정근의 생장과 게르마늄 및 사포닌 함량에 미치는 영향)

  • Chang, Eun-Jung;Oh, Hoon-Il
    • Journal of Ginseng Research
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    • v.29 no.3
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    • pp.145-151
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    • 2005
  • This study was carried out to determine the optimal submerged culture conditions for production of ginseng root containing germanium using plant tissue culture technology. The ginseng (Panx ginseng C.A. Meyer) .cot induced by plant growth regulators of 0.5 mg/L BAP and 3.0 mg/L NAA was cultured on SH medium and the effects of various $GeO_2$ concentrations, addition time of $GeO_2$ and pH of medium were investigated on fresh weight, saponin production and germanium accumulation in ginseng root. Optimal $GeO_2$ concentrations for fresh weight, saponin and germanium content were 10, 0 and 110ppm, respectively. When $GeO_2$ was added after 2 weeks cultivation of ginseng root, germanium content was higher than that of adding $GeO_2$ at the initial cultivation time, but saponin content and fresh weight were lower. pH 5.5 was found to be the most favorable condition for the growth of ginseng root and germanium accumulation, but saponin production was best at pH 6.0.

Optimal Conditions for the Production of Exopolysaccharide by Marine Microoranism Hahella chejebsis

  • Ko, Sung-Hwan;Lee, Hyun-Sang;Park, Shin hye;Lee, Hong-Kum
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.3
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    • pp.181-185
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    • 2000
  • A marine microorganism, strain 96CJ10356 produced exopolysaccharide, designated as EPS-R. To optimize culmize culture conditions for the production of EPS-R, carbon and nitrogen sources, mineral salts, temperature, and pH were exmined. From this study, STN medium for the production of EPS-R was suggested as follows; sucrose 20g, typtone 10g, NaCl 10g, MgSO45g, CaCl21g, KH2PO4 76mg, K2HPO4 83mg, FeCl2 5mg, MnCl2 1mg, NaMoO4 1mg, and ZnCl2 1mg per liter at pH 7.0. About 9.23g/L of EPS-R was obtained from STN medium after cultivation for 120h at $25^{\circ}C$ in a 5-liter jar fermentor with an aearation rate of 0.17 vvm. Apparent viscosity and flocculation activity of the culture broth were increased with the production of EPS-R and the maximal values were 415 cP and 1400 unit/mL against 0.5% activated carbon, respectively.

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Preparation of $Mg(OH)_2$and MgO from Acid Leaching $Mg^{++}$ Solution (산 침출$Mg^{++}$액으로부터 $Mg(OH)_2$및 MgO 粉末의 製造)

  • 최용각;이종현;원창환;이갑호
    • Resources Recycling
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    • v.10 no.5
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    • pp.16-21
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    • 2001
  • Ultrafine $Mg(OH)l_2$and MgO powders were recovered from the waste solution containing $Mg^{++}$ which was a by-product of SHS (Self-propagating High temperature Synthesis)process. The optimum experimental conditions to prepare $Mg(OH)_2$were 13.0 of pH and 0.7M of $Mg^{++}$ content with addition of 9M of KOH as a pH regulator in acid leaching solution. Complete pre-cipitation of Mg(OH)$_2$from $Mg^{++}$ was realized at that condition. The dehydration reaction of the prepared Mg(OH)$_2$was studied by DSC, and the result was used for calcination process. In order to obtain MgO powder, dried Mg(OH)2 powder was calcined at $400~450^{\circ}C$. Particle size and shape of the prepared $Mg(OH)_2$and MgO powder was similar to those of the commercial powders.

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Ionic Characteristics of the Ground Water for Hydroponics in Kyeongnam Area (경남지역 양액재배용 지하수의 이온 분포특성)

  • 이영한;전성건;황연현;조강희;신원교
    • Journal of Bio-Environment Control
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    • v.7 no.3
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    • pp.246-252
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    • 1998
  • This study was carried out to investigate the quality of ground water for hydroponics in Kyeongnam area in 1995. Water samples were collected and analyzed from 77 wells in green houses throughout Kyeongnam area. The values of several components in well water were as follows ; 7.4 in pH, 0.46dS/m in EC, 0.3mg/L in N $H_{4}$-N, 25.4mg/L in $Ca^{2+}$, 42.6mg/L in C $l^{[-10]}$ and 72.5mg/L in S $O_{4}$$^{2-}$. The pH value showed high positive significance of correlationships with $Ca^{2+}$ and EC. Also, the EC value showed high positive significance with N $a^{+}$, $Ca^{2+}$, S $O_{4}$$^{2-}$, $Mg^{2+}$ and C $l^{[-10]}$ .

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Surface Reaction Products of CP- Ti and Ti-25wt%Pd Castings Used for Dental Application (치과용 티타늄 및 Ti-25wt%Pd 주조체의 표면반응생성물)

  • 정준영;문수;이진형
    • Journal of Biomedical Engineering Research
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    • v.25 no.5
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    • pp.383-389
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    • 2004
  • A commercially pure Ti(CP-Ti) and Ti-25wt%Pd alloy for dental applications were cast into a phosphate-bonded Al$_2$ $O_3$/ $SiO_2$ investment mold and the surface of the casting specimens were investigated by means of SEM/EDS, XRD and XPS. The addition of 25wt%Pd in CP-Ti showed a moderate mold reaction owing to the considerable lowering of melting point. XRD analysis of the investment after burn-out treatment revealed that it consisted essentially of $SiO_2$, Al$_2$ $O_3$, P$_2$O$\_$5/, Mg$_3$(P $O_4$)$_2$, AlP $O_4$, Mg$_2$ $SiO_4$, MgAl$_2$ $O_4$ The mold reaction products were Ti$\_$5/Si$_3$ and Ti $O_2$ in case of CP-Ti casting and Ti $O_2$ and SiO$\_$x/ in case of Ti-25wt% Pd casting.