• Title/Summary/Keyword: $Mg(OH)_2$

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The Effect of Additives on Properties of Sintered $ZrSiO_4$ ($ZrSiO_4$ 소결체의 특성에 미치는 첨가제의 영향에 관한 연구)

  • 박금철;차명진
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.71-75
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    • 1985
  • This study deals with sintering and corrosive behavior of sintered zircons mixed with 5wt% of clay $Cr_2O_3$ $CrO_3-MgO$ aqueous solution and $CrO_3-Mg(OH)_2$ aqueous solution. Measurements were conducted by firing specimens at 135$0^{\circ}C$ 145$0^{\circ}C$ and 155$0^{\circ}C$ 1$650^{\circ}C$ for 3hrs in oxidized and reduced atmospheric conditions. Following results were obtained. 1. Sintered zircon with 5 wt% clay showed that highest compressive strength and the lowest apparent porosity and the other showed less positive result than above specimen in order of zircon with $CrO_3-MgO$ aqueous solution $CrO_3-Mg(OH)_2$ aqueous solution and $Cr_2O_3$. 2. The more firing temperature increased the more its strength improved and porosity decreased and specimen which was fired over 155$0^{\circ}C$ and in reduced atmospheric condition showed better results. 3. Zircon with additives which was fired over 155$0^{\circ}C$ showed the evidence of thermal dissociation but it was not rebonded completely during cooling. 4. Zircon with $CrO_3-MgO$ aqueous solution and $CrO_3-Mg(OH)_2$ aqueous solutiion showed more corrosive resistance than zircon itself and zircon-clay system.

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Corrosion Control in Water Pipes by Adjusting the Corrosivity of Drinking Water : Effect and impact of the Corrosion Inhibitor (수돗물 부식성 제어를 통한 수도관 부식방지 : 부식억제제별 효과와 영향에 대한 분석)

  • Park, Young-Bog;Park, Ju-Hyun;Park, Eun-Hee;Lee, Jin-Suk;Kim, Hyen-Ton;Choi, Young-June;Chung, Hyen-Mi;Huh, Yu-jeong;Choi, In-cheol
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.303-310
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    • 2016
  • The tap water used in Seoul was found to be corrosive. Its corrosivity was effectively reduced by that the additions of alkali agent such as NaOH, $Ca(OH)_2$ and corrosion inhibitor such as $H_3PO_4$. For the corrosion test, carbon steel pipe 50 m long was exposed to the drinking water produced by a pilot plant at $36.5^{\circ}C$, similar to the existing process where it takes about 20 minutes to reduce the initial chlorine content of 0.5 mg/L to 0.05 mg/L. $CO_2$ and $Ca(OH)_2$ was added not only to control the Langelier index (LI) above -1.0 and but also, to increase the duration time of residual chlorine by about 6 times. The persistence effect of residual chlorine was in the order of $H_3PO_4$ > $Ca(OH)_2$ > NaOH. Measurements of weight loss showed that corrosion inhibition was effective in order of $Ca(OH)_2$ > $H_3PO_4$ > NaOH > no addition, where the concentrations of $Ca(OH)_2$ and phosphate were 5 ~ 10 mg/L (as $Ca^{2+}$) and 1 mg/L (as $PO{_4}^{3-}$), respectively.

Free Radical Scavenging Activity of Butanol Fraction from the Fruit of Citrus junos

  • Cho, Eun-Ju;Li, Li;Piao, Xiang-Lan;Lee, Sang-Hyun;Kim, Hyun-Young
    • Preventive Nutrition and Food Science
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    • v.14 no.1
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    • pp.86-89
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    • 2009
  • In this study, we investigated the free radical [1,1-diphenyl-2-picrylhydrazyl (DPPH), hydroxyl radical (${\cdot}OH$) and superoxide anion (${O_2}^-$)] scavenging activity of MeOH extract and 3 fractions of Citrus junos. Of the tested fractions, the BuOH fraction showed the strongest DPPH scavenging activity, showing the $IC_{50}$ values of 63.4 mg/mL. Therefore, we continuously carried out DPPH, ${\cdot}OH$ and ${O_2}^-$ scavenging activity tests of BuOH fraction of Citrus junos. The BuOH fraction of Citrus junos inhibited DPPH radical to 97.5% at a concentration of 1000 mg/mL and the scavenging activities were increased concentration-dependently. In addition, BuOH fraction from Citrus junos also scavenged ${\cdot}OH$ in a concentration dependent manner from 5 to 1000 mg/mL. Furthermore, BuOH fraction showed about 56% ${O_2}^-$-scavengimg activity at 25 mg/mL concentration but, the scavenging activities were not enhanced in a dose dependent manner. The present results suggest that BuOH fraction of Citrus junos would have the protective potential from oxidative stress induced by free radicals.

Antioxidant Activities of the Ethanol Extract of Hamcho (Salicornia herbacea L.) Cake Prepared by Enzymatic Treatment

  • Oh, Ji-Hae;Kim, Eun-Ok;Lee, Sung-Kwon;Woo, Mee-Hee;Choi, Sang-Won
    • Food Science and Biotechnology
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    • v.16 no.1
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    • pp.90-98
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    • 2007
  • The antioxidant activities of water ($H_2O$) and ethanol (EtOH) extracts from hamcho (Salicornia herbacea L.) juice and cake prepared by enzymatic treatments were evaluated by in vitro assays against DPPH, superoxide, and hydroxyl radicals. Among the $H_2O$ and EtOH extracts from five different carbohydrases treated, the EtOH extract from viscozyme-treated hamcho cake had higher yield and phenolic content, and exhibited the strongest radical scavenging activity against DPPH ($IC_{50}=186.91\;{\mu}g/mL$), superoxide ($IC_{50}=87.54\;{\mu}g/mL$), and hydroxyl radicals ($IC_{50}=367.07\;{\mu}g/mL$). Antioxidant assay-guided fractionation and purification of the EtOH extract led to isolation and identification of five phenolic compounds, procatechuic, ferulic and caffeic acids, quercetin, and isorhamnetin. Most of these phenolic compounds exhibited considerable DPPH, superoxide, and hydroxyl radical scavenging activities, and in particular, caffeic and ferulic acids had stronger superoxide and hydroxyl radical scavenging activities than the well-known antioxidant radical scavenger, (+)-catechin (p<0.05). Quercetin and isorhamnetin were the primary compounds responsible for the strong antioxidant activity in the EtOH extract of the viscozyme-treated hamcho cake. Meanwhile, these five phenolic compounds were detected in the EtOH extract of the viscozyme-treated hamcho cake at the following levels (dry base of hamcho); procatechuic acid (1.54 mg%), caffeic acid (6.87 mg%), ferulic acid (8.45 mg%), quercetin (12.63 mg%), and isorhamnetin (6.65 mg%). However, three of these phenolic compounds (procatechuic, caffeic acid, and ferulic acids) were detectable in the $H_2O$ extract of viscozyme-treated hamcho juice. These results suggest that the EtOH extract of viscozyme-treated hamcho cake may be a potential source of natural antioxidants.

Antimicrobial Activity of Extracts from Medicinal Herbs Against Escherichia coli (Escherichia coli에 대한 한약재의 항균활성)

  • Chang, Hyung-Soo;Choi, Il
    • The Korean Journal of Community Living Science
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    • v.18 no.2
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    • pp.293-300
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    • 2007
  • The antimicrobial activity of 10 different traditional medicinal herbs extracts against E. coli was determined using paper disc method. Caesalpinia sappan and Rhus javanica, extracts in 5 mg/ml, and Paeonia suffruticosa and Seutellaria baicalensis extracts in 10 mg/ml showed significant antimicrobial activity against E. coli. Minimum inhibitory concentrations of medicinal herbs extracts were in the range of $1.4{\sim}8mg/ml\;and\;1.2{\sim}12mg/ml$, for MeOH extracts and EtOH extracts, respectively. In addition, the antimicrobial activity of each solvent fraction was most significant with the EtOAc layer. Optical density at 620nm after 24 hours incubation of E. coli in the presence of 100, 300 or 500 ppm of Caesalpinia sappan extract ranged from 0.02 to 0.1 compared to 0.6 in the absence of Caesalpinia sappan extract, indicating that growth of E. coli was significantly inhibited within 24 hours by the addition of at least 300 ppm of Caesalpinia sappan extract. Optical density at 620 nm after 24 hours incubation of E. coli in the presence of 300 ppm of Rhus javanica extract ranged from 0.02 to 0.2 compared to 0.5 in the absence of Rhus javanica extract, indicating that growth of E. coli was also significantly inhibited within 24 hours by the addition of at least 500 ppm of Rhus javanica extract. In conclusion, these findings suggest that extracts from medicinal herbs may play important roles in antimicrobial activities against E. coli.

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The hydration resistance improvement of MgO ceramics by $TiO_2$ addition ($TiO_2$ 첨가에 의한 MgO 세라믹스의 표현 수화 저항성 향상)

  • Ryu, Su-Chak;Kim, Jin-Kon;Hyun Cho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.6
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    • pp.269-273
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    • 2001
  • The effect of $TiO_2$addition on the hydration reaction of MgO ceramics were studied after being heated at $1450^{\circ}C$. The pure MgO ceramics showed significant weight change after exposure to water due to the hydration reaction through the formation of $Mg(OH)_2$while $TiO_2$-added MgO ceramics did not. The $Mg_2TiO_4$phase were observed in the $TiO_2$-added MgO ceramics sintered at 145$0^{\circ}C$. Bulk density increased as the amount of $TiO_2$increased and the apparent porosity and water absorption decreased by $TiO_2$addition. The hydration resistance of MgO ceramics was found to be improved by $TiO_2$addition.

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Inhibitory Effect of DPPH Radical Scavenging Activity and Hydroxyl Radicals (OH) Activity of Hydrocotyle sibthorpioides Lamarck (피막이풀의 DPPH 라디칼과 hydroxyl radicals (OH) 항산화 활성 및 리폭시게나아제 저해 효과)

  • Cho, Kyung-Soon
    • Journal of Life Science
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    • v.26 no.9
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    • pp.1022-1026
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    • 2016
  • In this study the hot water extract was prepared from Hydrocotyle sibthorpioides (Araliaceae) leaves and stems to study antioxidant activities and lipoxygenase inhibition. The extract showed the protective hydroxyl radical (-OH) which can damage virtually all types of macromolecules: carbohydrates, nucleic acids (mutations), lipids (lipid peroxidation), and amino acids. Hydroxyl radical scavenging activity of H. sibthorpioides was 78.6%. The extract showed strong activity against 1, 1- diphenyl 2-picrylhyorazyl (DPPH) which is a well-known radical and a trap (scavenger) for other radicals. DPPH scavenging activity of leaves of H. sibthorpioides was evaluated at 8.0 mg/ml was 86.0%. Lipoxygenases (LOXs) constitute a heterogeneous family of lipid peroxidizing enzymes capable of oxygenating polyunsaturated fatty acids to their corresponding hydroperoxy derivatives. The inhibitory effect of 15-LOX by H. sibthorpioides was assayed using a Morgan microplate assay. The extract of H. sibthorpioides was 55.5% inhibitory effects on the inhibition of LOX at 8.0 mg/ml. The IC50 values for OH activity, DPPH activity, and LOX inhibition from leaves 5.23 mg/ml, 6.44 mg/ml, and 3.71 mg/ml, respectively. Antioxidative activity assay showed that the water extracts from leaf and stem had a strong reducing power. These results show that H. sibthorpioides has some phytochemical constituents which may be active against the free radicals (OH and DPPH) and lipoxygenase enzyme.

A Study on Synthesis of Ca and Mg Compounds from Dolomite with Salt Additional React (MgCl2·6H2O) (염 첨가 반응(MgCl2·6H2O)을 이용하여 백운석으로부터 Ca 화합물과 Mg 화합물 합성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan;Cho, Kye Hong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.399-409
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    • 2021
  • In order to utilize dolomite as a calcium/magnesium compound material, it was prepared highly reactive calcined dolomite(CaO·MgO) using a microwave kiln (950 ℃, 60 min). The experiment was performed according to the standard of the hydration test (ASTM C 110) and hydration reactivity was analyzed as medium reactivity (max 74.1 ℃, 5 min). Experiments were performed with calcined dolomite and salt (MgCl2·6H2O) (a) 1:1, (b) 1:1.5, and (c) 1:2 wt% based on the hydration reaction of calcined dolomite. The result of X-ray diffraction analysis confirmed that MgO of calcined dolomite increased to Mg(OH)2 as the salt addition ratio increased. After the separating reaction, calcium was stirred at 80 ℃, 24 hr that produced CaCl2 of white crystal. XRD results, it was confirmed calcium chloride hydrate (CaCl2·(H2O)x) and CaO of calcined dolomite and salt additional reaction was separated into CaCl2. And it was synthesized with Ca(OH)2 99 wt% by NaOH adding reaction to the CaCl2 solution, and the synthesized Ca(OH)2 was manufactured CaO through the heat treatment process. In order to prepare calcium carbonate, CaCO3 was synthesized by adding Na2CO3 to CaCl2 solution, and the shape was analyzed in cubic form with a purity of 99 wt%.

The Content of N-nitrosamine in Mollusk Crustacea and Shellfish (연체류, 갑각류 및 패류 중 N-Nitrosamine 함량)

  • Oh, Myung-Cheol;Oh, Chang-Kyung;Yang, Tai-Suk;Kim, Bong-Oh;Kim, Soo-Hyun;Oh, Hyuk-Soo
    • Culinary science and hospitality research
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    • v.11 no.4 s.27
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    • pp.1-13
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    • 2005
  • This study analyzed the levels of N-nitrosamine(NA) and its precursors such as nitrite, nitrate, dimethylamine and trimethylamine in 10 samples of mollusk fish, 4 samples of crustacea fish and 11 samples of shellfish from fish distributed in a local markets. Mollusk fishes had nitrite concentrations ranging from non-detectable(ND) to 9.4 mg/kg, crustacea fishes ND to 8.8 mg/kg, and shellfishes ND to 4.3 mg/kg. Nitrates in mollusk fishes ranged from ND to 19.3 mg/kg, crustacea fishes 4.1 to 79.9 mg/kg, and shellfishes 1.5 to 61.9 mg/kg. DMK concentrations were 11.2 to 551.4 mg/100g in mollusk fishes, 44.4 to 79.9 mg/100g in crustacea fishes, and 1.3 to 5.9 mg/100g in shellfishes. TMA concentrations in mollusk fishes, crustacea fishes, and shellfishes were 10.3${\sim}$292.4 mg/100g, 35.5${\sim}$90.3 mg/100g, and 2.3${\sim}$17.1 mg/100g respectively. Only N-nitrosodimethylamine (NDMA) was detected for NA in fish distributed in local markets. NDMA contentrations ranged from ND to 41.4 ${\mu}g/kg$ in mollusk fishes, 3.0 to 47.3 ${\mu}g/kg$ in crustacea fishes, and 1.7 to 12.1 ${\mu}g/kg$ in shellfishes.

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Utilization of Fly Ash as a Source of Mineral Fertilizers -IV. Development of Slowly Released K Fertilizer (Fly Ash 비료화(肥料化) 연구(硏究) -IV. Fly Ash를 이용(利用)한 지효성(遲效性) 가리(加里) 비료(肥料) 개발(開發))

  • Shin, Jae-Sung;Seong, Ki-Seog;Choi, Du-Hoi
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.1
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    • pp.10-14
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    • 1994
  • The slowly released potassium fertilizer was developed by mixing fly ash with KOH, anthracite coal powder, KCI, $K_2CO_3$ and $Mg(OH)_2$ as the substances for accelerating calcination. Measuring proper ratios of raw materials, we found that the anthracite coal powder was 12 percent and $Mg(OH)_2$ was two to three percent. The optimal calcination temperature and time were proved to be $850^{\circ}C$ and 30 minutes, respectively, however, the trial product with lower temperature and shorter time in calcination had low quality. The K solubility of the product was very low compared to that of the KCl fertilizer.

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